CN107841355A - A kind of boiler oil containing industrial fusel and preparation method thereof - Google Patents

A kind of boiler oil containing industrial fusel and preparation method thereof Download PDF

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Publication number
CN107841355A
CN107841355A CN201711373500.XA CN201711373500A CN107841355A CN 107841355 A CN107841355 A CN 107841355A CN 201711373500 A CN201711373500 A CN 201711373500A CN 107841355 A CN107841355 A CN 107841355A
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parts
fusel
industrial
gained
industrial fusel
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CN107841355B (en
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李法香
孔永平
陈荣霞
刘建付
王素勤
郑冀鲁
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Henan Longzheng Bioenergy Co ltd
Henan Yulong Science And Technology Research Institute Co ltd
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Zhengzhou Star Creation Energy Technology Co Ltd
HENAN LONGZHENG BIOLOGICAL ENERGY Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/28—Organic compounds containing silicon

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Detergent Compositions (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses a kind of boiler oil containing industrial fusel, it is made up of the raw material of following mass percent：24 parts of industrial 70 80 parts of fusel, 20 30 parts of durol, 25 parts of butanone, castor oil and ethylene oxide condensate, 36 parts of tween, 24 parts of NPE, 38 parts of silane coupler, Na2O25 10 parts.The main material of boiler oil prepared by the present invention is industrial fusel, and raw material sources are secure, cost is low；The calorific value of this boiler oil is up to 9600Kcal/kg, the 8000Kcal/kg of calorific value about 6000 of the existing boiler oil prepared using methanol.

