CN1078489A - Fractional quench oil compound - Google Patents
Fractional quench oil compound Download PDFInfo
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- CN1078489A CN1078489A CN 92103404 CN92103404A CN1078489A CN 1078489 A CN1078489 A CN 1078489A CN 92103404 CN92103404 CN 92103404 CN 92103404 A CN92103404 A CN 92103404A CN 1078489 A CN1078489 A CN 1078489A
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Abstract
A kind of fractional quench oil compound, said composition is by mineral type base oil and urge cryogen, rust-preventive agent, brightening agent, oxidation inhibitor are formed, this hierarchical quenching oil has good cooling performance and thermooxidizing security, and have characteristics nontoxic, that pollution is little, cleaning is convenient, safe and reliable and the parts quenching after strain is little, this hierarchical quenching oil is applicable to the bearing inner and outer ring that bearing steel, converted steel are made, quenchings such as precision component and automobile gear, semiaxis.
Description
The present invention relates to a kind of heat-treated oil, specifically is hierarchical quenching oil.
Along with mechanotronic, national defense industry, the particularly development of aerospace flight technology, quenching technique to metallic substance requires more and more higher, many special-purpose quenching oils have been succeeded in developing on the sixties national defence, resemble vacuum quenching oil, quick bright quenc hing oil and hypervelocity quenching wet goods, the seventies, in order to solve precision component and large module gear quenching strain problem, industrially developed country develops use temperature at 120～200 ℃ isothermal quenching oil and hierarchical quenching oil, Martemp 722 hierarchical quenching oils as U.S. Houghton company, the DaphneA oil that Japan bright dipping company produces, the cooling performance of above-mentioned hierarchical quenching oil and thermal oxidation stability are all not ideal enough.
The research work of China's heat-treated oil is started late, special-purpose quenching oil begins one's study in early eighties, treatment production is not because there is the high temperature grading quenching oil at present, have to substitute with high viscosity machinery oil and superheated steam cylinder oil, because these oily cooling poweies are poor, adverse consequencess such as the inhomogeneous and thermal oxidation stability of conducting heat is bad etc., causes part hardness low, and oil coke is serious.
It is strong to the purpose of this invention is to provide a kind of cooling performance, and oxidation stability is good, the hierarchical quenching oil that life cycle is long.
Hierarchical quenching oil usually under protective atmosphere as the quenchant of heated components; require quenching rear surface light; base oil fraction and refining depth are all influential to its cooling performance, oxidation stability and piece surface luminance brightness, and the present invention adopts mineral oil 650SN to make base oil.
The cryogen of urging that the present composition is selected for use has two kinds, a kind of is petroleum sodium sulfonate, another kind is that molecular-weight average is 40,000 Atactic Polypropelene, in order to guarantee the luminance brightness of part, need to add rust-preventive agent and brightening agent in the component, the rust-preventive agent that the present composition is selected for use is dodecenylsuccinic acid, brightening agent is a sorbitol monooleate, because hierarchical quenching oil is at high temperature to use, must select excellent high-temperature oxidation inhibitor, the oxidation inhibitor that the present invention selects for use has two kinds, a kind of is the 2.6-ditertbutylparacresol, and another kind is that molecular structure is
4.4 methylene radical-2.6 DI-tert-butylphenol compounds, this oxidation inhibitor is a kind of new type high temperature oxidation inhibitor, is produced by Beijing Chemical Factory No. 3.
The composition proportioning of fractional quench oil compound of the present invention is to contain petroleum sodium sulfonate 0.3～1.5g, Atactic Polypropelene 0.3～2.0g, dodecenylsuccinic acid 0.02～0.08g, sorbitol monooleate 0.3～1.0g, 2.6-ditertbutylparacresol 0.5～0.8g, 4.4 methylene radical-2.6 DI-tert-butylphenol compounds, 0.3～1.0g in the 100g base oil.
The preparation of hierarchical quenching oil of the present invention is that Atactic Polypropelene is mixed with base oil by nitrogen protection under 100～120 ℃ of temperature; be mixed into certain density mother liquor, then this mother liquor other additive, base oil in composition stirred under 70 ± 5 ℃ of temperature.
