CN101045832A - Polymer coating composite and preparation method thereof - Google Patents

Polymer coating composite and preparation method thereof Download PDF

Info

Publication number
CN101045832A
CN101045832A CNA2007102003150A CN200710200315A CN101045832A CN 101045832 A CN101045832 A CN 101045832A CN A2007102003150 A CNA2007102003150 A CN A2007102003150A CN 200710200315 A CN200710200315 A CN 200710200315A CN 101045832 A CN101045832 A CN 101045832A
Authority
CN
China
Prior art keywords
weight ratio
ground
coating
agent
gathers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2007102003150A
Other languages
Chinese (zh)
Inventor
袁景华
袁谞虹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CNA2007102003150A priority Critical patent/CN101045832A/en
Publication of CN101045832A publication Critical patent/CN101045832A/en
Priority to PCT/EP2008/002342 priority patent/WO2008113609A2/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02—Agglomerated materials, e.g. artificial aggregates
    • C04B18/021—Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34—Non-shrinking or non-cracking materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Abstract

This invention relates to a dope combination. The film coating it formed is amorphous gelatinous substance, base unit is three-dimensional network formed by connection of silicon - oxygen tetrahedron and aluminium - oxygen tetrahedron. end product takes electrovalent bond and covalent bond as main, vander waas bond as complement, possess linkage structure of organic heavy polymer, and double property of inorganic polymer and organic polymer. The unique performance supple the insufficiency of organic high molecular polymer. It possesses favorable performance of acid-proof, alkali-proof, impervious, antifreeze, seawater resistance and high temperature resistance.

