CN107879664A - A kind of artificial stone having high density sheet material and preparation method thereof - Google Patents

A kind of artificial stone having high density sheet material and preparation method thereof Download PDF

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Publication number
CN107879664A
CN107879664A CN201711143300.5A CN201711143300A CN107879664A CN 107879664 A CN107879664 A CN 107879664A CN 201711143300 A CN201711143300 A CN 201711143300A CN 107879664 A CN107879664 A CN 107879664A
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China
Prior art keywords
parts
powder
sheet material
high density
artificial stone
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CN201711143300.5A
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Chinese (zh)
Inventor
邵明洋
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Zaozhuang Boyuan Artificial Stone Co Ltd
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Zaozhuang Boyuan Artificial Stone Co Ltd
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Priority to CN201711143300.5A priority Critical patent/CN107879664A/en
Publication of CN107879664A publication Critical patent/CN107879664A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/045Polyalkenes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/82Coloured materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Floor Finish (AREA)

Abstract

The invention discloses a kind of artificial stone having high density sheet material, include the raw material of following parts by weight:30 50 parts of polyethylene, 15 20 parts of cement, 10 20 parts of abalone shell powder, 38 parts of carborundum, 46 parts of bamboo charcoal powder, 38 parts of magnesia, 25 parts of flyash, 35 parts of diatomite, 14 parts of sodium carbonate, 5 10 parts of powder of straw, 5 10 parts of acrylate, 25 parts of glass micro mist, 13 parts of aluminium powder, 13 parts of titanium dioxide, 25 parts of borax, 12 parts of sodium citrate.The artificial slabstone of the present invention has excellent property, its density is high, it is solid it is durable, surface is moist, using effect is preferable, the problems such as will not producing contractions in use, deform;Preparation method is simple, and raw material is easy to get, and is advantageous to industrialized production, and market popularization value is high.

