CN107868368A - A kind of nano combined photovoltaic material and its preparation technology - Google Patents
A kind of nano combined photovoltaic material and its preparation technology Download PDFInfo
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- CN107868368A CN107868368A CN201711328038.1A CN201711328038A CN107868368A CN 107868368 A CN107868368 A CN 107868368A CN 201711328038 A CN201711328038 A CN 201711328038A CN 107868368 A CN107868368 A CN 107868368A
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- photovoltaic material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08L61/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/204—Applications use in electrical or conductive gadgets use in solar cells
Abstract
The invention discloses a kind of nano combined photovoltaic material and its preparation technology, photovoltaic material component includes 10 20 parts of polyvinyl chloride resin, 8 20 parts of phenol-formaldehyde resin modified, 4 12 parts of nanometer grade silica, 39 parts of nano silicon micronization, 8 20 parts of silane coupler, 4 12 parts of fire retardant, 5 10 parts of glass fibre, 28 parts of nano zine oxide in parts by weight, preparation technology of the present invention is simple, obtained photovoltaic material has excellent shock resistance, wear-resisting and fire resistance, effectively extends the service life of photovoltaic material.
Description
Technical field
The present invention relates to photovoltaic material preparing technical field, specially a kind of nano combined photovoltaic material and its preparation work
Skill.
Background technology
Photo-thermal, opto-electronic conversion are carried out using solar energy, exploitation solar cell, which turns into, solves worldwide energy danger
Machine and the important channel of environmental pollution.The solar cell of present industrialization is with compound solar cells such as Si systems, CIGS
Based on, but Si systems solar cell preparation technology is complicated, seriously polluted, for other compound solar cells, indium and selenium
All it is that rarer element, cadmium have severe toxicity.Therefore, this kind of battery development is necessarily restricted again.Just because of this, in recent years
Come, consideration the problems such as environmental pollution, we are necessary to develop new semiconductor solar cell.
Current photovoltaic material used for solar batteries is wear-resisting, poor flame retardant properties, is further improved.
The content of the invention
It is an object of the invention to provide a kind of nano combined photovoltaic material and its preparation technology, to solve above-mentioned background skill
The problem of being proposed in art.
To achieve the above object, the present invention provides following technical scheme：A kind of nano combined photovoltaic material, photovoltaic material group
Divide includes polyvinyl chloride resin 10-20 parts, phenol-formaldehyde resin modified 8-20 parts, nanometer grade silica 4-12 parts, nano-silicon in parts by weight
Micro mist 3-9 parts, silane coupler 8-20 parts, fire retardant 4-12 parts, glass fibre 5-10 parts, nano zine oxide 2-8 parts.
Preferably, the preferable composition proportion of photovoltaic material component includes 15 parts of polyvinyl chloride resin, 14 parts of phenol-formaldehyde resin modified, received
8 parts of meter level silica, 6 parts of nano silicon micronization, 14 parts of silane coupler, 8 parts of fire retardant, 8 parts of glass fibre, nano zine oxide
5 parts.
Preferably, the fire retardant is by 30% cobalt aluminate, 20% artificial mica, 20% magnesium chloride, 15% diatomite, 15% swelling
Local soil type into.
Preferably, its preparation technology comprises the following steps：
A, add and stir after mixing polyvinyl chloride resin, phenol-formaldehyde resin modified, nanometer grade silica, nano silicon micronization, silane coupler
The stirring of kettle high speed is mixed, stir speed (S.S.) is 5000 revs/min, time 25min, obtains mixture A；
B, add after fire retardant, glass fibre, nano zine oxide are sufficiently mixed to add in kneading machine in mixture A and be kneaded, mix
It is 130 DEG C to refine temperature, time 10min, obtains mixture B；
C, mixture B is stood into 10min at normal temperatures, that is, obtains composite.
Compared with prior art, the beneficial effects of the invention are as follows：Preparation technology of the present invention is simple, obtained photovoltaic material tool
There are excellent shock resistance, wear-resisting and fire resistance, effectively extend the service life of photovoltaic material；Wherein, the nanometer of addition
Grade silicon dioxide, nano silicon micronization, nano zine oxide can improve resistance to compression and the break-draw rate of photovoltaic material；That adds is fire-retardant
Agent has excellent heat-insulating, fire-preventing performance；Obtained through overtesting, photovoltaic material compression strength produced by the present invention is 30MPA, is broken
Split extensibility and reach 150%.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
The present invention provides following technical scheme：A kind of nano combined photovoltaic material, photovoltaic material component are wrapped in parts by weight
Include polyvinyl chloride resin 10-20 parts, phenol-formaldehyde resin modified 8-20 parts, nanometer grade silica 4-12 parts, nano silicon micronization 3-9 parts, silane
Coupling agent 8-20 parts, fire retardant 4-12 parts, glass fibre 5-10 parts, nano zine oxide 2-8 parts；Wherein, fire retardant is by 30% aluminic acid
Cobalt, 20% artificial mica, 20% magnesium chloride, 15% diatomite, 15% bentonite composition.