Description

Ground polymer coating composite and preparation method thereof
Technical field
The present invention relates to a kind of inorganic paint, particularly a kind of ground polymer coating composite that possesses organic high molecular polymer keyed jointing structure and preparation method thereof.
Background technology
Coatings industry is the intensive manufacturing of material.Most of organic coatings have used in manufacturing processed human body and the deleterious material of environment.Most of deleterious material can evaporate in the atmospheric environment in organic coating manufacturing, construction process or after the construction, and the detrimentally affect that environment is produced has caused the common concern in the whole world thus.Simultaneously, the manufacturing of organic coating is also consuming a large amount of natural resourcess, and the research emphasis of especially petroleum resources, so people has forwarded on the inorganic paint.The inorganic paint advantage is a lot, its feature of environmental protection, the functional and comprehensive outstanding representation of Technological Economy have promoted various inorganic coating composition patents constantly to occur, and water glass, potassium silicate, lithium silicate resin are for example arranged, cement, silicon sol, phosphoric acid salt and polysiloxane-based inorganic coating composition.The just visible inorganic paint of " inorganicization of coating " theory that proposes from developed country has occupied very consequence.
The performance of inorganic paint exists some defectives and deficiency, major cause is that the base-material of inorganic paint is all with water glass, potassium silicate, lithium silicate resin, cement, silicon sol, phosphoric acid salt and polysiloxane-based binding agent are filmogen, the formed fragility of filming is big, snappiness is poor, easy to crack, to the poor adhesive force of organic ground and plastics class ground, range of application is restricted thus.Also there is the bad shortcoming of levelling property in inorganic paint, so decorative effect is not as organic coating.Inorganic paint is of less types simultaneously, still can not satisfy the demand in market aspect a lot.
Though inorganic paint has very long developing history and numerous patents of invention, its filmogen always is centered around water glass, potassium silicate, lithium silicate resin, cement, silicon sol, changes between phosphoric acid salt and the polysiloxane-based binder material.Since water glass, potassium silicate, lithium silicate resin, cement, silicon sol, phosphoric acid salt and polysiloxane-based binding agent inherent rerum natura can't change, and inorganic paint is difficult to have breakthrough on performance.
Ground polymers (Geopolymer) is that its original meaning is meant the aluminium silicate mineral polymkeric substance that is formed by the geochemistry effect by the notion of French scientist Joseph Davidovits in the proposition of nineteen seventies proposition.The ground polymers is to be main raw material with metakaolin or other alumina-silica material, specific reaction takes place and the polymeric material that forms through the effect of chemical activator.The polymerisate of ground polymers is the amorphous inorganic polymer of network-like structure, has high adhesive property, shows higher early stage cohesive strength especially.Also has good acid-and base-resisting, anti-seawater and high thermal resistance.Its compactness extent is higher, and impervious freezing tolerance is strong, and especially interfacial bonding property is good, can form firm bonding surface with different basal planes, and can keep the stable of volume for a long time.
With the ground polymers is that binding agent can be made multiple product, and coating is exactly one of them, because coating is to have ornamental, protective and functional product, great majority all will have color supporting, therefore, with white metakaolin is aluminosilicate preparation ground polymers, and the matrix of white can be provided for coating, helps allocating bright-coloured lucid and lively color.
The patent that publish in the whole world had the report of a lot of relevant inorganic paints with paper, but the report that gathers coating actually rare relevantly.Discussed with metakaolin 20% weight ratio, alkali-activator (the liquid soluble glass that the water glass of chemical pure sodium hydroxide (potassium) and technical grade is mixed with) 45% weight ratio in the experimental study of polymers base coating " " literary composition that retrieves that China's " New Building Materials " delivers 2004.5 phases of magazine with certain modulus and concentration, (light calcium carbonate, fineness are 600 orders to filler; Wollastonite powder, fineness is 600 orders) 12% weight ratio is raw material, through weighing, stir and place 1h, with painting brush it is painted on the base plate of getting ready (asbestos cement plate) equably then, brush again behind the 5h 1 time (the about 0.5mm of total thickness), carry out performance test behind the storing 28d.
The ground polymers base coating of introducing in the experimental study of polymers base coating " " literary composition is a kind of two-component coating, liquid ingredient (alkali-activator) to be mixed mutually, stirs with solid ingredient (metakaolin, filler) before use and place 1h, with painting brush it is painted on the base plate of getting ready (asbestos cement plate) equably then.
Two-pack ground polymers base coating is in packing, transportation and store that compare its expense with onepot coating higher, and main is to use inconvenience at the construction field (site), occurs the allotment error easily, and influences coating quality.
Liquid soluble glass in the alkali-activator component of two-pack ground polymers base coating is the mixing solutions of poly-silicic acid hydrogen sodium, the polymerization degree of (new system liquid surpasses 15mim) poly-silicic acid begins to take place disproportionation immediately in the seasoning process, micelle is on the increase in the water glass solution, to promote the gelation process, generation can not be from the aging disaster that reverses.Be fuzzy relatively and be difficult to expection through the time of market circulation because ground polymers base coating leaves production line to construction, the viscosity of the alkali-activator of two-pack ground polymers base coating but constantly descends along with the variation of time and environment, the quality parameter that manifests during construction, directly have influence on the estimated performance of ground polymers base coating, until product failure.
Use the ground polymers base coating of the traditional coating fixed pattern preparation of blending dispersion packing, equally distributed pigment, filler gluing can only be got up, form thin deposited lid of filming of one deck at matrix surface.Experimental results show that between ground polymers binding agent and pigment, the filler and can not react, can not form transition layer.And the solidification process that the ground polymers is filmed carries out under nature (except the singularity) condition, factor such as envrionment temperature, humidity can not meet the ideal conditions that ground polymers adhesive cures becomes to film, the mechanical property of local polymers is not in full use, and filming easily, the generation filler exposes, comes off and the rimose surface imperfection.Snappiness, levelling property that the ground polymers is filmed are difficult to the performance index near organic coating film.
Summary of the invention
Main purpose of the present invention has provided a kind of ground polymer coating composite that possesses inorganic polymer and organic polymer dual nature.Can improve defective and deficiency that existing inorganic paint exists effectively, be broad-spectrum green environmental friendly coatings.
Another purpose of the present invention has provided the preparation method of a kind of ground polymer coating composite.
Technical scheme of the present invention
The weight proportion that is included in each component in the described ground polymer coating composite is:
The ground of 10-70% weight ratio gathers the paint adhesion agent,
The ground of 30-90% weight ratio gathers the coating wrap,
The filler of 0-50% weight ratio,
The water of 0-80% weight ratio,
In the described ground polymer coating composite each component preferably weight proportion be:
The ground of 25-60% weight ratio gathers the paint adhesion agent,
