CN107811880A - Transparent class shampoo Compositions - Google Patents
Transparent class shampoo Compositions Download PDFInfo
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- CN107811880A CN107811880A CN201710816995.2A CN201710816995A CN107811880A CN 107811880 A CN107811880 A CN 107811880A CN 201710816995 A CN201710816995 A CN 201710816995A CN 107811880 A CN107811880 A CN 107811880A
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- 0 C*(C[C@](C)*)C(C)(C)N(C)C(*)=O Chemical compound C*(C[C@](C)*)C(C)(C)N(C)C(*)=O 0.000 description 1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
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- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of transparent class shampoo Compositions, and it is difficult to trigger liquid drippage when being taken in hand, the combing property of finger when rinsing shampoo is good and ageing stability at low temperature is excellent.The transparent class shampoo Compositions are characterised by, are contained：1~20 mass % (a) composition：Surfactant, 1~20 mass % (b) composition represented by formula (1)：(c) composition of amphoteric surfactant, 0.01~2 mass %：Weight average molecular weight is 5 × 105~30 × 105Cationized cellulose and 0.5~2.5 mass % (d) composition：Sodium chloride, (a) composition are 1~9 relative to mass ratio (a)/(b) of (b) composition, [chemical formula 1]In formula (1), RCO represents the aliphatic acyl radical that carbon number is 8~22, M1Represent alkali metal atom, alkanolamine, the alkali metal salt of taurine.
Description
Technical field
The present invention relates to a kind of transparent class shampoo Compositions, and it is difficult to trigger liquid drippage when being taken in hand, rinsed
The ageing stability of combing property of finger during shampoo well and at low temperature is excellent.
Background technology
Acyl amino acids surfactant, due to that the excitant to skin and hair is small, foaming characteristic is high is excellent
Use feeling, therefore be used as the main component of the body cleaning agent of such as scalp, hair or human body cleaning agent.In the acyl
In base amino acid surfactant, during due to acyl methyl taurine salt being used for into shampoo, foaming characteristic during hair washing is good,
Smooth effect, therefore suitable use can be obtained.To sum up reason, attempt by blending acyl group in high proportion into shampoo
Methyl tauride, further improve foaming characteristic and smooth use feeling when having one's hair wash.
In recent years, except aspect of performances such as foaming characteristic and use feelings, also require that shampoo has higher surcharge, example
Such as, for the purpose of showing feeling of high class, a kind of transparent class shampoo for not blending silicone or pearling agent of demand sometimes.Due to acyl
Base amino acid surfactant includes sodium chloride micro, from the fat acyl chloride as acylating agent, therefore, particularly exists
In the case of being blended at high proportion, due to sodium chloride contained in shampoo, it result in low temperature in shampoo sometimes
Muddiness can be produced, the possibility of generation be present for being envisioned for the commodity of transparent class shampoo.
In patent document 1, as matching somebody with somebody for ageing stability (following, also referred to as " low-temperature stability ") improved at low temperature
A kind of side, it is proposed that the cleansing composition of the polyalcohol of dihydric alcohol containing such as 1,3-BDO or DPG etc..But
In to have blended the shampoo of acyl methyl taurine salt at high proportion, the polynary of the amount that can improve low-temperature stability has been blended
During alcohol, the viscosity of shampoo Compositions substantially reduces, and the problem of shampoo for being difficult to manufacture with proper viscosity be present.
A kind of shampoo is recorded in patent document 2, it with specific content by blending acyl methyl taurine salt, two
Property surfactant and cationization polymer so that combing property of finger during flushing is good, low temperature when ageing stability it is excellent
It is different.By making an effort blending formula, although a certain degree of low-temperature stability can be improved, to blend at high proportion
In the shampoo of acyl methyl taurine salt, it is difficult to obtain appropriate viscosity sometimes.In this case, although can use
Add a small amount of sodium chloride with improve viscosity, so that be taken at will not trigger when in hand liquid drip formula, still, exist
Produced under low temperature in shampoo muddy, it is impossible to maintain the situation of the transparency.
