CN107854324A - A kind of preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide - Google Patents

A kind of preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide Download PDF

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Publication number
CN107854324A
CN107854324A CN201711053956.8A CN201711053956A CN107854324A CN 107854324 A CN107854324 A CN 107854324A CN 201711053956 A CN201711053956 A CN 201711053956A CN 107854324 A CN107854324 A CN 107854324A
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CN
China
Prior art keywords
graphene oxide
layer web
mask substrate
high water
water conservation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711053956.8A
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Chinese (zh)
Inventor
陈志华
张炜栋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Textile Vocational Technology College
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Nantong Textile Vocational Technology College
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Filing date
Publication date
Application filed by Nantong Textile Vocational Technology College filed Critical Nantong Textile Vocational Technology College
Priority to CN201711053956.8A priority Critical patent/CN107854324A/en
Priority to PCT/CN2017/116977 priority patent/WO2019085190A1/en
Publication of CN107854324A publication Critical patent/CN107854324A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43835Mixed fibres, e.g. at least two chemically different fibres or fibre blends
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212Face masks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/10General cosmetic use
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52Stabilizers
    • A61K2800/524Preservatives

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Medicinal Preparation (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

The invention discloses a kind of preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide, the base fabric is combined by nutritive layer web and hydrophobic framework layer web, described nutritive layer web is by graphene oxide nylon fibre and biomass fiber homogeneous blend, is prepared by spunlace non-woven cloth technique;Described hydrophobic framework layer web is that graphene oxide nylon fibre is prepared by spunlace non-woven cloth technique.The antibacterial mask substrate skin-friendly of the high water conservation of graphene oxide of the present invention, antibiotic property, moisture retention are good, simple in construction, and production efficiency is high, cost is low, and use is safer.Mask substrate meets green, ecology, environmental protection, the requirement of health, can obtain relatively more preferable facial beauty care effect without using preservative.