The ground of 45-80% weight ratio gathers the coating wrap,
The filler of 0-50% weight ratio,
The water of 0-80% weight ratio,
The better weight proportion of each component is in the described ground polymer coating composite:
The ground of 40-50% weight ratio gathers the paint adhesion agent,
The ground of 55-70% weight ratio gathers the coating wrap,
The filler of 0-50% weight ratio,
The water of 0-80% weight ratio,
Below will specifically describe technical scheme of the present invention:
The ground that is included in the described ground polymer coating composite gathers the paint adhesion agent, and the weight proportion that this ground gathers each component in the paint adhesion agent is:
The metakaolin of 15-60% weight ratio (d≤44 μ m),
At least a above water glass of 35-80% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
At least a above solid sodium hydroxide, potassium hydroxide, the lithium hydroxide of 1-8% weight ratio,
The toughner of 1-25% weight ratio; VINNAPAS 8.RI551 Z,
The hydrophober of 0.1-0.5% weight ratio; SILRES 8.BS Powder A,
The dispersion agent of 1-8% weight ratio; Na 5P 3O 10,
The defoamer of 0.01-0.1% weight ratio; AGITAN 8.P803,
The water reducer of 0.1-1% weight ratio; MELMENT F10,
The water-holding agent of 0.2-1% weight ratio; PMC-15US,
The stiffening agent of 0-10% weight ratio; NaSiF 6,
The ground that is included in the described ground polymer coating composite gathers the paint adhesion agent, this ground gather in the paint adhesion agent each component preferably weight proportion be:
The metakaolin of 25-50% weight ratio (d≤44 μ m),
At least a above water glass of 45-70% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
At least a above solid sodium hydroxide of 1-8% weight ratio, potassium hydroxide, lithium hydroxide,
The toughner of 5-20% weight ratio; VINNAPAS 8.RI551 Z,
The hydrophober of 0.1-0.5% weight ratio; SILRES 8.BS Powder A
The dispersion agent of 1-8% weight ratio; Na 5P 3O 10
The defoamer of 0.01-0.1% weight ratio; AGITAN 8.P803
The water reducer of 0.1-1% weight ratio; MELMENT F10
The water-holding agent of 0.2-1% weight ratio; PMC-15US
The stiffening agent of 0-10% weight ratio; NaSiF 6,
The ground that is included in the described ground polymer coating composite gathers the paint adhesion agent, and this ground gathers that the better weight proportion of each component is in the paint adhesion agent:
The metakaolin of 35-40% weight ratio (d≤44 μ m),
At least a above water glass of 50-60% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
At least a above solid sodium hydroxide of 1-8% weight ratio, potassium hydroxide, lithium hydroxide,
The toughner of 10-15% weight ratio; VINNAPAS 8.RI551 Z,
The hydrophober of 0.1-0.5% weight ratio; SILRES 8.BS Powder A
The dispersion agent of 1-8% weight ratio; Na 5P 3O 10
The defoamer of 0.01-0.1% weight ratio; AGITAN 8.P803
The water reducer of 0.1-1% weight ratio; MELMENT F10
The water-holding agent of 0.2-1% weight ratio; PMC-15US
The stiffening agent of 0-10% weight ratio; NaSiF 6,
The ground that is included in the described ground polymer coating composite gathers the paint adhesion agent, and the polymeric reaction product that this ground gathers the paint adhesion agent comprises a kind of material of following structure at least:
1) single sial ground polymers [Poly (siaiate)]
Figure A20071020031500111
2) two sial ground polymers [Poly (sialate-siloxo)]
Figure A20071020031500121
3) three sial ground polymers [Poly (sialate-dsiloxo)]
Figure A20071020031500122
Be included in ground in the described ground polymer coating composite and gather toughner in the paint adhesion agent, this toughner consumption is higher than and gathers paint adhesion agent 25% weight ratio or when higher describedly, inorganic, organic dual nature of described ground polymer coating composite, the trend of organising will occur, disappear up to inorganic nature.Consumption should be looked the purposes of described ground polymer coating composite and change, and consumption is to gather paint adhesion agent 1-25% weight ratio describedly; Be the 5-20% weight ratio preferably; Be the 10-15% weight ratio better.
The ground that is included in the described ground polymer coating composite gathers the paint adhesion agent, and this ground gathers that paint adhesion agent consumption is lower than described ground polymer coating composite 10% weight ratio or when lower, the strength of coating of described ground polymer coating composite is lower.When consumption surpasses 70% weight ratio, the coating of described ground polymer coating composite have be full of cracks just to.Consumption should be looked the purposes of described ground polymer coating composite and change, and consumption is a described ground polymer coating composite 10-70% weight ratio; Better consumption is the 25-60% weight ratio; Better consumption is the 40-50% weight ratio.
The ground that is included in the described ground polymer coating composite gathers the coating wrap, and the weight proportion that this ground gathers each component in the coating wrap is:
The ground of 8-40% weight ratio gathers the coating coating agent,
The pigment of 0-92% weight ratio,
The functional agent of 0-92% weight ratio,
The ground that is included in the described ground polymer coating composite gathers the coating wrap, this ground gather in the coating wrap each component preferably weight proportion be:
The ground of 12-32% weight ratio gathers the coating coating agent,
The pigment of 0-88% weight ratio,
The functional agent of 0-88% weight ratio,
The ground that is included in the described ground polymer coating composite gathers the coating wrap, and this ground gathers that the better weight proportion of each component is in the coating wrap:
The ground of 18-24% weight ratio gathers the coating coating agent,
The pigment of 0-82% weight ratio,
The functional agent of 0-82% weight ratio,
Be included in the ground that gathers in the coating wrap on the ground in the described ground polymer coating composite and gather the coating coating agent, the weight proportion that this ground gathers each component in the coating coating agent is:
The metakaolin of 15-60% weight ratio (d≤44 μ m),
At least a above water glass of 35-80% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
At least a above solid sodium hydroxide, potassium hydroxide, the lithium hydroxide of 1-8% weight ratio,
The dispersion agent of 1-8% weight ratio; Na 5P 3O 10,
The defoamer of 0.01-0.1% weight ratio; AGITAN 8.P803,
The water reducer of 0.1-1% weight ratio; MELMENT F10,
The stiffening agent of 0-10% weight ratio; NaSiF 6,
Be included in the ground that gathers in the coating wrap on the ground in the described ground polymer coating composite and gather the coating coating agent, this ground gather in the coating coating agent each component preferably weight proportion be:
The metakaolin of 22-49% weight ratio (d≤44 μ m),
At least a above water glass of 46-71% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
At least a above solid sodium hydroxide, potassium hydroxide, the lithium hydroxide of 1-8% weight ratio,
The dispersion agent of 1-8% weight ratio; Na 5P 3O 10,
The defoamer of 0.01-0.1% weight ratio; AGITAN 8.P803,
The water reducer of 0.1-1% weight ratio; MELMENT F10,
The stiffening agent of 0-10% weight ratio; NaSiF 6,
Be included in the ground that gathers in the coating wrap on the ground in the described ground polymer coating composite and gather the coating coating agent, this ground gathers that the better weight proportion of each component is in the coating coating agent:
The metakaolin of 31-40% weight ratio (d≤44 μ m),
At least a above water glass of 52-63% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
At least a above solid sodium hydroxide, potassium hydroxide, the lithium hydroxide of 1-8% weight ratio,
The dispersion agent of 1-8% weight ratio; Na 5P 3O 10,
The defoamer of 0.01-0.1% weight ratio; AGITAN 8.P803,
The water reducer of 0.1-1% weight ratio; MELMENT F10,
The stiffening agent of 0-10% weight ratio; NaSiF 6,
Be included in the ground that gathers in the coating wrap on the ground in the described ground polymer coating composite and gather the coating coating agent, the polymeric reaction product that this ground gathers the coating coating agent comprises a kind of material of following structure at least:
1) single sial ground polymers [Poly (siaiate)]
2) two sial ground polymers [Poly (sialate-siloxo)]
3) three sial ground polymers [Poly (sialate-dsiloxo)]
Figure A20071020031500143