Like this, in have blended the shampoo of acyl methyl taurine salt at high proportion, hand during a kind of flushing is sought
Refer to combing property well and add sodium chloride even in selecting with the formula of the viscosity with the degree that liquid drippage will not occur
When, ageing stability during low temperature also excellent transparent class shampoo Compositions.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 10-218744 publications
Patent document 2：Japanese Unexamined Patent Publication 5-246829 publications
The content of the invention
The technical problem to be solved in the present invention
The present invention is completed based on situation as described above, its object is to provide a kind of transparent class shampoo Compositions,
Its difficulty or ease when being taken in hand triggers liquid drippage, combing property of finger when rinsing shampoo is good and at low temperature through when
Excellent in stability.
Solves the technological means of technical problem
In order to solve the above-mentioned technical problem the present inventors, are conscientiously studied, its result is found, blend acyl
The cationized cellulose of ylmethyl taurate, amphoteric surfactant and specified molecular weight, and the chlorination containing specified quantitative
The transparent class shampoo Compositions of sodium, when to have blended acyl methyl taurine salt at high proportion, rinse shampoo when
Combing property of finger is also good, and ageing stability during low temperature is excellent, so as to complete the present invention.
That is, the present invention is a kind of transparent class shampoo Compositions, it is characterised in that is contained：1~20 mass % (a) into
Point：Surfactant represented by formula (1), 1~20 mass % (b) composition：Amphoteric surfactant, 0.01~2 mass %
(c) composition：Weight average molecular weight is 5 × 105~30 × 105Cationized cellulose, and 0.5~2.5 mass % (d)
Composition：Sodium chloride, (a) composition are 1~9 relative to mass ratio (a)/(b) of (b) composition.
[chemical formula 1]
In formula (1), RCO represents the aliphatic acyl radical that carbon number is 8~22, M1Represent alkali metal atom, alkanolamine,
The alkali metal salt of taurine.
Invention effect
According to the transparent class shampoo Compositions of the present invention, even in have blended acyl methyl taurine salt at high proportion
When, it can also obtain following effects, i.e. be taken at the combing property of finger when being difficult to trigger liquid drippage, flushing shampoo when in hand
Ageing stability well and at low temperature is excellent.
Embodiment
Hereinafter, embodiments of the present invention are illustrated.
The transparent class shampoo Compositions of the present invention contain (a) composition, (b) composition, (c) composition and (d) composition.With
Under, each composition is illustrated.
[(a) composition]
Surfactant of (a) composition represented by formula (1) used in the present invention, is acyl methyl taurine salt.
RCO expression carbon numbers in formula (1) are 8~22, the aliphatic acyl radical that preferably carbon number is 8~18.Fat
Race's acyl group is not only included from the saturated fatty acid that carbon number is 8~22 or the acyl group of unrighted acid, is also included and is come from
Acyl group containing the two or more fatty acid mixeds in these aliphatic acid.As the aliphatic acyl radical, such as coconut palm can be included
Oleoyl, palm-kernel oil acyl group, caprylyl, capryl, lauroyl, myristoyl, palmityl, stearyl, oleoyl
Base, behenyl acyloxy (behenoyl group) etc..It is preferred that lauroyl, myristoyl, cocoyl, palm kernel oleoyl
Base, particularly preferred lauroyl, cocoyl, palm-kernel oil acyl group.
M in formula (1)1Represent alkali metal atom, alkanolamine, the alkali metal salt of taurine.As alkali metal atom, example
Sodium, potassium can such as be included.As alkanolamine, such as MEA, diethanol amine, triethanolamine etc. can be included.In addition,
As the alkali metal salt of taurine, such as sodium taurocholate, taurine potassium etc. can be included.Wherein, preferably sodium, potassium, triethanolamine,
Sodium taurocholate.
As the concrete example of the acyl methyl taurine salt represented by formula (1), such as methyl lauroyl ox can be included
Sodium sulfonate, methyl lauroyl taurine potassium, methyl myristoyl sodium taurocholate, methyl myristoyl taurine potassium, first
Base cocoyl sodium taurocholate, methyl cocoyl taurine potassium, methyl lauroyl taurine sodium taurocholate, cocounut oil acyl methyl
Taurine sodium taurocholate etc..
In the present invention, (a) composition can properly select and using one in the compound included in above-mentioned formula (1)
Kind is two or more.
