CN107869053A - A kind of preparation method of the temperature-sensitive formative memory bafta based on N N-isopropylacrylamides - Google Patents
A kind of preparation method of the temperature-sensitive formative memory bafta based on N N-isopropylacrylamides Download PDFInfo
- Publication number
- CN107869053A CN107869053A CN201711184574.9A CN201711184574A CN107869053A CN 107869053 A CN107869053 A CN 107869053A CN 201711184574 A CN201711184574 A CN 201711184574A CN 107869053 A CN107869053 A CN 107869053A
- Authority
- CN
- China
- Prior art keywords
- bafta
- temperature
- sensitive
- solution
- nipa
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
- D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2400/00—Specific information on the treatment or the process itself not provided in D06M23/00-D06M23/18
- D06M2400/01—Creating covalent bondings between the treating agent and the fibre
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of preparation method of the temperature-sensitive formative memory bafta based on N N-isopropylacrylamides, including：Bafta is immersed in solution and stirred, is roughened, washing, the bafta after being roughened；Immerse in band mercaptosilane coupling agents solution, solidification, obtain sulfhydryl modified bafta；Immerse in N N-isopropylacrylamide solution, add light trigger, ultra-violet curing, obtain temperature-sensitive formative memory bafta.The bafta that the present invention obtains has thermo-responsive formative memory function, has heated curling as a kind of intelligent textile, cool the characteristic replied, rolled efficiency is obvious, also certain wash durability, and a kind of new method is provided for research fabric temperature-sensitive formative memory function.
Description
Technical field
It is more particularly to a kind of to be based on N- isopropyls third the invention belongs to the preparing technical field of thermo-responsive formative memory fabric
The preparation method of the temperature-sensitive formative memory bafta of acrylamide.
Background technology
Shape-memory polymer, also known as shape memory high molecule, the product for referring to have original shape is in certain bar
After changing its primary condition under part and fixing, by external condition, such as heat, the stimulation of electricity, light, chemical co-ordination, it can recover again
The high polymer material of its original shape, compared to other shapes memory material, shape-memory polymer has light weight, anticorrosive,
The advantages that easy processing.
Thermally sensitive polymeric is a kind of high polymer material that predetermined response change of ambient temperature can occur, and works as ambient temperature
During change, polymer can also change accordingly.Traditional heat sensitive shape memory fiber mainly includes two major classes：Shape memory
Alloy textile and shape memory polyurethane textile.
Most start marmem being applied to textile process, be by the less Nitinol silk blend of string diameter to weaving
In fabric.There is two kinds of high-temperature-phase austenite phase and low-temperature phase martensitic phase in marmem.The institute of marmem
With deformation-recovery ability, to be because the thermoelastic martensitic transformation that material internal occurs in deformation process.Shape memory is imitated
It should can be divided into one-way memory effect, double-pass memory effect and whole memory effect three major types.Shape memory at a lower temperature
Alloy deformation, the shape after heating before recoverable deformation are this to only have shape-memory phenomena present in heating process to be referred to as list
Journey memory effect；Recover high-temperature-phase shape during the heating of some alloys, and can recovers low-temperature phase shape during cooling, and referred to as round trip is remembered
Effect；Recover high-temperature-phase shape during heating, it is identical and be orientated opposite low-temperature phase shape to be changed into shape during cooling, is referred to as whole note
Recall effect.Marmem has excellent shape-memory properties, but often its hardness is high, elasticity is big, cohesive force is low, cost
Height, these factors cause marmem limited in field of textiles application.