Be included in the ground that gathers in the coating wrap on the ground in the described ground polymer coating composite and gather the coating coating agent, this ground gathers coating coating agent consumption and is lower than and gathers coating wrap 8% weight ratio or when lower describedly, the intensity of gathering the coating wrap lower describedly, and " dressing " is thinner.When consumption surpassed 40% weight ratio, " dressing " that gathers the coating wrap blocked up describedly.Consumption should be looked the purposes of described ground polymer coating composite and change, and consumption is the 8-40% weight ratio of gathering the coating wrap describedly; Better consumption is the 12-32% weight ratio; Better consumption is the 18-24% weight ratio.
Be included in ground in the described ground polymer coating composite and gather pigment in the coating wrap, the color harmony that this pigment should be looked described ground polymer coating composite requires to choose wantonly.
Be included in ground in the described ground polymer coating composite and gather functional agent in the coating wrap, this functional agent comprises following material: expanded graphite, melamine phosphate, hydrated glass powder, tetramethylolmethane, aluminium hydroxide, weisspiessglanz, spherical closed pore expanded perlite, expanded vermiculite, coal fly ash hollow micro bead, hollow glass bead, aluminum silicate fiber powder, rock wool fibers powder, iron mica, zinc phosphate, metal zinc, zinc oxide, glass flake, oxidized metal (cobalt, manganese, nickel, iron, barium, zinc) pyroceramic powder, Ag 3PO 4-Zn 3(PO 4) 2(Ag-Zn) composite antibiosis powder, carbonyl iron dust, scale graphite powder, silver-plated copper powder, silver-plated nickel powder, silvered glass powder, silvered mica powder, aluminium powder, Stainless Steel Powder, (MoS 2), glass with lower alkali content powder, carborundum powder, Red copper oxide, capsicine, Cu 2(HgI 4), cobalt chloride vulkacit H, PbO, BaSO 4, Fe 2O 3, concrete kind should be looked the purposes of described ground polymer coating composite and be required to select.
Be included in the filler in the described ground polymer coating composite, this filler comprises silica powder, talcum powder, mica powder, wollastonite powder, diatomite, wilkinite, kaolin, sepiolite powder, polypropylene staple fibre, pigment.Concrete kind should be looked the purposes of described ground polymer coating composite and be required to select.
The method for preparing the ground polymer coating composite:
One, prepare ground polymer coating composite method may further comprise the steps:
1) preparation ground gathers the paint adhesion agent, according to filling a prescription metakaolin, at least a above water glass, potassium silicate, lithium silicate powdered resin, at least a above solid sodium hydroxide, potassium hydroxide, lithium hydroxide and VINNAPAS 8.RI551Z, SILRES 8.BS Powder A, Na 5P 3O 10, AGITAN 8.P803, MELMENT F10, PMC-15US, NaSiF 6Accurately weighing is sent in the mixer, goes into the interior dry process of pulverizer after mixing to d≤44 μ m, and the feed bin I that packs into promptly finishes.
2) preparation ground gathers the coating wrap, and at first preparation ground gathers the coating coating agent, and the foundation prescription is with metakaolin, at least a above water glass, potassium silicate, lithium silicate liquid resin, at least a above solid sodium hydroxide, potassium hydroxide, lithium hydroxide, Na 5P 3O 10, AGITAN 8.P803, MELMENT F10, NaSiF 6With the true weighing of level, send in the mixer, mix after wet grinding mill is machined into d≤44 μ m is qualified, inject the tempering tank IV of band stirrer.
Preparation ground gathers the coating wrap, according to the prescription of ground polymer coating composite, with pigment or the accurate weighing of functional agent, puts among the tempering tank IV that gathers the coating coating agent with being equipped with, stirs into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot and descend sclerosis 24h or air-set 7d under normal temperature and pressure conditions with 50-150 ℃ of temperature condition, the sclerosis back demoulding is pulverized, purposes according to the ground polymer coating composite, the ground that filters out required particle diameter gathers coating wrap particle, and be dried to moisture content≤2%, among the feed bin II that packs into.
3) according to the prescription of ground polymer coating composite, the ground that takes by weighing among the feed bin I gathers the paint adhesion agent, and the ground of feed bin II gathers the coating wrap, the filler of 0-50% weight ratio (when being necessary), send in the mixer, be transported to after mixing among the finished bin VI, i.e. powdery ground polymer coating composite is finished in preparation.
4) prescription of foundation ground polymer coating composite, the ground that takes by weighing earlier among the feed bin II gathers the coating wrap, puts among the tempering tank VII of band stirrer, taking by weighing the filler (when being necessary) and the cleaning water of ground among the feed bin I gathering paint adhesion agent, 0-50% weight ratio again sends in the mixer, mix after the grinding machine wet processes to d≤44 μ m be qualified, be injected among the tempering tank VII that gathers the coating wrap with being equipped with, be mixed into uniform lotion, tinning promptly prepares finishes paste ground polymer coating composite.
The characteristics of the present invention ground polymer coating composite
1) the present invention ground polymer coating composite is a single-component product, and its expense is upward compared in packing, transportation and storage with two-component coating lower, and main is to be convenient to on-the-spot the use, stops to allocate error, guarantees coating quality.
2) water glass, potassium silicate, lithium silicate powdered resin and solid sodium hydroxide, potassium hydroxide, the lithium hydroxide in the present invention ground polymer coating composite has enough metakaolins to be dissolved by it at dissolved simultaneously, the fracture of siloxane bond and alumina key takes place in the alkali environment, form oligomeric silicon (aluminium)-oxygen tetrahedron element depolymerization reaction, stoped the gelation process.Effectively having prevented can not be from the aging generation that reverses.
3) pot life of ground of the present invention polymer coating composite (dry powder) is almost unrestricted.The pot life of described ground polymer coating composite (lotion) can be satisfied the seasoning standard of traditional coating.
4) ground of the present invention polymer coating composite in ground gather the coating coating agent required function material, pigment wrapped up, under optimal conditions, carry out " depolymerization-polycondensation " reaction, the ground that obtains best mechanical property gathers the coating wrap.
5) ground in the ground of the present invention polymer coating composite gathers the coating wrap, optimisedly is ground into required size particles.There is best size distribution coating structure inside.
6) gather coating wrap granule interior of the present inventionly closely be wrapped in functional materials, pigment, and appearance has the ground polymers " dressing " of customization under the optimal conditions, when gathering the paint adhesion agent once more during hybrid reaction with ground, two-phase all is the ground polymers, and best consistency is arranged.
7) gather coating wrap particle surface of the present inventionly be inlaid with active particle,, will preferentially finish " depolymerization-polycondensation " reaction, form complete filming jointly when gathering the paint adhesion agent when mixing once more with ground.
8) gather coating wrap particle surface because of pulverizing damaged ground polymers " dressing " breach of the present inventionly, gather the paint adhesion agent with ground and can fill up the damaged of ground polymers " dressing " automatically during hybrid reaction once more.
9) formed filming is the non-crystalline state gum material in the ground of the present invention polymer coating composite, its elementary cell is the three-dimensional network that silicon-oxygen tetrahedron links to each other with aluminium-oxygen tetrahedron and forms, final product is based on ionic linkage and covalent linkage, van der waals bond is auxilliary, possesses the dual nature of organic high molecular polymer keyed jointing structure and inorganic polymer and organic polymer.Its particular performances has been replenished the deficiency of organic high molecular polymer.Manifesting good acidproof, alkaline-resisting, impervious, freeze proof, anti-seawater and resistance to elevated temperatures, is a kind of nontoxic, pollution-free, not aging, does not shrink, with eco-friendly durable coating.
