CN107825791A - One kind can show polychrome pearly-lustre film and preparation method thereof - Google Patents
One kind can show polychrome pearly-lustre film and preparation method thereof Download PDFInfo
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- CN107825791A CN107825791A CN201711273265.9A CN201711273265A CN107825791A CN 107825791 A CN107825791 A CN 107825791A CN 201711273265 A CN201711273265 A CN 201711273265A CN 107825791 A CN107825791 A CN 107825791A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B2038/0052—Other operations not otherwise provided for
- B32B2038/0076—Curing, vulcanising, cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/409—Iridescent, pearlescent surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/752—Corrosion inhibitor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2451/00—Decorative or ornamental articles
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses one kind can show polychrome pearly-lustre film, including PVC base film layers, solidify in the pearl powder layer and hyaline layer of PVC base film layers upper surface, wherein contain adhesion agent in pearl powder layer, it is made up of the composition of following mass fraction, polyisoprene 20% ~ 30%, photo-curing material 40% ~ 50%, sensitising agent 3% ~ 6%, activated monomer 15% ~ 25% and auxiliary agent 3% ~ 7% form, visible-light curing pearl powder layer is used in the present invention, hardening time is short, volatilized without pernicious gas, light source is harmless, safety and environmental protection, it is easy to operate, construction cost can be greatly lowered.
Description
Technical field
The invention belongs to PVC decorative Film technical field, and in particular to one kind can show polychrome pearly-lustre film and its preparation side
Method.
Background technology
With the development in epoch, PVC film also just with its good performance, simple technique and other plurality of advantages gradually
The favor of people has been won, has been received and is approved by increasing people, has been the favorite of building trade in American-European countries's PVC film,
PVC film is seen everywhere in daily life.In Germany, 40% furniture is all to make surfacing with PVC film, is seen
To those natural in color, the desk that color is magnificent, rich and varied, pattern is beautiful, style is elegant and high-grade, bookshelf, sofa, kitchen
Cabinet, who will not also associate them together with street corner those scarred " white garbages ", less will recognize that exactly PVC film
Impart their so beautiful coats.PVC material has the characteristics that lightweight, heat-insulated, insulation, moistureproof, fire-retardant, easy construction,
Its specification, color, pattern are various, are rich in dicoration, can be applied to a series of dress such as room interior wall, window, floor and furred ceiling
Decorations, are one of ornament materials being most widely used in plastic materials.PVC decorative material product has been widely applied at present
In daily life, production, such as PVC monochrome films cosmetic sheet, PVC high temperature resistant interior trims film, PVC transparent film, PVC wood
The smooth decorating film of line floor film, PVC, PVC light diaphragms etc., still, with the continuous improvement of people's demand, for pearlescent pigment
Caused decorative effect favor, which has, to be added, and therefore, a kind of PVC films that can have pearly-lustre decorative effect of research and development turn into the industry
The problem of more paying close attention to.
Patent CN203974188U discloses a kind of production method in pearly-lustre PVC film, and pearl essence and adhesive are mixed
Compound is placed between PVC base film layers and PVC transparent piece, while is processed by drawing method, forms pearl powder layer, and this method needs
The PVC base film layers of sizing are placed in solidification more than 48h at 200 DEG C, it is time-consuming longer, and during solidification, there are about
60% organic solvent will be evaporated into air, and while causing seriously to pollute to air, also workshop worker can be made
Into certain actual bodily harm, the traditional drying time is oversize in addition, can cause a uncontrollable factor in the drying process（Such as ash
Dirt, make moist）Infringement to product, cause the rise of product percent defective in production process.
In order to further improve the deficiency of above-mentioned curing, those skilled in the art use the method that ultraviolet light solidifies,
Qualitatively PVC base film layers, this method substantially reduce the solidification dry time for solidification, reduce the percent defective of product；It is but ultraviolet
Photocuring has higher requirements to light source, and optical source wavelength is narrow, and solidification cost is high, and Long Term Contact ultraviolet, and damage is easily caused to human body
Wound, environmental safety is poor, and thick film curability is bad.
The content of the invention
It is an object of the invention to：In order to solve the problems, such as that the prior art in above-mentioned background technology is present, there is provided a kind of
Polychrome pearly-lustre film and preparation method thereof can be shown, the solidification of pearl layer, harmless, safety collar are completed using visible ray
Protect, it is easy to operate, construction cost can be greatly lowered.