[(b) composition]
(b) composition used in the present invention is amphoteric surfactant, for example, can include with have concurrently N- acyl groups or
N- alkyl, cationic groups, anionic property group structure surfactant.Specifically, such as alkyl can be included
Glycine betaine, alkyl amido betaine, alkyl hydroxy sulfobetaines, alkylamide hydroxyl sulfo betaine, alkyl carboxymethyl hydroxyl
Base ethyl imidazol(e) quinoline glycine betaine, alkylamide Hydroxy-ethylamino acid type amphoteric surfactant, alkyl iminodiacetic hydrochlorate
Deng.
Contained N- acyl groups in above-mentioned amphoteric surfactant, for example, carbon number are 8~18 straight or branched
Fatty acid residue.As the aliphatic acid in the fatty acid residue, for example, can include octanoic acid, capric acid, laurate, myristic acid,
The saturated fatty acids such as palmitic acid, stearic acid, isostearic acid；The unsaturations such as palmitoleic acid, oleic acid, elaidic acid, linoleic acid, leukotrienes
Aliphatic acid；And the coco-nut oil fatty acid of the mixture sour as these, palm kernel fatty acid, tallow acid, hardening ox
Fatty acid oil etc..Wherein, preferably laurate, myristic acid, palmitic acid, oleic acid, coco-nut oil fatty acid, palm kernel fatty acid.
Particularly preferred laurate, coco-nut oil fatty acid, palm kernel fatty acid.
Contained alkyl in above-mentioned amphoteric surfactant, for example, carbon number are 8~18 alkyl, also include and come from
The alkyl of fatty acid mixed.Such as the alkane such as octyl group, decyl, lauryl, myristyl, palmityl, stearyl, oil base can be included
Base；The mixed alkyls such as coconutalkyl, palm-kernel oil alkyl, tallow alkyl.Wherein, preferably lauryl, myristyl, palm
Base, coconutalkyl, palm-kernel oil alkyl.Particularly preferred lauryl, coconutalkyl, palm-kernel oil alkyl.
As the concrete example of the amphoteric surfactant of (b) composition, such as lauryl betaine, coconut oleoyl amine can be included
CAB, palm-kernel oil amido propyl betaine, lauryl dimethyl oxyneurine, lauryl weight ratio sweet tea
Dish alkali etc..
In the present invention, (b) composition can properly select and using one kind or two in above-mentioned amphoteric surfactant
More than kind.
[(c) composition]
(c) composition used in the present invention is that weight average molecular weight is 5 × 105~30 × 105Cationized cellulose.
(c) weight average molecular weight of the cationized cellulose of composition is preferably 7 × 105~25 × 105, particularly preferably 9 × 105~20
×105。
(c) composition has the function that to form complex with the mixed micelle of each composition of (a) and (b).The complex leads to
Cross and (coacervation) is separated out when rinsing hair and is adsorbed on hair, finger when improving hair washing so as to assign and when rinsing
The conditioning effect of combing property.
(c) composition, such as can include：As the addition glycidyltrimetiiylammonium ammonium chloride on hydroxyethyl cellulose
The polymer of obtained quaternary ammonium salt, O- (2- hydroxyls -3 (trimethyl ammonium) propyl group) hydroxyethyl cellulose chloride.It is equal as weight
Molecular weight is 5 × 105~30 × 105Commercially available cationized cellulose, such as can include Lion Corporation's
" Reogado MGP ", TOHO Chemical Industry Co., Ltd. " Catinal HC-200 " or " Catinal LC-
200 ", Kao Corporation " POIZ C-150L " etc..
In the present invention, the measure for carrying out weight average molecular weight is determined using static light scattering.I.e., it is possible to use differential refraction
Concentration-differential refraction rate the curve for the water-soluble polymers that rate detector measure has diluted, surveyed using scattering strength measure device
Determine concentration-dependence of angle of scattering strength, weight is determined by being extrapolated to concentration 0, the angle 0 of Zimm figures (Zimm plot)
Average molecular weight.
In the present invention, (c) composition can properly select and using one kind or two in these cationized celluloses
More than kind.
[(d) composition]
(d) composition used in the present invention is sodium chloride, for example, can be by used in included in (a) composition
Sodium chloride is used as (d) composition, according to required, can also use sodium chloride in addition.
[transparent class shampoo Compositions]
The content of each composition in the transparent class shampoo Compositions of the present invention is illustrated below.
