CN107823102A - A kind of silk gum moisturiser and preparation method thereof - Google Patents
A kind of silk gum moisturiser and preparation method thereof Download PDFInfo
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- CN107823102A CN107823102A CN201711340510.3A CN201711340510A CN107823102A CN 107823102 A CN107823102 A CN 107823102A CN 201711340510 A CN201711340510 A CN 201711340510A CN 107823102 A CN107823102 A CN 107823102A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
- A61K8/988—Honey; Royal jelly, Propolis
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/673—Vitamin B group
- A61K8/675—Vitamin B3 or vitamin B3 active, e.g. nicotinamide, nicotinic acid, nicotinyl aldehyde
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/78—Enzyme modulators, e.g. Enzyme agonists
- A61K2800/782—Enzyme inhibitors; Enzyme antagonists
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
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Abstract
The invention belongs to cosmetic technical field, and in particular to a kind of silk gum moisturiser and preparation method thereof.A kind of silk gum moisturiser of the present invention, include the raw material of following parts by weight：10 20 parts of rose wate, 20 parts of silk gum protein 10, 5 10 parts of glycerine, 38 parts of cyclohexasiloxane, 38 parts of carbonic acid dioctyl ester, 38 parts of isomery hexadecane, 13 parts of sucrose stearate, 38 parts of amino acid humectant, 14 parts of soybean oil, 13 parts of carbomer, 13 parts of triethanolamine, 35 parts of niacinamide, 13 parts of vitamin E, 13 parts of glycerol caprylate, 0.1 0.3 parts of Chlorphenesin, 0.1 1 parts of ginkgo biloba extract, 0.1 1 parts of royal jelly extract, 0.1 1 parts of Rhizoma Polygonati Odorati extract, 0.1 1 parts of Gotu Kola P.E, 0.1 1 parts of edelweiss extract, 20 40 parts of 0.1 1 parts of glycyrrhiza glabra extract and water.
Description
Technical field
The invention belongs to cosmetic technical field, and in particular to a kind of silk gum moisturiser and preparation method thereof.
Background technology
Silk gum protein is ease of solubility globulin, is held easily absorbed by the body.Silk glue protein is mainly by serine
33.43%th, 18 kinds of amino acid such as asparatate 16.71%, glycine 13.49% and rich in more carboxyls form, be natural
Moisturizing ingredient, water-retaining property is strong, has the effect such as moisturizing, wrinkle resistant, whitening antioxidation.Therefore sericin is as nutraceutical, doctor
There is many unique functions and larger market potential in terms of the functional material use for treating health products and other field.
Traditional sericin extraction process is mainly what is reclaimed in the waste liquid excluded from throwing factory.Extraction process
Not only cumbersome, efficiency are low, cost is high, seriously polluted, and the sericine purity reclaimed is low, and denaturation is strong, and quality reaches
Less than requiring.
The content of the invention
The main purpose of the present invention is to provide a kind of silk gum moisturiser and preparation method thereof.
The technical scheme is that：
A kind of silk gum moisturiser, include the raw material of following parts by weight：
Rose wate 10-20 parts, -20 parts of silk gum protein 10, glycerine 5-10 parts, cyclohexasiloxane 3-8 parts, carbonic acid two are pungent
Ester 3-8 parts, isomery hexadecane 3-8 parts, sucrose stearate 1-3 parts, amino acid humectant 3-8 parts, soybean oil 1-4 parts, card ripple
Nurse 1-3 parts, triethanolamine 1-3 parts, niacinamide 3-5 parts, vitamin E 1-3 parts, glycerol caprylate 1-3 parts, Chlorphenesin 0.1-
0.3 part, ginkgo biloba extract 0.1-1 parts, royal jelly extract 0.1-1 parts, Rhizoma Polygonati Odorati extract 0.1-1 parts, Gotu Kola P.E
0.1-1 parts, edelweiss extract 0.1-1 parts, glycyrrhiza glabra extract 0.1-1 parts and water 20-40 parts.
Further, the rose that rose wate of the present invention distills to obtain using Bulgarian Rosa rugosa.
Ginkgo biloba extract of the present invention, royal jelly extract, Rhizoma Polygonati Odorati extract, Gotu Kola P.E, glycyrrhiza glabra
Extract and edelweiss extract are all to use milling process, hydrodistillation, organic solvent extraction or supercritical extract
Method is made.