Description

A kind of preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide
Technical field
The present invention relates to weaving and makeups articles for use field, and in particular to a kind of antibacterial mask substrate of high water conservation of graphene oxide Preparation method.
Background technology
Facial mask is just increasingly liked that mounted facial mask is mainly made up of mask substrate, nutrition Essence by consumer.Often Advise mask substrate generally use terylene short fiber and short rayon fiber shredding mixes, then shaped through cross lapping, then through Hydroentangled It is made.In order to control bacterial reproduction on facial mask for a long time, antiseptic and antibiotic agent must be artificially added in nutrition Essence.It is but added Antiseptic and antibiotic agent suppresses to skin cell proliferation, the skin histology of contact is had undesirable effect, this makes it possible to face Film can exist in various degree when in use produces certain stimulation, hereby endophytic bacteria to skin, or even produces thorn to skin Swash infringement, so that situations such as allergic phenomena occurs.
Therefore in order to improve security that facial mask uses, it is necessary to be improved in the raw material selection of mask substrate, make Mask substrate itself has certain antibacterial functions.Graphene oxide (GO) has good anti-microbial property.Chinese section in 2010 Shanghai Applied Physics research institute of institute Hu W et al. publish an article in ACS Nano, have studied graphene oxide (GO) first, go back The anti-microbial property of former graphene oxide (RGO).GO, RGO can effectively suppress the growth of EHEC, and cytotoxicity Very little.Graphene can occur very strong dispersion with the phospholipid molecule on bacterial cell membrane and interact, it is thus possible to extensive The phospholipid molecule on cell membrane is directly extracted, bacterium is killed, effectively plays antibacterial action.
The content of the invention
Goal of the invention:The present invention provides a kind of preparation method of the antibacterial mask substrate of high water conservation of graphene oxide.
Technical scheme:A kind of preparation method of the antibacterial mask substrate of high water conservation of graphene oxide, the base fabric is by nutritive layer Web and hydrophobic framework layer web are combined, and described nutritive layer web is by graphene oxide nylon fibre and life Material fibrils homogeneous blend, it is prepared by spunlace non-woven cloth technique;Described hydrophobic framework layer web is will to aoxidize stone Black alkene nylon fibre is prepared by spunlace non-woven cloth technique.
Further, described graphene oxide nylon fibre accounts for the 10-20% of nutritive layer web gross weight, biomass Fiber accounts for the 80-90% of nutritive layer web gross weight.
Further, described graphene oxide nylon fibre is the described graphite oxide using graphene oxide as raw material The degree of graphene weight is 0.5-0.9% in alkene nylon fibre.
Further, described graphene oxide nylon fibre specification is 7.22-8.33tex (65-75D)/36F.
Further, described biomass fiber is viscose glue, aloe fibre, copper ion fiber, alginate fibre, ramie pulp fiber Or the one or more in regenerated celulose fibre.
Further, described nutritive layer web carries out hydrophilic finiss, and moisture absorbing and sweat releasing soil-releasing finishing agent is configured to 10-15% solution, to nutritive layer web carry out spray 80 DEG C of infrared dryings, layer web that have additional nutrients it is hydrophilic, perspire, Dirt-removing power.
Beneficial effect:The antibacterial mask substrate skin-friendly of the high water conservation of graphene oxide in the present invention, antibiotic property, moisture retention Good, simple in construction, production efficiency is high, cost is low, and use is safer.Mask substrate meets green, life without using preservative State, environmental protection, the requirement of health, relatively more preferable facial beauty care effect can be obtained.
Guarantee of the biomass fiber as the carrier and high water conservation of nutrient solution in the present invention, parent is carried out to nutritive layer web Water arrange augment nutritional layer web it is hydrophilic, perspire, dirt-removing power, graphene oxide nylon fibre provides the anti-of nutrient solution Bacterium, anti-corrosion function, while graphene oxide nylon fibre line density is small in hydrophobic framework layer web, is formed compared with fine capillary, Nutritive layer web is formed compared with coarse wool tubule, is formed led from hydrophobic framework layer web to the unidirectional of nutritive layer web between the two It is moist.Be advantageous to have additional nutrients layer web moisture retention and the nutrient delivery efficiency to face.
Specific embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, so that the technology of this area Personnel can be better understood from advantages and features of the invention, so as to make apparent boundary to protection scope of the present invention It is fixed.Embodiment described in the invention is only part of the embodiment of the present invention, rather than whole embodiments, based on the present invention In embodiment, the every other implementation that those of ordinary skill in the art are obtained on the premise of creative work is not made Example, belongs to the scope of protection of the invention.
Embodiment 1
A kind of preparation method of the antibacterial mask substrate of high water conservation of graphene oxide, the base fabric is by nutritive layer web and dredges Water casing play web is combined, and described nutritive layer web is that graphene oxide nylon fibre and biomass fiber is equal Even blending, it is prepared by spunlace non-woven cloth technique;Described hydrophobic framework layer web is that graphene oxide polyamide fibre is fine Dimension is prepared by spunlace non-woven cloth technique.
Described graphene oxide nylon fibre accounts for the 20% of nutritive layer web gross weight, and biomass fiber accounts for nutritive layer The 80% of web gross weight.
Described graphene oxide nylon fibre is the described graphene oxide nylon fibre using graphene oxide as raw material The degree of middle graphene weight is 0.5%.
Described graphene oxide nylon fibre specification is 7.22tex (65D)/36F.
Described biomass fiber is that viscose glue, aloe fibre, copper ion fiber, alginate fibre, ramie pulp fiber or regeneration are fine One or more in cellulose fiber.
Described nutritive layer web carries out hydrophilic finiss, by moisture absorbing and sweat releasing soil-releasing finishing agent be configured to 10% it is molten Liquid, to nutritive layer web carry out spray 80 DEG C of infrared dryings, layer web that have additional nutrients it is hydrophilic, perspire, dirt-removing power.
Embodiment 2
A kind of preparation method of the antibacterial mask substrate of high water conservation of graphene oxide, the base fabric is by nutritive layer web and dredges Water casing play web is combined, and described nutritive layer web is that graphene oxide nylon fibre and biomass fiber is equal Even blending, it is prepared by spunlace non-woven cloth technique;Described hydrophobic framework layer web is that graphene oxide polyamide fibre is fine Dimension is prepared by spunlace non-woven cloth technique.
Described graphene oxide nylon fibre accounts for the 10% of nutritive layer web gross weight, and biomass fiber accounts for nutritive layer The 90% of web gross weight.
Described graphene oxide nylon fibre is the described graphene oxide nylon fibre using graphene oxide as raw material The degree of middle graphene weight is 0.9%.
Described graphene oxide nylon fibre specification is 8.33tex (75D)/36F.
Described biomass fiber is that viscose glue, aloe fibre, copper ion fiber, alginate fibre, ramie pulp fiber or regeneration are fine One or more in cellulose fiber.
Described nutritive layer web carries out hydrophilic finiss, by moisture absorbing and sweat releasing soil-releasing finishing agent be configured to 15% it is molten Liquid, to nutritive layer web carry out spray 80 DEG C of infrared dryings, layer web that have additional nutrients it is hydrophilic, perspire, dirt-removing power.
Embodiment 3
A kind of preparation method of the antibacterial mask substrate of high water conservation of graphene oxide, the base fabric is by nutritive layer web and dredges Water casing play web is combined, and described nutritive layer web is that graphene oxide nylon fibre and biomass fiber is equal Even blending, it is prepared by spunlace non-woven cloth technique;Described hydrophobic framework layer web is that graphene oxide polyamide fibre is fine Dimension is prepared by spunlace non-woven cloth technique.
Described graphene oxide nylon fibre accounts for the 14% of nutritive layer web gross weight, and biomass fiber accounts for nutritive layer The 87% of web gross weight.
Described graphene oxide nylon fibre is the described graphene oxide nylon fibre using graphene oxide as raw material The degree of middle graphene weight is 0.7%.
Described graphene oxide nylon fibre specification is 7.86tex (69D)/36F.
Described biomass fiber is that viscose glue, aloe fibre, copper ion fiber, alginate fibre, ramie pulp fiber or regeneration are fine One or more in cellulose fiber.
Described nutritive layer web carries out hydrophilic finiss, by moisture absorbing and sweat releasing soil-releasing finishing agent be configured to 13% it is molten Liquid, to nutritive layer web carry out spray 80 DEG C of infrared dryings, layer web that have additional nutrients it is hydrophilic, perspire, dirt-removing power.
The antibacterial mask substrate skin-friendly of the high water conservation of graphene oxide in the present invention, antibiotic property, moisture retention are good, structure letter Single, production efficiency is high, cost is low, and use is safer.Mask substrate without use preservative, meet green, ecology, it is environmentally friendly, The requirement of health, can obtain relatively more preferable facial beauty care effect.
Guarantee of the biomass fiber as the carrier and high water conservation of nutrient solution in the present invention, parent is carried out to nutritive layer web Water arrange augment nutritional layer web it is hydrophilic, perspire, dirt-removing power, graphene oxide nylon fibre provides the anti-of nutrient solution Bacterium, anti-corrosion function, while graphene oxide nylon fibre line density is small in hydrophobic framework layer web, is formed compared with fine capillary, Nutritive layer web is formed compared with coarse wool tubule, is formed led from hydrophobic framework layer web to the unidirectional of nutritive layer web between the two It is moist.Be advantageous to have additional nutrients layer web moisture retention and the nutrient delivery efficiency to face.

