CN106328739B - Solar cell flexible cover plate and preparation method thereof - Google Patents
Solar cell flexible cover plate and preparation method thereof Download PDFInfo
- Publication number
- CN106328739B CN106328739B CN201610698325.0A CN201610698325A CN106328739B CN 106328739 B CN106328739 B CN 106328739B CN 201610698325 A CN201610698325 A CN 201610698325A CN 106328739 B CN106328739 B CN 106328739B
- Authority
- CN
- China
- Prior art keywords
- cover plate
- solar cell
- flexible cover
- cell flexible
- glass microballoon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002360 preparation method Methods 0.000 title abstract description 19
- 239000011521 glass Substances 0.000 claims abstract description 55
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000013536 elastomeric material Substances 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 8
- 229910052681 coesite Inorganic materials 0.000 claims description 8
- 229910052593 corundum Inorganic materials 0.000 claims description 8
- 229910052906 cristobalite Inorganic materials 0.000 claims description 8
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229910052682 stishovite Inorganic materials 0.000 claims description 8
- 229910052905 tridymite Inorganic materials 0.000 claims description 8
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 8
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 4
- 239000004005 microsphere Substances 0.000 claims description 4
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 3
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 239000011325 microbead Substances 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims description 2
- 229920002379 silicone rubber Polymers 0.000 claims description 2
- 239000004945 silicone rubber Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 3
- 238000002834 transmittance Methods 0.000 abstract description 2
- 210000004027 cell Anatomy 0.000 description 12
- 239000000084 colloidal system Substances 0.000 description 6
- 239000003292 glue Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000003471 anti-radiation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 239000006059 cover glass Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- -1 wherein Chemical compound 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/095—Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The invention discloses a kind of solar cell flexible cover plate materials and preparation method thereof, wherein the flexible cover plate, using glass microballoon as dispersed phase, using elastomeric material as continuous phase, the mass ratio of the glass microballoon and elastomeric material is (0.1~10):1.The advantages that flexible cover plate provided in an embodiment of the present invention has high transmittance concurrently, can twisted with excellent radiation-resistant property simultaneously, is expected to obtain important application on space solar cell.
Description
Technical field
The present invention relates to solar cell cover plate technique field, more particularly to a kind of solar cell flexible cover plate materials and
Its preparation method.
Background technology
Solar energy has the advantages of inexhaustible as a kind of green energy resource.Solar energy is in industry, agriculture
The fields such as industry, Aero-Space obtain extensive use.Cover plate is covered in solar cell surface, protects solar cell from high energy
The radiation and bombardment of ray and high energy particle, so as to extend the service life of solar cell.
At present, solar cell cover plate is stabilized glass piece, such as resistance to irradiation borosilicate glass.In the prior art
Referred to for stabilized glass and preparation method thereof.However, because glass is a kind of fragile material, cover glass is in the sun
It often can occur to crush in battery motion process, make solar cell exposed in high energy Space Particle, cause space electronic to set
Standby damage, situations such as having had a strong impact on the normal work of Space Facilities, or even caused Space Facilities to damage.Therefore, solves the sun
The energy breakable problem of battery cover board is extremely urgent.
The content of the invention
In view of this, the embodiment of the present invention provides a kind of solar cell flexible cover plate and preparation method thereof, main purpose
It is to solve the breakable problem of solar cell cover plate.
To reach above-mentioned purpose, present invention generally provides following technical scheme:
On the one hand, the embodiments of the invention provide a kind of solar cell flexible cover plate, the cover plate using glass microballoon as
Dispersed phase, using elastomeric material as continuous phase, the mass ratio of the glass microballoon and elastomeric material is (0.1~10):1.
Preferably, the particle size of glass microspheres is less than or equal to 40 μm.
Preferably, the particle size of glass microspheres is 10~30 μm.
Preferably, the glass microballoon is space stabilized glass microballon, the elastomeric material is the resistance to irradiation rubber in space
Glue material.
Preferably, the glass microballoon is made up of the oxide of following weight/mass percentage composition:10~70% SiO2, 0
~30% X2O, 0~20% YO, 0~5% Al2O3, 5~20% Tb2O3, 0~15% B2O3, 1~5% Gd2O3
With 0.1~10% CeO2, wherein, X2O is Li2O、Na2O and K2At least one of O, the YO be BaO, SrO, ZnO, MgO,
One or more in CaO.