Description

A kind of artificial stone having high density sheet material and preparation method thereof
Technical field
The present invention relates to artificial stone technical field, specifically a kind of artificial stone having high density sheet material and preparation method thereof.
Background technology
Artificial slabstone is made of non-natural mixture, and such as resin, cement, bead, aluminium stone flour add broken Stone binder.Artificial stone is a kind of new composite, is to be mixed with unsaturated polyester resin with filler, pigment, is added few Initiator is measured, through made of certain procedure.Be equipped with the fabrication process different colorants can be made into it is beautiful in colour, Gloss exactly likes the product of natural marble such as jade.Because it has non-toxic, "dead", anti-flammability, non-viscous oil, not permeable dirty, anti- Bacterium is mould proof, wear-resisting, impact resistance, easily maintains, splices the advantages that seamless, any moulding, just progressively as decoration material in the market New lover.At present, most of artificial slabstone materials are coarse, and consolidation is inadequate, and using effect is bad.Therefore, the present invention provides one Kind artificial stone having high density sheet material and preparation method thereof.
The content of the invention
It is an object of the invention to provide a kind of artificial stone having high density sheet material and preparation method thereof, to solve above-mentioned background skill The problem of being proposed in art.
To achieve the above object, the present invention provides following technical scheme:
A kind of artificial stone having high density sheet material, include the raw material of following parts by weight:Polyethylene 30-50 parts, cement 15-20 parts, Bao Fish shell powder 10-20 parts, carborundum 3-8 parts, bamboo charcoal powder 4-6 parts, magnesia 3-8 parts, flyash 2-5 parts, diatomite 3-5 parts, carbon Sour sodium 1-4 parts, powder of straw 5-10 parts, acrylate 5-10 parts, glass micro mist 2-5 parts, aluminium powder 1-3 parts, titanium dioxide 1-3 parts, Borax 2-5 parts, sodium citrate 1-2 parts.
As the further scheme of the present invention:Include the raw material of following parts by weight:44 parts of polyethylene, 17 parts of cement, Bao 13 parts of fish shell powder, 5 parts of carborundum, 5 parts of bamboo charcoal powder, 6 parts of magnesia, 4 parts of flyash, 4 parts of diatomite, 2 parts of sodium carbonate, powder of straw 7 parts, 7 parts of acrylate, 3 parts of glass micro mist, 2 parts of aluminium powder, 2 parts of titanium dioxide, 4 parts of borax, 1.6 parts of sodium citrate.
As the further scheme of the present invention:The titanium dioxide uses Nano titanium dioxide.
As the further scheme of the present invention:The borax sieving 200-400 mesh.
As the further scheme of the present invention:The abalone shell powder sieving 200-300 mesh.
A kind of preparation method of artificial stone having high density sheet material, comprises the following steps:(1)By cement, abalone shell powder, carbonization Silicon, flyash, magnesia, sodium carbonate are well mixed, and 1-2h is calcined at 300-500 DEG C, are cooled down after taking-up, are ground sieving 100- 200 mesh;(2)Upper step gains are mixed with polyethylene, diatomite, bamboo charcoal powder, powder of straw, acrylate and glass micro mist, 1-2h is mixed at 88-110 DEG C;(3)Aluminium powder, titanium dioxide, borax, sodium citrate are added and walked in gains, in 95- 10-30min is mixed at 105 DEG C;(4)It is compressing that upper step gains are transferred to vacuum press, heating makes it tentatively solid Change, then raise temperature and carry out solidify afterwards;(5)The demoulding, fixed thick, polishing, finished product.
As the further scheme of the present invention:Step(1)By cement, abalone shell powder, carborundum, flyash, magnesia, carbon Sour sodium is well mixed, and 1.6h is calcined at 425 DEG C, is cooled down after taking-up, is ground 160 mesh of sieving.
As the further scheme of the present invention:Step(2)By upper step gains and polyethylene, diatomite, bamboo charcoal powder, stalk Powder, acrylate and glass micro mist mixing, 1.6h is mixed at 95 DEG C.
As the further scheme of the present invention:Step(3)Aluminium powder, titanium dioxide, borax, sodium citrate are added and walk institute Obtain in thing, 20min is mixed at 100 DEG C.
