CN107828306A - A kind of hydrophobicity ship coating that can be self-cleaning - Google Patents
A kind of hydrophobicity ship coating that can be self-cleaning Download PDFInfo
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- CN107828306A CN107828306A CN201711128672.0A CN201711128672A CN107828306A CN 107828306 A CN107828306 A CN 107828306A CN 201711128672 A CN201711128672 A CN 201711128672A CN 107828306 A CN107828306 A CN 107828306A
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- self
- resin
- hydrophobicity
- ship coating
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to a kind of hydrophobicity ship coating that can be self-cleaning, specifically it is made by following component:Resin-oatmeal, liquid paraffin, coupling agent, defoamer, levelling agent, hard barium powder, calcium silicates, nano size Titania, nano level active charcoal, carbonic acid silicon, color stuffing.The present invention adds the titanium oxide of Graphene powder and nano micropore structure in traditional ship coating, the organic pollution of material surface being oxidized quickly can be made to be attached to, become carbon dioxide and water, automatic volatilization elimination reaches self-cleaning effect, it largely avoided the problem of corrosion and marine attaching organism of the seawater on hull influence hull service life, maintenance cost is greatly reduced simultaneously, has filled up ship coating technology blank both domestic and external, the market competitiveness is extremely strong.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of hydrophobicity ship coating that can be self-cleaning.
Background technology
Ship coating is to be used for ship and each position of ocean engineering structure, satisfaction prevent seawater, sea atmosphere corrosion and
Marine organisms adhere to and the general designation of the coating of other particular/special requirements.Therefore need solve corrosion and ocean attachment of the seawater to hull
The problem of biotic influence hull service life.
The content of the invention
In order to solve the above problems, the invention provides a kind of hydrophobicity ship coating that can be self-cleaning.
The present invention is achieved through the following technical solutions：
A kind of hydrophobicity ship coating that can be self-cleaning, according to the mass fraction, is specifically made by following component:Resin-oatmeal 50-
60 parts, liquid paraffin 5-8 parts, coupling agent 1-2 parts, defoamer 1-2 parts, levelling agent 1-2 parts, Graphene powder 1.5-2 parts, hard barium powder
3-5 parts, calcium silicates 6-8 parts, nano size Titania 1-2 parts, nano level active charcoal 0.5-1 parts, carbonic acid silicon 0.2-0.6 parts, face are filled out
Expect 5-8 parts, solvent 100-120 parts；Its preparation method, specially following steps:
(1) resin-oatmeal, liquid paraffin are placed in high mixer, melting 10- is sufficiently mixed at a temperature of 120-130 DEG C
12 minutes, obtain material A；
(2) treat that the material A naturally cools to less than 100 DEG C, be blended with the solvent in the container equipped with dispersion machine,
Then dispersing speed is adjusted to 300-400r/min, is sufficiently stirred the 60-80 seconds, obtain material B；
(3) remaining raw material and the material B are blended, dispersing speed are adjusted to 800-1000r/min, at stirring
3-8 minutes are managed, after the completion of stirring, obtain slurry；
(4) slurry is placed in refiner, and is heated to 50-60 DEG C, be fully ground 5-10 minutes, obtain fine grinding slurry；
(5) by fine grinding slurry 120 mesh of sieving, get product.
Further, the resin-oatmeal, by vinyl chloride-vinyl acetate resin, rosin modified phenolic resin, amino resins, asphalt tree
Fat, vinyl 10-15 in mass ratio:5:20:3:It is made after 1 mixing.
Further, the coupling agent, by dihydro MU, isobutyl ethyl triethoxy silicane 2-5 in mass ratio:After 20 mixing
It is made.
Further, the defoamer, by silicone emulsion, dimethyl silicone polymer 10-15 in mass ratio:Made after 1 mixing
.