The technical solution adopted for the present invention to solve the technical problems is：
One kind can show polychrome pearly-lustre film, including PVC base film layers, solidify in PVC base film layers upper surface pearl powder layer and
Hyaline layer, contain adhesion agent in pearl powder layer, be made up of the composition of following mass fraction：Polyisoprene 20% ~ 30%, photocuring
Material 40% ~ 50%, sensitising agent 3% ~ 6%, activated monomer 15% ~ 25% and auxiliary agent 3% ~ 7% form.
Preferably, photo-curing material is VLC-720 resins, VLC-760 resins or VLC-630 resins.
Preferably, sensitising agent is the sensitising agent of commercially available model 184, the sensitising agent of commercially available model 1173, commercially available model
For 907 sensitising agent.
Preferably, activated monomer is 2- phenoxy group second propyl acrylates (PHEA), propylene glycol diacrylate
(DPGDA), tripropylene glycol diacrylate (TPGDA) or trimethylolpropane trimethacrylate（TMPTA）.
Preferably, auxiliary agent is dispersant, defoamer or levelling agent one or more therein.
It is highly preferred that dispersant is the one or more in Sodium Polyacrylate or sodium citrate；Defoamer disappears for organosilicon
One or more in infusion, polyether antifoam agent, mineral oil antifoam agent；Levelling agent is polyurethane levelling agent, polyacrylate stream
One or more in flat agent, organosilicon levelling agent.
Preferably, the gross thickness of PVC base film layers, pearl powder layer and PVC transparent piece is 20 ~ 120um.
Preferably, hyaline layer is transparent PVC film or transparent PET film.
The invention also discloses a kind of method for showing polychrome pearly-lustre film, comprise the following steps：
A, pearl essence is mixed with bonding agent, stirred, the pearl essence mixed is uniformly applied to by PVC bases by coating machine
On membrane surface, pearl powder layer is tentatively shaped using blower fan or heating tube；
B, 1 ~ 2min of cure under visible light is placed in after the PVC base film layers tentatively shaped are wound；
C, the PVC film being cured is placed on make-up machine, compound plus slide progress on pearl powder layer surface, producing to show
Polychrome pearly-lustre film.
Preferably, make-up machine temperature is 170 DEG C ~ 190 DEG C, and speed is 10 ~ 15m/min；Visible light illumination is 50 ~ 70mW/
cm2, irradiation distance is 50 ~ 70cm.
Compared with prior art, the invention has the advantages that：
（1）Contain photo-curing material, active material and sensitising agent, after the irradiation of visible ray, light in pearl layer in the present invention
Quick dose of rapid cleavage is sent out into free radical or cation, the free radical or cation with the ethylene linkage in photo-curing material and activated monomer
Raw rapid polymerisation forms dry paint film, and whole reaction only needs 1 ~ 2min, instantaneous solidification pearl layer, realizes to pearl layer
Wink-dry, greatly improve operating efficiency；
（2）The present invention is entered by the way that pearl essence and adhesive mixture are placed between PVC base film layers and hyaline layer by drawing method
Row processing, forms pearl powder layer, PVC film is had pearly-lustre decorative effect, strengthens its mechanical strength, expands use range, can use
In the decoration of the material such as body sticker and building, exhibit.
（3）Compared with traditional heat cure, it is seen that photocuring has dangerous peroxide without adding, without cumbersome
De-aeration, the time of solidify afterwards greatly reduces, and the volatilization of the organic solvent such as styrene has been lowered to minimum point, improves life
While producing efficiency, construction cost is greatly lowered；
（4）Compared with traditional ultraviolet light solidification, it is seen that requirement of the photocuring to light source is relatively low, summer outdoor solar light, searchlight
Deng all can be used, production cost is reduced, and harmless；Optional wave-length coverage is wide, and the visible ray of 380 ~ 780nm scopes is all
It is curable, safety and environmental protection, it is widely used；
（5）Pearl layer hardening time in the present invention is only 1 ~ 2min, shortens the production time of pearly-lustre film, reduces production work
Sequence, continuous or automated production can be achieved, greatly reduce product percent defective, obtained pearly-lustre film storage period is longer；
（6）Pearly-lustre film produced by the present invention has excellent adhesive force at initial stage, and also has well under the conditions of hot and humid
Adhesive force, and can water-fast, organic solvent-resistant and acid-alkali-corrosive-resisting, be also applicable to high-end in the display devices such as LCD, PDP
Optical film material field.
Brief description of the drawings
Fig. 1 is the structural representation produced by the present invention for showing polychrome pearly-lustre film
Wherein：1st, PVC base film layers 2, pearl powder layer 3, hyaline layer.
Embodiment
Presently in connection with embodiment and accompanying drawing to inventing further details of explanation.
