CN107868308A - A kind of graphene strengthens rubber - Google Patents
A kind of graphene strengthens rubber Download PDFInfo
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- CN107868308A CN107868308A CN201711264858.9A CN201711264858A CN107868308A CN 107868308 A CN107868308 A CN 107868308A CN 201711264858 A CN201711264858 A CN 201711264858A CN 107868308 A CN107868308 A CN 107868308A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
- F16G1/00—Driving-belts
- F16G1/06—Driving-belts made of rubber
- F16G1/08—Driving-belts made of rubber with reinforcement bonded by the rubber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
- F16G1/00—Driving-belts
- F16G1/28—Driving-belts with a contact surface of special shape, e.g. toothed
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention discloses a kind of graphene to strengthen rubber, and described graphene enhancing rubber is used for high-strength abrasion-proof driving belt, and described graphene enhancing rubber is made up of the raw material of following parts by weight：25 parts of iron oxide, 100 parts of neoprene, 20 50 parts of butadiene-styrene rubber, 0.01 0.05 parts of graphene, 12 parts of age resistor, 10 20 parts of cyclization, 12 parts of pva powder, 12 parts of vulcanizing agent, 10 20 parts of graphite, 0.1 0.5 parts of coupling agent, 5 10 parts of inorganic inert powder.
Description
The application is application number 2016103765979, title：A kind of high-strength abrasion-proof driving belt, 2016 applyings date
The divisional application of 31 days 05 month.
Technical field
The present invention relates to transmission device, is specifically a kind of high-strength abrasion-proof driving belt.
Background technology
Driving belt is the important device of mechanical energy transmission and transport article in industry, by the motor or hair of prime mover
Power caused by motivation rotation, is transmitted in plant equipment by belt wheel by adhesive tape, therefore also referred to as powered belt.It is that electromechanics is set
Standby core coupling component, species is extremely various, and purposes is extremely wide.It is small to deficiency from greatly to the huge motor of several megawatts
One kilowatt of micromachine, or even transmission belt is all be unable to do without including the precision optical machineries such as household electrical appliances, computer, robot.
Existing driving belt is mainly prepared by framework material and rubber or elastomeric material, and its middle skeleton is generally adopted
With the polyester cord that intensity is high, small, the heat-resisting and resistance to bend(ing) of elongation is good, occurs the modification of Gao Dingshen, lower shrinkage again the eighties
Polyester cord, wherein the V-type band for requiring high-load transmission, the variable velocity zone of impact resistance and agricultural machinery, have oneself start to make
With aramid fiber, and framework material best at present is glass fibre, and it can make elongation during engaged transmission small, and with suitable
The linear expansion coefficient of degree, in addition the shortcoming such as flexural fatigue property is allowed to be used widely.From now on, intensity will be higher, bending resistance
The more preferable aramid fiber of song would be possible to part substitution glass fibre and get into the optimal framework material ranks of tooth-like belt.At present,
There is a kind of non-twist polyester tempering monofilament skeleton in the market, this framework material with its relative low price, high intensity, resistance to bend
The features such as flexible good, service life is long, progressively obtains everybody accreditation.Wherein rubber and elastomer widely use at present heat resistance,
The materials such as the preferable butadiene-styrene rubber of wearability, polyurethane elastomer.
With China's industrial expansion, the requirement more and more higher to plant equipment, it is strong that the quality of driving belt is particularly its
Degree and wearability not enough have become the bottleneck of development of machinery industry, seriously govern China's industrial expansion, there is an urgent need to
High intensity, wearability, the driving belt of service life length.
The content of the invention
It is an object of the invention to：For above-mentioned problem, there is provided the strong transmission skin of a kind of high intensity, wearability
Band.
The technical solution adopted by the present invention is as follows：
The invention discloses a kind of high-strength abrasion-proof driving belt, it is characterised in that including V-type burr, belt body layer, the back of the body
Layer, described body layer is between V-type burr and backing layer, and described V-type burr arranges in a direction, described body
Layer, which is provided with carbon fiber, to be strengthened feed belt, and the cross section of described V-type burr is trapezoidal.
Preferably, the differently- oriented directivity of described carbon fiber and the width angle of belt are less than more than 0 degree 30 degree.
Preferably, the spacing between the adjacent V-type burr is 0.6-15cm.
