CN107805435A - A kind of aqueous laser thin-film material of anti-rejection material - Google Patents
A kind of aqueous laser thin-film material of anti-rejection material Download PDFInfo
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- CN107805435A CN107805435A CN201711252392.0A CN201711252392A CN107805435A CN 107805435 A CN107805435 A CN 107805435A CN 201711252392 A CN201711252392 A CN 201711252392A CN 107805435 A CN107805435 A CN 107805435A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The application provides a kind of aqueous laser thin-film material of anti-rejection material, including：10 20 parts of 40 60 parts of acrylic resin, 10 15 parts of ethanol, 10 20 parts of water-based wax emulsion, 37 parts of diethylene glycol, 1 10 parts of glycerine, 13 parts of wetting agent, 0.1 0.3 parts of defoamer and water；The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid resin is 05 parts, and the hard acrylic resin is 01 parts.The application also provides a kind of preferred scheme, 15 parts of 50 parts of acrylic resin, 12.5 parts of ethanol, 15 parts of water-based wax emulsion, 5 parts of diethylene glycol, 2 parts of wetting agent, 0.2 part of defoamer and water.The aqueous laser thin-film material for the anti-rejection material that the application provides, film-formation result is good, and adhesion is strong, wear-resisting, and without organic solvent, green non-pollution, more it is essential that the aqueous laser thin-film material is not susceptible to get rid of material phenomenon in coating, coating effect is good.
Description
Technical field
The application is related to technical field of coatings, more particularly to a kind of aqueous laser thin-film material of anti-rejection material.
Background technology
Radium-shine packaging is the segmented industry in packaging industry, achieves quick development, with its in packaging industry
He compares product, and radium-shine packaging material not only has novel, beautiful appearance, while also has high-tech antiforge function,
It is referred to as the technical products of forefront in world's packages printing industry.The application field of radium-shine material is very extensive, food,
The industries such as medicine, daily chemical product, tobacco and wine, clothes, gift wrap and ornament materials are all promoted faster.
From product composition composition on divide, laser film product can be roughly divided into BOPP laser films, PET laser films and
Three kinds of PVC laser films.From technology level, the anti-counterfeit laser film product applied to label printing field belongs to the sector
In high-end product, its production process, which is related to multiple sport technique segments, the products such as laser anti-counterfeiting plate-making, mould, coating, transfer, to be had
Higher added value.Also it is widely used in packaging for foodstuff, commodity packaging, such as box for moon-cake, toothpaste box etc., and these fields pair
Using for radium-shine technology can be more and more.
Laser film main feature has three aspects, and first, intrinsic fragrance, anti-counterfeiting performance is strong, attractive in appearance, green, environmental protection；Its
Secondary, resistance to ink corrodes, and barrier steam, carbon dioxide etc. ability is high；Finally, laser film has cigarette high glaze, and hologram layer assigns
Film is preferably antistatic, and adhesion inhibiting properties are high with upper machine adaptability.
However, the laser film material shown in prior art often gets rid of material phenomenon in coating, coating effect is poor.
The content of the invention
The application provides a kind of aqueous laser thin-film material of anti-rejection material, to solve the laser film material shown in prior art
Material often gets rid of material phenomenon in coating, and coating effect is poor.
The application provides a kind of aqueous laser thin-film material of anti-rejection material, including：
The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid resin is
0-5 parts, the hard acrylic resin is 0-1 parts.
Further, the material includes：
Further, the material includes：
Further, the soft propene acid resin is 0 part.
Further, the hard acrylic resin is 0 part.
Further, the soft propene acid resin is 5 parts,
The hard acrylic resin is 1 part.
Further, the glass transition temperature of the soft propene acid resin is 80 DEG C.
Further, the glass transition temperature of the hard acrylic resin is 105 DEG C.
Further, the main component of the water-based wax emulsion is aqueous polyethylene wax.
Further, defoamer is the defoamer without organosilicon.
