CN107814514A - A kind of titanium dioxide coating for wall surface and preparation method thereof - Google Patents
A kind of titanium dioxide coating for wall surface and preparation method thereof Download PDFInfo
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- CN107814514A CN107814514A CN201711183932.4A CN201711183932A CN107814514A CN 107814514 A CN107814514 A CN 107814514A CN 201711183932 A CN201711183932 A CN 201711183932A CN 107814514 A CN107814514 A CN 107814514A
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- wall surface
- titanium dioxide
- dioxide coating
- wetting agent
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
- C04B2111/00827—Photocatalysts
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
Abstract
The invention provides a kind of titanium dioxide coating for wall surface, it is made up of the component of following parts by weight：20 30 parts of water, 0.2 0.3 parts of hydroxyethyl cellulose；0.6 0.8 parts of polycarboxylate sodium, 0.1 0.2 parts of wetting agent, 3 parts of isopropanol 1.5 part, 15 25 parts of rutile titanium white powder, 58 parts of calcined kaolin, 58 parts of calcium carbonate, 0.6 0.8 parts of diatomite, 12 parts of 0.2 0.4 parts of myristyl benzyl dimethyl ammonium chloride, 0.1 0.2 parts of dimethyl silicone polymer, 0.1 0.3 parts of pH adjusting agent and propane diols.Titanium dioxide coating for wall surface of the present invention, coating cost is low, nontoxic, long-acting can remove aldehyde, except aldehyde efficiency high, requires smaller to use condition, without illumination, can play preferably to decompose under normal temperature normality and remove aldehyde, have good mould proof, fungistatic effect.Present invention also offers the preparation method of described titanium dioxide coating for wall surface.
Description
Technical field
The invention belongs to technical field of coatings, more particularly to a kind of titanium dioxide coating for wall surface and preparation method thereof.
Background technology
Coating is to be coated in the body surface protected or decorated, and can form the continuous thin of firm attachment with coated article
Film, typically based on resin or oil or emulsion, add or do not add pigment, filler, add corresponding additive, use organic solvent
Or the thick liquid that water is formulated.Coating plays an important role in national economy, is that modern society is indispensable.
At present, discharging the low-grade interior wall coating of toxic gas more at home, commercially hexyl is originally eliminated, great Liang Huo
The medium and high classes environmental-protection construction coating for internal wall such as aqua type, latex type are generally used, these coating have good film-forming property, applied
Film has good water resistance, weatherability and anti-stain characteristic, and environment influences the advantages that small, but these coating are remained at some not
Foot, such as complex manufacturing, price, it is impossible to meet the huge market demand；The some auxiliary agents added in production can still discharge
Toxic gas, though environmental pollution is smaller, but still the harmful substances such as certain formaldehyde, volatile organic matter, the feature of environmental protection can be produced
Can be poor, the easy mouldy generation peculiar smell of metope, inconvenience is brought to consumer.Therefore, be badly in need of finding it is a kind of it is cheap, nontoxic,
There is fungistatic effect human health is not had a negative impact environmentally friendly interior wall coating for environmental protection.
The content of the invention
For defect present in prior art, it is an object of the invention to provide a kind of titanium dioxide coating for wall surface, with drop
Low production cost, the formaldehyde clearance of coating is improved, improve fungistatic effect.
The technical solution adopted by the present invention is：
A kind of titanium dioxide coating for wall surface, is made up of the component of following parts by weight：Water 30-35 parts, hydroxyethyl cellulose 0.2-
0.3 part；Polycarboxylate sodium's 0.6-0.8 parts, wetting agent 0.1-0.2 parts, isopropanol 1.5-3 parts, rutile titanium white powder 15-25 parts,
Calcined kaolin 5-8 parts, calcium carbonate 5-8 parts, diatomite 0.6-0.8 parts, myristyl benzyl dimethyl ammonium chloride 0.2-0.4
Part, dimethyl silicone polymer 0.1-0.2 parts, pH adjusting agent 0.1-0.3 parts and propane diols 1-2 parts.
