CN107868501A - A kind of coating for the protection of liquid gasification tank - Google Patents
A kind of coating for the protection of liquid gasification tank Download PDFInfo
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- CN107868501A CN107868501A CN201711317912.1A CN201711317912A CN107868501A CN 107868501 A CN107868501 A CN 107868501A CN 201711317912 A CN201711317912 A CN 201711317912A CN 107868501 A CN107868501 A CN 107868501A
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- Prior art keywords
- parts
- coating
- protection
- liquid gasification
- gasification tank
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- 238000000576 coating method Methods 0.000 title claims abstract description 31
- 239000011248 coating agent Substances 0.000 title claims abstract description 29
- 238000002309 gasification Methods 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 title claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 44
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 14
- 150000003505 terpenes Chemical class 0.000 claims abstract description 10
- 235000007586 terpenes Nutrition 0.000 claims abstract description 10
- AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 claims abstract description 10
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 9
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000001206 Amorphophallus rivieri Nutrition 0.000 claims abstract description 9
- 229920002581 Glucomannan Polymers 0.000 claims abstract description 9
- 229920002752 Konjac Polymers 0.000 claims abstract description 9
- 239000000252 konjac Substances 0.000 claims abstract description 9
- 235000010485 konjac Nutrition 0.000 claims abstract description 9
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 9
- 239000001923 methylcellulose Substances 0.000 claims abstract description 9
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 9
- 239000005011 phenolic resin Substances 0.000 claims abstract description 9
- 235000011187 glycerol Nutrition 0.000 claims abstract description 8
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims abstract description 5
- 229940046240 glucomannan Drugs 0.000 claims abstract description 5
- 241001312219 Amorphophallus konjac Species 0.000 claims abstract 3
- 238000012545 processing Methods 0.000 claims description 36
- 239000010445 mica Substances 0.000 claims description 32
- 229910052618 mica group Inorganic materials 0.000 claims description 32
- 238000001035 drying Methods 0.000 claims description 29
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 20
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 10
- 238000002525 ultrasonication Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000007654 immersion Methods 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical class [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 229940099259 vaseline Drugs 0.000 claims description 5
- 239000000203 mixture Substances 0.000 abstract description 12
- PSYGHMBJXWRQFD-UHFFFAOYSA-N 2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate Chemical compound SCC(=O)OCCOC(=O)CS PSYGHMBJXWRQFD-UHFFFAOYSA-N 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 230000006872 improvement Effects 0.000 abstract description 2
- 230000013011 mating Effects 0.000 abstract description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 12
- 244000247812 Amorphophallus rivieri Species 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 235000021180 meal component Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- -1 phenolic aldehyde Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/405—Compounds of aluminium containing combined silica, e.g. mica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of coating for the protection of liquid gasification tank, it is made up of following material:Styrene resin, Isooctyl acrylate monomer, terpene resin, phenolic resin, methylcellulose, triethyl borate, GDMA, konjac glucomannan, modified micaceous powder, glycerine.Improvement is optimized to the component of coating in the present invention, under the common mating reaction of each composition, coating produced by the present invention has the characteristics such as good wear-resisting, corrosion resistant, heatproof, intensity, coating uniform, the compactness height formed, protective capacities is strong, service life is grown, and is not easily cracked and comes off, great popularizing value.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of coating for the protection of liquid gasification tank.
Background technology
Modern society to Some Petrochemical Byproducts and the remaining raffinate of liquefied petroleum gas in order to make full use of, typically with raffinate
For raw material, combustion gas is made in raffinate., it is necessary to gasify to raw material liq in gas-making process.And then liquid gasification can be used
Tank equipment, and the tank body of liquid gasification tank is typically to be made up of steel, in order to lift its surface quality in atmospheric environment, is needed
Preservative treatment is carried out to it.Common is exactly that one layer of protective coating is coated on its surface, and the effect of protective treatment and coating
Quality it is closely bound up.The integrated quality of presently commercially available most coating is bad, causes the tank body of liquid gasification tank often to occur
The bad phenomenons such as corrosion, abrasion, it have impact on its outward appearance condition and using quality, it is necessary to constantly be improved.
The content of the invention
The purpose of the present invention is to be directed to the problem of existing, there is provided a kind of coating for the protection of liquid gasification tank.
The present invention is achieved by the following technical solutions:
A kind of coating for the protection of liquid gasification tank, it is made up of the material of following parts by weight:
65 ~ 70 parts of styrene resins, 33 ~ 36 parts of Isooctyl acrylate monomers, 12 ~ 16 parts of terpene resins, 7 ~ 9 parts of phenolic resin, 5 ~ 8 parts
Methylcellulose, 4 ~ 6 parts of triethyl borates, 3 ~ 5 parts of GDMAs, 1 ~ 3 part of konjac glucomannan, 10 ~ 14 parts of modifications
Mica powder, 4 ~ 7 parts of glycerine.