Preferably, the glass microballoon is made up of the component of following weight/mass percentage composition:
50~65% SiO2, 10~20% X2O, 5~15% YO, 1~2% Al2O3, 9~15% Tb2O3, 3
~10% B2O3, 2~5% Gd2O3With 0.2~3.0% CeO2。
Preferably, the glass microballoon is made up of the component of following weight/mass percentage composition:
55~60% SiO2, 15~20% X2O, 5~10% YO, 1~1.5% Al2O3, 10~15%
Tb2O3, 5~8% B2O3, 4~5% Gd2O3With 0.2~1.0% CeO2。
Preferably, the glass microballoon is solid microbeads.
Preferably, the glass microballoon can be prepared by powder method, solwution method or flame floating method etc..
Preferably, thickness≤0.15mm of the cover plate, average transmission of the cover plate in 400~2000nm optical bands
Rate >=80%.
Preferably, the elastomeric material is space level addition type room temperature vulcanized silicone rubber.Can be specifically the U.S.
Any one in DC93-500 and German RTV-S691.
Preferably, the cover plate is 1 × 10 by integral dose15e/cm2After electron irradiation, transmitance decay is less than etc.
In 0.35%.
On the other hand, the embodiments of the invention provide a kind of preparation side of the solar cell flexible cover plate of above-described embodiment
Method, raw material is mixed in proportion;The flow casting molding on solar battery sheet, and by 100~200 DEG C of drying 0.1~24
Hour.
Compared with prior art, the beneficial effects of the present invention are:
For flexible cover plate provided in an embodiment of the present invention using glass microballoon as dispersed phase, the binding agent using elastomeric material is continuous
Phase, while the advantages that have high transmittance, excellent anti-radiation performance concurrently and can arbitrarily twist.
Embodiment
The present invention is described in further detail with reference to specific embodiment, but it is not as a limitation of the invention.
In the description below, what different " embodiment " or " embodiment " referred to is not necessarily the same embodiment.In addition, one or more are implemented
Special characteristic, structure or feature in example can be combined by any suitable form.
Unless otherwise specified, the percentage composition in the embodiment of the present invention is mass percent.
Embodiment 1
The preparation of glass microballoon:By 59% SiO2, 20% K2O, 5% BaO, 1.5% Al2O3, 10%
Tb2O3, 4% Gd2O3With 0.5% CeO2Proportioning is weighed and mixed, and forms compound.By compound in 1550 DEG C of platinums
Melted in crucible 4 hours and form glass metal, in fusion process, exclusion gas is stirred to glass metal using platinum stirrer
Bubble, speed of agitator 50r/min, glass metal was poured into room temperature water tank and obtained by glass metal in 1450 DEG C of clarifying treatments 6 hours after stirring
To stabilized glass fragment.Glass fragment is arrived into stabilized glass micro mist after high energy ball mill is ground 8 hours.By glass
Grain is sent into high temperature flame, and in the presence of flame, the softening of glass micro mist particle, melting, pearlization, cooling and solidifying obtain particle diameter
Scope is 10 μm~40 μm of solid stabilized glass microballon.
The preparation of pearl colloid:2kg stabilized glass microballon and 1kg U.S. DC93-500 are weighed, is mixed in agate mortar
And stir, 8 hours are stood, emptying bubble caused by stirring, obtains pearl colloid.
The preparation of flexible cover plate:By above-mentioned pearl colloid on homemade casting machine flow casting molding, it is 0.12mm to obtain thickness,
The long a width of 200 × 200mm of * flexible cover plate blank, move into 150 DEG C of Muffle furnace and be incubated 8 hours, then furnace cooling, you can
The resistance to irradiation cover plate materials of a ultrathin flexible are obtained, its properties is shown in Table 1.
Embodiment 2
The composition and preparation method of the glass microballoon of embodiment 2, the proportioning and preparation method of pearl colloid, and flexible cover plate
Preparation process it is all same as Example 1, be a difference in that sulphurated siliastic uses German RTV-S691, it is preparation-obtained super
The thin resistance to irradiation cover plate materials properties of flexibility are shown in Table 1.
Embodiment 3
In addition to glass microballoon composition and the difference of embodiment 1, embodiment 3 is made as the preparation process of embodiment 1
The standby obtained resistance to irradiation cover plate materials properties of ultrathin flexible are shown in Table 1.The glass microballoon composition of embodiment 3 is:57%SiO2,
19.5%K2O, 5%BaO, 1.5%Al2O3, 10%Tb2O3, 4%Gd2O3And 3%CeO2。
Embodiment 4
The pearl glue ratio of embodiment 4 is 1:1, the composition of microballon is same as Example 1, and colloid is U.S. DC93-500, other
Preparation process and embodiment 1 are identical, and the preparation-obtained resistance to irradiation cover plate materials properties of ultrathin flexible are shown in Table 1.