The content of (a) composition in the transparent class shampoo Compositions of the present invention is 1~20 mass %, preferably 2~16
Quality %, particularly preferably 3~12 mass %.When the content of (a) composition is very few, foaming characteristic when hair washing be present is deteriorated or punching
The situation that combing property of finger when washing declines；When content is excessive, when low temperature be present the problems such as the precipitation of generation surfactant
Possibility.
The content of (b) composition in the transparent class shampoo Compositions of the present invention is 1~20 mass %, preferably 2~16
Quality %, particularly preferably 3~12 mass %.When the content of (b) composition is very few, foam quality when hair washing be present decline or
The situation that combing property of finger during flushing declines；When content is excessive, precipitation of surfactant etc. is produced when low temperature be present and is asked
The possibility of topic.
The content of (c) composition in the transparent class shampoo Compositions of the present invention is 0.01~2 mass %, preferably 0.05
~1.5 mass %, particularly preferably 0.1~1.0 mass %.When the content of (c) composition is very few, the generation that coacervate be present becomes
It is extremely micro, the situation of good combing property of finger can not be obtained during flushing；When content is excessive, shampoo Compositions be present
The impaired possibility of low-temperature stability.
The content of (d) composition in the transparent class shampoo Compositions of the present invention is 0.5~2.5 mass %, is preferably
0.75~2.1 mass %, particularly preferably 1.0~1.7 mass %.When the content of (d) composition is very few, shampoo Compositions are taken
Easily liquid is triggered to drip when in hand；When content is excessive, there is a possibility that the low-temperature stability of shampoo Compositions is impaired.
In addition, the content of (d) composition in transparent class shampoo Compositions, can be by being wrapped in used (a) composition
The content meter of the sodium chloride contained calculates, and according to required, can also carry out it is possible to additionally incorporate mode of sodium chloride etc. to adjust content.
In the transparent class shampoo Compositions of the present invention, (a) composition is 1 relative to the mass ratio ((a)/(b)) of (b) composition
~9, preferably 1.1~6.0, particularly preferably 1.2~4.5, more preferably 1.3~3.0.As mass ratio ((a)/(b))
When excessive or too small, there is a possibility that the low-temperature stability of shampoo Compositions is impaired.
In addition, for the transparent class shampoo Compositions of the present invention, particularly when above-mentioned mass ratio (a)/(b) is more than 3
When, examined from the angle for meeting for shampoo Compositions to be taken at difficulty that liquid when in hand drips and low-temperature stability simultaneously
Consider, preferably above-mentioned mass ratio (a)/(b) relative to (d) composition mass ratio { (a)/(b) }/(d) meet 1.9~2.4, it is especially excellent
It is selected to meet 2.0~2.2.
The transparent class shampoo Compositions of the present invention, can be manufactured according to usual way.The transparent class of the present invention
Shampoo Compositions can also further contain solvent.As solvent, such as the lower alcohols such as water outlet, ethanol or lower alcohol can be enumerated
The aqueous solution, particularly preferred water.
In the transparent class shampoo Compositions of the present invention, the total content of (a)~(d) each composition and water equal solvent is
Below 100 mass %.
The transparent class shampoo Compositions of the present invention, if for the purpose of cleaning hair, liquid, gel etc. use form
It is not limited, for example, can be used in the form of shampoo, two-in-one shampoo (リ Application ス イ Application シ ャ ン プ ー).
In addition, the effect of the present invention can also not damaged according to required, of the invention transparent class shampoo Compositions
In the range of containing other surfactants or NMF, oil, water soluble polymer, preservative, bactericide, pH adjusting agent,
Chelating agent, antioxidant, the extract from animals and plants, pigment, spices etc. are commonly used in the cleaning agent of hair or body
Various composition.
Embodiment
[embodiment 1~11 and comparative example 1~11]
Hereinafter, the present invention is specifically described by embodiment and comparative example.
Based on the blending described in table 1 and table 2, shampoo Compositions are conventionally prepared.
In addition, it is used as (c) composition in table using following materials.
(c) -1 cationized cellulose A：[Lion Corporation are manufactured Reogado MGP, and weight average molecular weight is 17 × 105]
(c) -2 cationized cellulose B：Catinal HC-200[TOHO Chemical Indus try Co.,Ltd.