Compare with existing hierarchical quenching oil, hierarchical quenching oil of the present invention has good cooling performance and thermal oxidation stability, and have nontoxic, pollute little, it is convenient to clean, safe in utilization and little characteristics of parts quenching after strain, this hierarchical quenching oil is applicable to the bearing inner and outer ring that bearing steel, converted steel are made, quenchings such as precision component and automobile gear, semiaxis.
Embodiment: the hierarchical quenching oil with the described composition proportioning of table 1 is a sample
Table 1
| Composition | Content (g) |
| 650SN neutral oil petroleum sodium sulfonate random polypropylene dodecenylsuccinic acid sorbitol monooleate 2.6--BHT 4.4 methylene--2.6 DI-tert- |
100 0.5 0.1 0.04 0.5 0.6 0.4 |
Do not carried out the cooling performance test with present embodiment hierarchical quenching oil and Japanese DaphneA oil content, Fig. 1 is a DaphneA hierarchical quenching oil speed of cooling curve, Fig. 2 is a hierarchical quenching oil speed of cooling curve of the present invention, from Fig. 1 and Fig. 2 as can be seen, hierarchical quenching oil cooling performance of the present invention is better than Japanese DaphneA oil, the maximum cooling velocity ratio of hierarchical quenching oil of the present invention is very fast, and appear at the high-temperature zone, and the zone below 300 ℃, the speed of cooling of oil is slack-off, this is unusual ideal, to reducing the distortion of part, demonstrates favorable cooling effect.
Do the test of quenching light respectively with hierarchical quenching oil of the present invention and Japanese DaphneA oil and U.S. Houghton722 hierarchical quenching oil in little vacuum oven, test-results sees Table 2.
As can be seen from Table 2, the part luminance brightness is better after the marquenching oil quenching of the present invention.
Carry out oxidation test with present embodiment oil and Daphne A oil and Houghton 722 oil, this test is in the presence of Fe, Cu catalyzer, in 165 ℃ of feeding dry airs, the viscosity ratio and the carbon residue increased value of formation testing measured in oxidation after 96 hours continuously, and it the results are shown in Table 3.Hierarchical quenching oil thermal oxidation stability result of the present invention as can be seen from Table 3 is better than Daphne A oil and Houghton 722 oil.
Claims (5)
1, a kind of fractional quench oil compound of being made up of base oil and additive is characterized in that in the 100g base oil that contained additive and content thereof are respectively:
Urge cryogen petroleum sodium sulfonate 0.3～1.5g
Olefin polymer 0.3～2.0g
Rust-preventive agent dodecenylsuccinic acid 0.02～0.08g
Brightening agent sorbitol monooleate 0.3～1.0g
Phenol type antioxidant (I) 0.5～0.8g
Phenol type antioxidant (II) 0.3～1.0g
2,, it is characterized in that described olefin polymer is that molecular-weight average is 40,000 Atactic Polypropelene according to the described fractional quench oil compound of claim 1.
3, fractional quench oil compound according to claim 1 is characterized in that described phenol type antioxidant (II) is that molecular structure is
4.4 methylene radical-2.6 DI-tert-butylphenol compounds.
4,, it is characterized in that described base oil is a mineral oil according to the described marquenching oil ingredient of claim 1.
5,, it is characterized in that described base oil is a 650SN neutral oil according to claim 1 and the described marquenching oil ingredient of claim 5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92103404 CN1032314C (en) | 1992-05-15 | 1992-05-15 | Fractional quench oil compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92103404 CN1032314C (en) | 1992-05-15 | 1992-05-15 | Fractional quench oil compound |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1078489A true CN1078489A (en) | 1993-11-17 |
| CN1032314C CN1032314C (en) | 1996-07-17 |
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ID=4940183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92103404 Expired - Fee Related CN1032314C (en) | 1992-05-15 | 1992-05-15 | Fractional quench oil compound |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1032314C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1060799C (en) * | 1995-09-08 | 2001-01-17 | 国际壳牌研究有限公司 | Polyolefin-substituted dicarboxylic acid or anhydride ester derivatives |
| CN102212662A (en) * | 2011-06-09 | 2011-10-12 | 上海德润宝特种润滑剂有限公司 | Ultra quick quenching oil and preparation method thereof |
| CN103667629A (en) * | 2012-09-20 | 2014-03-26 | 中国石油化工股份有限公司 | Low-temperature tempering method |
| CN105950842A (en) * | 2016-04-28 | 2016-09-21 | 昌利锻造有限公司 | Quenching oil for bearing end caps |
| CN106435111A (en) * | 2016-11-03 | 2017-02-22 | 金福英 | Efficient bright quenching oil and preparation method thereof |
| CN106435110A (en) * | 2016-09-20 | 2017-02-22 | 中国石油化工股份有限公司 | Quenching oil composition and application thereof |
| CN107151728A (en) * | 2017-05-08 | 2017-09-12 | 三河市炬峰生物能源有限公司 | A kind of genetically engineered soybean oil type metal heat treatmet quenching oil and preparation method thereof |
| WO2019006660A1 (en) * | 2017-07-04 | 2019-01-10 | 江苏鑫露新材料股份有限公司 | Overspeed quenching oil composition having excellent cooling rate stability, and preparation method therefor |
| CN110358893A (en) * | 2019-07-25 | 2019-10-22 | 诸暨市裕荣弹簧有限公司 | A kind of preparation process of scroll spring |
| CN112094991A (en) * | 2020-09-27 | 2020-12-18 | 上海中孚特种油品有限公司 | Environment-friendly high-temperature isothermal graded quenching oil and preparation method thereof |
| CN113755674A (en) * | 2021-07-20 | 2021-12-07 | 宁国市华丰耐磨材料有限公司 | Quenching oil composition |
-
1992
- 1992-05-15 CN CN 92103404 patent/CN1032314C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1060799C (en) * | 1995-09-08 | 2001-01-17 | 国际壳牌研究有限公司 | Polyolefin-substituted dicarboxylic acid or anhydride ester derivatives |
| CN102212662A (en) * | 2011-06-09 | 2011-10-12 | 上海德润宝特种润滑剂有限公司 | Ultra quick quenching oil and preparation method thereof |
| CN102212662B (en) * | 2011-06-09 | 2012-10-03 | 上海德润宝特种润滑剂有限公司 | Ultra quick quenching oil and preparation method thereof |
| CN103667629A (en) * | 2012-09-20 | 2014-03-26 | 中国石油化工股份有限公司 | Low-temperature tempering method |
| CN105950842A (en) * | 2016-04-28 | 2016-09-21 | 昌利锻造有限公司 | Quenching oil for bearing end caps |
| CN106435110A (en) * | 2016-09-20 | 2017-02-22 | 中国石油化工股份有限公司 | Quenching oil composition and application thereof |
| CN106435111A (en) * | 2016-11-03 | 2017-02-22 | 金福英 | Efficient bright quenching oil and preparation method thereof |
| CN107151728A (en) * | 2017-05-08 | 2017-09-12 | 三河市炬峰生物能源有限公司 | A kind of genetically engineered soybean oil type metal heat treatmet quenching oil and preparation method thereof |
| CN107151728B (en) * | 2017-05-08 | 2018-11-02 | 三河市炬峰生物能源有限公司 | A kind of genetically engineered soybean oil type metal heat treatmet quenching oil and preparation method thereof |
| WO2019006660A1 (en) * | 2017-07-04 | 2019-01-10 | 江苏鑫露新材料股份有限公司 | Overspeed quenching oil composition having excellent cooling rate stability, and preparation method therefor |
| CN110358893A (en) * | 2019-07-25 | 2019-10-22 | 诸暨市裕荣弹簧有限公司 | A kind of preparation process of scroll spring |
| CN112094991A (en) * | 2020-09-27 | 2020-12-18 | 上海中孚特种油品有限公司 | Environment-friendly high-temperature isothermal graded quenching oil and preparation method thereof |
| CN113755674A (en) * | 2021-07-20 | 2021-12-07 | 宁国市华丰耐磨材料有限公司 | Quenching oil composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1032314C (en) | 1996-07-17 |
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