From above technical scheme, the aqueous laser thin-film material for the anti-rejection material that the embodiment of the present application provides, including：Third
Olefin(e) acid resin 40-60 parts, ethanol 10-15 parts, water-based wax emulsion 10-20 parts, diethylene glycol 3-7 parts, glycerine 1-10 parts, wetting
Agent 1-3 parts, defoamer 0.1-0.3 parts and water 10-20 parts；The acrylic resin includes soft propene acid resin and hard acrylic acid
Resin, wherein, the soft propene acid resin is 0-5 parts, and the hard acrylic resin is 0-1 parts.The application also provides a kind of excellent
It is 50 parts of acrylic resin, 12.5 parts of ethanol, 15 parts of water-based wax emulsion, 5 parts of diethylene glycol, 5 parts of glycerine, wetting to select scheme
15 parts of 2 parts of agent, 0.2 part of defoamer and water.The aqueous laser thin-film material for the anti-rejection material that the application provides, film-formation result is good,
Adhesion is strong, wear-resisting, without organic solvent, green non-pollution, and more it is essential that the aqueous laser thin-film material is in coating,
It is not susceptible to get rid of material phenomenon, coating effect is good.
Brief description of the drawings
In order to illustrate more clearly of the technical scheme of the application, letter will be made to the required accompanying drawing used in embodiment below
Singly introduce, it should be apparent that, for those of ordinary skills, without having to pay creative labor,
Other accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 is the method for the aqueous laser thin-film material for preparing anti-rejection material of the application according to an exemplary embodiment
Flow chart.
Embodiment
According to embodiments herein, there is provided a kind of aqueous laser thin-film material, including：
The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid resin is
0-5 parts, the hard acrylic resin is 0-1 parts.
In the aqueous laser thin-film material each component for the anti-rejection material that the embodiment of the present application provides, acrylic resin is film forming
Base substance, and laser effect can be produced, adhesion is strong；On the one hand ethanol plays a part of dispersant and solvent, on the other hand,
When material is coated with, moreover it is possible to accelerate drying, improve the levelability of material, avoid because of slow drying speed and caused by material coating not
Equal phenomenon；The main function of water-based wax emulsion is to make material that haftplatte not occur during mould, while improves the wear-resisting of film
Performance；Diethylene glycol further lifts film-formation result as coalescents；Glycerine has preferable water retention property, Jin Erping
Weigh colloid rate of drying, avoids getting rid of the generation of material phenomenon.Wetting agent makes the surface wettability of film, and Painting effect is good；Defoamer is used
In eliminating caused bubble in material preparation process, make material more stable homogeneous.Acrylic resin, Chinese nickname include propylene
Acid resin emulsion, acrylic acid modified resin etc., color are shallow, water-white transparent.Film performance is excellent, fast light, weatherability is good, heat-resisting, resistance to
Paint baking over, chemical-resistant and the performance such as corrosion-resistant are all fabulous.Therefore, the coating manufactured with acrylic resin.Widely used,
It is various in style.The varieties and characteristicses of different acrylic resins all have impact on the performance of coating products, these all with acrylic resin
Composition, structure are relevant.
Emulsion acrylic resin is HMW, the low viscosity emulsus hare resin that acrylate is primary raw material, typically
For multiple copolymer, its film forming has the characteristics that bright, flexible, caking property is strong, water-fast and wear-resisting.Emulsion acrylic resin is by third
Olefin(e) acid ester, comonomer, emulsifying agent, initiator etc. are produced through emulsion copolymerization.Selection and proportioning by comonomer, it can adjust
The performance of emulsion acrylic resin and the soft durometer of film forming, to meet different purposes requirements.
The emulsion acrylic resin that the embodiment of the present application uses, can at least be prepared by following steps：
By the butyl acrylate of 28-30 parts by weight, the methacrylate of 22.8-24.6 mass parts, 5.4-7.2 mass parts
Acrylic acid, the ammonium persulfate of 0.6-2 mass parts, the NONIN HS 240 of 1.5-2.1 mass parts and dodecyl sulphur
The deionized water mixing of the mixture of sour sodium, the sodium acid carbonate of 0.4-0.8 mass parts and 95-105 mass parts, addition pH value are adjusted
Agent is saved, is reacted, emulsion acrylic resin is obtained after curing.
