CN107936725A - A kind of aqueous laser thin-film material - Google Patents
A kind of aqueous laser thin-film material Download PDFInfo
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- CN107936725A CN107936725A CN201711251492.1A CN201711251492A CN107936725A CN 107936725 A CN107936725 A CN 107936725A CN 201711251492 A CN201711251492 A CN 201711251492A CN 107936725 A CN107936725 A CN 107936725A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The application provides a kind of aqueous laser thin-film material, including：40 60 parts of acrylic resin；10 15 parts of ethanol；Water-based 10 20 parts of wax emulsion；37 parts of diethylene glycol；13 parts of wetting agent；0.1 0.3 parts of defoamer；10 20 parts of water；The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid resin is 05 parts, and the hard acrylic resin is 01 parts.The application also provides a kind of preferred solution, 50 parts of acrylic resin；12.5 parts of ethanol；Water-based 15 parts of wax emulsion；5 parts of diethylene glycol；2 parts of wetting agent；0.2 part of defoamer；15 parts of water.The aqueous laser thin-film material that the application provides, film-formation result is good, and adhesion is strong, wear-resisting, more it is essential that the aqueous laser thin-film material is free of organic solvent, green non-pollution.
Description
Technical field
This application involves technical field of coatings, more particularly to a kind of aqueous laser thin-film material.
Background technology
Radium-shine packaging is the segmented industry in packaging industry, achieves quick development, with its in packaging industry
He compares product, and radium-shine packaging material not only has novel, beautiful appearance, while also has high-tech antiforge function,
It is referred to as the technical products of forefront in world's packages printing industry.The application field of radium-shine material is very extensive, food,
The industries such as medicine, daily chemical product, tobacco and wine, clothes, gift wrap and ornament materials are all promoted faster.
From product composition composition on divide, laser film product can be roughly divided into BOPP laser films, PET laser films and
Three kinds of PVC laser films.From technology level, the anti-counterfeit laser film product applied to label printing field belongs to the sector
In high-end product, its production process, which is related to multiple sport technique segments, the products such as laser anti-counterfeiting plate-making, membrane pressure, coating, transfer, to be had
Higher added value.Also it is widely used in packaging for foodstuff, commodity packaging, such as box for moon-cake, toothpaste box etc., and these fields pair
Using for radium-shine technology can be more and more.
Laser film main feature has three aspects, and first, intrinsic fragrance, anti-counterfeiting performance is strong, beautiful, green, environmental protection；Its
Secondary, resistance to ink corrodes, and barrier steam, carbon dioxide etc. ability is high；Finally, laser film has cigarette high glaze, and hologram layer assigns
Film is preferably antistatic, and adhesion inhibiting properties are high with upper machine adaptability.
However, the laser film material shown in the prior art contains substantial amounts of organic solvent, human body and environment can be made
Into harm.
The content of the invention
The application provides a kind of aqueous laser thin-film material, is contained greatly with solving the laser film material shown in the prior art
The problem of organic solvent of amount.
The application provides a kind of aqueous laser thin-film material, including：
The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid resin is
0-5 parts, the hard acrylic resin is 0-1 parts.
Further, the material includes：
Further, the material includes：
Further, the soft propene acid resin is 0 part.
Further, the hard acrylic resin is 0 part.
Further, the soft propene acid resin is 5 parts,
The hard acrylic resin is 1 part.
Further, the glass transition temperature of the soft propene acid resin is 80 DEG C.
Further, the glass transition temperature of the hard acrylic resin is 105 DEG C.
Further, the main component of the water-based wax emulsion is aqueous polyethylene wax.
Further, defoamer is the defoamer without organosilicon.