Shape memory polyurethane textile has that machine-shaping is easy, applied widely, shape compared to marmem
The advantages that variable is big and light inexpensive.Polyurethane is to pass through progressively polyaddition reaction by polyisocyanates and polyol
Prepared by polyurethanes.The linear block polymer that most of polyurethane are made up of soft segment and hard section, wherein firmly
Hard section microfacies area is formed by hydrogen bond between section, is distributed in soft segment matrix, forms a kind of physical crosslinking points.The property of polyurethane
It can be varied from the kind of soft segment and hard section, the difference with when molecular weight, and not all polyurethane material
All there are shape-memory properties.The soft segment of shape memory polyurethane is the reversible of shape can be reversibly changed with the change of temperature
Phase, hard section are then that the stationary phase of solid shape is kept in shape recovery process.The mechanism of action of shape memory polyurethane can be managed
Xie Wei：When temperature is increased to more than hard section glass transition temperature, shaping is processed to material, be cooled to soft segment glass transition temperature with
Lower formation initial configuration；When temperature is increased to more than the glass transition temperature of soft segment, soft segment glass is cooled in the presence of external force
Change temperature deformation states formed below；Again when temperature is increased to more than the glass transition temperature of soft segment, stress release, deformation recover to
Initial configuration.The Shape memory behavior of shape memory polyurethane is substantially the motion of flexible molecule chain in soft segment, and it is to temperature
Dependence depends on the glass transition temperature of soft segment；And the recovery rate and resume speed of shape memory are then decided by hard section region
Stability.At present there are diversified forms in the shape memory polyurethane applied to field of textiles, including fiber, yarn, knit
Thing, finishing agent etc..Shape memory polyurethane fiber both can pure spinning or prepared with other natural, synthetic fibers blending a variety of have
The fabric of shape memory function.The initial configuration of shape memory fiber can be designed to linear, ripple according to different use demands
Shape wave, spiral shape or other shapes.Except the fabric formed by shape memory polyurethane fiber weaving, most of fabric is by making
The mode for being laminated or being arranged with shape memory polyurethane obtains shape memory function.Utilize setting for shape memory polyurethane temperature
Meter property, can be that human body wears uncomfortable temperature by the memory triggering temperature design of polyurethane, so as to obtain with thermal insulating and water-proof moisture-inhibiting
The fabric of function.When environment temperature is less than triggering temperature, the arrangement of polyurethane macromolecular segment is close, prevents the transmission of heat,
Fabric has warmth retention property；When temperature is higher than triggering temperature, polymer segment thaws, and the increase of its gap, makes fabric at high temperature
With breathable moisture permeability, and the space of its coating is less than the diameter of hydrone, has water proofing property concurrently.
Temperature-sensitive formative memory fabric plays in fields such as biomedical, weaving dress ornament, toy, packaging, defence and militaries focuses on
The effect wanted.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of temperature-sensitive formative memory based on NIPA
The preparation method of bafta, sulfydryl is grafted to fiber using the hydroxyl reaction with mercaptosilane coupling agents and surface of cotton fabric
On, being reacted using the double bond on sulfydryl and NIPA makes NIPA be grafted to fabric table
Face, fabric is set to obtain temperature-sensitive formative memory function.
A kind of preparation method of temperature-sensitive formative memory bafta based on NIPA of the present invention, including：
(1) bafta is immersed in solution and stirred, is roughened, washing, the bafta after being roughened；
(2) bafta after the roughening for obtaining step (1) is immersed in band mercaptosilane coupling agents solution, solidification, is obtained
Sulfhydryl modified bafta；Concentration wherein with mercaptosilane coupling agents solution is 5~10wt%；
(3) the sulfhydryl modified bafta for obtaining step (2) is immersed in NIPA solution, is added light-initiated
Agent, ultra-violet curing, obtain temperature-sensitive formative memory bafta；Wherein NIPA, the amount ratio of light trigger are 10
~20：1.
Bafta in the step (1) is pure cotton yarn fabric or cotton fiber blended fabric.
Solution in the step (1) is sodium hydroxide and the mixed solution of paregal O, naoh concentration is 15~
20g/L, paregal O concentration are 7~10g/L；The bath raio of bafta and solution is 1：40~50.
The technological parameter of roughening is in the step (1)：Coarsening Temperature is 60~70 DEG C, and coarsening time is 15~20min.