Beneficial effects of the present invention：The present invention adds Graphene powder and nano micropore structure in traditional ship coating
Titanium oxide, can make to be attached to the organic pollution of material surface being oxidized quickly, become carbon dioxide and water, wave automatically
Hair elimination reaches self-cleaning effect, and largely avoided corrosion and marine attaching organism of the seawater on hull influences hull service life
Problem, while maintenance cost is greatly reduced, ship coating technology blank both domestic and external is filled up, the market competitiveness is extremely strong.
Embodiment
Embodiment 1
A kind of hydrophobicity ship coating that can be self-cleaning, according to the mass fraction, is specifically made by following component:Resin-oatmeal 50
Part, 5 parts of liquid paraffin, 1 part of coupling agent, 1 part of defoamer, 1 part of levelling agent, 1.5 parts of Graphene powder, 3 parts of hard barium powder, calcium silicates 6
Part, 1 part of nano size Titania, 0.5 part of nano level active charcoal, 0.2 part of carbonic acid silicon, 5 parts of color stuffing, 100 parts of solvent；Its preparation side
Method, specially following steps:
(1) resin-oatmeal, liquid paraffin are placed in high mixer, melting 10- is sufficiently mixed at a temperature of 120-130 DEG C
12 minutes, obtain material A；
(2) treat that the material A naturally cools to less than 100 DEG C, be blended with the solvent in the container equipped with dispersion machine,
Then dispersing speed is adjusted to 300-400r/min, is sufficiently stirred the 60-80 seconds, obtain material B；
(3) remaining raw material and the material B are blended, dispersing speed are adjusted to 800-1000r/min, at stirring
3-8 minutes are managed, after the completion of stirring, obtain slurry；
(4) slurry is placed in refiner, and is heated to 50-60 DEG C, be fully ground 5-10 minutes, obtain fine grinding slurry；
(5) by fine grinding slurry 120 mesh of sieving, get product.
Further, resin-oatmeal, by vinyl chloride-vinyl acetate resin, rosin modified phenolic resin, amino resins, asphalt resin, second
Olefine resin in mass ratio 10:5:20:3:It is made after 1 mixing.
Further, coupling agent is by dihydro MU, isobutyl ethyl triethoxy silicane in mass ratio 2:It is made, disappears after 20 mixing
Infusion, by silicone emulsion, dimethyl silicone polymer in mass ratio 10:It is made after 1 mixing.
Graphene powder makes each composition and hull combination closer, strengthens the adhesive force of coating, and is not susceptible to corrode, and prolongs
Its long service life.
Embodiment 2
A kind of hydrophobicity ship coating that can be self-cleaning, according to the mass fraction, is specifically made by following component:Resin-oatmeal 60
Part, 8 parts of liquid paraffin, 2 parts of coupling agent, 2 parts of defoamer, 2 parts of levelling agent, 2 parts of Graphene powder, 5 parts of hard barium powder, 8 parts of calcium silicates,
2 parts of nano size Titania, 1 part of nano level active charcoal, 0.6 part of carbonic acid silicon, 8 parts of color stuffing, 120 parts of solvent；Its preparation method, tool
Body is following steps:
(1) resin-oatmeal, liquid paraffin are placed in high mixer, melting 10- is sufficiently mixed at a temperature of 120-130 DEG C
12 minutes, obtain material A；
(2) treat that the material A naturally cools to less than 100 DEG C, be blended with the solvent in the container equipped with dispersion machine,
Then dispersing speed is adjusted to 300-400r/min, is sufficiently stirred the 60-80 seconds, obtain material B；
(3) remaining raw material and the material B are blended, dispersing speed are adjusted to 800-1000r/min, at stirring
3-8 minutes are managed, after the completion of stirring, obtain slurry；
(4) slurry is placed in refiner, and is heated to 50-60 DEG C, be fully ground 5-10 minutes, obtain fine grinding slurry；
(5) by fine grinding slurry 120 mesh of sieving, get product.
Further, the resin-oatmeal, by vinyl chloride-vinyl acetate resin, rosin modified phenolic resin, amino resins, asphalt tree
Fat, vinyl in mass ratio 15:5:20:3:It is made after 1 mixing.