Embodiment 5
The pearl glue ratio of embodiment 5 is 1:1, the composition of microballon is same as Example 1, and colloid is German RTV-S691, other
Preparation process and embodiment 1 are identical, and the preparation-obtained resistance to irradiation cover plate materials properties of ultrathin flexible are shown in Table 1.
Embodiment 6
In addition to glass microballoon composition and the difference of embodiment 1, embodiment 6 is made as the preparation process of embodiment 1
The standby obtained resistance to irradiation cover plate materials properties of ultrathin flexible are shown in Table 1.The glass microballoon composition of embodiment 6 is:57%SiO2,
2.5%K2O, 7%Li2O, 10%Na2O, 5%BaO, 1.5%Al2O3, 10%Tb2O3, 4%Gd2O3And 3%CeO2, prepared
To ultrathin flexible it is resistance to irradiation cover plate materials properties be shown in Table 1.
Embodiment 7
In addition to glass microballoon composition and the difference of embodiment 1, embodiment 6 is made as the preparation process of embodiment 1
The standby obtained resistance to irradiation cover plate materials properties of ultrathin flexible are shown in Table 1.The glass microballoon composition of embodiment 6 is:51.5%
SiO2, 25%Na2O, 5%BaO, 1.5%Al2O3, 10%Tb2O3, 4%Gd2O3And 3%CeO2, preparation-obtained ultrathin flexible
Resistance to irradiation cover plate materials properties are shown in Table 1.
The glass microballoon component of table 1, pearl glue ratio, preparation technology parameter and cover plate materials properties
The good glass microballoon of several radiation-resistant properties is given in above-described embodiment to prepare flexible cover plate, it is not excluded that its
The glass microballoon that his raw material composition or other raw materials matched obtain.It is, of course, preferable to it is stabilized glass microballon.The present invention is implemented
Glass microballoon in example can be prepared by powder method, solwution method or flame floating method etc..Also commercially available appropriate glass
Microballon.
To the particle diameter of glass microballoon without particular/special requirement in the embodiment of the present invention.But preferably not greater than 40 μm, particularly glass
When main between 10-30 μm or with the glass microballoon of the particle size range, obtained flexible cover plate will have higher the particle diameter of glass microballon
Transmitance.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
Those familiar with the art the invention discloses technical scope in, change or replacement can be readily occurred in, should all be contained
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (8)
1. a kind of solar cell flexible cover plate, it is characterised in that it is continuous using elastomeric material using glass microballoon as dispersed phase
Phase, the mass ratio of the glass microballoon and elastomeric material is (0.1~10):1;
The glass microballoon is solid microbeads, and the glass microballoon is made up of the component of following weight/mass percentage composition:
50~65% SiO2, 10~20% X2O, 5~15% YO, 1~2% Al2O3, 9~15% Tb2O3, 3~
10% B2O3, 2~5% Gd2O3With 0.2~3.0% CeO2;
Wherein, X2O is Li2O、Na2O and K2At least one of O, the YO be BaO, SrO, ZnO, MgO, CaO in one kind or
It is a variety of.
2. solar cell flexible cover plate according to claim 1, it is characterised in that the glass microballoon is the resistance to spoke in space
According to glass microballoon, the elastomeric material is the space elastomeric material of resistance to irradiation.
3. solar cell flexible cover plate according to claim 1, it is characterised in that the elastomeric material is that space level adds
It is molded room temperature vulcanized silicone rubber.
4. solar cell flexible cover plate according to claim 1, it is characterised in that the solar cell flexible cover plate
Thickness≤0.15mm, mean transmissivity >=80% of the solar cell flexible cover plate in 400~2000nm optical bands.
5. solar cell flexible cover plate according to claim 1, it is characterised in that the solar cell flexible cover plate
It is 1 × 10 by integral dose15e/cm2After electron irradiation, transmitance decay≤0.5%.