Band mercaptosilane coupling agents solution in the step (2) is by that will add volume ratio with mercaptosilane coupling agents
4~5：The in the mixed solvent of 1 second alcohol and water, with second acid for adjusting pH value to 2~5, the then stirring reaction 25 at 20~30 DEG C
~30min is made；Wherein, the bafta after roughening and the bath raio with mercaptosilane coupling agents solution are 1：40~50.
Band mercaptosilane coupling agents in the step (2) are 3- Mercaptopropyltriethoxysilanes.
The time immersed in the step (2) is 1~3min.
The technological parameter of solidification is in the step (2)：Solidification temperature is 100~140 DEG C, and hardening time is 3~5min.
The bath raio of sulfhydryl modified bafta and NIPA solution in the step (3) is 1：40~50.
Light trigger in the step (3) is 2,2- hydroxymethyl propionic acids.
The process conditions of ultra-violet curing are in the step (3)：Using 500W uviol lamp cold light sources, lamp away from 10~15cm,
2~2.5h of illumination.
Beneficial effect
(1) present invention can be shown using the ethyoxyl of silane coupler one end by condensation reaction and cotton-textile fibres
Hydroxyl reaction forms grafting, Modification of Cotton Fabric is carried sulfydryl, can be with the NIPA with heat shrinkable characteristic
On double bond carry out click chemistry reaction, be successfully grafted, obtain the bafta with temperature-sensitive formative memory characteristic.
(2) present invention makes bafta obtain temperature-sensitive formative memory function using chemical method, has heated curling, cools back
Multiple characteristic, rolled efficiency is obvious, also certain wash durability, and one is provided for research fabric temperature-sensitive formative memory function
The new method of kind.
Brief description of the drawings
Fig. 1 is the reaction mechanism schematic diagram of the invention with mercaptosilane coupling agents modified cotton fabric；
Fig. 2 is the reaction mechanism schematic diagram of NIPA of the present invention and sulfhydryl modified bafta；
Fig. 3 is the obtained temperature-sensitive formative memory bafta of the embodiment of the present invention 1 and raw cotton fabric at different temperatures grand
See form contrast picture；Wherein A is temperature-sensitive formative memory bafta (right side) and form of the raw cotton fabric (left side) at 25 DEG C；B is heat
Quick formative memory bafta (right side) is being warming up to 70 DEG C of form with raw cotton fabric (left side)；C is temperature-sensitive formative memory bafta
(right side) is cooled to 25 DEG C of form with raw cotton fabric (left side) again.
Fig. 4 is the washing times and maximum bend angle for the temperature-sensitive formative memory bafta that the embodiment of the present invention 1~3 obtains
Relation curve comparison diagram.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention.In addition, it is to be understood that after the content of the invention lectured has been read, people in the art
Member can make various changes or modifications to the present invention, and these equivalent form of values equally fall within the application appended claims and limited
Scope.
Embodiment 1
(1) mixed solution of sodium hydroxide and paregal O, naoh concentration 15g/L are prepared, paregal O concentration is
7g/L；Bafta is immersed in above-mentioned mixed solution at 70 DEG C and stirs 20min and is roughened, bath raio 1：50, then use deionization
Water cleans, the bafta after being roughened.
(2) 3- Mercaptopropyltriethoxysilanes are added into volume ratio 4：The in the mixed solvent of 1 second alcohol and water, uses acetic acid
PH value is adjusted to 3.5, then stirring reaction 30min obtains 5wt% 3- Mercaptopropyltriethoxysilane solution at 25 DEG C；
Bafta after the roughening that step (1) is obtained immerses 1min in above-mentioned 3- Mercaptopropyltriethoxysilanes solution, bath raio 1：
50, solidify 3min at 120 DEG C, obtain sulfhydryl modified bafta.