Embodiment
Scope of the present invention is not limited to the following example
Embodiment 1
Water glass dry powder resin, the potassium silicate dry powder resin of 5kg modulus=1.6, the lithium silicate dry powder resin of 1kg modulus=1.5,2kg sodium hydroxide, 1kg potassium hydroxide, 0.5kg lithium hydroxide, 3kgVINNAPAS with 22kg metakaolin, 30kg modulus=1.2 8.RI551 Z, 0.3kgSILRES 8.BS Powder A, 0.6kg Na 5P 3O 10, 0.06kg AGITAN 8.P803,0.6kg MELMENT F10,0.2kg PMC-15US, 4kg NaSiF 6Concentrate and mix, gather the paint adhesion agent with becoming through grinding and processing.
Embodiment 2
Water glass dry powder resin, the potassium silicate dry powder resin of 5kg modulus=1.6, the lithium silicate dry powder resin of 1kg modulus=1.5,2kg sodium hydroxide, 1kg potassium hydroxide, 0.5kg lithium hydroxide, 0.8kgNa with 36kg metakaolin, 30kg modulus=1.2 5P 3O 10, 0.06kg AGITAN 8.P803,0.45kg MELMENT F10,6kg NaSiF 6After concentrating mixing, gather the coating coating agent through grinding and processing with becoming.
Embodiment 3
30kg ground is gathered coating coating agent, 5kg titanium dioxide, 0.01kg ultramarine blue and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 95 ℃ of temperature condition, sclerosis back separating powder is broken to d≤15 μ m, and be dried to moisture content≤2%, send in the mixer, and then adding 35kg ground gathers the paint adhesion agent, 0.1kg the polypropylene staple fibre mixes, mixture homogeneity≤1% is the discharging packing.This example is an anti-cracking waterproof type white construction coating.
Embodiment 4
7kg ground is gathered coating coating agent, 82kg metal zinc and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 125 ℃ of temperature condition, sclerosis back separating powder is broken to d≤16 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 10kg ground gathers the paint adhesion agent, the 1kg sepiolite powder mixes, and mixture homogeneity≤1% is the discharging packing.This example is the anti-cracking waterproof zinc-rich paint.
Embodiment 5
16kg ground is gathered coating coating agent, 8kg spherical closed pore expanded perlite, 8kg expanded vermiculite, 20kg coal fly ash hollow micro bead, 10kg hollow glass bead, 12kg diatomite and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 65 ℃ of temperature condition, sclerosis back separating powder is broken to d≤3mm, and be dried to moisture content≤2% and send in the mixer, and then adding 22kg ground gathers the paint adhesion agent, the 4kg rock wool fibers mixes, and mixture homogeneity≤1% is the discharging packing.This example is the anti-cracking waterproof adiabatic coating.
Embodiment 6
18kg ground is gathered coating coating agent, 10kg melamine phosphate, 10kg tetramethylolmethane, 12kg expanded graphite, 8kg hydrated glass powder, 5kg aluminium hydroxide, 2kg weisspiessglanz, 12kg diatomite and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 65 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 21kg ground gathers the paint adhesion agent, 2kg aluminum silicate fiber powder mixes, and mixture homogeneity≤1% is the discharging packing.This example is indoor outer frie retardant coating.
Embodiment 7
30kg ground is gathered coating coating agent, 20kg iron mica, 8kg zinc phosphate, 7kg zinc oxide, 10kg glass flake and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 110 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 24kg ground gathers the paint adhesion agent, 0.1kg the polypropylene staple fibre mixes, mixture homogeneity≤1% is the discharging packing.This example is a rust proof paint.
Embodiment 8
40kg ground is gathered coating coating agent, 10kg Ag 3PO 4-Zn 3(PO 4) 2(Ag-Zn) composite antibiosis powder and water drop in the tempering tank under whipped state, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 110 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 24kg ground gathers the paint adhesion agent, 6kg sepiolite powder, 5kg talcum powder, 15kg ground dolomite mix, and mixture homogeneity≤1% is the discharging packing.This example is a mould-repellant coating.
Embodiment 9
36kg ground is gathered coating coating agent, 18kg oxidized metal pyroceramic powder (cobalt, manganese, nickel, iron, barium, zinc), 20kg carbonyl iron dust and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 135 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 25kg ground gathers the paint adhesion agent, 1kg aluminum silicate fiber powder mixes, and mixture homogeneity≤1% is the discharging packing.This example is an invisible coating.
Embodiment 10
33kg ground is gathered coating coating agent, 17kg scale graphite powder, 5kg silvered mica powder, 12kg silvered glass powder, 2kg silver-plated copper powder, the silver-plated nickel powder of 2kg and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 86 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 28kg ground gathers the paint adhesion agent, 1kg aluminum silicate fiber powder mixes, and mixture homogeneity≤1% is the discharging packing.This example is an electrically conducting coating.
Embodiment 11
33kg ground is gathered coating coating agent, 10kg Stainless Steel Powder, 6kg sepiolite powder, 18kg aluminium powder and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 145 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 31kg ground gathers the paint adhesion agent, 2kg aluminum silicate fiber powder mixes, and mixture homogeneity≤1% is the discharging packing.This example is a heat resisting coating.
Embodiment 12
23kg ground is gathered coating coating agent, 32kg scale graphite powder, 6kg MoS 2Drop in the tempering tank under whipped state with water, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 86 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 35kg ground gathers the paint adhesion agent, the 4kg talcum powder mixes, and mixture homogeneity≤1% is the discharging packing.This example is a slip coating.
Embodiment 13
13kg ground is gathered coating coating agent, 51kg glass with lower alkali content powder, 6kg carborundum powder, drops in the tempering tank under whipped state with water, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 120 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 27kg ground gathers the paint adhesion agent, 2kg sepiolite powder, 1kg aluminum silicate fiber powder mix, and mixture homogeneity≤1% is the discharging packing.This example is anti-nitrogen antioxidizing paint.
Embodiment 14
17kg ground is gathered coating coating agent, 25kg Red copper oxide, 12kg capsicine, drops in the tempering tank under whipped state with water, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 55 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 38kg ground gathers the paint adhesion agent, 5kg sepiolite powder, 3kg aluminum silicate fiber powder mix, and mixture homogeneity≤1% is the discharging packing.This example is an antifouling paint.
Embodiment 15
18kg ground is gathered coating coating agent, 16kg cobalt chloride vulkacit H, 10kg kaolin and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 56 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 39kg ground gathers the paint adhesion agent, 10kg ground dolomite, 6kg sepiolite powder, 1kg aluminum silicate fiber powder mix, and mixture homogeneity≤1% is the discharging packing.This example is a thermo-paint.
Embodiment 16
27kg ground is gathered coating coating agent, 10kgPbO, 19kBaSO 4, 15k Fe 2O 3, drop in the tempering tank under whipped state with water, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot with sclerosis 24h under 86 ℃ of temperature condition, sclerosis back separating powder is broken to d≤44 μ m, and be dried to moisture content≤2% and send in the mixer, and then adding 27kg ground gathers the paint adhesion agent, 1kg wilkinite, 1kg aluminum silicate fiber powder mix, and mixture homogeneity≤1% is the discharging packing.This example is penetrated coating for the anti-width of cloth.
Embodiment 17
38kg ground is gathered coating coating agent, 17kg glass flake, 15kg mica powder and water under whipped state, drop in the tempering tank, stir into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into the 7d that hardens under the natural condition, sclerosis back separating powder is broken to d≤44 μ m, send in the mixer, and then adding 18kg ground gathers paint adhesion agent, 12kgVINNAPAS 8.RI551 Z, 0.1kg polypropylene staple fibre mixes, regulating pondage, solids content 〉=52%, mixing is the discharging packing.This example is an elastic water proofing paint.