Preferably, described body layer, which is graphene, strengthens elastomeric material.
Preferably, described graphene enhancing rubber is made up of the raw material of following parts by weight：Iron oxide 2-5 parts, neoprene
100 parts of rubber, butadiene-styrene rubber 20-50 parts, graphene 0.01-0.05 parts, age resistor 1-2 parts, cyclization 10-20 parts,
Pva powder 1-2 parts, vulcanizing agent 1-2 parts, graphite 10-20 parts, coupling agent 0.1-0.5 parts, inorganic inert powder 5-10 parts.
Further, the preparation method of graphene enhancing elastomeric material material is as follows：:
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 10-20h at 80-100 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 100-120 DEG C, with 100-150 DEG C
Banburying 4 minutes, product prepared by step 3 is added, vulcanizing agent, 120-140 DEG C is warming up to, with 400-600r/min speed banburying
10-15min, obtain elastomeric material.
Preferably, described inorganic inert powder is selected from diatomite, flyash, blanc fixe, Iron Ore Powder, quartz sand
One or more in powder, agstone, talcum powder, ground phosphate rock, asbestos miberal powder, silica flour.
Preferably, described coupling agent is TMC-201, TMC-102, TMC-101, KH792, the one of DL602, DL171
Kind is several.
Preferably, the particle diameter of described inorganic inert powder is more than 100 mesh.
The present invention discloses application of such a high-strength abrasion-proof driving belt on automobile.
In summary, by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
First, driving belt provided by the invention has excellent in strength, can be widely used among various heavy industry plant equipment, effectively
Raising equipment operating efficiency, reduce equipment damage；
2nd, driving belt provided by the invention has stronger rub resistance, after extended periods, the V-type burr above belt
Also be not in polish damage, service life is longer.
Brief description of the drawings
Fig. 1 is the cross-sectional view of driving belt provided by the invention；
Fig. 2 is the surface V-type burr figure of driving belt provided by the invention；
Marked in figure：1-V type burrs, 2- body layers, 3- backing layers, 4- carbon fibers.
Embodiment
Below in conjunction with the accompanying drawings, the present invention is described in detail.
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples
The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and
It is not used in the restriction present invention.
Specific embodiment 1：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 0 degree, adjacent V-type
Burr（1）Between spacing be 0.6cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：2 parts of iron oxide, neoprene
100 parts, 20 parts of butadiene-styrene rubber, 0.01 part of graphene, 1 part of age resistor, 10 parts of cyclization, 1 part of pva powder, sulphur
1 part of agent, 10 parts of graphite, 0.1 part of coupling agent, 5 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 10h at 80 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 100 DEG C, is divided in 100 DEG C of banburyings 4
Clock, product prepared by step 3 is added, vulcanizing agent, 120 DEG C is warming up to, with 400r/min speed banburying 10min, obtains rubber
Material.
The inorganic inert powder of the present embodiment is diatomite, and particle diameter is 100 mesh, coupling agent TMC-201.
Specific embodiment 2：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 30 degree, adjacent V
Type burr（1）Between spacing be 15cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：5 parts of iron oxide, neoprene
100 parts, 50 parts of butadiene-styrene rubber, 0.05 part of graphene, 2 parts of age resistor, 20 parts of cyclization, 2 parts of pva powder, sulphur
2 parts of agent, 20 parts of graphite, 0.5 part of coupling agent, 10 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 20h at 100 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, 120 DEG C is warming up to, banburying 4 minutes, adds step
Rapid 3 products prepared, vulcanizing agent, are warming up to 140 DEG C, with 600r/min speed banburying 15min, obtain elastomeric material.
The inorganic inert powder of the present embodiment is flyash, and particle diameter is 120 mesh, coupling agent TMC-102.
Specific embodiment 3：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 10 degree, adjacent V
Type burr（1）Between spacing be 10cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：3 parts of iron oxide, neoprene
100 parts, 30 parts of butadiene-styrene rubber, 0.03 part of graphene, 1.5 parts of age resistor, 15 parts of cyclization, pva powder 1.5
Part, 1.5 parts of vulcanizing agent, 15 parts of graphite, 0.3 part of coupling agent, 8 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 15h at 90 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 110 DEG C, is divided with 120 DEG C of banburyings 4
Clock, product prepared by step 3 is added, vulcanizing agent, 130 DEG C is warming up to, with 500r/min speed banburying 12min, obtains rubber
Material.