Further, the coupling agent, by dihydro MU, isobutyl ethyl triethoxy silicane in mass ratio 5:Made after 20 mixing
.
Further, the defoamer, by silicone emulsion, dimethyl silicone polymer in mass ratio 15:It is made after 1 mixing.
Embodiment 3
A kind of hydrophobicity ship coating that can be self-cleaning, according to the mass fraction, is specifically made by following component:Resin-oatmeal 55
Part, 7 parts of liquid paraffin, 1.5 parts of coupling agent, 1.5 parts of defoamer, 1.5 parts of levelling agent, 1.8 parts of Graphene powder, 4 parts of hard barium powder, silicon
Sour 7 parts of calcium, 1.5 parts of nano size Titania, 0.8 part of nano level active charcoal, 0.4 part of carbonic acid silicon, 6 parts of color stuffing, 110 parts of solvent；
Its preparation method, specially following steps:
(1) resin-oatmeal, liquid paraffin are placed in high mixer, melting 10- is sufficiently mixed at a temperature of 120-130 DEG C
12 minutes, obtain material A；
(2) treat that the material A naturally cools to less than 100 DEG C, be blended with the solvent in the container equipped with dispersion machine,
Then dispersing speed is adjusted to 300-400r/min, is sufficiently stirred the 60-80 seconds, obtain material B；
(3) remaining raw material and the material B are blended, dispersing speed are adjusted to 800-1000r/min, at stirring
3-8 minutes are managed, after the completion of stirring, obtain slurry；
(4) slurry is placed in refiner, and is heated to 50-60 DEG C, be fully ground 5-10 minutes, obtain fine grinding slurry；
(5) by fine grinding slurry 120 mesh of sieving, get product.
Further, the resin-oatmeal, by vinyl chloride-vinyl acetate resin, rosin modified phenolic resin, amino resins, asphalt tree
Fat, vinyl in mass ratio 12:5:20:3:It is made after 1 mixing.
Further, the coupling agent, by dihydro MU, isobutyl ethyl triethoxy silicane in mass ratio 3:Made after 20 mixing
.
Further, the defoamer, by silicone emulsion, dimethyl silicone polymer in mass ratio 12:It is made after 1 mixing.
Comparative example
This comparative example compared with Example 1, is added without nano size Titania and nano level active charcoal, in addition method and step
All same.
By experiment, hydrophobicity ship coating that can be self-cleaning provided by the invention has preferably certainly compared to comparative example
Clean effect and resistance seawater and the performance of organic pollution corrosion, hull cleaning non-corroding for a long time is can effectively ensure that, significantly
Hull maintenance cost is reduced, is worth of widely use.
Finally it should be noted that：The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although
The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing
Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., the protection of the present invention should be included in
Within the scope of.
Claims (8)
1. a kind of hydrophobicity ship coating that can be self-cleaning, it is characterised in that according to the mass fraction, be specifically made by following component:
Resin-oatmeal 50-60 parts, liquid paraffin 5-8 parts, coupling agent 1-2 parts, defoamer 1-2 parts, levelling agent 1-2 parts, Graphene powder 1.5-2
Part, hard barium powder 3-5 parts, calcium silicates 6-8 parts, nano size Titania 1-2 parts, nano level active charcoal 0.5-1 parts, carbonic acid silicon 0.2-
0.6 part, color stuffing 5-8 parts, solvent 100-120 parts；Its preparation method, specially following steps:
(1) resin-oatmeal, liquid paraffin are placed in high mixer, 10-12 points of melting is sufficiently mixed at a temperature of 120-130 DEG C
Clock, obtain material A；
(2) treat that the material A naturally cools to less than 100 DEG C, be blended with the solvent in the container equipped with dispersion machine, then
Dispersing speed is adjusted to 300-400r/min, is sufficiently stirred the 60-80 seconds, obtains material B；
(3) remaining raw material and the material B are blended, dispersing speed is adjusted to 800-1000r/min, stir process 3-
8 minutes, after the completion of stirring, obtain slurry；
(4) slurry is placed in refiner, and is heated to 50-60 DEG C, be fully ground 5-10 minutes, obtain fine grinding slurry；
(5) by fine grinding slurry 120 mesh of sieving, get product.