Embodiment 1
One kind can show polychrome pearly-lustre film, by PVC base film layers 1, solidify in PVC base film layers upper surface pearl powder layer 2 and
Hyaline layer 3 forms, and hyaline layer is transparent PVC film, contains adhesion agent in pearl powder layer, includes the composition of following mass fraction：It is poly-
Isoprene 25%, VLC-720 resins 40%, the sensitising agent 6% of commercially available model 184,2- phenoxy group second propyl acrylates
(PHEA) 25% and sodium citrate 4% form.
This can show that the preparation process of polychrome pearly-lustre film is as follows：
A, pearl essence is mixed with bonding agent, stirred, the pearl essence mixed is uniformly applied to by PVC bases by coating machine
On membrane surface, pearl powder layer is tentatively shaped using blower fan or heating tube；
B, it is placed in cure under visible light 1min after the PVC base film layers tentatively shaped are wound, it is seen that illuminance 50mW/cm2, shine
It is 50cm to penetrate distance；
C, the PVC film being cured is placed on make-up machine, compound, make-up machine temperature is carried out plus slide on pearl powder layer surface
For 170 DEG C, speed 10m/min, polychrome pearly-lustre film can be shown by producing.
Embodiment 2
One kind can show polychrome pearly-lustre film, by PVC base film layers 1, solidify in PVC base film layers upper surface pearl powder layer 2 and
Hyaline layer 3 forms, and hyaline layer is transparent PET film, contains adhesion agent in pearl powder layer, includes the composition of following mass fraction：It is poly-
Isoprene 20%, VLC-760 resins 50%, the sensitising agent 5% of commercially available model 1173, propylene glycol diacrylate (DPGDA)
20% and polyether antifoam agent 5% form.
This can show that the preparation process of polychrome pearly-lustre film is as follows：
A, pearl essence is mixed with bonding agent, stirred, the pearl essence mixed is uniformly applied to by PVC bases by coating machine
On membrane surface, pearl powder layer is tentatively shaped using blower fan or heating tube；
B, it is placed in cure under visible light 1.5min after the PVC base film layers tentatively shaped are wound, it is seen that illuminance 60mW/cm2,
Irradiation distance is 60cm；
C, the PVC film being cured is placed on make-up machine, compound, make-up machine temperature is carried out plus slide on pearl powder layer surface
For 180 DEG C, speed 12m/min, polychrome pearly-lustre film can be shown by producing.
Embodiment 3
One kind can show polychrome pearly-lustre film, by PVC base film layers 1, solidify in PVC base film layers upper surface pearl powder layer 2 and
Hyaline layer 3 forms, and hyaline layer is transparent PET film, contains adhesion agent in pearl powder layer, includes the composition of following mass fraction：It is poly-
Isoprene 30%, VLC-630 resins 45%, sensitising agent 3%, the trimethylolpropane trimethacrylate of commercially available model 907
（TMPTA）15% and polyurethane levelling agent 7% form.
This can show that the preparation process of polychrome pearly-lustre film is as follows：
A, pearl essence is mixed with bonding agent, stirred, the pearl essence mixed is uniformly applied to by PVC bases by coating machine
On membrane surface, pearl powder layer is tentatively shaped using blower fan or heating tube；
B, it is placed in cure under visible light 2min after the PVC base film layers tentatively shaped are wound, it is seen that illuminance 70mW/cm2, shine
It is 70cm to penetrate distance；
C, the PVC film being cured is placed on make-up machine, compound, make-up machine temperature is carried out plus slide on pearl powder layer surface
For 190 DEG C, speed 15m/min, polychrome pearly-lustre film can be shown by producing.
Comparative example 1
One kind can show polychrome pearly-lustre film, by PVC base film layers 1, solidify in PVC base film layers upper surface pearl powder layer 2 and
Hyaline layer 3 forms, and hyaline layer is transparent PVC film, contains adhesion agent in pearl powder layer, includes the composition of following mass fraction：It is poly-
Isoprene 25%, epoxy acrylate 40%, the sensitising agent 6% of commercially available model 184,2- phenoxy group second propyl acrylates
(PHEA) 25% and sodium citrate 4% form.
This can show that the preparation process of polychrome pearly-lustre film is as follows：
A, pearl essence is mixed with bonding agent, stirred, the pearl essence mixed is uniformly applied to by PVC bases by coating machine
On membrane surface, pearl powder layer is tentatively shaped using blower fan or heating tube；
B, it is placed in after the PVC base film layers tentatively shaped are wound under ultraviolet light and solidifies 1min；
C, the PVC film being cured is placed on make-up machine, compound, make-up machine temperature is carried out plus slide on pearl powder layer surface
For 170 DEG C, speed 10m/min, polychrome pearly-lustre film can be shown by producing.