A kind of preparation method of silk gum moisturiser, comprises the following steps：
(1) silk glue protein is prepared：
High-quality All Pure Nature is chosen without fibroin full wire glue silk cocoon, extracts after the impurity on surface the constant temperature at a temperature of 50-60 DEG C
Dried 10 minutes in air blower, then be ground into full wire rubber powder end；The mass percent that full wire rubber powder end is added to 100 times of weight is
In 0.4-1% sodium acid carbonate salting liquid, 0.5-2 hours are hydrolyzed in the water bath with thermostatic control below 65 DEG C；The silk of gained will be hydrolyzed
The filter yarn that glue crosses 200-400 mesh removes impurity, the full wire collagen solution dialysis desalination in 4 hours being filtrated to get, that is, silk gum is made
Albumen；
(2) finished product is prepared：
A. carbonic acid dioctyl ester, isomery hexadecane, glycerol caprylate, triethanolamine, sucrose stearate are heated to 80-85
DEG C melted completely to each composition, soybean oil, cyclohexasiloxane and vitamin E mixing are added after temperature is reduced to 60-70 DEG C
Uniformly form oil phase；
B. glycerine, carbomer, niacinamide, water are heated into 80-85 DEG C to be completely dissolved to each component, treat that temperature is reduced to
Silk glue protein is added in aqueous phase at 60-50 DEG C, amino acid humectant, rose are added when temperature is reduced to 60-50 DEG C
Hua Shui, silk glue protein, edelweiss extract, ginkgo biloba extract, royal jelly extract, Rhizoma Polygonati Odorati extract, centella carry
Take thing, glycyrrhiza glabra extract and Chlorphenesin to be well mixed, form aqueous phase；
C. aqueous phase is added in main emulsification pot, oil phase is poured into emulsification pot after stirring and carries out emulsifying 30-60 points
Silk gum moisturiser is made in clock.
The present invention is to provide a kind of moisturiser of sericin, formula is unique, the silk collagen sources of use in
Jin Gui natural full wire glue silk cocoon -- gold cocoon, silk collagen protein active is saved using low temperature hydrolysis technology, and combine dimension
The natural plant essences such as raw plain E, ginkgo, royal jelly, radix polygonati officinalis, centella, edelweiss, in the same of supplement skin collagen
When can strengthen skin and resist UV resistance, delaying skin aging, skin is remained youthful forever.The white body worked it out clearly moistens,
Comfortably soft and smooth using rear skin, water profit is full, and elastic force is full.The silk glue protein that the present invention is obtained using low temperature hydrolysis, has
Advantages below：1st, the activity of sericin is maintained, is eliminated, the old cutin of the skin that comes off.2nd, the tyrosine in pure silk collagen solution, color
Propylhomoserin, phenylalanine etc. can effectively absorb ultraviolet, prevent damage of the daylight middle-ultraviolet lamp to skin, resist because ultraviolet shines
Spot caused by penetrating and tanned.3rd, inoxidizability is high, can effectively suppress the characteristic of tyrosinase activity, therefore can prevent in skin
The formation of melanin, skin whitening.4th, there is very strong antibiotic property, and with disinfecting mite-removing effect.
Embodiment
Embodiment 1
A kind of silk gum moisturiser, include the raw material of following parts by weight：
10 parts of rose wate, silk gum protein 10 part, 5 parts of glycerine, 3 parts of cyclohexasiloxane, 3 parts of carbonic acid dioctyl ester, isomery
3 parts of hexadecane, 1 part of sucrose stearate, 3 parts of amino acid humectant, 1 part of soybean oil, 1 part of carbomer, 1 part of triethanolamine, cigarette
3 parts of acid amides, 1 part of vitamin E, 1 part of glycerol caprylate, 0.1 part of Chlorphenesin, 0.1 part of ginkgo biloba extract, royal jelly extract
0.1 part, 0.1 part of Rhizoma Polygonati Odorati extract, 0.1 part of Gotu Kola P.E, 0.1 part of edelweiss extract, glycyrrhiza glabra extract
0.1 part and 20 parts of water.Wherein the chemical name of carbomer is acrylic resin, and the chemical name of amino acid humectant is trimethyl
Glycine, the rose that rose wate distills to obtain using Bulgarian Rosa rugosa, ginkgo biloba extract, royal jelly extraction
Thing, Rhizoma Polygonati Odorati extract, Gotu Kola P.E, glycyrrhiza glabra extract and edelweiss extract are all using conventional squeezing
Method is made.