Description

A kind of boiler oil containing industrial fusel and preparation method thereof
Technical field
The invention belongs to technical field of fuel oil, and in particular to a kind of boiler oil containing industrial fusel and its preparation Method.
Background technology
Methanol is important industrial chemicals, and clean fuel.Greatly develop ammonia from coal, and be processed as alcohol fuel with Fossil energy is substituted, is the needs of development of chemical industry.But during ammonia from coal, generate substantial amounts of with pungent Stink industry fusel, the main component of fusel is methanol, and impurity mainly has water, polyalcohol and amine.The calorific value of methanol only has 5000Kcal/kg, the calorific value of fusel is lower, how to improve the calorific value of fusel, be allowed to be applied to Industrial Boiler, kiln field be The problem of in the urgent need to address.
The content of the invention
It is an object of the invention to overcome the shortcomings of existing fusel reutilization technology, there is provided a kind of containing industrial fusel Boiler oil and preparation method thereof.
The purpose of the present invention is realized in the following manner：
A kind of boiler oil containing industrial fusel, is made up of the raw material of following mass percent：Industrial fusel 70-80 parts, Durol 20-30 parts, butanone 2-5 parts, castor oil and ethylene oxide condensate 2-4 parts, tween 3-6 parts, polyoxyethylene nonyl phenyl second Alkene ether 2-4 parts, silane coupler 3-8 parts, Na2O25-10 parts.
The industrial fusel is made up of the raw material of following mass percent：Methanol 43.10-52.40 parts, ethanol 10.27- 14.33 parts, propyl alcohol 0.35-0.49 parts, butanol 0.17-0.26 parts, moisture 31.54-36.91 parts, trimethylamine 0.001-0.002 Part.
The preparation method of boiler oil containing industrial fusel described above, comprises the following steps：
（1）Industrial fusel is filtered, removes upper strata floating object；
（2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
（3）According to acid-alcohol ratio 1:0.0005-1:0.005, aluminium borate is added into step（2）In the industrial fusel of gained, 30- is stirred 50min, precipitate acid sludge of draining；Add Na2CO3Neutralized, precipitate residue of draining；
（4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
（5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
（6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 30-50min is stirred, you can boiler oil is made.
Relative to prior art, the present invention is first with aluminium borate to industrial fusel pickling, then uses Na2CO3Neutralized, can be had Effect removes the stink of fusel；Butanone is dissolved in durol, is then re-dissolved in fusel, the calorific value of boiler oil can be improved； Na2O2For oxygenation agent, the oxygen content of fuel oil is improved, fuel oil is fully burnt；Castor oil and ethylene oxide condensate are scattered Agent, promote the uniform mixing between different material, solution is turned into homogeneous single-phase；Tween, NPE are emulsification Agent, the surface tension between material is reduced, improve compatibility；Silane coupler is adhesive, improves the knot between different functional groups Performance is closed, is allowed to be tightly combined.Boiler oil, production process three-waste free discharge, wiper ring are produced under normal temperature and pressure of the present invention Protect.The main material of boiler oil prepared by the present invention is industrial fusel, and raw material sources are secure, cost is low；This boiler oil The calorific value of oil is up to 9600Kcal/kg, the calorific value about 6000-8000Kcal/ of the existing boiler oil prepared using methanol kg。
Embodiment
Castor oil is commercially available with ethylene oxide condensate, purchased from haian Guoli Chemical Co., Ltd.；Industrial fusel is city Sell, purchased from Hebi Coal Industry Group.
Embodiment 1：
A kind of boiler oil containing industrial fusel, is made up of the raw material of following mass percent：Industrial fusel 70-80 parts, Durol 20-30 parts, butanone 2-5 parts, castor oil and ethylene oxide condensate 2-4 parts, tween 3-6 parts, polyoxyethylene nonyl phenyl second Alkene ether 2-4 parts, silane coupler 3-8 parts, Na2O25-10 parts.
The industrial fusel is made up of the raw material of following mass percent：Methanol 43.10-52.40 parts, ethanol 10.27- 14.33 parts, propyl alcohol 0.35-0.49 parts, butanol 0.17-0.26 parts, moisture 31.54-36.91 parts, trimethylamine 0.001-0.002 Part.
The preparation method of boiler oil containing industrial fusel described above, comprises the following steps：
（1）Industrial fusel is filtered, removes upper strata floating object；
（2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
（3）According to acid-alcohol ratio 1:0.0005-1:0.005, aluminium borate is added into step（2）In the industrial fusel of gained, 30- is stirred 50min, precipitate acid sludge of draining；Add Na2CO3Neutralized, precipitate residue of draining；
（4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
（5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
（6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 30-50min is stirred, you can boiler oil is made.
Embodiment 2：
A kind of boiler oil containing industrial fusel, is made up of the raw material of following mass percent：Industrial fusel 70kg, equal four Toluene 20kg, butanone 2kg, castor oil and ethylene oxide condensate 2kg, tween 3kg, NPE 2kg, silane are even Join agent 3kg, Na2O25kg。
Industrial fusel is made up of the raw material of following mass percent：Methanol 43.10kg, ethanol 10.27kg, propyl alcohol 0.35kg, butanol 0.17kg, moisture 31.54kg, trimethylamine 0.001kg.
The preparation method of boiler oil containing industrial fusel described above, comprises the following steps：
（1）Industrial fusel is filtered, removes upper strata floating object；
（2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
（3）According to acid-alcohol ratio 1:0.0005, aluminium borate is added into step（2）In the industrial fusel of gained, 30min, precipitation are stirred Drain acid sludge；Add Na2CO3Neutralized, precipitate residue of draining；
（4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
（5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
（6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 30min is stirred, you can boiler oil is made.
Embodiment 3：