Wherein, NONIN HS 240 and the mass ratio of lauryl sodium sulfate are (0.8-1.2):2；
It should also be noted that make above-mentioned reaction temperature be 60-95 DEG C, mixing speed be 60r/min-3000r/min's
Under the conditions of carry out；The temperature of above-mentioned curing is 70-95 DEG C, and the time is 0.16-24 hours, and the pH value for reacting progress is 6-7.
Further, it is possible to pH value is adjusted by the mixed solution of Strong oxdiative sodium and ammoniacal liquor.
In above-mentioned the step of preparing emulsion acrylic resin, butyl acrylate, methyl methacrylate and acrylic acid structure
Into the monomer component in formula, butyl acrylate is soft monomer, assigns resin certain pliability and extensibility, methacrylic acid
Methyl esters is hard monomer, act as improving the hardness and tensile strength of resin；Acrylic acid is functional monomer, and its main function is regulation
Viscosity and participation polymerisation, solidification generation linear polymer, are advantageous to improve the pliability and adhesive force of glue-line, pass through change
The content of acrylic acid can be with the surface energy and adhesion work of regulation system.
In above-mentioned the step of preparing emulsion acrylic resin, ammonium persulfate is water-soluble heat decomposition type initiator, preferably
0.6-1.5 mass parts, it act as triggering monomer to carry out polymerisation.Sodium acid carbonate is buffer, preferably 0.5-0.7 weight
Part, it is the pH value for maintaining emulsion that it, which is acted on, stable to polymerize environment.In emulsion polymerization process, ammonium persulfate, which decomposes, makes system pH
Value reduces, and adding buffer with the pH value of maintenance system, can ensure the activity of initiator, triggers chain and is normally carried out.
NONIN HS 240 and the mixture of lauryl sodium sulfate are emulsifying agent, preferably 1.7-1.9 mass parts,
Its reduction interfacial tension acted on, make immiscible water-oil phase by the role transformation of stirring can be stabilized, long
Put the emulsion for being easily difficult to be layered.
Influenceing the factor of acrylic resin performance includes：1st, molecular weight distribution and size；2nd, the chemical constitution of monomer and tree
The characteristics of fat；3rd, glass transition temperature.Technical scheme is by selecting different copolymer monomer and matching the difference being prepared
The soft durometer emulsion acrylic resin of performance and film forming, to prepare aqueous laser thin-film material.
In addition, in addition to the emulsion acrylic resin that the above method is prepared, pure-acrylic emulsion, vinegar third also can be selected in the application
Two kinds in the tertiary vinegar milk liquid of emulsion (tertiary carbonic ester-vinylacetate) emulsion or uncle third (tertiary carbonic ester-acrylate) emulsion.
Water-based wax emulsion refers to aqueous polyethylene wax emulsion, is high density polyethylene waxes, in present embodiments,
The molecular weight of high density polyethylene waxes is between 80000-120000.
The defoamer that the application uses is the defoamer without organosilicon.In each embodiment of the application, what defoamer was selected
It is 830 high type defoamers of German enlightening.
For the wetting agent that the application uses for modified poly ester, active component is 39-41% by weight percentage, and solids content is pressed
Percentage by weight is 49-51%.What the wetting agent in each embodiment of the application was selected is the high 740W type wetting agents of German enlightening.
Refering to Fig. 1, according to the embodiment of the present application, a kind of method for preparing aqueous laser thin-film material comprises the following steps：
Step S01, the absolute ethyl alcohol of 10-20 parts deionized water and 10-15 mass parts is weighed, is added into reactor；
Step S02, weighs 3-7 parts diethylene glycol and 1-10 part glycerine is added into reactor, starts dispersion machine, with
500-600r/min starts to disperse；
Step S03,40-60 part acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added
To reactor；
Step S04, the water-based wax emulsion of 10-20 parts, 1-3 parts wetting agent and 0.1-0.3 part defoamers are weighed, is added to anti-
Answer in device；
After step S05,30-100 minute, dispersion machine is closed, obtains the aqueous laser thin-film material of anti-rejection material.