Titanium dioxide coating for wall surface of the present invention, wherein, it is made up of the component of following parts by weight：30 parts of water, ethoxy
0.25 part of cellulose；0.7 part of polycarboxylate sodium, 0.15 part of wetting agent, 2 parts of isopropanol, 20 parts of rutile titanium white powder, calcine kaolinite
6 parts of soil, 7 parts of calcium carbonate, 0.7 part of diatomite, 0.3 part of myristyl benzyl dimethyl ammonium chloride, dimethyl silicone polymer 0.2
Part, 1 part of 0.15 part of pH adjusting agent and propane diols.
Titanium dioxide coating for wall surface of the present invention, wherein, the wetting agent is wetting agent D-504.
The preparation method of titanium dioxide coating for wall surface of the present invention, comprises the following steps：
(1) prepare raw material by proportioning, water, hydroxyethyl cellulose, polycarboxylate sodium, isopropanol and wetting agent are sequentially added
Stirred into mixer, mixing speed 200-300r/min, mixing time 15-25min；
(2) and then rutile titanium white powder, calcined kaolin, calcium carbonate and diatomite are sequentially added, improves rotating speed to 1000-
1200r/min grinding distributions 35-45min is to fineness less than 30 μm；
(3) rotating speed about 250-350r/min is adjusted, adds myristyl benzyl dimethyl ammonium chloride, polydimethylsiloxanes
Alkane, propane diols and pH adjusting agent, scattered stirring 10-15min can obtain product.
The preparation method of titanium dioxide coating for wall surface of the present invention, wherein, mixing speed is 300r/ in step (1)
Min, mixing time 20min.
The preparation method of titanium dioxide coating for wall surface of the present invention, wherein, rotating speed is improved in step (1) to 1000r/
Min grinding distributions 40min.
Beneficial effect of the present invention：
Titanium dioxide coating for wall surface of the present invention, coating cost is low, nontoxic, long-acting can remove aldehyde, right except aldehyde efficiency high
Use condition requires smaller, without illumination, can play preferably to decompose under normal temperature normality and remove aldehyde, have well mould proof,
Fungistatic effect.
The preparation method of titanium dioxide coating for wall surface of the present invention, cost is relatively low, preparation technology is simple, easy to implement.
Embodiment
Embodiment 1
A kind of titanium dioxide coating for wall surface, is made up of the component of following parts by weight：30 parts of water, 0.25 part of hydroxyethyl cellulose；
0.7 part of polycarboxylate sodium, 0.15 part of wetting agent, 2 parts of isopropanol, 20 parts of rutile titanium white powder, 6 parts of calcined kaolin, calcium carbonate 7
Part, 0.7 part of diatomite, 0.3 part of myristyl benzyl dimethyl ammonium chloride, 0.2 part of dimethyl silicone polymer, pH adjusting agent 0.15
1 part of part and propane diols；The wetting agent is wetting agent D-504.
The preparation method of titanium dioxide coating for wall surface described in the present embodiment, comprises the following steps：
(1) prepare raw material by proportioning, water, hydroxyethyl cellulose, polycarboxylate sodium, isopropanol and wetting agent are sequentially added
Stirred into mixer, mixing speed 300r/min, mixing time 20min；
(2) and then rutile titanium white powder, calcined kaolin, calcium carbonate and diatomite are sequentially added, improves rotating speed and arrive
1000r/min grinding distributions 40min is to fineness less than 30 μm；
(3) rotating speed about 300r/min is adjusted, adds myristyl benzyl dimethyl ammonium chloride, dimethyl silicone polymer, third
Glycol and pH adjusting agent, scattered stirring 10min can obtain product.
Embodiment 2
A kind of titanium dioxide coating for wall surface, is made up of the component of following parts by weight：35 parts of water, 0.2 part of hydroxyethyl cellulose；It is poly-
0.8 part of carboxylic acid sodium salt, 0.2 part of wetting agent, 1.5 parts of isopropanol, 25 parts of rutile titanium white powder, 5 parts of calcined kaolin, calcium carbonate 5
Part, 0.8 part of diatomite, 0.2 part of myristyl benzyl dimethyl ammonium chloride, 0.2 part of dimethyl silicone polymer, pH adjusting agent 0.1
2 parts of part and propane diols, the wetting agent is wetting agent D-504.