A kind of boiler oil containing industrial fusel, is made up of the raw material of following mass percent：Industrial fusel 72kg, equal four Toluene 22kg, butanone 2.5kg, castor oil and ethylene oxide condensate 2.4kg, tween 3.5kg, NPE 2.4kg, silane coupler 4kg, Na2O26kg。
Industrial fusel is made up of the raw material of following mass percent：Methanol 45.62kg, ethanol 11.05kg, propyl alcohol 0.38kg, butanol 0.19kg, moisture 32.28kg, trimethylamine 0.0012kg.
The preparation method of boiler oil containing industrial fusel described above, comprises the following steps：
（1）Industrial fusel is filtered, removes upper strata floating object；
（2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
（3）According to acid-alcohol ratio 1:0.001, aluminium borate is added into step（2）In the industrial fusel of gained, 34min, precipitation row are stirred Fall acid sludge；Add Na2CO3Neutralized, precipitate residue of draining；
（4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
（5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
（6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 34min is stirred, you can boiler oil is made.
Embodiment 4：
A kind of boiler oil containing industrial fusel, is made up of the raw material of following mass percent：Industrial fusel 74kg, equal four Toluene 24kg, butanone 3kg, castor oil and ethylene oxide condensate 2.8kg, tween 4kg, NPE 2.8kg, silicon Alkane coupling agent 5kg, Na2O27kg。
Industrial fusel is made up of the raw material of following mass percent：Methanol 47.25kg, ethanol 12.23kg, propyl alcohol 0.40kg, butanol 0.20kg, moisture 33.71kg, trimethylamine 0.0014kg.
The preparation method of boiler oil containing industrial fusel described above, comprises the following steps：
（1）Industrial fusel is filtered, removes upper strata floating object；
（2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
（3）According to acid-alcohol ratio 1:0.002, aluminium borate is added into step（2）In the industrial fusel of gained, 38min, precipitation row are stirred Fall acid sludge；Add Na2CO3Neutralized, precipitate residue of draining；
（4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
（5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
（6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 38min is stirred, you can boiler oil is made.
Embodiment 5：
A kind of boiler oil containing industrial fusel, is made up of the raw material of following mass percent：Industrial fusel 76kg, equal four Toluene 26kg, butanone 3.5kg, castor oil and ethylene oxide condensate 3.2kg, tween 4.5kg, NPE 3.2kg, silane coupler 6kg, Na2O28kg。
Industrial fusel is made up of the raw material of following mass percent：Methanol 49.03kg, ethanol 13.41kg, propyl alcohol 0.42kg, butanol 0.22kg, moisture 34.62kg, trimethylamine 0.0016kg.
The preparation method of boiler oil containing industrial fusel described above, comprises the following steps：
（1）Industrial fusel is filtered, removes upper strata floating object；
（2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
（3）According to acid-alcohol ratio 1:0.003, aluminium borate is added into step（2）In the industrial fusel of gained, 42min, precipitation row are stirred Fall acid sludge；Add Na2CO3Neutralized, precipitate residue of draining；
（4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
（5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
（6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 42min is stirred, you can boiler oil is made.
Embodiment 6：
A kind of boiler oil containing industrial fusel, is made up of the raw material of following mass percent：Industrial fusel 78kg, equal four Toluene 28kg, butanone 4kg, castor oil and ethylene oxide condensate 3.6kg, tween 5kg, NPE 3.6kg, silicon Alkane coupling agent 7kg, Na2O29kg。
Industrial fusel is made up of the raw material of following mass percent：Methanol 50.59kg, ethanol 14.08kg, propyl alcohol 0.45kg, butanol 0.24kg, moisture 35.86kg, trimethylamine 0.0018kg.
The preparation method of boiler oil containing industrial fusel described above, comprises the following steps：
（1）Industrial fusel is filtered, removes upper strata floating object；
（2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
（3）According to acid-alcohol ratio 1:0.004, aluminium borate is added into step（2）In the industrial fusel of gained, 46min, precipitation row are stirred Fall acid sludge；Add Na2CO3Neutralized, precipitate residue of draining；
（4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
（5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
（6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 46min is stirred, you can boiler oil is made.
Embodiment 7：
A kind of boiler oil containing industrial fusel, is made up of the raw material of following mass percent：Industrial fusel 80kg, equal four Toluene 30kg, butanone 5kg, castor oil and ethylene oxide condensate 4kg, tween 6kg, NPE 4kg, silane are even Join agent 8kg, Na2O210kg。
Industrial fusel is made up of the raw material of following mass percent：Methanol 52.40kg, ethanol 14.33kg, propyl alcohol 0.49kg, butanol 0.26kg, moisture 36.91kg, trimethylamine 0.002kg.
The preparation method of boiler oil containing industrial fusel described above, comprises the following steps：
（1）Industrial fusel is filtered, removes upper strata floating object；
（2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
（3）According to acid-alcohol ratio 1:0.005, aluminium borate is added into step（2）In the industrial fusel of gained, 50min, precipitation row are stirred Fall acid sludge；Add Na2CO3Neutralized, precipitate residue of draining；
（4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
（5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
（6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 50min is stirred, you can boiler oil is made.
The performance of boiler oil prepared by the present invention is as follows：Flash-point >=73 DEG C, acid number（In terms of KOH）≤ 0.3mg/g, it is close Spend 0.842-0.883g/cm3, ash content≤0.002%, sulfur content≤0.01%, copper corrosion（50 DEG C, 3h）Less than 1 grade, motion is viscous Degree≤6.1mm2/ s, condensation point≤- 10 DEG C, cold filter plugging point≤- 6 DEG C, calorific value >=9600Kcal/kg, reach GB25989-2010《Stove is used Fuel oil》National standard.
Above-described is only the preferred embodiment of the present invention, it is noted that for those skilled in the art, Under the premise of general idea of the present invention is not departed from, some changes and improvements can also be made, these should also be considered as the present invention's Protection domain.