6. solar cell flexible cover plate according to claim 1, it is characterised in that the μ of the particle size of glass microspheres≤40
m。
7. solar cell flexible cover plate according to claim 5, it is characterised in that the particle size of glass microspheres be 10~
30μm。
8. a kind of method for being used to prepare the solar cell flexible cover plate according to claim any one of 1-7, including step
Suddenly:Glass microballoon and elastomeric material are fully mixed in proportion, the flow casting molding on solar battery sheet, move into 80~200 DEG C
Drying oven is incubated 0.1~24 hour, obtains ultra-thin composite and flexible cover plate materials.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610698325.0A CN106328739B (en) | 2016-08-19 | 2016-08-19 | Solar cell flexible cover plate and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610698325.0A CN106328739B (en) | 2016-08-19 | 2016-08-19 | Solar cell flexible cover plate and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106328739A CN106328739A (en) | 2017-01-11 |
CN106328739B true CN106328739B (en) | 2018-02-09 |
Family
ID=57741495
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610698325.0A Active CN106328739B (en) | 2016-08-19 | 2016-08-19 | Solar cell flexible cover plate and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106328739B (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109686803A (en) * | 2018-12-25 | 2019-04-26 | 中国电子科技集团公司第十八研究所 | A kind of space solar cell flexible package structure |
CN109817758A (en) * | 2018-12-25 | 2019-05-28 | 中国电子科技集团公司第十八研究所 | A kind of space flexible solar cell cover plate packaging method |
CN114806493A (en) * | 2022-06-08 | 2022-07-29 | 北京化工大学 | High-filling flexible anti-irradiation fake glass cover plate and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102675881A (en) * | 2012-05-16 | 2012-09-19 | 中国电子科技集团公司第三十三研究所 | High temperature resistant rubber base composite material used for chip packaging and application thereof |
CN103972264A (en) * | 2013-01-25 | 2014-08-06 | 财团法人工业技术研究院 | Flexible electronic device |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002026361A (en) * | 2000-07-07 | 2002-01-25 | Hitachi Ltd | Double-sided light receiving solar cell module |
-
2016
- 2016-08-19 CN CN201610698325.0A patent/CN106328739B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102675881A (en) * | 2012-05-16 | 2012-09-19 | 中国电子科技集团公司第三十三研究所 | High temperature resistant rubber base composite material used for chip packaging and application thereof |
CN103972264A (en) * | 2013-01-25 | 2014-08-06 | 财团法人工业技术研究院 | Flexible electronic device |
Also Published As
Publication number | Publication date |
---|---|
CN106328739A (en) | 2017-01-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN112724716B (en) | High-reflection glass slurry for photovoltaic module glass backboard and preparation method thereof | |
CN106328739B (en) | Solar cell flexible cover plate and preparation method thereof | |
CN101723589B (en) | Lead-free glass powder with low melting point for sealing PDP and preparation method thereof | |
JP5733811B2 (en) | Manufacturing method of glass substrate for solar cell | |
CN110255932B (en) | Alkali-activated solid waste type high-temperature-resistant high-shear-force inorganic adhesive and preparation method thereof | |
JP2003267753A (en) | Glass composition for manufacturing inorganic fiber and its molding | |
CN102643023A (en) | Environmental-friendly black glaze for automotive glass and preparation method of black glaze | |
CN104529172A (en) | Lead-free and cadmium-free glass powder for automobile toughened glass ink and preparation method thereof | |
CN110092589A (en) | Household electrical appliance shock resistance ink low-temperature lead-free glass powder and preparation method thereof | |
CN106098144A (en) | A kind of glass dust and with its solar cell front side silver paste prepared and preparation method thereof | |
CN103601369A (en) | Preparation method of lead-free electronic glass powder for back aluminum slurry of solar cell | |
CN113772959A (en) | High-reflection low-temperature crystallized glass slurry for double-glass solar cell module and preparation method thereof | |
CN102603195A (en) | Lead-free glass powder for solar electrode sizing agent and preparation method thereof | |
CN103693854B (en) | A kind of Unlead low-smelting point microcrystalline glass powder and preparation method thereof | |
CN110683775B (en) | Solid waste utilization type flame-retardant-high shear force integrated inorganic adhesive and preparation method thereof | |
CN113248946A (en) | Coating composition for manufacturing ceramic-like coating and preparation method and application thereof | |
CN110668722B (en) | Oxidation-flame retardation-high shear force integrated solid waste inorganic adhesive and preparation method thereof | |
CN107010837A (en) | A kind of rare earth doped element leadless and low-melting point sealing glass powder and its manufacture method | |
CN109369027A (en) | Add the novel environment friendly glass powder and preparation method thereof of nano-metal-oxide | |
JP2014182055A (en) | Organic inorganic composite | |
KR20090052566A (en) | A sealing materials contained alumina particle for solid oxide fuel cell | |
CN112551902A (en) | Low-melting-point glass powder containing alkaline earth metal and preparation method and application thereof | |
JP2013136470A (en) | Sealing composition, method for producing sealing composition and sealed structure | |
CN112851126B (en) | Lead-free composite glass powder for insulating side surface of ZnO resistance card, preparation method and glass glaze | |
CN103922600A (en) | Composite tourmaline/glass material and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |