CN107828278A - A kind of packing box printing environment-friendly type aqueous ink and its production technology - Google Patents
A kind of packing box printing environment-friendly type aqueous ink and its production technology Download PDFInfo
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- CN107828278A CN107828278A CN201711098905.7A CN201711098905A CN107828278A CN 107828278 A CN107828278 A CN 107828278A CN 201711098905 A CN201711098905 A CN 201711098905A CN 107828278 A CN107828278 A CN 107828278A
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- packing box
- friendly type
- aqueous ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/04—Printing inks based on proteins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of environment-friendly type aqueous ink of packing box printing, it is characterised in that：Include following component in parts by weight：75 parts of water-soluble resin 35 part, 25 parts of organic pigment 15 part, 15 parts of solvent 10 part, 5 parts of link stuff 3 part, 3 parts of PH conditioning agents 1 part, 8 parts of auxiliary agent 5 part；Wherein, water-soluble resin is one or more mixtures in methyl acrylate, ethyl acrylate, 2 methyl methacrylates, 2 EMAs；The solvent is the mixture of water and organic solvent, and mixed proportion is 89:1.The invention also discloses a kind of production technology of the environment-friendly type aqueous ink of packing box printing.
Description
Technical field
The present invention relates to a kind of packing box printing environment-friendly type aqueous ink and its production technology, belong to water-based ink system
Make technical field.
Background technology
Ink is the important materials for printing, and it is shown pattern, word on stock by printing or air brushing.Oil
Ink is typically made up of link stuff, pigment, filler, auxiliary agent and solvent etc., for books and periodicals, packing and decorating, building decoration and electric wire
The various printings such as road sheet material.As social demand increases, ink kind and yield also respective extension and growth.
But existing ink is typically used as solvent, not only in preparation process using methanol, benzene, ethyl acetate etc.
Inflammable and explosive during preparation, transport, use, security is low, and after being printed onto on packing box, the solvent of residual can be right
The food of packing box causes a certain degree of pollution, and is recycled for the later stage, produces certain environmental pollution for a moment and asks
Topic.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of packing box printing environment-friendly type aqueous ink and its production
Technique, carried out by selecting water to add the mixture of a small amount of organic solvent to be used as solvent, and from water-soluble resin as raw material
The preparation of water-based ink, the harmful components of ink in itself are greatly reduced, also allow for the later stage enters to the product for having printed the ink
Formula processing that row is pollution-free.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of environment-friendly type aqueous ink of packing box printing, it is characterised in that：Include following component in parts by weight：
35 parts -75 parts of water-soluble resin
15 parts -25 parts of organic pigment
10 parts -15 parts of solvent
3 parts -5 parts of link stuff
1 part -3 parts of PH conditioning agents
5 parts -8 parts of auxiliary agent；
Wherein, water-soluble resin is methyl acrylate, ethyl acrylate, 2- methyl methacrylates, ethyl 2-methacrylate
In one or more mixtures；The solvent is the mixture of water and organic solvent, mixed proportion 8-9:1.
A kind of foregoing environment-friendly type aqueous ink of packing box printing, it is characterised in that：The link stuff is starch, albumen
One or more mixtures in matter, animal glue, rosin.
A kind of foregoing environment-friendly type aqueous ink of packing box printing, it is characterised in that：The auxiliary agent is to include dispersant
And lubricant, the wherein ratio of dispersant and lubricant is 1-1.5:1.
A kind of foregoing environment-friendly type aqueous ink of packing box printing, it is characterised in that：The dispersant be triethyl group oneself
One or more mixtures in base phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol.
A kind of foregoing environment-friendly type aqueous ink of packing box printing, it is characterised in that：The lubricant is mineral oil.
A kind of production technology of the environment-friendly type aqueous ink of the printing of packing box as the aforementioned, it is characterised in that：Including as follows
Step：
（1）Water-soluble resin, solvent are added into reaction unit, control the temperature of reaction unit to be protected between 85 DEG C -95 DEG C
It is mixed evenly after holding 1h-1.5h, forms bed material；
（2）The temperature of reaction unit is reduced to 35 DEG C -40 DEG C, in step（1）Bed material in add PH conditioning agents, by bed material
PH value is adjusted between 7.5-8,
（3）Organic pigment, link stuff and auxiliary agent are added in bed material, is mixed and is ground, water-based ink is made.
A kind of production technology of the foregoing environment-friendly type aqueous ink of packing box printing, it is characterised in that：The step（3）
The fineness of middle grinding is less than 6 μm.
The beneficial effects of the invention are as follows：
1st, by selecting water to add the mixture of a small amount of organic solvent to be used as solvent, and carried out from water-soluble resin as raw material
The preparation of water-based ink, the harmful components of ink in itself are greatly reduced, also allow for the later stage enters to the product for having printed the ink
Formula processing that row is pollution-free；
2nd, pigment can be made to be uniformly dispersed as link stuff by using bioadhesive, makes ink that there is necessary dryness and print
Brush adaptability, and during the later stage recycles, it is degradable, do not pollute the environment.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment 1
The environment-friendly type aqueous ink of a kind of packing box printing, in parts by weight including following component：
55 parts of water-soluble resin
20 parts of organic pigment
12 parts of solvent
4 parts of link stuff
1 part of PH conditioning agents
8 parts of auxiliary agent；
Water-soluble resin is methyl acrylate, the mixture of ethyl acrylate；The solvent is the mixture of water and organic solvent,
Mixed proportion is 8.5:1.The link stuff is starch, the mixture of protein, and the auxiliary agent is to include dispersant and lubricant,
Wherein the ratio of dispersant and lubricant is 1.2:1, dispersant is triethyl group hexyl phosphoric acid, and lubricant is mineral oil.
Pass through 8.5:The solvent of 1 water and the mixture of organic solvent as water-based ink, and select water-soluble resin
The preparation of water-based ink is carried out as raw material, all the components in a small amount of organic solvent dissolved constituent can not only be utilized, greatly
The harmful components of ink in itself are reduced greatly, also allow for the later stage carries out pollution-free formula processing to the product for having printed the ink, its
In selected organic solvent be styrene.
By selecting the mixture of starch, protein to be used as link stuff, pigment is uniformly dispersed, making ink that there is necessity
Dryness and while printing adaptability, because both materials are all bioadhesives, during the later stage recycles,
It is degradable, do not pollute the environment.Lubricant uses mineral oil simultaneously, is equally beneficial for the recycling in later stage, avoids polluting ring
Border.
Embodiment 2
The environment-friendly type aqueous ink of a kind of packing box printing, in parts by weight including following component：
65 parts of water-soluble resin
18 parts of organic pigment
15 parts of solvent
3 parts of link stuff
2 parts of PH conditioning agents
6 parts of auxiliary agent；
Water-soluble resin is methyl acrylate, the mixture of ethyl acrylate；The solvent is the mixture of water and organic solvent,
Mixed proportion is 9:1.The link stuff is starch, the mixture of protein, and the auxiliary agent is to include dispersant and lubricant, its
The ratio of middle dispersant and lubricant is 1.5:1, dispersant is triethyl group hexyl phosphoric acid, and lubricant is mineral oil.
Pass through 9:The solvent of 1 water and the mixture of organic solvent as water-based ink, and made from water-soluble resin
The preparation of water-based ink is carried out for raw material, all the components in a small amount of organic solvent dissolved constituent can not only be utilized, significantly
The harmful components of ink in itself are reduced, also allow for the later stage carries out pollution-free formula processing to the product for having printed the ink, wherein
Selected organic solvent is styrene.
By selecting the mixture of starch, protein to be used as link stuff, pigment is uniformly dispersed, making ink that there is necessity
Dryness and while printing adaptability, because both materials are all bioadhesives, during the later stage recycles,
It is degradable, do not pollute the environment.Lubricant uses mineral oil simultaneously, is equally beneficial for the recycling in later stage, avoids polluting ring
Border.
In summary, a kind of packing box printing environment-friendly type aqueous ink and its production technology provided by the invention, pass through
Selection water adds the mixture of a small amount of organic solvent as solvent, and carries out water-based ink as raw material from water-soluble resin
Prepare, greatly reduce the harmful components of ink in itself, also allow for the later stage carries out pollution-free formula to the product for having printed the ink
Processing.
General principle, the main features and advantages of the present invention have been shown and described above.The technical staff of the industry should
Understand, the present invention is not limited to the above embodiments, the original for simply illustrating the present invention described in above-described embodiment and specification
Reason, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes and improvements
It all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its equivalent
Boundary.
Claims (7)
- A kind of 1. environment-friendly type aqueous ink of packing box printing, it is characterised in that：Include following component in parts by weight：35 parts -75 parts of water-soluble resin15 parts -25 parts of organic pigment10 parts -15 parts of solvent3 parts -5 parts of link stuff1 part -3 parts of PH conditioning agents5 parts -8 parts of auxiliary agent；Wherein, water-soluble resin is methyl acrylate, ethyl acrylate, 2- methyl methacrylates, ethyl 2-methacrylate In one or more mixtures；The solvent is the mixture of water and organic solvent, mixed proportion 8-9:1.
- A kind of 2. environment-friendly type aqueous ink of packing box printing according to claim 1, it is characterised in that：The link stuff For one or more mixtures in starch, protein, animal glue, rosin.
- A kind of 3. environment-friendly type aqueous ink of packing box printing according to claim 1, it is characterised in that：The auxiliary agent is Including dispersant and lubricant, the wherein ratio of dispersant and lubricant is 1-1.5:1.
- A kind of 4. environment-friendly type aqueous ink of packing box printing according to claim 3, it is characterised in that：The dispersant For one or more mixtures in triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol.
- A kind of 5. environment-friendly type aqueous ink of packing box printing according to claim 3, it is characterised in that：The lubricant For mineral oil.
- 6. a kind of production technology of the environment-friendly type aqueous ink of packing box printing in 1-5 such as claim as described in any one, It is characterized in that：Comprise the following steps：（1）Water-soluble resin, solvent are added into reaction unit, control the temperature of reaction unit to be protected between 85 DEG C -95 DEG C It is mixed evenly after holding 1h-1.5h, forms bed material；（2）The temperature of reaction unit is reduced to 35 DEG C -40 DEG C, in step（1）Bed material in add PH conditioning agents, by bed material PH value is adjusted between 7.5-8,（3）Organic pigment, link stuff and auxiliary agent are added in bed material, is mixed and is ground, water-based ink is made.
- A kind of 7. production technology of the environment-friendly type aqueous ink of packing box printing according to claim 6, it is characterised in that： The step（3）The fineness of middle grinding is less than 6 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711098905.7A CN107828278A (en) | 2017-11-09 | 2017-11-09 | A kind of packing box printing environment-friendly type aqueous ink and its production technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711098905.7A CN107828278A (en) | 2017-11-09 | 2017-11-09 | A kind of packing box printing environment-friendly type aqueous ink and its production technology |
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| Publication Number | Publication Date |
|---|---|
| CN107828278A true CN107828278A (en) | 2018-03-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711098905.7A Pending CN107828278A (en) | 2017-11-09 | 2017-11-09 | A kind of packing box printing environment-friendly type aqueous ink and its production technology |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109401427A (en) * | 2018-10-11 | 2019-03-01 | 厦门欧化实业有限公司 | A kind of colored ink and preparation method thereof on packing |
| CN109517436A (en) * | 2018-12-12 | 2019-03-26 | 杭州全为包装印刷有限公司 | A kind of water-based ink and the preparation method and application thereof |
| CN112280378A (en) * | 2020-11-16 | 2021-01-29 | 黄展才 | Environment-friendly water-based ink for printing packaging cartons and preparation method thereof |
| CN113292767A (en) * | 2021-06-02 | 2021-08-24 | 张家港市黎明化工有限公司 | Renewable resin for edible ink, application and preparation method |
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| WO2008119390A1 (en) * | 2007-04-02 | 2008-10-09 | Inxel Trademark & Patents Sagl | Method for preparing paints and inks using a resin coated pigment |
| CN104031463A (en) * | 2014-07-03 | 2014-09-10 | 繁昌县朱氏印务有限责任公司 | Water-based plastic composite printing ink |
| CN106905773A (en) * | 2015-12-23 | 2017-06-30 | 谈学文 | A kind of fluorescent ink |
| CN107118614A (en) * | 2017-06-22 | 2017-09-01 | 汕头市瑞宇科技有限公司 | A kind of environment-friendly type aqueous ink and preparation method thereof |
-
2017
- 2017-11-09 CN CN201711098905.7A patent/CN107828278A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008119390A1 (en) * | 2007-04-02 | 2008-10-09 | Inxel Trademark & Patents Sagl | Method for preparing paints and inks using a resin coated pigment |
| CN104031463A (en) * | 2014-07-03 | 2014-09-10 | 繁昌县朱氏印务有限责任公司 | Water-based plastic composite printing ink |
| CN106905773A (en) * | 2015-12-23 | 2017-06-30 | 谈学文 | A kind of fluorescent ink |
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Non-Patent Citations (1)
| Title |
|---|
| 周祥兴: "《中国塑料制品配方大全》", 31 May 1999, 中国物质出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109401427A (en) * | 2018-10-11 | 2019-03-01 | 厦门欧化实业有限公司 | A kind of colored ink and preparation method thereof on packing |
| CN109517436A (en) * | 2018-12-12 | 2019-03-26 | 杭州全为包装印刷有限公司 | A kind of water-based ink and the preparation method and application thereof |
| CN112280378A (en) * | 2020-11-16 | 2021-01-29 | 黄展才 | Environment-friendly water-based ink for printing packaging cartons and preparation method thereof |
| CN113292767A (en) * | 2021-06-02 | 2021-08-24 | 张家港市黎明化工有限公司 | Renewable resin for edible ink, application and preparation method |
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Application publication date: 20180323 |
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