Comparative example 2
One kind can show polychrome pearly-lustre film, by PVC base film layers 1, solidify in PVC base film layers upper surface pearl powder layer 2 and
Hyaline layer 3 forms, and hyaline layer is transparent PVC film, contains adhesion agent in pearl powder layer, includes the composition of following mass fraction：It is poly-
Isoprene 25%, VLC-720 resins 39%, methyl ethyl ketone peroxide 0.8%, cobalt naphthenate 0.2%, commercially available model 184 it is photosensitive
Agent 6%, 2- phenoxy group second propyl acrylates (PHEA) 25% and sodium citrate 4% form.
This can show that the preparation process of polychrome pearly-lustre film is as follows：
A, pearl essence is mixed with bonding agent, stirred, the pearl essence mixed is uniformly applied to by PVC bases by coating machine
On membrane surface, pearl powder layer is tentatively shaped using blower fan or heating tube；
B, it is placed in after the PVC base film layers tentatively shaped are wound in 200 DEG C of isothermal curing room and carries out 48h heat cure；
C, the PVC film being cured is placed on make-up machine, compound, make-up machine temperature is carried out plus slide on pearl powder layer surface
For 170 DEG C, speed 10m/min, polychrome pearly-lustre film can be shown by producing.
Performance test
1st, tension test（Tensile strength）
Experimental condition：Sample size is 200mm × 20mm, and batten quantity 15, clamp of stretching tester spacing is 150mm, is used
Cupping machine measures tensile strength respectively, the coupon results averaged as the sample.
2nd, barrier properties for gases is tested
According to GB/T1038-2000《Plastic sheeting and thin slice gas-premeable test method pressure differential method》In required pressure differential method
Measure.
3rd, optical performance test
Experimental condition：Film is put in sphere haze meter and tests its mist degree, the nm of lambda1-wavelength 400nm ~ 700, observation is thin
The influence of film mist degree.
The performance test results of table 1
As shown in Table 1, either visible ray photocuring, ultraviolet light solidification or heat cure, three without big difference, compare
Compared with for, it is seen that when light light and ultraviolet light solidify, the toughness of obtained product is more preferable, and fire resistance and transparent performance are more excellent.
The measure of styrene volatile quantity
Using IR Prestige-21 type pulsed infrared testers, mensuration distance can be shown in polychrome pearly-lustre film horizontal middle
The volatile quantity of styrene at square 15cm（Unit is ppm）, every 5min, measure once, determines 8 times, as a result such as table 2 altogether；
The volatile quantity of the styrene of the different time of table 2 measure
| 5 min | 10min | 15min | 20min | 25min | 30min | 35min | 40min | |
| Embodiment 1 | 45 | 25 | 17 | 5 | 0 | 0 | 0 | 0 |
| Embodiment 2 | 44 | 23 | 18 | 6 | 0 | 0 | 0 | 0 |
| Embodiment 3 | 43 | 24 | 17 | 4 | 0 | 0 | 0 | 0 |
| Comparative example 1 | 45 | 25 | 18 | 4 | 0 | 0 | 0 | 0 |
| Comparative example 2 | 250 | 220 | 150 | 130 | 70 | 26 | 8 | 0 |
As shown in Table 2, it is seen that photocuring and UV curing process are compared with heat cure, and styrene volatile quantity much less is safer, more
Environmental protection, and in the preparation process that can show polychrome pearly-lustre film, can avoid adding the dangerous peroxide of tool, without
Cumbersome de-aeration, reduces production cost.
In summary, show that polychrome pearly-lustre film exists by what visible-light curing, ultraviolet light solidification and heat cure obtained
In mechanical performance, big difference is had no, but the volatilization of substantial amounts of alkenes material using thermal curing method be present, curing rate is relative will
Slowly, environmental safety is poor；When being solidified using ultraviolet light, optical source wavelength scope is 200 ~ 380nm, application relative narrower,
Light source easily damages to human body, and the cost of light source is higher；And it is more to use the visible-light curing preparation in the present invention to show
During color pearly-lustre film, optional wave-length coverage is wider, and the visible ray of 380 ~ 780nm scopes is all curable, harmless, safety collar
Protect, be widely used, its preparation technology is simple, cost is cheap, hardening time can arbitrarily control, obtained shows that polychrome pearly-lustre is thin
Film properties are excellent.
Claims (10)
1. one kind can show polychrome pearly-lustre film, including PVC base film layers, solidify pearl powder layer in PVC base film layers upper surface with
And hyaline layer, it is characterised in that：Contain adhesion agent in pearl powder layer, be made up of the composition of following mass fraction, polyisoprene
20% ~ 30%, photo-curing material 40% ~ 50%, sensitising agent 3% ~ 6%, activated monomer 15% ~ 25% and auxiliary agent 3% ~ 7% form.