Compared with prior art, the beneficial effects of the invention are as follows:
The artificial slabstone of the present invention has excellent property, its density is high, it is solid it is durable, surface is moist, using effect Preferably, the problems such as contraction, deformation will not be produced in use;Preparation method is simple, and raw material is easy to get, and is advantageous to industrialized production, Market popularization value is high.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of artificial stone having high density sheet material, include the raw material of following parts by weight:30 parts of polyethylene, 15 parts of cement, abalone shell powder 10 parts, 3 parts of carborundum, 4 parts of bamboo charcoal powder, 3 parts of magnesia, 2 parts of flyash, 3 parts of diatomite, 1 part of sodium carbonate, 5 parts of powder of straw, third 5 parts of olefin(e) acid ester, 2 parts of glass micro mist, 1 part of aluminium powder, 1 part of titanium dioxide, 2 parts of borax, 1 part of sodium citrate.The titanium dioxide is adopted Use Nano titanium dioxide.200 mesh of the borax sieving.200 mesh of the abalone shell powder sieving.
A kind of preparation method of artificial stone having high density sheet material, comprises the following steps:(1)By cement, abalone shell powder, carbonization Silicon, flyash, magnesia, sodium carbonate are well mixed, and 1h is calcined at 300 DEG C, are cooled down after taking-up, are ground 100 mesh of sieving;(2) Upper step gains are mixed with polyethylene, diatomite, bamboo charcoal powder, powder of straw, acrylate and glass micro mist, mixed at 88 DEG C Stir 1h;(3)Aluminium powder, titanium dioxide, borax, sodium citrate are added and walked in gains, is mixed at 95 DEG C 10min;(4)It is compressing that upper step gains are transferred to vacuum press, heating makes its primary solidification, then raises temperature and carries out Solidify afterwards;(5)The demoulding, fixed thick, polishing, finished product.
Embodiment 2
A kind of artificial stone having high density sheet material, include the raw material of following parts by weight:50 parts of polyethylene, 20 parts of cement, abalone shell powder 20 parts, 8 parts of carborundum, 6 parts of bamboo charcoal powder, 8 parts of magnesia, 5 parts of flyash, 5 parts of diatomite, 4 parts of sodium carbonate, 10 parts of powder of straw, 10 parts of acrylate, 5 parts of glass micro mist, 3 parts of aluminium powder, 3 parts of titanium dioxide, 5 parts of borax, 2 parts of sodium citrate.The titanium dioxide Using Nano titanium dioxide.400 mesh of the borax sieving.300 mesh of the abalone shell powder sieving.
A kind of preparation method of artificial stone having high density sheet material, comprises the following steps:(1)By cement, abalone shell powder, carbonization Silicon, flyash, magnesia, sodium carbonate are well mixed, and 2h is calcined at 500 DEG C, are cooled down after taking-up, are ground 200 mesh of sieving;(2) Upper step gains are mixed with polyethylene, diatomite, bamboo charcoal powder, powder of straw, acrylate and glass micro mist, mixed at 110 DEG C Close stirring 2h;(3)Aluminium powder, titanium dioxide, borax, sodium citrate are added and walked in gains, is mixed at 105 DEG C 30min;(4)It is compressing that upper step gains are transferred to vacuum press, heating makes its primary solidification, then raises temperature and carries out Solidify afterwards;(5)The demoulding, fixed thick, polishing, finished product.
Embodiment 3
A kind of artificial stone having high density sheet material, include the raw material of following parts by weight:44 parts of polyethylene, 17 parts of cement, abalone shell powder 13 parts, 5 parts of carborundum, 5 parts of bamboo charcoal powder, 6 parts of magnesia, 4 parts of flyash, 4 parts of diatomite, 2 parts of sodium carbonate, 7 parts of powder of straw, third 7 parts of olefin(e) acid ester, 3 parts of glass micro mist, 2 parts of aluminium powder, 2 parts of titanium dioxide, 4 parts of borax, 1.6 parts of sodium citrate.The titanium dioxide Using Nano titanium dioxide.300 mesh of the borax sieving.250 mesh of the abalone shell powder sieving.
