CN107814510A - A kind of artificial quartz stone plate and preparation method thereof - Google Patents
A kind of artificial quartz stone plate and preparation method thereof Download PDFInfo
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- CN107814510A CN107814510A CN201711029503.1A CN201711029503A CN107814510A CN 107814510 A CN107814510 A CN 107814510A CN 201711029503 A CN201711029503 A CN 201711029503A CN 107814510 A CN107814510 A CN 107814510A
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- Prior art keywords
- stone plate
- artificial quartz
- quartz stone
- stirred
- mixed
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Developing Agents For Electrophotography (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a kind of artificial quartz stone plate and preparation method thereof, composition includes：Quartz sand, silica flour, unsaturated polyester resin, toner, curing agent, coupling agent, white mica powder, property-modifying additive；A part of toner and silica flour are mixed, obtain system 1；System 1 is stirred with quartz sand, obtains system 2；Unsaturated polyester resin and property-modifying additive are stirred, obtain system 3；System 2 is mixed with system 3, obtains system 4；System 4 and remaining toner are stirred, obtain system 5；System 5 is mixed with curing agent, silane coupler, white mica powder mixes；Shaping；Solidification；Fixed thickness, polishing.The invention has the advantages that：The compactness of quartzite slate is high；Property-modifying additive is added in unsaturated polyester resin can assign product more preferably toughness and impact strength, and curing agent, silane coupler, white mica powder synergy improve product crack resistence performance.
Description
Technical field
The present invention relates to a kind of quartzite slate manufacturing field.
Background technology
Quartz is artificial manufactured Novel stone, and main material is quartz.Quartz is not easy to scratch, is not easy because it has
Pollute, be not easy to wear, fire resisting, the excellent properties such as nontoxic and be widely used in laboratory, market, office, in domestic environment.So
And not all quartz disclosure satisfy that the specific demand of different places, for example, toughness, crack resistence etc. performance not
It is enough prominent.
The content of the invention
It is an object of the invention to provide a kind of artificial quartz stone plate and preparation method thereof, to solve stone in the prior art
Diamond stone sheet material toughness deficiency, the power that is easily hit influence the phenomenon to ftracture.
The present invention adopts the following technical scheme that in order to achieve the above object：
A kind of artificial quartz stone plate, in percentage by weight, composition includes：
Further, the unsaturated polyester resin includes epoxy resin and polyurethane resin, epoxy resin and polyurethane
Weight resin ratio is 1:2-1:4.
Further, the curing agent includes methyl ethyl ketone peroxide, TEPA, trimethylhexane diamine, peroxidating first
Ethyl ketone, TEPA, the weight ratio of trimethylhexane diamine are 3:3:4.
Further, the coupling agent includes the double trimethoxy silicon substrate ethane of 1,2-.
Further, the property-modifying additive includes calcium carbonate, the boric acid ester coupler modification that boric acid ester coupler is modified
Borate whisker in it is one or two kinds of.
A kind of preparation method of artificial quartz stone plate, comprises the following steps：
(1) each component is measured in proportion；
(2) 1/3-1/4 volumes toner and silica flour mixing 6-8h, system 1 is obtained；
(3) system 1 is stirred with quartz sand, obtains system 2；
(4) unsaturated polyester resin and property-modifying additive are stirred, obtain system 3
(5) system 2 is mixed with system 3, obtains system 4；
(6) system 4 and remaining toner are stirred, obtain system 5；
(7) system 5 is mixed with curing agent, silane coupler, white mica powder mixes；
(8) the mixed material vibration moulding under vacuum with press device step (7)；
(9) compacting finishes, in curing apparatus, with 70-270 DEG C of solidification 1-1.5h；
(10) polished after room temperature cooling with the fixed thickness of the fixed thick equipment of sheet material with water mill polissoir.
Further, vacuum is less than -0.098MPa in the step (8).
Curing agent provided by the invention is used in mixed way in proportion, makes product solidification effect good；Quartz slate is prepared in order
Material can ensure the compactness of quartzite slate, and properties of product will not be adversely affected；By in unsaturated polyester resin
Middle addition property-modifying additive can assign product more preferably toughness and impact strength, curing agent, silane coupler, white mica powder
Synergy improves product crack resistence performance.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment, herein with the illustrative examples and explanation of the present invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment one
A kind of artificial quartz stone plate, in percentage by weight, composition includes：
The unsaturated polyester resin includes epoxy resin and polyurethane resin, epoxy resin and polyurethane resin weight ratio
It is 1:2.