Manufacture, weight average molecular weight are 20 × 105]
(c) -3 cationized cellulose C：[Kao Corporation are manufactured POIZ C-150L, and weight average molecular weight is 15 × 105]
Using shampoo Compositions resulting in embodiment and comparative example as sample, carry out in the manner as described below
Evaluation, its result is summarised in table 1 and table 2.
(1) difficulty of liquid drippage
It has rated the degree of liquid drippage when each composition to be taken to palm.Select 20 men and women to be used as (24~47 years old) to comment
Member is examined, will not feel that the situation that liquid drips from palm is denoted as 2 points；Though it will somewhat feel that liquid is dripped but felt from palm
Feel and be denoted as 1 point using the upper situation that there is no problem；It will feel that the situation that liquid drips from palm is denoted as 0 point, obtain
The total score of 20, evaluation as described below is carried out.
◎：Total score is more than 35 points；Almost no liquid is dripped when being taken at palm, fully can be coated on hair.
○：Total score is 20 points less than 35 points；Somewhat there is liquid drippage when being taken at palm, but can be coated on hair.
△：Total score is 10 points less than 20 points；Liquid drippage occurs when being taken at palm, is not easy to be coated on hair.
×：Total score is less than 10 points；Liquid drippage when being taken at palm is serious, it is impossible to is coated on hair.
(2) the combing property of finger when rinsing
Select 20 men and women for having contaminated hair to be used as syndic in (24~47 years old), have rated the water using 40 DEG C, the sample with 5mL
Combing property of finger when (shampoo Compositions) are had one's hair wash and rinsed.It will feel that finger combs smoothly and will not block head
The situation of hair is denoted as 2 points, will somewhat feel that the situation that hair is stuck on finger is denoted as 1 point, and it is excessively poor will to feel that finger combs
Situation is denoted as 0 point, obtains the total score of 20, has carried out evaluation as described below.
◎：Total score is more than 35 points；Combing property of finger is very excellent.
○：Total score is 30 points less than 35 points；Combing property of finger is excellent.
△：Total score is 20 points less than 30 points；Finger combing property a bit deficient in.
×：Total score is less than 20 points；Lack combing property of finger.
(3) ageing stability
Each composition is sealed in transparent glass container, is preserved respectively at 0 DEG C, 5 DEG C 1 week, its outward appearance is observed, with as follows
3 shown grades are evaluated.
○：Without cosmetic variation at 0 DEG C, 5 DEG C.
△：Although at 5 DEG C without cosmetic variation, composition change is gonorrhoea shape at 0 DEG C.
×：Composition, which becomes, at 0 DEG C, 5 DEG C turns to gonorrhoea shape.
Embodiment 1~11 obtains good evaluation in all projects.
On the other hand, because comparative example 1 does not include (a) composition, therefore, liquid drippage when composition to be taken to palm is tight
Again, the combing property of finger during flushing is also insufficient.
In comparative example 2, because without (b) composition, therefore, liquid drippage when composition to be taken to palm is serious, punching
Combing property of finger when washing is also insufficient, and the ageing stability under low temperature has problem.
In comparative example 3, due to without (c) composition, therefore, when composition is taken at into palm, easily triggering liquid drippage,
Combing property of finger during flushing is also insufficient, lacks ageing stability at low temperature.
In comparative example 4, because the content of (a) composition is more, therefore, there is problem in the ageing stability under low temperature.
In comparative example 5, because the content of (b) composition is more, and mass ratio ((a)/(b)) not present invention provide that model
In enclosing, therefore, there is problem in the ageing stability under low temperature.
In comparative example 6, because the content of the sodium chloride of (d) composition is few, accordingly, there exist by composition when being taken at palm
Liquid drippage is serious, it is impossible to the problem of being coated on hair.
In comparative example 7, because the content of the sodium chloride of (d) composition is more, therefore, lack at low temperature through when it is stable
Property.
In comparative example 8, comparative example 9, comparative example 10, due to containing JR-125, poly dimethyl methylene respectively
PhenylpiperidinesChloride (polydimethylmethylenepiperidium chloride), dimethyl diallyl chlorination
Ammonium-acrylamide copolymer replaces (c) composition, and therefore, the ageing stability under low temperature has problem.