(3) 10wt%N- N-isopropylacrylamide solution is prepared；On the sulfhydryl modified bafta that step (2) is obtained immerses
State in NIPA solution, bath raio 1：50, light trigger 2,2- hydroxymethyl propionic acids are added, dosage is the aqueous solution
0.5wt%, ultra-violet curing, using 500W uviol lamp cold light sources, lamp obtains temperature-sensitive formative memory bafta away from 10cm, illumination 2h.
The temperature-sensitive formative memory fabric by heat curling situation that the present embodiment obtains is as shown in figure 3, wherein A remembers for temperature-sensitive form
Recall bafta (right side) and form of the raw cotton fabric (left side) at 25 DEG C；B is temperature-sensitive formative memory bafta (right side) and raw cotton fabric
(left side) is being warming up to 70 DEG C of form；C is that temperature-sensitive formative memory bafta (right side) is cooled to 25 DEG C again with raw cotton fabric (left side)
Form, it is known that obtained bafta has temperature-sensitive formative memory characteristic, and can cool reply after heated curling.
Embodiment 2
(1) mixed solution of sodium hydroxide and paregal O, naoh concentration 15g/L are prepared, paregal O concentration is
7g/L；Bafta is immersed in above-mentioned mixed solution at 70 DEG C and stirs 20min and is roughened, bath raio 1：50, then use deionization
Water cleans, the bafta after being roughened.
(2) 3- Mercaptopropyltriethoxysilanes are added into volume ratio 4：The in the mixed solvent of 1 second alcohol and water, uses acetic acid
PH value is adjusted to 3.5, then stirring reaction 30min obtains 5wt% 3- Mercaptopropyltriethoxysilane solution at 25 DEG C；
Bafta after the roughening that step (1) is obtained immerses 1min in above-mentioned 3- Mercaptopropyltriethoxysilanes solution, bath raio 1：
50, solidify 3min at 120 DEG C, obtain sulfhydryl modified bafta.
(3) 5wt%N- N-isopropylacrylamide solution is prepared；On the sulfhydryl modified bafta that step (2) is obtained immerses
State in NIPA solution, bath raio 1：50, light trigger 2,2- hydroxymethyl propionic acids are added, dosage is the aqueous solution
0.5wt%, ultra-violet curing, using 500W uviol lamp cold light sources, lamp obtains temperature-sensitive formative memory bafta away from 10cm, illumination 2h,
Can cool reply after heated curling.
Embodiment 3
(1) mixed solution of sodium hydroxide and paregal O, naoh concentration 15g/L are prepared, paregal O concentration is
7g/L；Bafta is immersed in above-mentioned mixed solution at 70 DEG C and stirs 20min and is roughened, bath raio 1：50, then use deionization
Water cleans, the bafta after being roughened.
(2) 3- Mercaptopropyltriethoxysilanes are added into volume ratio 4：The in the mixed solvent of 1 second alcohol and water, uses acetic acid
PH value is adjusted to 3.5, then stirring reaction 30min obtains 5wt% 3- Mercaptopropyltriethoxysilane solution at 25 DEG C；
Bafta after the roughening that step (1) is obtained immerses 1min in above-mentioned 3- Mercaptopropyltriethoxysilanes solution, bath raio 1：
50, solidify 3min at 120 DEG C, obtain sulfhydryl modified bafta.
(3) 5wt%N- N-isopropylacrylamide solution is prepared；On the sulfhydryl modified bafta that step (2) is obtained immerses
State in NIPA solution, bath raio 1：10, light trigger 2,2- hydroxymethyl propionic acids are added, dosage is the aqueous solution
0.5wt%, ultra-violet curing, using 500W uviol lamp cold light sources, lamp obtains temperature-sensitive formative memory bafta away from 10cm, illumination 2h,
Can cool reply after heated curling.