Preferably, it is made up of the material of following parts by weight:
68 parts of styrene resins, 35 parts of Isooctyl acrylate monomers, 14 parts of terpene resins, 8 parts of phenolic resin, 7 parts of methylcellulose, 5
Part triethyl borate, 4 parts of GDMAs, 2 parts of konjac glucomannans, 12 parts of modified micaceous powder, 6 parts of glycerine.
Further, the preparation method of the modified micaceous powder comprises the following steps:
(1)Mica powder is first put into progress heating and calcining processing in heating furnace, it is 700 ~ 760 first to control the temperature in heating furnace
DEG C, the temperature in heating furnace is risen to 920 ~ 980 DEG C again after handling 35 ~ 40min, taken out after handling 45 ~ 50min, then by cloud
Female powder is put into 30 ~ 35min of immersion treatment in phosphoric acid solution, with standby after deionized water rinsing one time after taking-up;
(2)By step(1)Mica powder after processing, which is put into drying box, carries out primary drying processing, takes out, connects after 1 ~ 1.5h
And be put into solution A, while constantly carry out ultrasonication, filter out mica powder after 40 ~ 45min, finally again by mica powder
It is put into drying box and carries out redrying processing, is taken out after 1 ~ 2h;The solution A by following parts by weight material group
Into:16 ~ 20 parts of nano zirconium dioxides, 13 ~ 15 parts of titanate coupling agents, 2 ~ 5 parts of vaseline, 4 ~ 7 parts of methyl methacrylates,
350 ~ 380 parts of water.
Further, step(1)Described in phosphoric acid solution mass fraction be 8 ~ 11%.
Further, step(2)Described in primary drying processing when control temperature in drying box be 75 ~ 80 DEG C.
Further, step(2)Described in the frequency of ultrasonication be 88 ~ 92kHz.
Further, step(2)Described in redrying processing when control temperature in drying box be 85 ~ 90 DEG C.
The present invention has carried out special collocation to the component of coating and adjusted, and improves its synthesis well and uses quality.Its
In using styrene resin, Isooctyl acrylate monomer as main film forming matrix composition, then compounding with the addition of terpene resin, phenolic aldehyde tree
Fat, effectively improve overall waterproof, Anticorrosive Character, also added methylcellulose, konjac glucomannan come adjust overall viscosity and
Spreading property, promotes its more preferable film forming, and the triethyl borate of addition, GDMA composition are to film forming base
Body composition has carried out chain modified, enhances the complexity and intensity of cross-linked network, and it is special to improve overall wear-resisting, hardness, attachment
Property;In addition the modified micaceous powder filler composition of formulated is also added, it is to be modified to form as bulk composition using mica powder, first
Calcination processing has been carried out to mica powder, has improved its specific surface area and characterization of adsorption, has then carried out acid soak processing, has been removed
Impurity, and the reactivity on surface is improved, channel design has been dredged, has been laid a good foundation for follow-up processing, afterwards with only
The solution A matched somebody with somebody carries out immersion modification, by nano zirconium dioxide introduce it is intercalated grafted be fixed in mica powder, improve filler
Intensity, the rotproofness of entirety, while again because of the lamellar structure of mica powder so that filler has having good wearability again.
The present invention has advantages below compared with prior art:
Improvement is optimized to the component of coating in the present invention, under the common mating reaction of each composition, painting produced by the present invention
Material has the characteristics such as good wear-resisting, corrosion resistant, heatproof, intensity, and the coating uniform formed, compactness are high, and protective capacities is strong, makes
With long lifespan, and it is not easily cracked and comes off, great popularizing value.
Embodiment
Embodiment 1
A kind of coating for the protection of liquid gasification tank, it is made up of the material of following parts by weight:
65 parts of styrene resins, 33 parts of Isooctyl acrylate monomers, 12 parts of terpene resins, 7 parts of phenolic resin, 5 parts of methylcellulose, 4
Part triethyl borate, 3 parts of GDMAs, 1 part of konjac glucomannan, 10 parts of modified micaceous powder, 4 parts of glycerine.
Further, the preparation method of the modified micaceous powder comprises the following steps:
(1)Mica powder is first put into progress heating and calcining processing in heating furnace, it is 700 DEG C first to control the temperature in heating furnace,
The temperature in heating furnace is risen to 920 DEG C again after processing 35min, is taken out after handling 45min, mica powder is then put into phosphoric acid
Immersion treatment 30min in solution, with standby after deionized water rinsing one time after taking-up;
(2)By step(1)Mica powder after processing, which is put into drying box, carries out primary drying processing, takes out after 1h, then puts
Enter into solution A, while constantly carry out ultrasonication, filter out mica powder after 40min, be finally again put into mica powder dry
Redrying processing is carried out in dry case, is taken out after 1h;The solution A by following parts by weight material composition:16 parts of nanometers
Zirconium dioxide, 13 parts of titanate coupling agents, 2 parts of vaseline, 4 parts of methyl methacrylates, 350 parts of water.