The curing agent includes methyl ethyl ketone peroxide, TEPA, trimethylhexane diamine, methyl ethyl ketone peroxide, tetrem
The amine of alkene five, the weight ratio of trimethylhexane diamine are 3:3:4.
The coupling agent includes the double trimethoxy silicon substrate ethane of 1,2-.
The property-modifying additive includes the calcium carbonate that boric acid ester coupler is modified.
A kind of preparation method of artificial quartz stone plate, comprises the following steps：
(1) each component is measured in proportion；
(2) 1/3 volume toner and silica flour mixing 6-8h, system 1 is obtained；
(3) system 1 is stirred with quartz sand, obtains system 2；
(4) unsaturated polyester resin and property-modifying additive are stirred, obtain system 3
(5) system 2 is mixed with system 3, obtains system 4；
(6) system 4 and remaining toner are stirred, obtain system 5；
(7) system 5 is mixed with curing agent, silane coupler, white mica powder mixes；
(8) with press device the mixed material vibration moulding under vacuum of step (7), vacuum is less than-
0.098MPa；
(9) compacting finishes, in curing apparatus, with 250 DEG C of solidification 1h；
(10) polished after room temperature cooling with the fixed thickness of the fixed thick equipment of sheet material with water mill polissoir.
Embodiment two
A kind of artificial quartz stone plate, in percentage by weight, composition includes：
The unsaturated polyester resin includes epoxy resin and polyurethane resin, epoxy resin and polyurethane resin weight ratio
It is 1:4.
The curing agent includes methyl ethyl ketone peroxide, TEPA, trimethylhexane diamine, methyl ethyl ketone peroxide, tetrem
The amine of alkene five, the weight ratio of trimethylhexane diamine are 3:3:4.
The coupling agent includes the double trimethoxy silicon substrate ethane of 1,2-.
It is brilliant that the property-modifying additive includes the borate that calcium carbonate, the boric acid ester coupler that boric acid ester coupler is modified are modified
Palpus.
A kind of preparation method of artificial quartz stone plate, comprises the following steps：
(1) each component is measured in proportion；
(2) 1/3 volume toner and silica flour mixing 8h, system 1 is obtained；
(3) system 1 is stirred with quartz sand, obtains system 2；
(4) unsaturated polyester resin and property-modifying additive are stirred, obtain system 3
(5) system 2 is mixed with system 3, obtains system 4；
(6) system 4 and remaining toner are stirred, obtain system 5；
(7) system 5 is mixed with curing agent, silane coupler, white mica powder mixes；
(8) with press device the mixed material vibration moulding under vacuum of step (7), vacuum is less than-
0.098MPa；
(9) compacting finishes, in curing apparatus, with 210 DEG C of solidification 1.5h；
(10) polished after room temperature cooling with the fixed thickness of the fixed thick equipment of sheet material with water mill polissoir.
Embodiment three
A kind of artificial quartz stone plate, in percentage by weight, composition includes：
Further, the unsaturated polyester resin includes epoxy resin and polyurethane resin, epoxy resin and polyurethane
Weight resin ratio is 1:2.
Further, the curing agent includes methyl ethyl ketone peroxide, TEPA, trimethylhexane diamine, peroxidating first
Ethyl ketone, TEPA, the weight ratio of trimethylhexane diamine are 3:3:4.
Further, the coupling agent includes the double trimethoxy silicon substrate ethane of 1,2-.
Further, the property-modifying additive includes calcium carbonate, the boric acid ester coupler modification that boric acid ester coupler is modified
Borate whisker.
A kind of preparation method of artificial quartz stone plate, comprises the following steps：
(1) each component is measured in proportion；
(2) 1/4 volume and silica flour mixing 8h, system 1 is obtained；
(3) system 1 is stirred with quartz sand, obtains system 2；
(4) unsaturated polyester resin and property-modifying additive are stirred, obtain system 3
(5) system 2 is mixed with system 3, obtains system 4；
(6) system 4 and remaining toner are stirred, obtain system 5；
(7) system 5 is mixed with curing agent, silane coupler, white mica powder mixes；
(8) with press device the mixed material vibration moulding under vacuum of step (7), vacuum is less than-
0.098MPa；
(9) compacting finishes, in curing apparatus, with 270 DEG C of solidification 1h；
(10) polished after room temperature cooling with the fixed thickness of the fixed thick equipment of sheet material with water mill polissoir.