From above technical scheme, aqueous laser thin-film material provided by the embodiments of the present application, including：Acrylic resin
40-60 parts；10-15 parts of ethanol；Water-based wax emulsion 10-20 parts；3-7 parts of diethylene glycol；1-3 parts of wetting agent；Defoamer 0.1-0.3
Part；10-20 parts of water；The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid tree
Fat is 0-5 parts, and the hard acrylic resin is 0-1 parts.The application also provides a kind of preferred solution, 50 parts of acrylic resin；
12.5 parts of ethanol；Water-based 15 parts of wax emulsion；5 parts of diethylene glycol；2 parts of wetting agent；0.2 part of defoamer；15 parts of water.The application provides
Aqueous laser thin-film material, film-formation result is good, and adhesion is strong, wear-resisting, more it is essential that the aqueous laser thin-film material is free of
Organic solvent, green non-pollution.
Brief description of the drawings
In order to illustrate more clearly of the technical solution of the application, letter will be made to attached drawing needed in the embodiment below
Singly introduce, it should be apparent that, for those of ordinary skills, without having to pay creative labor,
Other attached drawings can also be obtained according to these attached drawings.
Fig. 1 is the method flow diagram for preparing aqueous laser thin-film material of the application according to an exemplary embodiment.
Embodiment
According to an embodiment of the present application, there is provided a kind of aqueous laser thin-film material, including：
The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid resin is
0-5 parts, the hard acrylic resin is 0-1 parts.
In aqueous laser thin-film material each component provided by the embodiments of the present application, acrylic resin is the basic thing of film forming
Matter, and laser effect can be produced, adhesion is strong；On the one hand ethanol plays the role of dispersant and solvent, on the other hand, in material
During coating, moreover it is possible to accelerate drying, improve the levelability of material, the material crawling for avoiding producing by slow drying speed shows
As；The main function of water-based wax emulsion is to make material that haftplatte not occur during membrane pressure, while improves the wear-resisting property of film；
Diethylene glycol further lifts film-formation result as coalescents；Wetting agent makes the surface wettability of film, and Painting effect is good；Disappear
Infusion is used to eliminate the bubble produced in material preparation process, makes material more stable homogeneous.
Acrylic resin, Chinese nickname include emulsion acrylic resin, acrylic acid modified resin etc., and color is shallow, water-white transparent.
Film performance is excellent, fast light, weatherability is good, heat-resisting, and resistance to paint baking over, chemical-resistant and the performance such as corrosion-resistant are all fabulous.Cause
This, the coating manufactured with acrylic resin.It is widely used, various in style.The varieties and characteristics of different acrylic resins all have impact on
The performance of coating products, these compositions all with acrylic resin, structure are related.
Emulsion acrylic resin is that acrylate is the high molecular weight of primary raw material, low viscosity emulsus hare resin, generally
For multiple copolymer, its film forming has the characteristics that bright, flexible, caking property is strong, water-fast and wear-resisting.Emulsion acrylic resin is by third
Olefin(e) acid ester, comonomer, emulsifying agent, initiator etc. are produced through emulsion copolymerization.Selection and proportioning by comonomer, adjust
The performance of emulsion acrylic resin and the hardness of film forming, to meet different purposes requirements.
The emulsion acrylic resin that the embodiment of the present application uses, can at least be prepared by following steps：
By the butyl acrylate of 28-30 parts by weight, the methacrylate of 22.8-24.6 mass parts, 5.4-7.2 mass parts
Acrylic acid, the ammonium persulfate of 0.6-2 mass parts, the NONIN HS 240 of 1.5-2.1 mass parts and dodecyl sulphur
The deionized water mixing of the mixture of sour sodium, the sodium acid carbonate of 0.4-0.8 mass parts and 95-105 mass parts, adds pH value tune
Agent is saved, is reacted, emulsion acrylic resin is obtained after curing.
Wherein, NONIN HS 240 and the mass ratio of lauryl sodium sulfate are (0.8-1.2):2；
It should also be noted that make above-mentioned reaction temperature be 60-95 DEG C, mixing speed be 60r/min-3000r/min's
Under the conditions of carry out；The temperature of above-mentioned curing is 70-95 DEG C, and when the time is 0.16-24 small, the pH value for reacting progress is 6-7.
Further, it is possible to pH value is adjusted by the mixed solution of Strong oxdiative sodium and ammonium hydroxide.