Claims (3)

  1. A kind of 1. boiler oil containing industrial fusel, it is characterised in that：It is made up of the raw material of following mass percent：Industry Fusel 70-80 parts, durol 20-30 parts, butanone 2-5 parts, castor oil and ethylene oxide condensate 2-4 parts, tween 3-6 parts, NPE 2-4 parts, silane coupler 3-8 parts, Na2O25-10 parts.
  2. 2. the boiler oil according to claim 1 containing industrial fusel, it is characterised in that：The industrial fusel by with The raw material composition of lower mass percent：Methanol 43.10-52.40 parts, ethanol 10.27-14.33 parts, propyl alcohol 0.35-0.49 parts, fourth Alcohol 0.17-0.26 parts, moisture 31.54-36.91 parts, trimethylamine 0.001-0.002 parts.
  3. 3. the preparation method of the boiler oil containing industrial fusel as described in claim 1-2 is any, it is characterised in that：Bag Include following steps：
    （1）Industrial fusel is filtered, removes upper strata floating object；
    （2）By step（1）The fusel of gained carries out standing sedimentation, discharges the moisture of bottom；
    （3）According to acid-alcohol ratio 1:0.0005-1:0.005, aluminium borate is added into step（2）In the industrial fusel of gained, 30- is stirred 50min, precipitate acid sludge of draining；Add Na2CO3Neutralized, precipitate residue of draining；
    （4）By step（3）The industrial fusel of gained, which is put into the funnel equipped with quartz sand, to be filtered, and further goes the removal of impurity；
    （5）Step is weighed in mass ratio（4）Industrial fusel and durol, the butanone of gained, it is under agitation that its is abundant Mixing；
    （6）According to mass ratio successively by castor oil and ethylene oxide condensate, tween, NPE, silane coupled Agent, Na2O2Add step（5）In the mixture of gained, 30-50min is stirred, you can boiler oil is made.
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101724474A (en) * 2008-10-14 2010-06-09 陈若歆 Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101724474A (en) * 2008-10-14 2010-06-09 陈若歆 Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology

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Address after: 459014 Liugou Village, Shaoyuan Town, Jiyuan City, Jiaozuo City, Henan Province

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Correct: Henan Yulong science and Technology Research Institute Co., Ltd.|450000 No. 45, floor 5, unit 1, building 4, No. 26, Dongqing street, high tech Industrial Development Zone, Zhengzhou, Henan Province

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