A kind of 2. hydrophobicity ship coating that can be self-cleaning according to claim 1, it is characterised in that：It is a kind of can be self-cleaning dredge
Water-based ship coating, according to the mass fraction, specifically it is made by following component:55 parts of resin-oatmeal, 7 parts of liquid paraffin, coupling agent 1.5
Part, 1.5 parts of defoamer, 1.5 parts of levelling agent, 1.8 parts of Graphene powder, 4 parts of hard barium powder, 7 parts of calcium silicates, nano size Titania 1.5
Part, 0.8 part of nano level active charcoal, 0.4 part of carbonic acid silicon, 6 parts of color stuffing, 110 parts of solvent.
A kind of 3. hydrophobicity ship coating that can be self-cleaning according to claim 1, it is characterised in that:The resin-oatmeal, by
Vinyl chloride-vinyl acetate resin, rosin modified phenolic resin, amino resins, asphalt resin, vinyl 10-15 in mass ratio:5:20:3:
It is made after 1 mixing.
A kind of 4. hydrophobicity ship coating that can be self-cleaning according to claim 1, it is characterised in that:The resin-oatmeal, by
Vinyl chloride-vinyl acetate resin, rosin modified phenolic resin, amino resins, asphalt resin, vinyl in mass ratio 12:5:20:3:1 is mixed
It is made after conjunction.
A kind of 5. hydrophobicity ship coating that can be self-cleaning according to claim 1, it is characterised in that:The coupling agent, by
Dihydro MU, isobutyl ethyl triethoxy silicane 2-5 in mass ratio:It is made after 20 mixing.
A kind of 6. hydrophobicity ship coating that can be self-cleaning according to claim 1, it is characterised in that:The coupling agent, by
Dihydro MU, isobutyl ethyl triethoxy silicane in mass ratio 3:It is made after 20 mixing.
A kind of 7. hydrophobicity ship coating that can be self-cleaning according to claim 1, it is characterised in that:The defoamer, by
Silicone emulsion, dimethyl silicone polymer 10-15 in mass ratio:It is made after 1 mixing.
A kind of 8. hydrophobicity ship coating that can be self-cleaning according to claim 1, it is characterised in that:The defoamer, by
Silicone emulsion, dimethyl silicone polymer in mass ratio 12:It is made after 1 mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711128672.0A CN107828306A (en) | 2017-11-15 | 2017-11-15 | A kind of hydrophobicity ship coating that can be self-cleaning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711128672.0A CN107828306A (en) | 2017-11-15 | 2017-11-15 | A kind of hydrophobicity ship coating that can be self-cleaning |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107828306A true CN107828306A (en) | 2018-03-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711128672.0A Pending CN107828306A (en) | 2017-11-15 | 2017-11-15 | A kind of hydrophobicity ship coating that can be self-cleaning |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108480550A (en) * | 2018-05-25 | 2018-09-04 | 邹峰 | A kind of preparation method of high-strength corrosion-resisting mold casting coating |
| CN115262273A (en) * | 2022-07-29 | 2022-11-01 | 浙江弘利新材料有限公司 | Surface sizing agent for improving water resistance of paperboard and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267052A (en) * | 2017-08-10 | 2017-10-20 | 合肥市田源精铸有限公司 | A kind of metal underwater paint |
-
2017
- 2017-11-15 CN CN201711128672.0A patent/CN107828306A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267052A (en) * | 2017-08-10 | 2017-10-20 | 合肥市田源精铸有限公司 | A kind of metal underwater paint |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108480550A (en) * | 2018-05-25 | 2018-09-04 | 邹峰 | A kind of preparation method of high-strength corrosion-resisting mold casting coating |
| CN115262273A (en) * | 2022-07-29 | 2022-11-01 | 浙江弘利新材料有限公司 | Surface sizing agent for improving water resistance of paperboard and preparation method thereof |
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Application publication date: 20180323 |