The inorganic inert powder of the present embodiment is blanc fixe, and particle diameter is 200 mesh, coupling agent TMC-101.
Specific embodiment 4：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 5 degree, adjacent V-type
Burr（1）Between spacing be 7cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：2 parts of iron oxide, neoprene
100 parts, 50 parts of butadiene-styrene rubber, 0.01 part of graphene, 2 parts of age resistor, 10 parts of cyclization, 2 parts of pva powder, sulphur
1 part of agent, 20 parts of graphite, 0.1 part of coupling agent, 10 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 20h at 80 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 100 DEG C, is divided with 150 DEG C of banburyings 4
Clock, product prepared by step 3 is added, vulcanizing agent, 120 DEG C is warming up to, with 600r/min speed banburying 10min, obtains rubber
Material.
The inorganic inert powder of the present embodiment is Iron Ore Powder, and particle diameter is more than 100 mesh, coupling agent KH792.
Specific embodiment 5：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 15 degree, adjacent V
Type burr（1）Between spacing be 0.6cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：5 parts of iron oxide, neoprene
100 parts, 20 parts of butadiene-styrene rubber, 0.05 part of graphene, 1 part of age resistor, 20 parts of cyclization, 1 part of pva powder, sulphur
2 parts of agent, 10 parts of graphite, 0.5 part of coupling agent, 5 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 10h at 100 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 120 DEG C, is divided with 100 DEG C of banburyings 4
Clock, product prepared by step 3 is added, vulcanizing agent, 140 DEG C is warming up to, with 400r/min speed banburying 15min, obtains rubber
Material.
The inorganic inert powder of the present embodiment is quartz sand powder, and particle diameter is more than 100 mesh, coupling agent DL602.
Specific embodiment 6：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 20 degree, adjacent V
Type burr（1）Between spacing be 0.6cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：5 parts of iron oxide, neoprene
100 parts, 30 parts of butadiene-styrene rubber, 0.01 part of graphene, 2 parts of age resistor, 12 parts of cyclization, 1 part of pva powder, sulphur
2 parts of agent, 12 parts of graphite, 0.1 part of coupling agent, 10 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 10h at 90 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 120 DEG C, is divided with 120 DEG C of banburyings 4
Clock, product prepared by step 3 is added, vulcanizing agent, 120 DEG C is warming up to, with 600r/min speed banburying 12min, obtains rubber
Material.
The inorganic inert powder of the present embodiment is agstone, and particle diameter is more than 100 mesh, coupling agent DL602.
Specific embodiment 7：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 12 degree, adjacent V
Type burr（1）Between spacing be 0.6cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：3 parts of iron oxide, neoprene
100 parts, 50 parts of butadiene-styrene rubber, 0.01 part of graphene, 1.5 parts of age resistor, 15 parts of cyclization, 1 part of pva powder,
1.5 parts of vulcanizing agent, 20 parts of graphite, 0.5 part of coupling agent, 8 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 20h at 80 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 100 DEG C, is divided with 150 DEG C of banburyings 4
Clock, product prepared by step 3 is added, vulcanizing agent, 120 DEG C is warming up to, with 600r/min speed banburying 12min, obtains rubber
Material.
The inorganic inert powder of the present embodiment is talcum powder, and particle diameter is more than 100 mesh, coupling agent DL171.
Specific embodiment 8：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 30 degree, adjacent V
Type burr（1）Between spacing be 0.6cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：5 parts of iron oxide, neoprene
100 parts, 50 parts of butadiene-styrene rubber, 0.03 part of graphene, 1 part of age resistor, 10 parts of cyclization, 2 parts of pva powder, sulphur
2 parts of agent, 15 parts of graphite, 0.1 part of coupling agent, 5 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 20h at 100 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 110 DEG C, is divided with 100 DEG C of banburyings 4
Clock, product prepared by step 3 is added, vulcanizing agent, 120 DEG C is warming up to, with 600r/min speed banburying 15min, obtains rubber
Material.
The inorganic inert powder of the present embodiment is ground phosphate rock, and particle diameter is more than 100 mesh, coupling agent TDL602.