2. one kind according to claim 1 can show polychrome pearly-lustre film, it is characterised in that：Photo-curing material is VLC-
720 resins, VLC-760 resins or VLC-630 resins.
3. one kind according to claim 1 can show polychrome pearly-lustre film, it is characterised in that：Sensitising agent is commercially available model
184 sensitising agent, the sensitising agent of commercially available model 1173, the sensitising agent of commercially available model 907.
4. one kind according to claim 1 can show polychrome pearly-lustre film, it is characterised in that：Activated monomer is 2- phenoxy groups
Second propyl acrylate (PHEA), propylene glycol diacrylate (DPGDA), tripropylene glycol diacrylate (TPGDA) or three
Hydroxymethyl-propane triacrylate（TMPTA）.
5. one kind according to claim 1 can show polychrome pearly-lustre film, it is characterised in that：Auxiliary agent is dispersant, defoaming
Agent or levelling agent one or more therein.
6. one kind according to claim 5 can show polychrome pearly-lustre film, it is characterised in that：Dispersant is Sodium Polyacrylate
Or the one or more in sodium citrate；Defoamer is one kind in organic silicon defoamer, polyether antifoam agent, mineral oil antifoam agent
It is or several；Levelling agent is the one or more in polyurethane levelling agent, polyacrylate flow agent, organosilicon levelling agent.
7. one kind according to claim 1 can show polychrome pearly-lustre film, it is characterised in that：PVC base film layers, pearl essence
The gross thickness of layer and PVC transparent piece is 20 ~ 120 um.
8. one kind according to claim 1 can show polychrome pearly-lustre film, it is characterised in that：Hyaline layer is transparent PVC film
Or transparent PET film.
A kind of 9. method for showing polychrome pearly-lustre film prepared described in claim 1, it is characterised in that comprise the following steps：
A, pearl essence is mixed with bonding agent, stirred, the pearl essence mixed is uniformly applied to by PVC bases by coating machine
On membrane surface, pearl powder layer is tentatively shaped using blower fan or heating tube；
B, 1 ~ 2min of cure under visible light is placed in after the PVC base film layers tentatively shaped are wound；
C, the PVC film being cured is placed on make-up machine, compound plus slide progress on pearl powder layer surface, producing to show
Polychrome pearly-lustre film.
A kind of 10. preparation method for showing polychrome pearly-lustre film according to claim 8, it is characterised in that：Make-up machine
Temperature is 170 DEG C ~ 190 DEG C, and speed is 10 ~ 15m/min；Visible light illumination is 50 ~ 70mW/cm2, irradiation distance is 50 ~ 70cm.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711273265.9A CN107825791A (en) | 2017-12-06 | 2017-12-06 | One kind can show polychrome pearly-lustre film and preparation method thereof |
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| CN201711273265.9A CN107825791A (en) | 2017-12-06 | 2017-12-06 | One kind can show polychrome pearly-lustre film and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019001145A (en) * | 2017-06-09 | 2019-01-10 | 富士フイルム株式会社 | Method for manufacturing decorative film |
| CN113956801A (en) * | 2020-07-21 | 2022-01-21 | 杭州玻美文化艺术有限公司 | Colored adhesive film, preparation method thereof and colored solar photovoltaic module |
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| CN102766428A (en) * | 2012-08-08 | 2012-11-07 | 番禺南沙殷田化工有限公司 | Ultraviolet curable resin composition and application thereof |
| CN103031106A (en) * | 2013-01-09 | 2013-04-10 | 王胜华 | Photocureable adhesion agent for bonding capacitive touch screen and preparation method of photocureable adhesion agent |
| CN203974188U (en) * | 2014-05-22 | 2014-12-03 | 河北正洋建材有限公司 | Pearly-lustre PVC film |
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| CN103031106A (en) * | 2013-01-09 | 2013-04-10 | 王胜华 | Photocureable adhesion agent for bonding capacitive touch screen and preparation method of photocureable adhesion agent |
| CN203974188U (en) * | 2014-05-22 | 2014-12-03 | 河北正洋建材有限公司 | Pearly-lustre PVC film |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2019001145A (en) * | 2017-06-09 | 2019-01-10 | 富士フイルム株式会社 | Method for manufacturing decorative film |
| CN113956801A (en) * | 2020-07-21 | 2022-01-21 | 杭州玻美文化艺术有限公司 | Colored adhesive film, preparation method thereof and colored solar photovoltaic module |
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