A kind of preparation method of artificial stone having high density sheet material, comprises the following steps:(1)By cement, abalone shell powder, carbonization Silicon, flyash, magnesia, sodium carbonate are well mixed, and 1.6h is calcined at 425 DEG C, are cooled down after taking-up, are ground 160 mesh of sieving. (2)Upper step gains are mixed with polyethylene, diatomite, bamboo charcoal powder, powder of straw, acrylate and glass micro mist, at 95 DEG C Mix 1.6h.(3)Aluminium powder, titanium dioxide, borax, sodium citrate are added and walked in gains, mixes and stirs at 100 DEG C Mix 20min.(4)It is compressing that upper step gains are transferred to vacuum press, heating makes its primary solidification, then raises temperature and enters Row solidify afterwards;(5)The demoulding, fixed thick, polishing, finished product.
Embodiment 4
A kind of artificial stone having high density sheet material, include the raw material of following parts by weight:33 parts of polyethylene, 18 parts of cement, abalone shell powder 12 parts, 7 parts of carborundum, 4.5 parts of bamboo charcoal powder, 7.6 parts of magnesia, 2.5 parts of flyash, 4.5 parts of diatomite, 1.8 parts of sodium carbonate, straw 9 parts of stalk powder, 6.6 parts of acrylate, 4.2 parts of glass micro mist, 1.8 parts of aluminium powder, 2.6 parts of titanium dioxide, 2.7 parts of borax, citric acid 1.7 parts of sodium.The titanium dioxide uses Nano titanium dioxide.220 mesh of the borax sieving.The abalone shell powder sieving 220 Mesh.
A kind of preparation method of artificial stone having high density sheet material, comprises the following steps:(1)By cement, abalone shell powder, carbonization Silicon, flyash, magnesia, sodium carbonate are well mixed, and 1.8h is calcined at 375 DEG C, are cooled down after taking-up, are ground 120 mesh of sieving; (2)Upper step gains are mixed with polyethylene, diatomite, bamboo charcoal powder, powder of straw, acrylate and glass micro mist, at 108 DEG C Mix 1.2h;(3)Aluminium powder, titanium dioxide, borax, sodium citrate are added and walked in gains, mixes and stirs at 102 DEG C Mix 14min;(4)It is compressing that upper step gains are transferred to vacuum press, heating makes its primary solidification, then raises temperature and enters Row solidify afterwards;(5)The demoulding, fixed thick, polishing, finished product.
Embodiment 5
A kind of artificial stone having high density sheet material, include the raw material of following parts by weight:44 parts of polyethylene, 16 parts of cement, abalone shell powder 18 parts, 4 parts of carborundum, 5.5 parts of bamboo charcoal powder, 3.8 parts of magnesia, 4.6 parts of flyash, 3.2 parts of diatomite, 3.5 parts of sodium carbonate, straw 6 parts of stalk powder, 9 parts of acrylate, 2.3 parts of glass micro mist, 2.3 parts of aluminium powder, 1.6 parts of titanium dioxide, 4.5 parts of borax, sodium citrate 1.2 part.The titanium dioxide uses Nano titanium dioxide.350 mesh of the borax sieving.280 mesh of the abalone shell powder sieving.
A kind of preparation method of artificial stone having high density sheet material, comprises the following steps:(1)By cement, abalone shell powder, carbonization Silicon, flyash, magnesia, sodium carbonate are well mixed, and 1.2h is calcined at 480 DEG C, are cooled down after taking-up, are ground 180 mesh of sieving; (2)Upper step gains are mixed with polyethylene, diatomite, bamboo charcoal powder, powder of straw, acrylate and glass micro mist, at 90 DEG C Mix 1.8h;(3)Aluminium powder, titanium dioxide, borax, sodium citrate are added and walked in gains, mixes and stirs at 98 DEG C Mix 26min;(4)It is compressing that upper step gains are transferred to vacuum press, heating makes its primary solidification, then raises temperature and enters Row solidify afterwards;(5)The demoulding, fixed thick, polishing, finished product.
The artificial slabstone of the present invention has excellent property, its density is high, it is solid it is durable, surface is moist, use Effect is preferable, the problems such as will not producing contraction in use, deform;Preparation method is simple, and raw material is easy to get, and is advantageous to industrial metaplasia Production, market popularization value are high.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, can also be on the premise of this patent objective not be departed from one skilled in the relevant art's possessed knowledge Make a variety of changes.