Claims (6)

  1. A kind of 1. preparation method of the antibacterial mask substrate of high water conservation of graphene oxide, it is characterised in that:The base fabric is by nutritive layer Web and hydrophobic framework layer web are combined, and described nutritive layer web is by graphene oxide nylon fibre and life Material fibrils homogeneous blend, it is prepared by spunlace non-woven cloth technique;Described hydrophobic framework layer web is will to aoxidize stone Black alkene nylon fibre is prepared by spunlace non-woven cloth technique.
  2. 2. the preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide according to claim 1, it is characterised in that:Institute The graphene oxide nylon fibre stated accounts for the 10-20% of nutritive layer web gross weight, and biomass fiber accounts for nutritive layer web The 80-90% of gross weight.
  3. 3. the preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide according to claim 2, it is characterised in that:Institute The graphene oxide nylon fibre stated is the graphene weight in described graphene oxide nylon fibre using graphene oxide as raw material The degree of amount is 0.5-0.9%.
  4. 4. the preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide according to claim 3, it is characterised in that:Institute The graphene oxide nylon fibre specification stated is 7.22-8.33tex (65-75D)/36F.
  5. 5. the preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide according to claim 1, it is characterised in that:Institute The biomass fiber stated is in viscose glue, aloe fibre, copper ion fiber, alginate fibre, ramie pulp fiber or regenerated celulose fibre One or more.
  6. 6. the preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide according to claim 1, it is characterised in that:Institute The nutritive layer web stated carries out hydrophilic finiss, moisture absorbing and sweat releasing soil-releasing finishing agent is configured to 10-15% solution, to nutrition Layer web carry out spray 80 DEG C of infrared dryings, layer web that have additional nutrients it is hydrophilic, perspire, dirt-removing power.
CN201711053956.8A 2017-10-31 2017-10-31 A kind of preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide Pending CN107854324A (en)

Priority Applications (2)

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CN201711053956.8A CN107854324A (en) 2017-10-31 2017-10-31 A kind of preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide
PCT/CN2017/116977 WO2019085190A1 (en) 2017-10-31 2017-12-18 Method for preparing high-water-retention bacteriostatic facial mask base cloth with graphene oxide

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Application Number Priority Date Filing Date Title
CN201711053956.8A CN107854324A (en) 2017-10-31 2017-10-31 A kind of preparation method of the antibacterial mask substrate of the high water conservation of graphene oxide

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Cited By (7)

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CN108797100A (en) * 2018-07-09 2018-11-13 合肥洁诺医疗用品有限公司 A kind of medical and hygiene article antibacterial moisture-inhibiting non-woven fabrics
CN108892814A (en) * 2018-07-12 2018-11-27 高昕文 A kind of preparation method being retained mask substrate
CN110453373A (en) * 2019-08-16 2019-11-15 广州康滤净化科技有限公司 A kind of graphene bacteria mildew-proof non-woven fabrics and preparation method thereof
CN111270413A (en) * 2020-02-11 2020-06-12 任国峰 Functional graphene mask cloth and preparation method thereof
CN112267209A (en) * 2020-09-23 2021-01-26 杨保成 Hydrophilic antibacterial non-woven fabric and preparation method thereof
CN113081871A (en) * 2021-04-16 2021-07-09 郝宝民 Graphene bacteriostatic moisturizing beauty mask
CN113186646A (en) * 2021-03-14 2021-07-30 杭州锴越新材料有限公司 Graphene spunlace non-woven fabric and preparation method thereof

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CN112760818B (en) * 2020-12-29 2022-07-19 常州琉璃光生物科技有限公司 Spunlace cloth with antibacterial and bacteriostatic effects
CN114053157B (en) * 2021-12-02 2024-02-02 李肖红 Self-generating micro-current mask cloth and preparation method thereof
CN114712294B (en) * 2022-05-10 2023-05-30 广州雅南无纺布制品有限公司 Graphene mask with magnetic therapy function and preparation method thereof
CN115054991B (en) * 2022-06-10 2024-06-04 武汉纺织大学 Preparation method of reusable air filtering material with good sterilization comfort
CN116575185B (en) * 2023-07-12 2023-10-10 山东华业无纺布有限公司 Mattress material containing mugwort modified fibers and preparation method thereof

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108797100A (en) * 2018-07-09 2018-11-13 合肥洁诺医疗用品有限公司 A kind of medical and hygiene article antibacterial moisture-inhibiting non-woven fabrics
CN108892814A (en) * 2018-07-12 2018-11-27 高昕文 A kind of preparation method being retained mask substrate
CN110453373A (en) * 2019-08-16 2019-11-15 广州康滤净化科技有限公司 A kind of graphene bacteria mildew-proof non-woven fabrics and preparation method thereof
CN111270413A (en) * 2020-02-11 2020-06-12 任国峰 Functional graphene mask cloth and preparation method thereof
CN112267209A (en) * 2020-09-23 2021-01-26 杨保成 Hydrophilic antibacterial non-woven fabric and preparation method thereof
CN112267209B (en) * 2020-09-23 2022-01-28 广东康尔医疗科技有限公司 Hydrophilic antibacterial non-woven fabric and preparation method thereof
CN113186646A (en) * 2021-03-14 2021-07-30 杭州锴越新材料有限公司 Graphene spunlace non-woven fabric and preparation method thereof
CN113081871A (en) * 2021-04-16 2021-07-09 郝宝民 Graphene bacteriostatic moisturizing beauty mask

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Application publication date: 20180330