Further, step(1)Described in phosphoric acid solution mass fraction be 8%.
Further, step(2)Described in primary drying processing when control temperature in drying box be 75 DEG C.
Further, step(2)Described in the frequency of ultrasonication be 88kHz.
Further, step(2)Described in redrying processing when control temperature in drying box be 85 DEG C.
Embodiment 2
A kind of coating for the protection of liquid gasification tank, it is made up of the material of following parts by weight:
68 parts of styrene resins, 35 parts of Isooctyl acrylate monomers, 14 parts of terpene resins, 8 parts of phenolic resin, 7 parts of methylcellulose, 5
Part triethyl borate, 4 parts of GDMAs, 2 parts of konjac glucomannans, 12 parts of modified micaceous powder, 6 parts of glycerine.
Further, the preparation method of the modified micaceous powder comprises the following steps:
(1)Mica powder is first put into progress heating and calcining processing in heating furnace, it is 730 DEG C first to control the temperature in heating furnace,
The temperature in heating furnace is risen to 950 DEG C again after processing 38min, is taken out after handling 47min, mica powder is then put into phosphoric acid
Immersion treatment 33min in solution, with standby after deionized water rinsing one time after taking-up;
(2)By step(1)Mica powder after processing, which is put into drying box, carries out primary drying processing, is taken out after 1.2h, then
It is put into solution A, while constantly carries out ultrasonication, mica powder is filtered out after 43min, is finally again put into mica powder
Redrying processing is carried out in drying box, is taken out after 1.5h;The solution A by following parts by weight material composition:18 parts
Nano zirconium dioxide, 14 parts of titanate coupling agents, 4 parts of vaseline, 6 parts of methyl methacrylates, 370 parts of water.
Further, step(1)Described in phosphoric acid solution mass fraction be 10%.
Further, step(2)Described in primary drying processing when control temperature in drying box be 78 DEG C.
Further, step(2)Described in the frequency of ultrasonication be 90kHz.
Further, step(2)Described in redrying processing when control temperature in drying box be 88 DEG C.
Embodiment 3
A kind of coating for the protection of liquid gasification tank, it is made up of the material of following parts by weight:
70 parts of styrene resins, 36 parts of Isooctyl acrylate monomers, 16 parts of terpene resins, 9 parts of phenolic resin, 8 parts of methylcellulose, 6
Part triethyl borate, 5 parts of GDMAs, 3 parts of konjac glucomannans, 14 parts of modified micaceous powder, 7 parts of glycerine.
Further, the preparation method of the modified micaceous powder comprises the following steps:
(1)Mica powder is first put into progress heating and calcining processing in heating furnace, it is 760 DEG C first to control the temperature in heating furnace,
The temperature in heating furnace is risen to 980 DEG C again after processing 40min, is taken out after handling 50min, mica powder is then put into phosphoric acid
Immersion treatment 35min in solution, with standby after deionized water rinsing one time after taking-up;
(2)By step(1)Mica powder after processing, which is put into drying box, carries out primary drying processing, is taken out after 1.5h, then
It is put into solution A, while constantly carries out ultrasonication, mica powder is filtered out after 45min, is finally again put into mica powder
Redrying processing is carried out in drying box, is taken out after 2h;The solution A by following parts by weight material composition:20 parts are received
Rice zirconium dioxide, 15 parts of titanate coupling agents, 5 parts of vaseline, 7 parts of methyl methacrylates, 380 parts of water.
Further, step(1)Described in phosphoric acid solution mass fraction be 11%.
Further, step(2)Described in primary drying processing when control temperature in drying box be 80 DEG C.
Further, step(2)Described in the frequency of ultrasonication be 92kHz.
Further, step(2)Described in redrying processing when control temperature in drying box be 90 DEG C.
Comparative example 1
This comparative example 1 compared with Example 2, eliminates terpene resin and phenolic resin composition, method and step in addition
All same.
Comparative example 2
This comparative example 2 compared with Example 2, eliminates triethyl borate and GDMA composition, removed
In addition method and step all same.
Comparative example 3
This comparative example 3 compared with Example 2, with etc. mass parts commercially available mica powder substituting modification mica meal component, except this
Outer method and step all same.
Control group
Existing commercially available common coating.