1~3 pair of NIPA concentration of embodiment is probed into dosage, its angle of bend and washing times
Relation curve is as shown in Figure 4, it is known that and the gained fabric of embodiment 1~3 is by 5~30 washings, still with certain rolled efficiency,
Prove gained fabric wash durability；In addition, understand that the rolled efficiency of the gained fabric of embodiment 1 is substantially better than the institute of embodiment 2,3
Fabric is obtained, the concentration and dosage for also demonstrating that NIPA can influence fabric by heat rolled efficiency.
Claims (10)
1. a kind of preparation method of the temperature-sensitive formative memory bafta based on NIPA, including：
(1) bafta is immersed in solution and stirred, is roughened, washing, the bafta after being roughened；
(2) bafta after the roughening for obtaining step (1) is immersed in band mercaptosilane coupling agents solution, solidification, obtains sulfydryl
Modified cotton fabric；Concentration wherein with mercaptosilane coupling agents solution is 5~10wt%；
(3) the sulfhydryl modified bafta for obtaining step (2) is immersed in NIPA solution, adds light trigger,
Ultra-violet curing, obtain temperature-sensitive formative memory bafta；Wherein the amount ratio of NIPA, light trigger for 10~
20：1.
A kind of 2. preparation side of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：Bafta in the step (1) is pure cotton yarn fabric or cotton fiber blended fabric.
A kind of 3. preparation side of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：Solution in the step (1) is sodium hydroxide and the mixed solution of paregal O, and naoh concentration is
15~20g/L, paregal O concentration are 7~10g/L；The bath raio of bafta and solution is 1：40~50.
A kind of 4. preparation side of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：The technological parameter of roughening is in the step (1)：Coarsening Temperature be 60~70 DEG C, coarsening time be 15~
20min。
A kind of 5. preparation side of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：Band mercaptosilane coupling agents solution in the step (2) is by will be added with mercaptosilane coupling agents
Volume ratio 4~5：The in the mixed solvent of 1 second alcohol and water, with second acid for adjusting pH value to 2~5, then stirred at 20~30 DEG C
25~30min of reaction is made；Wherein, the bafta after roughening and the bath raio with mercaptosilane coupling agents solution are 1：40~50.
A kind of 6. preparation side of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：Band mercaptosilane coupling agents in the step (2) are 3- Mercaptopropyltriethoxysilanes.
A kind of 7. preparation side of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：The time immersed in the step (2) is 1~3min；The technological parameter of solidification is：Solidification temperature is 100
~140 DEG C, hardening time is 3~5min.
A kind of 8. preparation side of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：The bath raio of sulfhydryl modified bafta and NIPA solution in the step (3) is 1：40
~50.
A kind of 9. preparation side of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：Light trigger in the step (3) is 2,2- hydroxymethyl propionic acids.
A kind of 10. preparation of temperature-sensitive formative memory bafta based on NIPA according to claim 1
Method, it is characterised in that：The process conditions of ultra-violet curing are in the step (3)：Using 500W uviol lamp cold light sources, lamp is away from 10
~15cm, 2~2.5h of illumination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711184574.9A CN107869053A (en) | 2017-11-23 | 2017-11-23 | A kind of preparation method of the temperature-sensitive formative memory bafta based on N N-isopropylacrylamides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711184574.9A CN107869053A (en) | 2017-11-23 | 2017-11-23 | A kind of preparation method of the temperature-sensitive formative memory bafta based on N N-isopropylacrylamides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107869053A true CN107869053A (en) | 2018-04-03 |
Family
ID=61754687
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711184574.9A Pending CN107869053A (en) | 2017-11-23 | 2017-11-23 | A kind of preparation method of the temperature-sensitive formative memory bafta based on N N-isopropylacrylamides |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107869053A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110080000A (en) * | 2019-05-27 | 2019-08-02 | 江苏阳光股份有限公司 | A kind of high conformal wool worsted clothes preparation method of spray decontamination |