The aqueous laser thin-film material film-formation result for the anti-rejection material being prepared using the above method is good, and adhesion is strong, resistance to
Mill, without organic solvent, green non-pollution, more it is essential that the aqueous laser thin-film material is not susceptible to get rid of material in coating
Phenomenon, coating effect are good.In some preferred embodiments, the material includes：
In other preferred embodiments, the material includes：
According to the embodiment of the present application, the acrylic resin of use is any one of soft propene acid resin and hard acrylic resin
Kind or two kinds of mixing.Therefore, in some embodiments, the soft propene acid resin is 0 part, or the hard acrylic resin is
0 part.
According to above-described embodiment, it is 5 parts that one kind of acrylic resin, which is preferably constituted as the soft propene acid resin, described hard
Acrylic resin is 1 part.
It should be noted that the glass transition temperature of the soft propene acid resin is 80 DEG C；The hard acrylic resin
Glass transition temperature is 105 DEG C.
The specific implementation of the aqueous laser thin-film material for the anti-rejection material that the application provides, referring also to following implementations
Example.
Embodiment 1
Step S110,15 parts of deionized waters and 12.5 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S120,5 parts of diethylene glycols and 5 parts of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S130,50 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S140,15 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S150,30-100 minute, dispersion machine is closed, obtains 1# samples.
Embodiment 2
Step S210,15 parts of deionized waters and 10 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S220,3 parts of diethylene glycols and 3 parts of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S230,40 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S240,10 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S250,30-100 minute, dispersion machine is closed, obtains 2# samples.
Embodiment 3
Step S310,15 parts of deionized waters and 12.5 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S320,5 parts of diethylene glycols and 1 part of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S330,40 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S340,15 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S350,30-100 minute, dispersion machine is closed, obtains 3# samples.
Embodiment 4
Step S410,15 parts of deionized waters and 15 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S420,7 parts of diethylene glycols and 1 part of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S430,40 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S440,20 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S450,30-100 minute, dispersion machine is closed, obtains 4# samples.
Embodiment 5
Step S510,15 parts of deionized waters and 10 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S520,5 parts of diethylene glycols and 5 parts of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S530,50 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S540,20 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S550,30-100 minute, dispersion machine is closed, obtains 5# samples.
Embodiment 6
Step S610,15 parts of deionized waters and 12.5 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S620,7 parts of diethylene glycols and 7 parts of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S630,50 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S640,10 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S650,30-100 minute, dispersion machine is closed, obtains 6# samples.
Embodiment 7
Step S710,15 parts of deionized waters and 15 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S720,3 parts of diethylene glycols and 10 parts of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S730,50 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S740,15 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S750,30-100 minute, dispersion machine is closed, obtains 7# samples.
Embodiment 8
Step S810,15 parts of deionized waters and 10 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S820,7 parts of diethylene glycols and 10 parts of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S830,60 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S840,15 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S850,30-100 minute, dispersion machine is closed, obtains 8# samples.
Embodiment 9
Step S910,15 parts of deionized waters and 12.5 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S920,3 parts of diethylene glycols and 10 parts of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S930,60 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added extremely
Reactor；
Step S940,20 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S950,30-100 minute, dispersion machine is closed, obtains 9# samples.
Embodiment 10
Step S1010,15 parts of deionized waters and 15 parts of absolute ethyl alcohol are weighed, is added into reactor；
Step S1020,5 parts of diethylene glycols and 5 parts of glycerine are weighed, are added into reactor, start dispersion machine, with 500-
600r/min starts to disperse；
Step S1030,60 parts of acrylic resins are weighed, including soft propene acid resin and hard acrylic resin, added
To reactor；
Step S1040,10 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer are weighed, is added into reactor；
After step S1050,30-100 minute, dispersion machine is closed, obtains 10# samples.