In order to contrast effect of the present invention, to above-described embodiment 2, comparative example 1, comparative example 2, comparative example 3,
Coating made from control group carries out performance test, and specific correction data is as shown in table 1 below:
Table 1
Alkaline-resisting duration(h) | Acidproof duration(h) | Interface bond strength between paint coatings and metallic matrix(MPa) | |
Embodiment 2 | 2440 | 2050 | 37.6 |
Comparative example 1 | 1980 | 1760 | 34.4 |
Comparative example 2 | 2060 | 1820 | 32.8 |
Comparative example 3 | 1870 | 1610 | 29.3 |
Control group | 1780 | 1520 | 27.8 |
Note:Alkaline-resisting duration described in upper table 1 refers to the sodium hydroxide solution immersion treatment that mass fraction is 6%, keeping temperature
For 35 DEG C, the unconverted duration of coating paint film is observed, its alkaline-resisting characteristic is contrasted with this;Described acidproof duration refers to use matter
The sulfuric acid solution immersion treatment that fraction is 6% is measured, keeping temperature is 35 DEG C, the unconverted duration of coating paint film is observed, with this
Contrast its acid-resistant property.
Coating integrated quality is good made from the inventive method it can be seen from upper table 1, and protection effect is strong, has good
Economic benefit and application value.
Claims (7)
1. a kind of coating for the protection of liquid gasification tank, it is characterised in that be made up of the material of following parts by weight:
65 ~ 70 parts of styrene resins, 33 ~ 36 parts of Isooctyl acrylate monomers, 12 ~ 16 parts of terpene resins, 7 ~ 9 parts of phenolic resin, 5 ~ 8 parts
Methylcellulose, 4 ~ 6 parts of triethyl borates, 3 ~ 5 parts of GDMAs, 1 ~ 3 part of konjac glucomannan, 10 ~ 14 parts of modifications
Mica powder, 4 ~ 7 parts of glycerine.
2. a kind of coating for the protection of liquid gasification tank according to claim 1, it is characterised in that by following parts by weight
Material be made:
68 parts of styrene resins, 35 parts of Isooctyl acrylate monomers, 14 parts of terpene resins, 8 parts of phenolic resin, 7 parts of methylcellulose, 5
Part triethyl borate, 4 parts of GDMAs, 2 parts of konjac glucomannans, 12 parts of modified micaceous powder, 6 parts of glycerine.
A kind of 3. coating for the protection of liquid gasification tank according to claim 1 or 2, it is characterised in that the modification
The preparation method of mica powder comprises the following steps:
(1)Mica powder is first put into progress heating and calcining processing in heating furnace, it is 700 ~ 760 first to control the temperature in heating furnace
DEG C, the temperature in heating furnace is risen to 920 ~ 980 DEG C again after handling 35 ~ 40min, taken out after handling 45 ~ 50min, then by cloud
Female powder is put into 30 ~ 35min of immersion treatment in phosphoric acid solution, with standby after deionized water rinsing one time after taking-up;
(2)By step(1)Mica powder after processing, which is put into drying box, carries out primary drying processing, takes out, connects after 1 ~ 1.5h
And be put into solution A, while constantly carry out ultrasonication, filter out mica powder after 40 ~ 45min, finally again by mica powder
It is put into drying box and carries out redrying processing, is taken out after 1 ~ 2h;The solution A by following parts by weight material group
Into:16 ~ 20 parts of nano zirconium dioxides, 13 ~ 15 parts of titanate coupling agents, 2 ~ 5 parts of vaseline, 4 ~ 7 parts of methyl methacrylates,
350 ~ 380 parts of water.
A kind of 4. coating for the protection of liquid gasification tank according to claim 3, it is characterised in that step(1)Middle institute
The mass fraction for the phosphoric acid solution stated is 8 ~ 11%.
A kind of 5. coating for the protection of liquid gasification tank according to claim 3, it is characterised in that step(2)Middle institute
It is 75 ~ 80 DEG C that the temperature in drying box is controlled during the primary drying processing stated.
A kind of 6. coating for the protection of liquid gasification tank according to claim 3, it is characterised in that step(2)Middle institute
The frequency for the ultrasonication stated is 88 ~ 92kHz.
A kind of 7. coating for the protection of liquid gasification tank according to claim 3, it is characterised in that step(2)Middle institute
It is 85 ~ 90 DEG C that the temperature in drying box is controlled during the redrying processing stated.
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CN201711317912.1A CN107868501A (en) | 2017-12-12 | 2017-12-12 | A kind of coating for the protection of liquid gasification tank |
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CN201711317912.1A CN107868501A (en) | 2017-12-12 | 2017-12-12 | A kind of coating for the protection of liquid gasification tank |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109135510A (en) * | 2018-08-23 | 2019-01-04 | 安徽江杰实业有限公司 | A kind of sheet metal anticorrosive paint |
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