Specific embodiment 9：As shown in Figure 1 and Figure 2, present embodiment discloses a kind of high-strength abrasion-proof driving belt, including V
Type burr 1, body layer 2, backing layer 3, for described body layer between V-type burr 1 and backing layer, described V-type burr is in one
Direction is arranged, and described body layer 2, which is provided with carbon fiber 4, to be strengthened feed belt, the cross section of described V-type burr 1
To be trapezoidal.
In the present embodiment, the differently- oriented directivity of described carbon fiber 4 and the width angle of belt are 0 degree, adjacent V-type
Burr（1）Between spacing be 0.6cm, described body layer is that graphene strengthens elastomeric material.
The graphene enhancing rubber of the present embodiment is made up of the raw material of following parts by weight：5 parts of iron oxide, neoprene
100 parts, 50 parts of butadiene-styrene rubber, 0.02 part of graphene, 1.5 parts of age resistor, 10 parts of cyclization, 1 part of pva powder,
2 parts of vulcanizing agent, 20 parts of graphite, 0.3 part of coupling agent, 5 parts of inorganic inert powder, preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 10h at 80 DEG C after bathing, standby after cooling.
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 120 DEG C, is divided with 150 DEG C of banburyings 4
Clock, product prepared by step 3 is added, vulcanizing agent, 130 DEG C is warming up to, with 400r/min speed banburying 10min, obtains rubber
Material.
The inorganic inert powder of the present embodiment is asbestos miberal powder, and particle diameter is more than 100 mesh, coupling agent TMC-102.
High-strength abrasion-proof driving belt disclosed in the present embodiment can use on the conveyer of automobile.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.
Claims (5)
1. a kind of graphene strengthens rubber, it is characterised in that described graphene enhancing rubber is used for high-strength abrasion-proof transmission skin
Band, described graphene enhancing rubber are made up of the raw material of following parts by weight：Iron oxide 2-5 parts, 100 parts of neoprene, butylbenzene
Rubber 20-50 parts, graphene 0.01-0.05 parts, age resistor 1-2 parts, cyclization 10-20 parts, pva powder 1-2
Part, vulcanizing agent 1-2 parts, graphite 10-20 parts, coupling agent 0.1-0.5 parts, inorganic inert powder 5-10 parts.
2. graphene according to claim 1 strengthens rubber, it is characterised in that preparation method is as follows：
Step 1：Iron oxide is surface-treated with coupling agent, according to mass ratio is 1 by coupling agent and absolute ethyl alcohol:1 mixing
Stir, add iron oxide, 30min is stirred under 90-100 degrees Celsius of scope, wash, filter, dry；
Step 2：Iron oxide after step 1 is added in cyclohexane solvent, it disperseed with ultrasonic wave mode, is being added
Graphene, graphite, inorganic inert powder, are disperseed with ultrasonic wave again, are then slowly added to hexamethylene evaporation, it is dried
It is dry, obtain dusty material；
Step 3：By the product after step 2 and be chopped after cyclization, age resistor, pva powder mix, then add
The calcium chloride solution for entering 1wt% is flocculated, and dries 10-20h at 80-100 DEG C after bathing, standby after cooling；
Step 4：Neoprene and butadiene-styrene rubber are added in banbury, are warming up to 100-120 DEG C, with 100-150 DEG C of banburying 4
Minute, product prepared by step 3 is added, vulcanizing agent, 120-140 DEG C is warming up to, with 400-600r/min speed banburying 10-
15min, obtain elastomeric material.
3. graphene according to claim 2 strengthens rubber, it is characterised in that described inorganic inert powder is selected from diatom
One in soil, flyash, blanc fixe, Iron Ore Powder, quartz sand powder, agstone, talcum powder, ground phosphate rock, asbestos miberal powder, silica flour
Kind is several.
4. graphene according to claim 3 strengthens rubber, it is characterised in that described coupling agent is TMC-201, TMC-
102nd, TMC-101, KH792, DL602, DL171 one or more.