Specific preparation method comprises the following steps：
(1) silk glue protein is prepared：
High-quality All Pure Nature is chosen without fibroin full wire glue silk cocoon, extracts the constant temperature air blast at a temperature of 50 DEG C after the impurity on surface
Dried 10 minutes in machine, then be ground into full wire rubber powder end；The mass percent that full wire rubber powder end is added to 100 times of weight is
In 0.4% sodium bicarbonate solution, hydrolyzed 0.5 hour in 65 DEG C of water bath with thermostatic control；The silk gum liquid for hydrolyzing gained is crossed into 200 mesh
Filter yarn remove impurity, the full wire collagen solution dialysis desalination in 4 hours being filtrated to get, that is, silk glue protein is made；
(3) finished product is prepared：
A. carbonic acid dioctyl ester, isomery hexadecane, glycerol caprylate, triethanolamine, sucrose stearate are heated to 80 DEG C
Melted completely to each composition, soybean oil, cyclohexasiloxane and vitamin E are added after temperature is reduced to 60 DEG C and is well mixed structure
Into oil phase；
B. glycerine, carbomer, niacinamide, water are heated into 80 DEG C to be completely dissolved to each component, treat that temperature is reduced to 60 DEG C
When by silk glue protein add aqueous phase in, amino acid humectant, rose wate, silk gum are added when temperature is reduced to 60 DEG C
Albumen, edelweiss extract, ginkgo biloba extract, royal jelly extract, Rhizoma Polygonati Odorati extract, Gotu Kola P.E, light fruit are sweet
Careless extract and Chlorphenesin are well mixed, and form aqueous phase；
C. aqueous phase is added in main emulsification pot, oil phase is poured into emulsification pot after stirring and carries out 30 minutes systems of emulsification
Into silk gum moisturiser, last filling and package.
Embodiment 2
A kind of silk gum moisturiser, include the raw material of following parts by weight：
20 parts of rose wate, silk gum protein 20 part, 10 parts of glycerine, 8 parts of cyclohexasiloxane, 8 parts of carbonic acid dioctyl ester, isomery
8 parts of hexadecane, 3 parts of sucrose stearate, 8 parts of amino acid humectant, 4 parts of soybean oil, 3 parts of carbomer, 3 parts of triethanolamine, cigarette
5 parts of acid amides, 3 parts of vitamin E, 3 parts of glycerol caprylate, 0.3 part of Chlorphenesin, 1 part of ginkgo biloba extract, royal jelly extract 1
Part, 1 part of Rhizoma Polygonati Odorati extract, 1 part of Gotu Kola P.E, 1 part of edelweiss extract, 1 part of glycyrrhiza glabra extract and water 40
Part.The wherein chemical name of carbomer is acrylic resin, and the chemical name of amino acid humectant is trimethylglycine, rose
The rose that Hua Shui distills to obtain using Bulgarian Rosa rugosa, ginkgo biloba extract, royal jelly extract, radix polygonati officinalis extraction
Thing, Gotu Kola P.E, glycyrrhiza glabra extract and edelweiss extract are made using conventional hydrodistillation.
Specifically preparation method is：
(1) silk glue protein is prepared：
High-quality All Pure Nature is chosen without fibroin full wire glue silk cocoon, extracts the constant temperature air blast at a temperature of 60 DEG C after the impurity on surface
Dried 10 minutes in machine, then be ground into full wire rubber powder end；It is 1% by the mass percent that full wire rubber powder end is added to 100 times of weight
Sodium bicarbonate solution in, hydrolyzed 2 hours in 60 DEG C of water bath with thermostatic control；The silk gum liquid for hydrolyzing gained is crossed to the filter yarn of 400 mesh
Impurity is removed, the full wire collagen solution dialysis desalination in 4 hours being filtrated to get, that is, silk glue protein is made；
(2) finished product is prepared：
A. carbonic acid dioctyl ester, isomery hexadecane, glycerol caprylate, triethanolamine, sucrose stearate are heated to 85 DEG C
Melted completely to each composition, soybean oil, cyclohexasiloxane and vitamin E are added after temperature is reduced to 70 DEG C and is well mixed structure
Into oil phase；
B. glycerine, carbomer, niacinamide, water are heated into 85 DEG C to be completely dissolved to each component, treat that temperature is reduced to 50 DEG C
When by silk glue protein add aqueous phase in, amino acid humectant, rose wate, silk gum are added when temperature is reduced to 50 DEG C
Albumen, edelweiss extract, ginkgo biloba extract, royal jelly extract, Rhizoma Polygonati Odorati extract, Gotu Kola P.E, light fruit are sweet
Careless extract and Chlorphenesin are well mixed, and form aqueous phase；
C. aqueous phase is added in main emulsification pot, oil phase is poured into emulsification pot after stirring and carries out 60 minutes systems of emulsification
Into silk gum moisturiser, last filling and package.