Claims (9)

1. a kind of artificial stone having high density sheet material, it is characterised in that include the raw material of following parts by weight:Polyethylene 30-50 parts, water Mud 15-20 parts, abalone shell powder 10-20 parts, carborundum 3-8 parts, bamboo charcoal powder 4-6 parts, magnesia 3-8 parts, flyash 2-5 parts, silicon Diatomaceous earth 3-5 parts, sodium carbonate 1-4 parts, powder of straw 5-10 parts, acrylate 5-10 parts, glass micro mist 2-5 parts, aluminium powder 1-3 parts, two Titanium oxide 1-3 parts, borax 2-5 parts, sodium citrate 1-2 parts.
2. artificial stone having high density sheet material according to claim 1, it is characterised in that include the raw material of following parts by weight: 44 parts of polyethylene, 17 parts of cement, 13 parts of abalone shell powder, 5 parts of carborundum, 5 parts of bamboo charcoal powder, 6 parts of magnesia, 4 parts of flyash, diatom 4 parts of soil, 2 parts of sodium carbonate, 7 parts of powder of straw, 7 parts of acrylate, 3 parts of glass micro mist, 2 parts of aluminium powder, 2 parts of titanium dioxide, borax 4 Part, 1.6 parts of sodium citrate.
3. artificial stone having high density sheet material according to claim 1, it is characterised in that the titanium dioxide uses nanoscale two Titanium oxide.
4. artificial stone having high density sheet material according to claim 1, it is characterised in that the borax sieving 200-400 mesh.
5. artificial stone having high density sheet material according to claim 1, it is characterised in that the abalone shell powder sieving 200-300 Mesh.
A kind of 6. preparation method of artificial stone having high density sheet material as described in claim 1-5 is any, it is characterised in that including with Lower step:(1)Cement, abalone shell powder, carborundum, flyash, magnesia, sodium carbonate are well mixed, forged at 300-500 DEG C 1-2h is burnt, cooled down after taking-up, grind sieving 100-200 mesh;(2)By upper step gains and polyethylene, diatomite, bamboo charcoal powder, straw Stalk powder, acrylate and glass micro mist mixing, 1-2h is mixed at 88-110 DEG C;(3)By aluminium powder, titanium dioxide, borax, Sodium citrate is added and walked in gains, and 10-30min is mixed at 95-105 DEG C;(4)Upper step gains are transferred to very Air compressor machine is compressing, and heating makes its primary solidification, then raises temperature and carries out solidify afterwards;(5)The demoulding, fixed thick, polishing, are made Finished product.
7. the preparation method of artificial stone having high density sheet material according to claim 6, it is characterised in that step(1)By cement, Abalone shell powder, carborundum, flyash, magnesia, sodium carbonate are well mixed, and 1.6h is calcined at 425 DEG C, cools down, grind after taking-up 160 mesh of honed sieve.
8. the preparation method of artificial stone having high density sheet material according to claim 6, it is characterised in that step(2)By upper step Gains mix with polyethylene, diatomite, bamboo charcoal powder, powder of straw, acrylate and glass micro mist, are mixed at 95 DEG C 1.6h。
9. the preparation method of artificial stone having high density sheet material according to claim 6, it is characterised in that step(3)By aluminium powder, Titanium dioxide, borax, sodium citrate are added and walked in gains, and 20min is mixed at 100 DEG C.
CN201711143300.5A 2017-11-17 2017-11-17 A kind of artificial stone having high density sheet material and preparation method thereof Pending CN107879664A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735407A (en) * 2009-12-17 2010-06-16 江苏大力士投资有限公司 Method for preparing manmade stone unsaturated resin
CN102922814A (en) * 2012-11-22 2013-02-13 昆山市大金机械设备厂 Artificial pattern slate and preparation method thereof
CN104446141A (en) * 2014-10-29 2015-03-25 佛山市高明区明城镇新能源新材料产业技术创新中心 Artificial stone and manufacturing method thereof
CN104478292A (en) * 2014-12-15 2015-04-01 田忠和 Artificial quartz stone sheet and preparation method thereof
CN104496282A (en) * 2014-11-27 2015-04-08 佛山市高明区明城镇新能源新材料产业技术创新中心 Artificial stone and production method thereof
CN104556823A (en) * 2015-01-12 2015-04-29 卓培琨 Energy-saving high-performance artificial stone and preparation method thereof
CN106467373A (en) * 2015-08-20 2017-03-01 沈阳创达技术交易市场有限公司 A kind of artificial stone having high density sheet material

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735407A (en) * 2009-12-17 2010-06-16 江苏大力士投资有限公司 Method for preparing manmade stone unsaturated resin
CN102922814A (en) * 2012-11-22 2013-02-13 昆山市大金机械设备厂 Artificial pattern slate and preparation method thereof
CN104446141A (en) * 2014-10-29 2015-03-25 佛山市高明区明城镇新能源新材料产业技术创新中心 Artificial stone and manufacturing method thereof
CN104496282A (en) * 2014-11-27 2015-04-08 佛山市高明区明城镇新能源新材料产业技术创新中心 Artificial stone and production method thereof
CN104478292A (en) * 2014-12-15 2015-04-01 田忠和 Artificial quartz stone sheet and preparation method thereof
CN104556823A (en) * 2015-01-12 2015-04-29 卓培琨 Energy-saving high-performance artificial stone and preparation method thereof
CN106467373A (en) * 2015-08-20 2017-03-01 沈阳创达技术交易市场有限公司 A kind of artificial stone having high density sheet material

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