Claims (18)

  1. One kind ground polymer coating composite, it is characterized in that: the weight proportion of each component is in the described ground polymer coating composite:
    The ground of 10-70% weight ratio gathers the paint adhesion agent,
    The ground of 30-90% weight ratio gathers the coating wrap,
    The filler of 0-50% weight ratio,
    The water of 0-80% weight ratio.
  2. 2. polymer coating composite according to claim 1ly is characterized in that: in the described ground polymer coating composite each component preferably weight proportion be:
    The ground of 25-60% weight ratio gathers the paint adhesion agent,
    The ground of 45-80% weight ratio gathers the coating wrap,
    The filler of 0-50% weight ratio,
    The water of 0-80% weight ratio.
  3. 3. polymer coating composite according to claim 1ly, it is characterized in that: the better weight proportion of each component is in the described ground polymer coating composite:
    The ground of 40-50% weight ratio gathers the paint adhesion agent,
    The ground of 55-70% weight ratio gathers the coating wrap,
    The filler of 0-50% weight ratio,
    The water of 0-80% weight ratio.
  4. 4. polymer coating composite according to claim 1ly, it is characterized in that: the weight proportion that gathers each component in the paint adhesion agent is describedly:
    The metakaolin of 15-60% weight ratio (d≤44 μ m),
    At least a above water glass of 35-80% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
    At least a above solid sodium hydroxide, potassium hydroxide, the lithium hydroxide of 1-8% weight ratio,
    The toughner of 1-25% weight ratio; VINNAPASRI551 Z,
    The hydrophober of 0.1-0.5% weight ratio; SILRESBS Powder A,
    The dispersion agent of 1-8% weight ratio; Na5P3O10,
    The defoamer of 0.01-0.1% weight ratio; AGITAN P803,
    The water reducer of 0.1-1% weight ratio; MELMENT F10,
    The water-holding agent of 0.2-1% weight ratio; PMC-15US,
    The stiffening agent of 0-10% weight ratio; NaSiF6.
  5. 5. polymer coating composite according to claim 1ly is characterized in that: gather in the paint adhesion agent describedly each component preferably weight proportion be:
    The metakaolin of 25-50% weight ratio (d≤44 μ m),
    At least a above water glass of 45-70% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
    At least a above solid sodium hydroxide of 1-8% weight ratio, potassium hydroxide, lithium hydroxide,
    The toughner of 5-20% weight ratio; VINNAPASRI551 Z,
    The hydrophober of 0.1-0.5% weight ratio; SILRESBS Powder A
    The dispersion agent of 1-8% weight ratio; Na5P3O10
    The defoamer of 0.01-0.1% weight ratio; AGITAN P803
    The water reducer of 0.1-1% weight ratio; MELMENT F10
    The water-holding agent of 0.2-1% weight ratio; PMC-15US
    The stiffening agent of 0-10% weight ratio; NaSiF6.
  6. 6. polymer coating composite according to claim 1ly is characterized in that: gather describedly that the better weight proportion of each component is in the paint adhesion agent:
    The metakaolin of 35-40% weight ratio (d≤44 μ m),
    At least a above water glass of 50-60% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
    At least a above solid sodium hydroxide of 1-8% weight ratio, potassium hydroxide, lithium hydroxide,
    The toughner of 10-15% weight ratio; VINNAPASRI551 Z,
    The hydrophober of 0.1-0.5% weight ratio; SILRESBS Powder A
    The dispersion agent of 1-8% weight ratio; Na5P3O10
    The defoamer of 0.01-0.1% weight ratio; AGITAN P803
    The water reducer of 0.1-1% weight ratio; MELMENT F10
    The water-holding agent of 0.2-1% weight ratio; PMC-15US
    The stiffening agent of 0-10% weight ratio; NaSiF6.
  7. 7. gather the paint adhesion agent according to claim 1 or 2 or 3 or 4 or 5 or 6 describedly, it is characterized in that: the polymeric reaction product that gathers the paint adhesion agent comprises a kind of material of following structure describedly at least:
    1) single sial ground polymers [Poly (siaiate)]
    Figure A2007102003150004C1
    2) two sial ground polymers [Poly (sialate-siloxo
    Figure A2007102003150004C2
    3) three sial ground polymers [Poly (sialate-disiloxo)]
    Figure A2007102003150004C3
  8. 8. polymer coating composite according to claim 1ly, it is characterized in that: the weight proportion that gathers each component in the coating wrap is describedly:
    The ground of 8-40% weight ratio gathers the coating coating agent,
    The pigment of 0-92% weight ratio,
    The functional agent of 0-92% weight ratio.
  9. 9. polymer coating composite according to claim 1ly is characterized in that: gather in the coating wrap describedly each component preferably weight proportion be:
    The ground of 12-32% weight ratio gathers the coating coating agent,
    The pigment of 0-88% weight ratio,
    The functional agent of 0-88% weight ratio.
  10. 10. polymer coating composite according to claim 1ly is characterized in that: gather describedly that the better weight proportion of each component is in the coating wrap:
    The ground of 18-24% weight ratio gathers the coating coating agent,
    The pigment of 0-82% weight ratio,
    The functional agent of 0-82% weight ratio.
  11. 11. gather the coating wrap according to claim 1 or 2 or 3 or 8 or 9 or 10, it is characterized in that describedly: the weight proportion that gathers each component in the coating coating agent is describedly:
    The metakaolin of 15-60% weight ratio (d≤44 μ m),
    At least a above water glass of 35-80% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
    At least a above solid sodium hydroxide, potassium hydroxide, the lithium hydroxide of 1-8% weight ratio,
    The dispersion agent of 1-8% weight ratio; Na5P3O10,
    The defoamer of 0.01-0.1% weight ratio; AGITAN P803,
    The water reducer of 0.1-1% weight ratio; MELMENT F10,
    The stiffening agent of 0-10% weight ratio; NaSiF6.
  12. 12. gather the coating wrap according to claim 1 or 2 or 3 or 8 or 9 or 10, it is characterized in that describedly: gather in the coating coating agent describedly each component preferably weight proportion be:
    The metakaolin of 22-49% weight ratio (d≤44 μ m),
    At least a above water glass of 46-71% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
    At least a above solid sodium hydroxide, potassium hydroxide, the lithium hydroxide of 1-8% weight ratio,
    The dispersion agent of 1-8% weight ratio; Na5P3O10,
    The defoamer of 0.01-0.1% weight ratio; AGITAN P803,
    The water reducer of 0.1-1% weight ratio; MELMENT F10,
    The stiffening agent of 0-10% weight ratio; NaSiF6.
  13. 13. gather the coating wrap according to claim 1 or 2 or 3 or 8 or 9 or 10, it is characterized in that describedly: gather describedly that the better weight proportion of each component is in the coating coating agent:
    The metakaolin of 31-40% weight ratio (d≤44 μ m),
    At least a above water glass of 52-63% weight ratio, potassium silicate, lithium silicate powdered resin (modulus=0.5-2)
    At least a above solid sodium hydroxide, potassium hydroxide, the lithium hydroxide of 1-8% weight ratio,
    The dispersion agent of 1-8% weight ratio; Na5P3O10,
    The defoamer of 0.01-0.1% weight ratio; AGITAN P803,
    The water reducer of 0.1-1% weight ratio; MELMENT F10,
    The stiffening agent of 0-10% weight ratio; NaSiF6.
  14. 14. according to Claim 8 or 9 or 10 or 11 or 12 or 13 gather the coating wrap, it is characterized in that: the polymeric reaction product that gathers the coating coating agent comprises a kind of material of following structure describedly at least describedly:
    1) single sial ground polymers [Poly (siaiate)]
    Figure A2007102003150006C1
    2) two sial ground polymers [Poly (sialate-siloxo)]
    3) three sial ground polymers [Poly (sialate-disiloxo)]
    Figure A2007102003150006C3
  15. 15. according to Claim 8 or 9 or 10 gather the coating wrap, it is characterized in that: described pigment requires optional with the color harmony of ground polymer coating composite describedly.
  16. 16. according to Claim 8 or 9 or 10 gather the coating wrap, it is characterized in that: described functional agent comprises expanded graphite describedly, melamine phosphate, the hydrated glass powder, tetramethylolmethane, aluminium hydroxide, weisspiessglanz, spherical closed pore expanded perlite, expanded vermiculite, coal fly ash hollow micro bead, hollow glass bead, the aluminum silicate fiber powder, the rock wool fibers powder, iron mica, zinc phosphate, metal zinc, zinc oxide, glass flake, oxidized metal (cobalt, manganese, nickel, iron, barium, zinc) pyroceramic powder, Ag3PO4-Zn3 (PO4) 2 (Ag-Zn) composite antibiosis powder, carbonyl iron dust, the scale graphite powder, silver-plated copper powder, silver-plated nickel powder, the silvered glass powder, the silvered mica powder, aluminium powder, Stainless Steel Powder, (MoS2), the glass with lower alkali content powder, carborundum powder, Red copper oxide, capsicine, Cu2 (HgI4), the cobalt chloride vulkacit H, PbO, BaSO4Fe2O3
  17. 17. according to claim 1 or 2 or 3 described ground polymer coating composites, it is characterized in that: described filler comprises silica powder, talcum powder, mica powder, wollastonite powder, diatomite, wilkinite, kaolin, sepiolite powder, polypropylene staple fibre, pigment.
  18. 18. the preparation method of a ground polymer coating composite, it is characterized in that: described preparation method may further comprise the steps:
    One, prepare ground polymer coating composite method may further comprise the steps:
    1) preparation ground gathers the paint adhesion agent, according to filling a prescription with metakaolin, at least a above water glass, potassium silicate, lithium silicate powdered resin, at least a above solid sodium hydroxide, potassium hydroxide, lithium hydroxide and VINNAPASRI551 Z, SILRESBSPowderA, Na5P3O10, AGITANP803, MELMENT F10, the accurate weighing of PMC-15US, NaSiF6, send in the mixer, go into the interior dry process of pulverizer after mixing to d≤44 μ m, among the feed bin I that packs into
    2) preparation ground gathers the coating wrap, at first preparation ground gathers the coating coating agent, according to filling a prescription with metakaolin, at least a above water glass, potassium silicate, lithium silicate liquid resin, at least a above solid sodium hydroxide, potassium hydroxide, lithium hydroxide, Na5P3O10, AGITANP803, the true weighing of MELMENT F10, NaSiF6 and level is sent in the mixer, mix after wet grinding mill is machined into d≤44 μ m is qualified, inject the tempering tank IV of band stirrer.
    Preparation ground gathers the coating wrap, according to the prescription of ground polymer coating composite, with pigment or the accurate weighing of functional agent, puts among the tempering tank IV that gathers the coating coating agent with being equipped with, stirs into the mould that injects 200mm * 200mm * 200mm behind the uniform lotion.By the time after the lotion final set mould is put into pressure-pot and descend sclerosis 24h or air-set 7d under normal temperature and pressure conditions with 50-150 ℃ of temperature condition, the sclerosis back demoulding is pulverized, purposes according to the ground polymer coating composite, the ground that filters out required particle diameter gathers coating wrap particle, and be dried to moisture content≤2%, among the feed bin II that packs into.
    3) according to the prescription of ground polymer coating composite, the ground that takes by weighing among the feed bin I gathers the paint adhesion agent, and the ground of feed bin II gathers the coating wrap, the filler of 0-50% weight ratio (when being necessary), send in the mixer, be transported to after mixing among the finished bin VI, i.e. powdery ground polymer coating composite is finished in preparation.
    4) prescription of foundation ground polymer coating composite, the ground that takes by weighing earlier among the feed bin II gathers the coating wrap, puts among the tempering tank VII of band stirrer, taking by weighing the filler (when being necessary) and the cleaning water of ground among the feed bin I gathering paint adhesion agent, 0-50% weight ratio again sends in the mixer, mix after the grinding machine wet processes to d≤44 μ m be qualified, be injected among the tempering tank VII that gathers the coating wrap with being equipped with, be mixed into uniform lotion, tinning promptly prepares finishes paste ground polymer coating composite.
CNA2007102003150A 2007-03-22 2007-03-22 Polymer coating composite and preparation method thereof Pending CN101045832A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CNA2007102003150A CN101045832A (en) 2007-03-22 2007-03-22 Polymer coating composite and preparation method thereof
PCT/EP2008/002342 WO2008113609A2 (en) 2007-03-22 2008-03-25 Geopolymer composition, coating obtainable therefrom and methods