5. graphene according to claim 4 strengthens rubber, it is characterised in that the particle diameter of described inorganic inert powder is big
In 100 mesh.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711264858.9A CN107868308A (en) | 2016-05-31 | 2016-05-31 | A kind of graphene strengthens rubber |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376597.9A CN105906883B (en) | 2016-05-31 | 2016-05-31 | A kind of high-strength abrasion-proof driving belt |
| CN201711264858.9A CN107868308A (en) | 2016-05-31 | 2016-05-31 | A kind of graphene strengthens rubber |
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| CN201610376597.9A Division CN105906883B (en) | 2016-05-31 | 2016-05-31 | A kind of high-strength abrasion-proof driving belt |
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| CN201711264858.9A Withdrawn CN107868308A (en) | 2016-05-31 | 2016-05-31 | A kind of graphene strengthens rubber |
| CN201711264676.1A Withdrawn CN107841016A (en) | 2016-05-31 | 2016-05-31 | A kind of preparation method of graphene enhancing rubber |
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| CN117489753B (en) * | 2023-10-12 | 2024-05-17 | 宁波伏龙同步带有限公司 | Toothed synchronous belt |
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| US4740192A (en) * | 1985-06-03 | 1988-04-26 | Mitsuboshi Belting Ltd. | Power transmission belt |
| CN101466557A (en) * | 2006-06-09 | 2009-06-24 | 赢创德固赛有限责任公司 | Rubber mixtures |
| CN101484311A (en) * | 2006-07-01 | 2009-07-15 | 朗盛德国有限责任公司 | Layer-type vulcanized products based on hydrogenated vinyl polybutadiene |
| CN104194102A (en) * | 2014-09-22 | 2014-12-10 | 安徽电气集团股份有限公司 | High-strength tear-resistant modified butadiene styrene rubber material |
| CN104828463A (en) * | 2015-04-09 | 2015-08-12 | 浙江三维橡胶制品股份有限公司 | Special conveyer belt for iron and steel sintered ore |
| CN105111531A (en) * | 2015-04-29 | 2015-12-02 | 宁波职业技术学院 | Graphene-modified wear-resistant rubber |
| CN105504412A (en) * | 2015-12-30 | 2016-04-20 | 三力士股份有限公司 | High-performance total chloroprene rubber adhesive wide-angle fabric V-belt |
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| CN104816913A (en) * | 2014-05-17 | 2015-08-05 | 郝明先 | Buffering and durable roller conveying belt |
| CN104356431A (en) * | 2014-09-26 | 2015-02-18 | 青岛桐晟桐橡塑科技有限公司 | Improved flame-retardant conveyer belt |
| CN204200954U (en) * | 2014-11-10 | 2015-03-11 | 宁波凯驰胶带有限公司 | A kind of colored thickening Timing Belt |
| CN104861236A (en) * | 2015-04-28 | 2015-08-26 | 安徽同丰橡塑工业有限公司 | Neoprene and styrene butadiene rubber nanocomposite |
-
2016
- 2016-05-31 CN CN201610376597.9A patent/CN105906883B/en active Active
- 2016-05-31 CN CN201711264858.9A patent/CN107868308A/en not_active Withdrawn
- 2016-05-31 CN CN201711264676.1A patent/CN107841016A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4740192A (en) * | 1985-06-03 | 1988-04-26 | Mitsuboshi Belting Ltd. | Power transmission belt |
| CN101466557A (en) * | 2006-06-09 | 2009-06-24 | 赢创德固赛有限责任公司 | Rubber mixtures |
| CN101484311A (en) * | 2006-07-01 | 2009-07-15 | 朗盛德国有限责任公司 | Layer-type vulcanized products based on hydrogenated vinyl polybutadiene |
| CN104194102A (en) * | 2014-09-22 | 2014-12-10 | 安徽电气集团股份有限公司 | High-strength tear-resistant modified butadiene styrene rubber material |
| CN104828463A (en) * | 2015-04-09 | 2015-08-12 | 浙江三维橡胶制品股份有限公司 | Special conveyer belt for iron and steel sintered ore |
| CN105111531A (en) * | 2015-04-29 | 2015-12-02 | 宁波职业技术学院 | Graphene-modified wear-resistant rubber |
| CN105504412A (en) * | 2015-12-30 | 2016-04-20 | 三力士股份有限公司 | High-performance total chloroprene rubber adhesive wide-angle fabric V-belt |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107841016A (en) | 2018-03-27 |
| CN105906883B (en) | 2018-07-27 |
| CN105906883A (en) | 2016-08-31 |
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Application publication date: 20180403 |