Only preferable specific embodiment of the invention described in detail above, it is impossible to the power of the present invention is limited with this
Scope is limited, is mainly the skin care ingredient using sericine as white product with signified sericin moisturiser of the invention, matches somebody with somebody
With other conventional components, such as：Sericin made of emulsifying agent, NMF, whitening agent, preservative, skin conditioner etc. is protected
Wet frost still falls within the scope that the present invention is covered.
Claims (4)
1. a kind of silk gum moisturiser, it is characterised in that include the raw material of following parts by weight：
Rose wate 10-20 parts, -20 parts of silk gum protein 10, glycerine 5-10 parts, cyclohexasiloxane 3-8 parts, carbonic acid dioctyl ester 3-
8 parts, isomery hexadecane 3-8 parts, sucrose stearate 1-3 parts, amino acid humectant 3-8 parts, soybean oil 1-4 parts, carbomer 1-3
Part, triethanolamine 1-3 parts, niacinamide 3-5 parts, vitamin E 1-3 parts, glycerol caprylate 1-3 parts, Chlorphenesin 0.1-0.3 parts,
Ginkgo biloba extract 0.1-1 parts, royal jelly extract 0.1-1 parts, Rhizoma Polygonati Odorati extract 0.1-1 parts, Gotu Kola P.E 0.1-1 parts,
Edelweiss extract 0.1-1 parts, glycyrrhiza glabra extract 0.1-1 parts and water 20-40 parts.
2. a kind of silk gum moisturiser according to claim, it is characterised in that described rose wate is using Bao Jiali
Sub- rose distills obtained rose.
3. a kind of silk gum moisturiser according to claim, it is characterised in that described ginkgo biloba extract, royal jelly extraction
Thing, Rhizoma Polygonati Odorati extract, Gotu Kola P.E, glycyrrhiza glabra extract and edelweiss extract are all using conventional squeezing
Method, hydrodistillation, organic solvent extraction or supercritical extraction are made.
4. the preparation method of a kind of silk gum moisturiser in claim 1-3 described in any one, it is characterised in that including following
Step：
(1) silk glue protein is prepared：
High-quality All Pure Nature is chosen without fibroin full wire glue silk cocoon, extracts the constant temperature air blast at a temperature of 50-60 DEG C after the impurity on surface
Dried 10 minutes in machine, then be ground into full wire rubber powder end；It is 0.4- by the mass percent that full wire rubber powder end is added to 100 times of weight
In 1% sodium acid carbonate salting liquid, 0.5-2 hours are hydrolyzed in the water bath with thermostatic control below 65 DEG C；The silk gum liquid of gained will be hydrolyzed
The filter yarn for crossing 200-400 mesh removes impurity, the full wire collagen solution dialysis desalination in 4 hours being filtrated to get, that is, silk glue protein is made；
(2) finished product is prepared：
A. carbonic acid dioctyl ester, isomery hexadecane, glycerol caprylate, triethanolamine, sucrose stearate are heated to 80-85 DEG C extremely
Each composition is melted completely, and soybean oil, cyclohexasiloxane and vitamin E are added after temperature is reduced to 60-70 DEG C and is well mixed
Form oil phase；
B. glycerine, carbomer, niacinamide, water are heated into 80-85 DEG C to be completely dissolved to each component, treat that temperature is reduced to 60-50
DEG C when will silk glue protein add aqueous phase in, added when temperature is reduced to 60-50 DEG C amino acid humectant, rose wate,
Silk glue protein, edelweiss extract, ginkgo biloba extract, royal jelly extract, Rhizoma Polygonati Odorati extract, Gotu Kola P.E,
Glycyrrhiza glabra extract and Chlorphenesin are well mixed, and form aqueous phase；
C. aqueous phase is added in main emulsification pot, oil phase is poured into emulsification pot after stirring and carries out emulsifying 30-60 minute systems
Into silk gum moisturiser.
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| CN108354891A (en) * | 2018-05-04 | 2018-08-03 | 西南大学 | One kind is releived creams and preparation method thereof |
| CN108715652A (en) * | 2018-06-05 | 2018-10-30 | 中国热带农业科学院环境与植物保护研究所 | A kind of composite foamed sponge material of silk-natural emulsion and preparation method thereof |
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| CN108354891A (en) * | 2018-05-04 | 2018-08-03 | 西南大学 | One kind is releived creams and preparation method thereof |
| CN108715652A (en) * | 2018-06-05 | 2018-10-30 | 中国热带农业科学院环境与植物保护研究所 | A kind of composite foamed sponge material of silk-natural emulsion and preparation method thereof |
| CN108715652B (en) * | 2018-06-05 | 2020-09-01 | 中国热带农业科学院环境与植物保护研究所 | Silk-natural latex composite foam sponge material and preparation method thereof |
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Application publication date: 20180323 |