The preparation method of titanium dioxide coating for wall surface described in the present embodiment, comprises the following steps：
(1) prepare raw material by proportioning, water, hydroxyethyl cellulose, polycarboxylate sodium, isopropanol and wetting agent are sequentially added
Stirred into mixer, mixing speed 200r/min, mixing time 25min；
(2) and then rutile titanium white powder, calcined kaolin, calcium carbonate and diatomite are sequentially added, improves rotating speed and arrive
1000r/min grinding distributions 45min is to fineness less than 30 μm；
(3) rotating speed about 250r/min is adjusted, adds myristyl benzyl dimethyl ammonium chloride, dimethyl silicone polymer, third
Glycol and pH adjusting agent, scattered stirring 10min can obtain product.
Embodiment 3
A kind of titanium dioxide coating for wall surface, is made up of the component of following parts by weight：30 parts of water, 0.3 part of hydroxyethyl cellulose；It is poly-
0.6 part of carboxylic acid sodium salt, 0.1 part of wetting agent, 3 parts of isopropanol, 25 parts of rutile titanium white powder, 8 parts of calcined kaolin, 8 parts of calcium carbonate,
0.6 part of diatomite, 0.4 part of myristyl benzyl dimethyl ammonium chloride, 0.1 part of dimethyl silicone polymer, 0.3 part of pH adjusting agent and
1 part of propane diols, the wetting agent are wetting agent D-504.
The preparation method of titanium dioxide coating for wall surface described in the present embodiment, comprises the following steps：
(1) prepare raw material by proportioning, water, hydroxyethyl cellulose, polycarboxylate sodium, isopropanol and wetting agent are sequentially added
Stirred into mixer, mixing speed 300r/min, mixing time 15min；
(2) and then rutile titanium white powder, calcined kaolin, calcium carbonate and diatomite are sequentially added, improves rotating speed and arrive
1200r/min grinding distributions 35min is to fineness less than 30 μm；
(3) rotating speed about 350r/min is adjusted, adds myristyl benzyl dimethyl ammonium chloride, dimethyl silicone polymer, third
Glycol and pH adjusting agent, scattered stirring 10min can obtain product.
Performance detection is carried out to product prepared by embodiment 1-3, according to " JC/T 1074-2008 function of purifying indoor air
Coating material purifying property " detection purifying formaldehyde performance, purifying formaldehyde effect persistence；Antibacterial ability detection method is with reference to country
《Sterile products are identified and inspection specifications》, experimental strain is Escherichia coli, and coating is surveyed after 40W houselights irradiates 1h
Examination, assay is as shown in table 1, and as shown in Table 1, product purifying formaldehyde better performances of the present invention, sterilizing rate is higher.
The performance test results of the titanium dioxide coating for wall surface of table 1
| Sequence number | Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| 1 | Purifying formaldehyde performance | 93.1 | 92.8 | 91.5 |
| 2 | Purifying formaldehyde effect persistence | 90.8 | 89.7 | 85.0 |
| 3 | Sterilizing rate % | 93.2 | 90.8 | 89.1 |
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention
Enclose and be defined, on the premise of design spirit of the present invention is not departed from, technical side of the those of ordinary skill in the art to the present invention
The various modifications and improvement that case is made, it all should fall into the protection domain of claims of the present invention determination.
Claims (6)
- A kind of 1. titanium dioxide coating for wall surface, it is characterised in that：It is made up of the component of following parts by weight：Water 30-35 parts, ethoxy are fine Tie up plain 0.2-0.3 parts；Polycarboxylate sodium's 0.6-0.8 parts, wetting agent 0.1-0.2 parts, isopropanol 1.5-3 parts, rutile titanium white powder 15-25 parts, calcined kaolin 5-8 parts, calcium carbonate 5-8 parts, diatomite 0.6-0.8 parts, myristyl benzyl dimethyl ammonium chloride 0.2-0.4 parts, dimethyl silicone polymer 0.1-0.2 parts, pH adjusting agent 0.1-0.3 parts and propane diols 1-2 parts.