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2007102003150A CN101045832A (en) 2007-03-22 2007-03-22 Polymer coating composite and preparation method thereof

Publications (1)

Publication Number Publication Date
CN101045832A true CN101045832A (en) 2007-10-03

Family

ID=38770761

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2007102003150A Pending CN101045832A (en) 2007-03-22 2007-03-22 Polymer coating composite and preparation method thereof

Country Status (2)

Country Link
CN (1) CN101045832A (en)
WO (1) WO2008113609A2 (en)

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010157A (en) * 2010-09-30 2011-04-13 华南理工大学 Bi-component environment-friendly inorganic polymer coating material and preparation method thereof
CN102173718A (en) * 2011-01-12 2011-09-07 中国科学院新疆理化技术研究所 Composite board of kaolin and expanded vermiculite
CN102701552A (en) * 2012-06-21 2012-10-03 南京大学 Covering material for immobilized in-situ remediation of nitrogen in bottom sediment and preparation method thereof
CN102741191A (en) * 2009-05-28 2012-10-17 陶氏环球技术有限责任公司 Modified geopolymer compositions, processes and uses
CN102898908A (en) * 2012-09-28 2013-01-30 启东市华亚工业配套有限公司 Waterproof coating
CN103232197A (en) * 2013-04-28 2013-08-07 长安大学 Geopolymer tunnel fireproof coating and preparation method thereof
CN105153769A (en) * 2015-09-29 2015-12-16 北京志盛威华化工有限公司 Water-based anticorrosive paint for metal
CN106746968A (en) * 2016-12-02 2017-05-31 武汉天意成再生资源股份有限公司 A kind of super low energy consumption decoration coating materials for being applied to construction refuse regenerated product
CN107032676A (en) * 2017-04-20 2017-08-11 常州创索新材料科技有限公司 The preparation method of a kind of ground polymers porous material
CN107352861A (en) * 2017-06-06 2017-11-17 浙江加州国际纳米技术研究院台州分院 A kind of application method of maritime concrete protection land used polymer coating materials
CN107352860A (en) * 2017-06-06 2017-11-17 浙江加州国际纳米技术研究院台州分院 A kind of preparation method of maritime concrete protection land used polymer coating materials
CN108863127A (en) * 2018-07-05 2018-11-23 浙江大学 A kind of micro-nano fiber composite toughening enhancing geopolymer and preparation method thereof based on hole optimization
CN108929114A (en) * 2017-05-23 2018-12-04 中国石油天然气股份有限公司 A kind of geopolymer coating and its preparation method and application
CN110724427A (en) * 2019-09-29 2020-01-24 深圳市亚仕德新材料有限公司 Waterproof acid-resistant paint, preparation method thereof and waterproof acid-resistant coating
CN111635652A (en) * 2020-06-09 2020-09-08 河南省建筑工程质量检验测试中心站有限公司 Road marking paint based on geopolymer material and preparation method thereof
CN112028551A (en) * 2020-07-21 2020-12-04 北京工业大学 3D printing geopolymer for complex rock physical model and use method thereof
CN112094066A (en) * 2020-06-17 2020-12-18 湖北益通建设股份有限公司 Phosphogypsum-based aggregate for asphalt mixture and preparation method thereof
CN113072878A (en) * 2021-03-29 2021-07-06 浙江大江节能科技有限公司 Anticorrosive paint for inner wall of waste heat boiler flue and construction method thereof
CN113087534A (en) * 2021-03-31 2021-07-09 彩虹集团（邵阳）特种玻璃有限公司 High-temperature-resistant alkali-activated aluminosilicate binder and preparation method thereof
CN113993953A (en) * 2019-07-07 2022-01-28 第一点有限公司 Coating composition and method of applying same
CN114196242A (en) * 2022-01-14 2022-03-18 石河子大学 Anti-cracking geopolymer-based inorganic powder coating and preparation method and application thereof
CN114292584A (en) * 2022-01-06 2022-04-08 黄鑫 Water-based nano sand consolidation agent

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2949227B1 (en) * 2009-08-21 2013-09-27 Laboratoire Central Des Ponts Et Chaussees GEOPOLYMERIC CEMENT AND USE THEREOF
DE102009043988A1 (en) 2009-09-11 2011-03-24 Inomat Gmbh Geopolymeric material
US20110132230A1 (en) * 2009-12-08 2011-06-09 Chan Han Geopolymer precursor dry mixture, package, processes and methods
US8536250B2 (en) * 2010-10-14 2013-09-17 Tnemec Company Inc. Geopolymer and epoxy simultaneous interpenetrating polymer network composition, and methods for the same
US8512468B2 (en) 2010-12-20 2013-08-20 Louisiana Tech University Research Foundation, A Division Of Louisiana Tech University Foundation, Inc. Geopolymer mortar and method
CN102767243B (en) * 2012-07-13 2015-01-21 张玉洪 Manufacturing process for insulation board of fireproof exterior wall
GB2521992A (en) * 2013-04-10 2015-07-15 Alsitek Ltd Foamed material
WO2016016385A1 (en) * 2014-07-30 2016-02-04 Alistek Limited Geopolymer coating and mortar
ITUB20154724A1 (en) * 2015-09-30 2017-03-30 Alex Reggiani GEOPOLYMERIC BINDING MORTAR FOR RESTORATION, SHAVING, GROUTING, THERMAL INSULATION FOR VERTICAL, HAND, READY TO USE APPLICATIONS
US9938414B2 (en) 2016-03-18 2018-04-10 Council Of Scientific & Industrial Research Nano phosphatic hybrid geopolymeric corrosion resistant coating material and a method of preparation thereof
CN105948304A (en) * 2016-05-02 2016-09-21 北京工业大学 Direct solidification processing method for arsenic wastewater
AU2017300725A1 (en) 2016-07-20 2019-02-07 Synthos S.A. Modified geopolymer and modified geopolymer composite and process for the production thereof
CN109562998A (en) * 2016-07-20 2019-04-02 西索斯公司 Application of the geo-polymer additive together with non-brominated fire retardant in foam of polymers
IT201600082173A1 (en) * 2016-08-04 2018-02-04 Rosa&Fauzza S R L Stp POLYMERIZABLE MIXTURE, PRODUCTION PROCESS AND 3D PRINTING DEVICE FOR THE PRODUCTION OF A MANUFACTURE IN A GEOPOLYMERIC COMPOSITE MATERIAL, AND GEOPOLYMERIC COMPOSITE MATERIAL
WO2019182513A1 (en) * 2018-03-20 2019-09-26 Agency For Science, Technology And Research A waterproofing formulation
SK288860B6 (en) * 2018-09-14 2021-05-26 Vuje A S Additives for vitrification of liquid radioactive wastes containing cesium radionuclides with high trapping effectiveness of said radionuclides within the whole temperature range of vitrification, the method for preparation thereof and their usage
IT201900002049A1 (en) * 2019-02-13 2020-08-13 Consiglio Nazionale Ricerche Mechanical vibration damping system.
CN111470825A (en) * 2019-08-27 2020-07-31 北京利尔高温材料股份有限公司 Water-cooling pipe wall spray coating
CN113493336B (en) * 2020-04-08 2022-06-24 新疆维吾尔自治区煤炭科学研究所 Preparation method of fly ash-slag-based cemented filling material
CN112625472B (en) * 2020-12-02 2022-05-10 武汉佳碧源科技有限责任公司 Double-component reaction film-forming inorganic dry powder coating and application method thereof
WO2024048681A1 (en) * 2022-08-31 2024-03-07 株式会社Ihi Powder mixture and method for producing geopolymer solidified material using same
CN115432950A (en) * 2022-10-08 2022-12-06 中国电建集团西北勘测设计研究院有限公司 Geopolymer and preparation method thereof
CN116891364B (en) * 2023-09-11 2023-11-14 石家庄铁道大学 Reinforced steel slag base polymer and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7745363B2 (en) * 2005-05-09 2010-06-29 Corning Incorporated Geopolymer composites and structures formed therefrom

Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102741191B (en) * 2009-05-28 2014-09-17 陶氏环球技术有限责任公司 Modified geopolymer compositions, processes and uses
CN102741191A (en) * 2009-05-28 2012-10-17 陶氏环球技术有限责任公司 Modified geopolymer compositions, processes and uses
CN102010157B (en) * 2010-09-30 2012-10-31 华南理工大学 Bi-component environment-friendly inorganic polymer coating material and preparation method thereof
CN102010157A (en) * 2010-09-30 2011-04-13 华南理工大学 Bi-component environment-friendly inorganic polymer coating material and preparation method thereof
CN102173718A (en) * 2011-01-12 2011-09-07 中国科学院新疆理化技术研究所 Composite board of kaolin and expanded vermiculite
CN102173718B (en) * 2011-01-12 2012-11-21 中国科学院新疆理化技术研究所 Composite board of kaolin and expanded vermiculite
CN102701552A (en) * 2012-06-21 2012-10-03 南京大学 Covering material for immobilized in-situ remediation of nitrogen in bottom sediment and preparation method thereof
CN102701552B (en) * 2012-06-21 2014-03-12 南京大学 Covering material for immobilized in-situ remediation of nitrogen in bottom sediment
CN102898908A (en) * 2012-09-28 2013-01-30 启东市华亚工业配套有限公司 Waterproof coating
CN103232197B (en) * 2013-04-28 2015-02-25 长安大学 Geopolymer tunnel fireproof coating and preparation method thereof
CN103232197A (en) * 2013-04-28 2013-08-07 长安大学 Geopolymer tunnel fireproof coating and preparation method thereof
CN105153769A (en) * 2015-09-29 2015-12-16 北京志盛威华化工有限公司 Water-based anticorrosive paint for metal
CN106746968A (en) * 2016-12-02 2017-05-31 武汉天意成再生资源股份有限公司 A kind of super low energy consumption decoration coating materials for being applied to construction refuse regenerated product
CN107032676A (en) * 2017-04-20 2017-08-11 常州创索新材料科技有限公司 The preparation method of a kind of ground polymers porous material
CN108929114B (en) * 2017-05-23 2021-07-02 中国石油天然气股份有限公司 Geopolymer coating and preparation method and application thereof
CN108929114A (en) * 2017-05-23 2018-12-04 中国石油天然气股份有限公司 A kind of geopolymer coating and its preparation method and application
CN107352861A (en) * 2017-06-06 2017-11-17 浙江加州国际纳米技术研究院台州分院 A kind of application method of maritime concrete protection land used polymer coating materials
CN107352860A (en) * 2017-06-06 2017-11-17 浙江加州国际纳米技术研究院台州分院 A kind of preparation method of maritime concrete protection land used polymer coating materials
CN107352860B (en) * 2017-06-06 2019-10-01 浙江加州国际纳米技术研究院台州分院 A kind of preparation method of maritime concrete protection land used polymer coating materials
CN107352861B (en) * 2017-06-06 2019-10-01 浙江加州国际纳米技术研究院台州分院 A kind of application method of maritime concrete protection land used polymer coating materials
CN108863127A (en) * 2018-07-05 2018-11-23 浙江大学 A kind of micro-nano fiber composite toughening enhancing geopolymer and preparation method thereof based on hole optimization
CN108863127B (en) * 2018-07-05 2020-06-19 浙江大学 Micro-nano fiber composite toughening and reinforcing geopolymer based on pore optimization and preparation method thereof
CN113993953A (en) * 2019-07-07 2022-01-28 第一点有限公司 Coating composition and method of applying same
CN113993953B (en) * 2019-07-07 2023-09-12 第一点有限公司 Coating composition and method of applying same
CN110724427A (en) * 2019-09-29 2020-01-24 深圳市亚仕德新材料有限公司 Waterproof acid-resistant paint, preparation method thereof and waterproof acid-resistant coating
CN111635652A (en) * 2020-06-09 2020-09-08 河南省建筑工程质量检验测试中心站有限公司 Road marking paint based on geopolymer material and preparation method thereof
CN112094066A (en) * 2020-06-17 2020-12-18 湖北益通建设股份有限公司 Phosphogypsum-based aggregate for asphalt mixture and preparation method thereof
CN112028551A (en) * 2020-07-21 2020-12-04 北京工业大学 3D printing geopolymer for complex rock physical model and use method thereof
CN113072878A (en) * 2021-03-29 2021-07-06 浙江大江节能科技有限公司 Anticorrosive paint for inner wall of waste heat boiler flue and construction method thereof
CN113087534A (en) * 2021-03-31 2021-07-09 彩虹集团（邵阳）特种玻璃有限公司 High-temperature-resistant alkali-activated aluminosilicate binder and preparation method thereof
CN113087534B (en) * 2021-03-31 2022-08-19 彩虹集团（邵阳）特种玻璃有限公司 High-temperature-resistant alkali-activated aluminosilicate binder and preparation method thereof
CN114292584A (en) * 2022-01-06 2022-04-08 黄鑫 Water-based nano sand consolidation agent
CN114196242A (en) * 2022-01-14 2022-03-18 石河子大学 Anti-cracking geopolymer-based inorganic powder coating and preparation method and application thereof

Also Published As

Publication number Publication date
WO2008113609A3 (en) 2009-03-12
WO2008113609A2 (en) 2008-09-25

Similar Documents

Publication Publication Date Title
CN101045832A (en) Polymer coating composite and preparation method thereof
CN1087008C (en) Novel binding phase for phosphorus-magnesium cements and use thereof
CN1061637C (en) Ready-mixed, setting type joint compound
CN1254451C (en) Inorganic matrix compositions and composite material incorporating matrix composite material
CN1749203A (en) Heat insulation and sound insulation material for flour and its preparing method
CN101323772B (en) Ultra-thin stone and aluminum honeycomb composite modified epoxy adhesive and preparation thereof
CN1094019A (en) Cement, cement products, moulding material, concrete member and their manufacture method
CN1847183A (en) Glass frit for dielectrics, multilayer ceramic capacitor, and method for manufacturing the same
CN111393054B (en) Low-alkali-excitation water-resistant geopolymer material, preparation method thereof and application thereof in building decorative plate
CN1116240C (en) Method for producing artificial admixture for cement and concrete, products thereby and use thereof
CN116120009A (en) Recycled aggregate concrete and preparation method thereof
CN110041007B (en) Anti-permeability marble powder composite admixture and application thereof
CN114315257A (en) Process method for producing thermal insulation mortar
CN113860822A (en) Inorganic recycled concrete aggregate
CN101343437B (en) Dry powder wood putty special for fluorine-carbon paint with plastic-aluminum plate effect and preparation thereof
CN114315249B (en) Pervious concrete and preparation process thereof
CN115196940A (en) Composite fiber reinforced basic magnesium sulfate cement and preparation method thereof
CN111777384B (en) Exterior wall decoration powder and exterior wall decoration construction method
CN101434762A (en) Shale heat-preserving heat-insulating wall putty
CN111517727B (en) Concrete for underwater engineering and preparation method thereof
CN109465380B (en) High-strength binder for cast iron
CN113773001A (en) Geopolymer material containing iron ore tailings powder and granite stone powder and preparation method thereof
CN102163497A (en) High-performance broadband electromagnetic radiation wave absorption extruded rubber and plastic magnetic sheet and preparation method thereof
CN110484047A (en) Greasy flat binding material of one kind and preparation method thereof
CN107814510A (en) A kind of artificial quartz stone plate and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Open date: 20071003