Embodiment one：
Photovoltaic material component in parts by weight include 10 parts of polyvinyl chloride resin, 8 parts of phenol-formaldehyde resin modified, 4 parts of nanometer grade silica,
3 parts of nano silicon micronization, 8 parts of silane coupler, 4 parts of fire retardant, 5 parts of glass fibre, 2 parts of nano zine oxide.
The preparation technology of the present embodiment comprises the following steps：
A, add and stir after mixing polyvinyl chloride resin, phenol-formaldehyde resin modified, nanometer grade silica, nano silicon micronization, silane coupler
The stirring of kettle high speed is mixed, stir speed (S.S.) is 5000 revs/min, time 25min, obtains mixture A；
B, add after fire retardant, glass fibre, nano zine oxide are sufficiently mixed to add in kneading machine in mixture A and be kneaded, mix
It is 130 DEG C to refine temperature, time 10min, obtains mixture B；
C, mixture B is stood into 10min at normal temperatures, that is, obtains composite.
Embodiment two：
Photovoltaic material component includes 20 parts of polyvinyl chloride resin, 20 parts of phenol-formaldehyde resin modified, nanometer grade silica 12 in parts by weight
Part, 9 parts of nano silicon micronization, 20 parts of silane coupler, 12 parts of fire retardant, 10 parts of glass fibre, 8 parts of nano zine oxide.
The preparation technology of the present embodiment comprises the following steps：
A, add and stir after mixing polyvinyl chloride resin, phenol-formaldehyde resin modified, nanometer grade silica, nano silicon micronization, silane coupler
The stirring of kettle high speed is mixed, stir speed (S.S.) is 5000 revs/min, time 25min, obtains mixture A；
B, add after fire retardant, glass fibre, nano zine oxide are sufficiently mixed to add in kneading machine in mixture A and be kneaded, mix
It is 130 DEG C to refine temperature, time 10min, obtains mixture B；
C, mixture B is stood into 10min at normal temperatures, that is, obtains composite.
Embodiment three：
Photovoltaic material component in parts by weight include 12 parts of polyvinyl chloride resin, 10 parts of phenol-formaldehyde resin modified, 6 parts of nanometer grade silica,
4 parts of nano silicon micronization, 9 parts of silane coupler, 6 parts of fire retardant, 6 parts of glass fibre, 3 parts of nano zine oxide.
The preparation technology of the present embodiment comprises the following steps：
A, add and stir after mixing polyvinyl chloride resin, phenol-formaldehyde resin modified, nanometer grade silica, nano silicon micronization, silane coupler
The stirring of kettle high speed is mixed, stir speed (S.S.) is 5000 revs/min, time 25min, obtains mixture A；
B, add after fire retardant, glass fibre, nano zine oxide are sufficiently mixed to add in kneading machine in mixture A and be kneaded, mix
It is 130 DEG C to refine temperature, time 10min, obtains mixture B；
C, mixture B is stood into 10min at normal temperatures, that is, obtains composite.
Example IV：
Photovoltaic material component in parts by weight include 15 parts of polyvinyl chloride resin, 14 parts of phenol-formaldehyde resin modified, 8 parts of nanometer grade silica,
6 parts of nano silicon micronization, 14 parts of silane coupler, 8 parts of fire retardant, 8 parts of glass fibre, 5 parts of nano zine oxide.
The preparation technology of the present embodiment comprises the following steps：
A, add and stir after mixing polyvinyl chloride resin, phenol-formaldehyde resin modified, nanometer grade silica, nano silicon micronization, silane coupler
The stirring of kettle high speed is mixed, stir speed (S.S.) is 5000 revs/min, time 25min, obtains mixture A；
B, add after fire retardant, glass fibre, nano zine oxide are sufficiently mixed to add in kneading machine in mixture A and be kneaded, mix
It is 130 DEG C to refine temperature, time 10min, obtains mixture B；
C, mixture B is stood into 10min at normal temperatures, that is, obtains composite.
Preparation technology of the present invention is simple, and obtained photovoltaic material has excellent shock resistance, wear-resisting and fire resistance, effectively
The service life for extending photovoltaic material；Wherein, the nanometer grade silica of addition, nano silicon micronization, nano zine oxide energy
Enough improve resistance to compression and the break-draw rate of photovoltaic material；The fire retardant of addition has excellent heat-insulating, fire-preventing performance；Through overtesting
Obtain, photovoltaic material compression strength produced by the present invention is 30MPA, and break-draw rate reaches 150%.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (4)
- A kind of 1. nano combined photovoltaic material, it is characterised in that：Photovoltaic material component includes polyvinyl chloride resin 10-20 in parts by weight Part, phenol-formaldehyde resin modified 8-20 parts, nanometer grade silica 4-12 parts, nano silicon micronization 3-9 parts, silane coupler 8-20 parts, Fire retardant 4-12 parts, glass fibre 5-10 parts, nano zine oxide 2-8 parts.