In comparative example 11, due to containing 1,3-BDO, therefore, easily liquid is triggered to drip when composition is taken at into palm
Fall, it is impossible to be fully coated on shampoo Compositions on hair.
Hereinafter, further it is specifically illustrated in the Formulation Example of the transparent class shampoo Compositions of the present invention.In addition, arbitrary
In Formulation Example, total amount is adjusted to 100 mass % using water.
[table 3]
Formulation Example 1
* cationized cellulose：Reogado MGP [Lion Corporation manufactures]
[table 4]
Formulation Example 2
* cationized cellulose：Catinal HC-200 [TOHO Chemical Industry Co., Ltd. manufacture]
[table 5]
Formulation Example 3
* cationized cellulose：POIZ C-150L [Kao Corporation manufactures]
Due to being difficult to trigger liquid drippage when the transparent class shampoo Compositions of these Formulation Examples are taken in hand, rinsing hair washing
The ageing stability of combing property of finger during agent well and at low temperature is excellent, therefore the effect of the present invention is confirmed.According to
The present invention, using the teaching of the invention it is possible to provide a kind of transparent class shampoo Compositions, its difficulty or ease when being taken in hand trigger liquid drippage, rinse hair washing
The ageing stability of combing property of finger during agent well and at low temperature is excellent.
Claims (1)
1. a kind of transparent class shampoo Compositions, it is characterised in that contain：
1~20 mass % (a) composition：Surfactant represented by formula (1),
1~20 mass % (b) composition：Amphoteric surfactant,
0.01~2 mass % (c) composition：Weight average molecular weight is 5 × 105~30 × 105Cationized cellulose and
0.5~2.5 mass % (d) composition：Sodium chloride,
(a) composition is 1~9 relative to mass ratio (a)/(b) of (b) composition.
[chemical formula 1]
In formula (1), RCO represents the aliphatic acyl radical that carbon number is 8~22, M1Represent alkali metal atom, alkanolamine, ox sulphur
The alkali metal salt of acid.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016179049 | 2016-09-13 | ||
| JP2016-179049 | 2016-09-13 |
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| CN107811880A true CN107811880A (en) | 2018-03-20 |
| CN107811880B CN107811880B (en) | 2021-12-31 |
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| CN201710816995.2A Active CN107811880B (en) | 2016-09-13 | 2017-09-12 | Transparent shampoo composition |
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| JP (1) | JP2018043980A (en) |
| CN (1) | CN107811880B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109288719A (en) * | 2018-11-23 | 2019-02-01 | 广州市科能化妆品科研有限公司 | A kind of mild shampoo composition and preparation method thereof |
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| KR20030016223A (en) * | 2000-12-22 | 2003-02-26 | 가부시키가이샤 시세이도 | Gel-form composition |
| JP3947668B2 (en) * | 2000-12-22 | 2007-07-25 | 株式会社資生堂 | Associative thickener for aqueous solvents, gel-like composition and emulsion composition containing the same |
| JP2004210658A (en) * | 2002-12-27 | 2004-07-29 | Kose Corp | Hair cosmetic |
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| JP5935466B2 (en) * | 2012-04-12 | 2016-06-15 | 日油株式会社 | Shampoo composition |
| JP6179184B2 (en) * | 2012-05-21 | 2017-08-16 | ライオン株式会社 | Hair cleaning composition and method for producing the same |
| JP2014122183A (en) * | 2012-12-21 | 2014-07-03 | Kose Corp | Dna damage inhibitor |
| JP2014125429A (en) * | 2012-12-25 | 2014-07-07 | Kose Corp | Dna damage inhibitor |
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- 2017-08-28 JP JP2017163815A patent/JP2018043980A/en active Pending
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| CN1805728A (en) * | 2003-06-17 | 2006-07-19 | 高砂香料工业株式会社 | Shampoo and body detergent composition |
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| JP2014148492A (en) * | 2013-02-04 | 2014-08-21 | Asanuma Corporation | Shampoo composition |
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| CN109288719A (en) * | 2018-11-23 | 2019-02-01 | 广州市科能化妆品科研有限公司 | A kind of mild shampoo composition and preparation method thereof |
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| CN107811880B (en) | 2021-12-31 |
| JP2018043980A (en) | 2018-03-22 |
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