The detection data of the sample to the 1# that embodiment 10 is prepared to 10# of above-described embodiment 1 are as shown in table 1：
Table 1
From above technical scheme, the aqueous laser thin-film material for the anti-rejection material that the embodiment of the present application provides, including：Third
Olefin(e) acid resin 40-60 parts, ethanol 10-15 parts, water-based wax emulsion 10-20 parts, diethylene glycol 3-7 parts, glycerine 1-10 parts, wetting
Agent 1-3 parts, defoamer 0.1-0.3 parts and water 10-20 parts；The acrylic resin includes soft propene acid resin and hard acrylic acid
Resin, wherein, the soft propene acid resin is 0-5 parts, and the hard acrylic resin is 0-1 parts.The application also provides a kind of excellent
It is 50 parts of acrylic resin to select scheme, 12.5 parts of ethanol, water-based 15 parts of wax emulsion, 5 parts of diethylene glycol, 5 parts of glycerine, wetting
2 parts of agent, 0.2 part of defoamer, 15 parts of water.The aqueous laser thin-film material that the application provides, film-formation result is good, and adhesion is strong, resistance to
Mill, without organic solvent, green non-pollution, more it is essential that the aqueous laser thin-film material of the anti-rejection material is not easy in coating
Material phenomenon is got rid of, coating effect is good.
It is required that those skilled in the art can be understood that the technology in the embodiment of the present invention can add by software
The mode of general hardware platform realize.Based on such understanding, the technical scheme in the embodiment of the present invention substantially or
Say that the part to be contributed to prior art can be embodied in the form of software product, the computer software product can be deposited
Storage is in storage medium, such as ROM/RAM, magnetic disc, CD, including some instructions are causing a computer equipment (can be with
Be personal computer, server, either network equipment etc.) perform some part institutes of each embodiment of the present invention or embodiment
The method stated.
In this specification between each embodiment identical similar part mutually referring to.Especially for embodiment 1-
For 10, because it is substantially similar to embodiment of the method, so description is fairly simple, related part is referring in embodiment of the method
Explanation.
Invention described above embodiment is not intended to limit the scope of the present invention..
Claims (10)
- A kind of 1. aqueous laser thin-film material of anti-rejection material, it is characterised in that including：The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid resin is 0-5 Part, the hard acrylic resin is 0-1 parts.
- 2. material according to claim 1, it is characterised in that the material includes：
- 3. material according to claim 2, it is characterised in that the material includes：
- 4. according to the material described in claim any one of 1-3, it is characterised in that the soft propene acid resin is 0 part.
- 5. according to the material described in claim any one of 1-3, it is characterised in that the hard acrylic resin is 0 part.
- 6. according to the material described in claim any one of 1-3, it is characterised in that the soft propene acid resin is 5 parts, described hard Acrylic resin is 1 part.
- 7. according to the material described in claim any one of 1-3, it is characterised in that the gamma transition temperature of the soft propene acid resin Spend for 80 DEG C.
- 8. according to the material described in claim any one of 1-3, it is characterised in that the gamma transition temperature of the hard acrylic resin Spend for 105 DEG C.
- 9. according to the material described in claim any one of 1-3, it is characterised in that the main component of the water-based wax emulsion is water Property Tissuemat E.
- 10. according to the material described in claim any one of 1-3, it is characterised in that defoamer is the defoamer without organosilicon.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711252392.0A CN107805435A (en) | 2017-12-01 | 2017-12-01 | A kind of aqueous laser thin-film material of anti-rejection material |
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| CN201711252392.0A CN107805435A (en) | 2017-12-01 | 2017-12-01 | A kind of aqueous laser thin-film material of anti-rejection material |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168637A (en) * | 2006-10-23 | 2008-04-30 | 吴达文 | Water highlight high conglutination-resistance printing gloss oil and its preparation method and application |
| CN103555180A (en) * | 2013-11-19 | 2014-02-05 | 三友（天津）高分子技术有限公司 | Water-based laser transfer coating for wine bottle glass baking paper, and preparation method thereof |
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2017
- 2017-12-01 CN CN201711252392.0A patent/CN107805435A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168637A (en) * | 2006-10-23 | 2008-04-30 | 吴达文 | Water highlight high conglutination-resistance printing gloss oil and its preparation method and application |
| CN103555180A (en) * | 2013-11-19 | 2014-02-05 | 三友（天津）高分子技术有限公司 | Water-based laser transfer coating for wine bottle glass baking paper, and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 钱鹭生等: "《涂布加工纸技术手册》", 31 May 2000, 中国轻工业出版社 * |
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Application publication date: 20180316 |