- A kind of 2. nano combined photovoltaic material according to claim 1, it is characterised in that：Photovoltaic material component preferably into It is even that distribution ratio includes 15 parts of polyvinyl chloride resin, 14 parts of phenol-formaldehyde resin modified, 8 parts of nanometer grade silica, 6 parts of nano silicon micronization, silane Join 14 parts of agent, 8 parts of fire retardant, 8 parts of glass fibre, 5 parts of nano zine oxide.
- A kind of 3. nano combined photovoltaic material according to claim 1, it is characterised in that：The fire retardant is by 30% aluminic acid Cobalt, 20% artificial mica, 20% magnesium chloride, 15% diatomite, 15% bentonite composition.
- 4. realize a kind of preparation technology of nano combined photovoltaic material described in claim 1, it is characterised in that：Its preparation technology Comprise the following steps：A, add and stir after mixing polyvinyl chloride resin, phenol-formaldehyde resin modified, nanometer grade silica, nano silicon micronization, silane coupler The stirring of kettle high speed is mixed, stir speed (S.S.) is 5000 revs/min, time 25min, obtains mixture A；B, add after fire retardant, glass fibre, nano zine oxide are sufficiently mixed to add in kneading machine in mixture A and be kneaded, mix It is 130 DEG C to refine temperature, time 10min, obtains mixture B；C, mixture B is stood into 10min at normal temperatures, that is, obtains composite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201711328038.1A CN107868368A (en) | 2017-12-13 | 2017-12-13 | A kind of nano combined photovoltaic material and its preparation technology |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711328038.1A CN107868368A (en) | 2017-12-13 | 2017-12-13 | A kind of nano combined photovoltaic material and its preparation technology |
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| Publication Number | Publication Date |
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| CN107868368A true CN107868368A (en) | 2018-04-03 |
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| CN201711328038.1A Withdrawn CN107868368A (en) | 2017-12-13 | 2017-12-13 | A kind of nano combined photovoltaic material and its preparation technology |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861379A (en) * | 2014-12-29 | 2015-08-26 | 殷培花 | High glowing wire ignition temperature and high flame retardation modified polyvinyl chloride cable material and preparation method thereof |
| CN106009373A (en) * | 2016-06-15 | 2016-10-12 | 潘海云 | Modified fiber reinforced PVC plastic pipe and preparation method thereof |
| CN106280074A (en) * | 2016-08-03 | 2017-01-04 | 安庆市悦发管业有限公司 | A kind of high-strength anti-flaming corrugated tube and processing method thereof |
| CN107011599A (en) * | 2017-06-05 | 2017-08-04 | 合肥嘉仕诚能源科技有限公司 | A kind of solar power plant nano electromagnetic shielding material and preparation method thereof |
| CN107226994A (en) * | 2017-07-26 | 2017-10-03 | 合肥同佑电子科技有限公司 | It is a kind of for plastics of environment-friendly trash can and preparation method thereof |
| CN107383708A (en) * | 2017-09-26 | 2017-11-24 | 马鞍山松鹤信息科技有限公司 | A kind of high molecule plastic master batch and its preparation technology |
-
2017
- 2017-12-13 CN CN201711328038.1A patent/CN107868368A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861379A (en) * | 2014-12-29 | 2015-08-26 | 殷培花 | High glowing wire ignition temperature and high flame retardation modified polyvinyl chloride cable material and preparation method thereof |
| CN106009373A (en) * | 2016-06-15 | 2016-10-12 | 潘海云 | Modified fiber reinforced PVC plastic pipe and preparation method thereof |
| CN106280074A (en) * | 2016-08-03 | 2017-01-04 | 安庆市悦发管业有限公司 | A kind of high-strength anti-flaming corrugated tube and processing method thereof |
| CN107011599A (en) * | 2017-06-05 | 2017-08-04 | 合肥嘉仕诚能源科技有限公司 | A kind of solar power plant nano electromagnetic shielding material and preparation method thereof |
| CN107226994A (en) * | 2017-07-26 | 2017-10-03 | 合肥同佑电子科技有限公司 | It is a kind of for plastics of environment-friendly trash can and preparation method thereof |
| CN107383708A (en) * | 2017-09-26 | 2017-11-24 | 马鞍山松鹤信息科技有限公司 | A kind of high molecule plastic master batch and its preparation technology |
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Application publication date: 20180403 |
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