The technical scheme provided above the embodiment of the present invention is described in detail, specific case used herein
The principle and embodiment of the embodiment of the present invention are set forth, the explanation of above example is only applicable to help and understands this
The principle of inventive embodiments；Meanwhile for those of ordinary skill in the art, according to the embodiment of the present invention, in specific embodiment party
There will be changes in formula and application, in summary, this specification content should not be construed as limiting the invention.
Claims (7)
- A kind of 1. artificial quartz stone plate, it is characterised in that：In percentage by weight, composition includes：
- A kind of 2. artificial quartz stone plate according to claim 1, it is characterised in that：The unsaturated polyester resin includes epoxy resin and polyurethane resin, and epoxy resin and polyurethane resin weight ratio are 1: 2-1:4。
- A kind of 3. artificial quartz stone plate according to claim 2, it is characterised in that：The curing agent includes methyl ethyl ketone peroxide, TEPA, trimethylhexane diamine, methyl ethyl ketone peroxide, four ethene five Amine, the weight ratio of trimethylhexane diamine are 3:3:4.
- A kind of 4. artificial quartz stone plate according to claim 1, it is characterised in that：The coupling agent includes the double trimethoxy silicon substrate ethane of 1,2-.
- A kind of 5. artificial quartz stone plate according to claim 1, it is characterised in that：The property-modifying additive is included in the borate whisker that calcium carbonate, the boric acid ester coupler that boric acid ester coupler is modified are modified It is one or two kinds of.
- A kind of 6. preparation method of artificial quartz stone plate as described in claim 1-5 is any, it is characterised in that：Comprise the following steps：(1) each component is measured in proportion；(2) the toner and silica flour mixing 6-8h of 1/3-1/4 volumes, system 1 is obtained；(3) system 1 is stirred with quartz sand, obtains system 2；(4) unsaturated polyester resin and property-modifying additive are stirred, obtain system 3(5) system 2 is mixed with system 3, obtains system 4；(6) system 4 and remaining toner are stirred, obtain system 5；(7) system 5 is mixed with curing agent, silane coupler, white mica powder mixes；(8) the mixed material vibration moulding under vacuum with press device step (7)；(9) compacting finishes, in curing apparatus, with 70-270 DEG C of solidification 1-1.5h；(10) polished after room temperature cooling with the fixed thickness of the fixed thick equipment of sheet material with water mill polissoir.
- 7. the preparation method of artificial quartz stone plate according to claim 6, it is characterised in that：It is true in the step (8) Reciprocal of duty cycle is less than -0.098MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711029503.1A CN107814510A (en) | 2017-10-30 | 2017-10-30 | A kind of artificial quartz stone plate and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711029503.1A CN107814510A (en) | 2017-10-30 | 2017-10-30 | A kind of artificial quartz stone plate and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107814510A true CN107814510A (en) | 2018-03-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201711029503.1A Pending CN107814510A (en) | 2017-10-30 | 2017-10-30 | A kind of artificial quartz stone plate and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110183145A (en) * | 2019-05-20 | 2019-08-30 | 福建师范大学 | It is a kind of to utilize blended textile fabric production green building material of recycling and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN104446142A (en) * | 2014-11-12 | 2015-03-25 | 广东中旗新材料科技有限公司 | Potassium titanate crystal whisker composite quartz plate product and preparation method of composite quartz plate product |
| CN105819722A (en) * | 2016-03-07 | 2016-08-03 | 山东源根化学技术研发有限公司 | Quartz stone plate made from modified calcium carbonate, and making method thereof |
-
2017
- 2017-10-30 CN CN201711029503.1A patent/CN107814510A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN104446142A (en) * | 2014-11-12 | 2015-03-25 | 广东中旗新材料科技有限公司 | Potassium titanate crystal whisker composite quartz plate product and preparation method of composite quartz plate product |
| CN105819722A (en) * | 2016-03-07 | 2016-08-03 | 山东源根化学技术研发有限公司 | Quartz stone plate made from modified calcium carbonate, and making method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110183145A (en) * | 2019-05-20 | 2019-08-30 | 福建师范大学 | It is a kind of to utilize blended textile fabric production green building material of recycling and preparation method thereof |
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Application publication date: 20180320 |