| WO2023225739A1 (en) * | 2022-05-26 | 2023-11-30 | Lululemon Athletica Canada Inc. | Responsive fabric and method of manufacturing of responsive fabric |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637960A (en) * | 2016-12-30 | 2017-05-10 | 东华大学 | Durable flame-retardant finish method for cotton fabric based on ultraviolet light curing reaction |
| CN107299529A (en) * | 2017-06-02 | 2017-10-27 | 东华大学 | A kind of bafta durability anti-crease finishing method based on click chemistry |
-
2017
- 2017-11-23 CN CN201711184574.9A patent/CN107869053A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637960A (en) * | 2016-12-30 | 2017-05-10 | 东华大学 | Durable flame-retardant finish method for cotton fabric based on ultraviolet light curing reaction |
| CN107299529A (en) * | 2017-06-02 | 2017-10-27 | 东华大学 | A kind of bafta durability anti-crease finishing method based on click chemistry |
Non-Patent Citations (2)
| Title |
|---|
| CAROLINE I. BIGGS ET AL.: ""Grafting to" of RAFTed Responsive Polymers to Glass Substrates by Thiol-Ene and Critical Comparison to Thiol-Gold Coupling", 《ACS》 * |
| 孙晋良主编: "《纤维新材料》", 31 August 2007, 上海大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110080000A (en) * | 2019-05-27 | 2019-08-02 | 江苏阳光股份有限公司 | A kind of high conformal wool worsted clothes preparation method of spray decontamination |
| CN110080000B (en) * | 2019-05-27 | 2022-05-06 | 江苏阳光集团有限公司 | Preparation method of spray decontamination high-shape-retention worsted clothes |
| WO2023225739A1 (en) * | 2022-05-26 | 2023-11-30 | Lululemon Athletica Canada Inc. | Responsive fabric and method of manufacturing of responsive fabric |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0367039B1 (en) | Shape memory fibrous sheet and method of imparting shape memory property to fibrous sheet product | |
| Hu et al. | A review of stimuli-responsive polymers for smart textile applications | |
| CN107869053A (en) | A kind of preparation method of the temperature-sensitive formative memory bafta based on N N-isopropylacrylamides | |
| CN101033286A (en) | Shape memory polyurethane yarn and fabric | |
| CN103174016A (en) | Compound finishing agent and preparation method thereof | |
| WO2017002682A1 (en) | Single fibre including thermally responsive liquid-crystal elastomer, filament yarn, and fibre product | |
| CN103233291B (en) | Preparation method of moisture-absorption polyacrylonitrile fiber | |
| CN105556026A (en) | Cross-linked acrylate fiber and fiber structure containing same | |
| CN103980483A (en) | Moisture-absorption and sweat-releasing finishing agent for chinlon, and preparation method thereof | |
| CN102199803A (en) | High elastic non-ironing cellulose fiber and preparation method thereof | |
| CN201545991U (en) | Shape memory polyurethane lapping yarn | |
| CN101481872A (en) | Heat storing heat preserving finishing method | |
| CN105908279B (en) | A kind of gloss converts reversible fiber and preparation method thereof | |
| CN102505490A (en) | Preparation method of anti-fuzzing and anti-pilling polyurethane finishing agents | |
| CN103132330B (en) | Textile having shape memory interpenetrating polymer network | |
| Islam et al. | Advanced textile engineering materials | |
| CN108486882A (en) | A kind of preparation method of antibacterial crease-resistant Silk Finishing agent | |
| CN104294472A (en) | Production process of warm knitted underwear real silk fabric | |
| Stylios | Engineering textile and clothing aesthetics using shape changing materials | |
| CN105078652A (en) | Intelligent compression system based on shape memory material | |
| CN112064165A (en) | Antistatic textile fabric and preparation method thereof | |
| CN103044630B (en) | Preparation method of acrylic acid modified low-temperature crosslinked non-ironing resin | |
| CN113235318A (en) | Preparation process of warm-keeping flame-retardant fabric | |
| CN110528211A (en) | A kind of preparation method of cashmere imitating with wool fabric | |
| CN102409494A (en) | Method for removing fine creases through hot water padding |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180403 |