- 2. titanium dioxide coating for wall surface according to claim 1, it is characterised in that：It is made up of the component of following parts by weight：Water 30 parts, 0.25 part of hydroxyethyl cellulose；0.7 part of polycarboxylate sodium, 0.15 part of wetting agent, 2 parts of isopropanol, rutile titanium white powder 20 Part, 6 parts of calcined kaolin, 7 parts of calcium carbonate, 0.7 part of diatomite, 0.3 part of myristyl benzyl dimethyl ammonium chloride, poly dimethyl 1 part of 0.2 part of siloxanes, 0.15 part of pH adjusting agent and propane diols.
- 3. titanium dioxide coating for wall surface according to claim 1 or 2, it is characterised in that：The wetting agent is wetting agent D- 504。
- 4. the preparation method of the titanium dioxide coating for wall surface described in claim 1-3 any one, it is characterised in that：Including following step Suddenly：(1) prepare raw material by proportioning, water, hydroxyethyl cellulose, polycarboxylate sodium, isopropanol and wetting agent are added sequentially to stir Mix in machine and stir, mixing speed 200-300r/min, mixing time 15-25min；(2) and then rutile titanium white powder, calcined kaolin, calcium carbonate and diatomite are sequentially added, improves rotating speed to 1000- 1200r/min grinding distributions 35-45min is to fineness less than 30 μm；(3) rotating speed about 250-350r/min is adjusted, adds myristyl benzyl dimethyl ammonium chloride, dimethyl silicone polymer, third Glycol and pH adjusting agent, scattered stirring 10min can obtain product.
- 5. the preparation method of titanium dioxide coating for wall surface according to claim 4, it is characterised in that：Stirring speed in step (1) Spend for 300r/min, mixing time 20min.
- 6. the preparation method of the titanium dioxide coating for wall surface according to claim 4 or 5, it is characterised in that：Improved in step (1) Rotating speed is to 1000r/min grinding distributions 40min.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711183932.4A CN107814514A (en) | 2017-11-23 | 2017-11-23 | A kind of titanium dioxide coating for wall surface and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711183932.4A CN107814514A (en) | 2017-11-23 | 2017-11-23 | A kind of titanium dioxide coating for wall surface and preparation method thereof |
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| CN107814514A true CN107814514A (en) | 2018-03-20 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101397431A (en) * | 2007-12-03 | 2009-04-01 | 三棵树涂料股份有限公司 | Environment friendly coating |
| CN103011700A (en) * | 2011-09-26 | 2013-04-03 | 卢丹 | Wall coating composition, preparation method and application of wall coating composition and wall coating containing wall coating composition |
| CN103351147A (en) * | 2013-06-28 | 2013-10-16 | 青岛极致节能环保有限公司 | Environmentally-friendly and energy-saving wall coating |
| CN106810134A (en) * | 2016-12-22 | 2017-06-09 | 莫锦雄 | A kind of scrubbable indoor wall coating and preparation method thereof |
| CN107129184A (en) * | 2017-04-19 | 2017-09-05 | 广东南天涂料有限公司 | A kind of application of novel colorful stone similar paint |
-
2017
- 2017-11-23 CN CN201711183932.4A patent/CN107814514A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101397431A (en) * | 2007-12-03 | 2009-04-01 | 三棵树涂料股份有限公司 | Environment friendly coating |
| CN103011700A (en) * | 2011-09-26 | 2013-04-03 | 卢丹 | Wall coating composition, preparation method and application of wall coating composition and wall coating containing wall coating composition |
| CN103351147A (en) * | 2013-06-28 | 2013-10-16 | 青岛极致节能环保有限公司 | Environmentally-friendly and energy-saving wall coating |
| CN106810134A (en) * | 2016-12-22 | 2017-06-09 | 莫锦雄 | A kind of scrubbable indoor wall coating and preparation method thereof |
| CN107129184A (en) * | 2017-04-19 | 2017-09-05 | 广东南天涂料有限公司 | A kind of application of novel colorful stone similar paint |
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Application publication date: 20180320 |
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