In above-mentioned the step of preparing emulsion acrylic resin, butyl acrylate, methyl methacrylate and acrylic acid structure
Into the monomer component in formula, butyl acrylate is soft monomer, assigns resin certain pliability and extensibility, methacrylic acid
Methyl esters is hard monomer, act as improving the hardness and tensile strength of resin；Acrylic acid is functional monomer, its main function is adjusting
Viscosity and participation polymerisation, cure generation linear polymer, are conducive to improve the pliability and adhesive force of glue-line, by varying
The content of acrylic acid can be with the surface energy and adhesion work of regulation system.
In above-mentioned the step of preparing emulsion acrylic resin, ammonium persulfate is water-soluble heat decomposition type initiator, preferably
0.6-1.5 mass parts, polymerisation is carried out it acts as monomer is triggered.Sodium acid carbonate is buffer, preferably 0.5-0.7 weight
Part, it is the pH value for maintaining lotion that it, which is acted on, stablizes polymerization environment.In emulsion polymerization process, ammonium persulfate, which decomposes, makes system pH
Value reduces, and adding buffer with the pH value of maintenance system, can ensure the activity of initiator, triggers chain and is normally carried out.
NONIN HS 240 and the mixture of lauryl sodium sulfate are emulsifying agent, preferably 1.7-1.9 mass parts,
Its reduction interfacial tension acted on, makes immiscible water-oil phase by the role transformation of stirring can be stabilized, long
Put the lotion for being easily difficult to be layered.
Influencing the factor of acrylic resin performance includes：1st, molecular weight distribution and size；2nd, the chemical constitution of monomer and tree
The characteristics of fat；3rd, glass transition temperature.Technical scheme is by selecting different copolymer monomer and matching the difference being prepared
The hardness emulsion acrylic resin of performance and film forming, to prepare aqueous laser thin-film material.
In addition, in addition to the emulsion acrylic resin that the above method is prepared, pure-acrylic emulsion, vinegar third also can be selected in the application
Two kinds in the tertiary vinegar milk liquid of lotion (tertiary carbonic ester-vinylacetate) lotion or uncle third (tertiary carbonic ester-acrylate) lotion.
Water-based wax emulsion refers to aqueous polyethylene wax emulsion, is high density polyethylene waxes, in present embodiments,
The molecular weight of high density polyethylene waxes is between 80000-120000.
The defoamer that the application uses is the defoamer without organosilicon.In each embodiment of the application, what defoamer was selected
It is 830 high type defoamers of German enlightening.
For the wetting agent that the application uses for modified poly ester, active ingredient is 39-41% by weight percentage, and solids content is pressed
Percentage by weight is 49-51%.What the wetting agent in each embodiment of the application was selected is the high 740W type wetting agents of German enlightening.
Refering to Fig. 1, according to the embodiment of the present application, a kind of method for preparing aqueous laser thin-film material comprises the following steps：
Step S01, weighs the absolute ethyl alcohol of 10-20 parts of deionized waters and 10-15 mass parts, adds into reactor；
Step S02, weighs 3-7 parts of diethylene glycols, adds into reactor, starts dispersion machine, is opened with 500-600r/min
Begin scattered；
Step S03, weighs 40-60 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds
To reactor；
Step S04, weighs 10-20 parts of water-based wax emulsions, 1-3 parts of wetting agents and 0.1-0.3 parts of defoamers, adds to anti-
Answer in device；
After step S05,30-100 minutes, dispersion machine is closed, obtains aqueous laser thin-film material.
The aqueous laser thin-film material film-formation result being prepared using the above method is good, and adhesion is strong, wear-resisting, more crucial
, which is free of organic solvent, green non-pollution.
In some preferred embodiments, the material includes：
In other preferred embodiments, the material includes：
According to the embodiment of the present application, the acrylic resin of use is any one of soft propene acid resin and hard acrylic resin
Kind or two kinds of mixing.Therefore, in some embodiments, the soft propene acid resin is 0 part, or the hard acrylic resin is
0 part.
According to above-described embodiment, it is 5 parts that one kind of acrylic resin, which is preferably constituted as the soft propene acid resin, described hard
Acrylic resin is 1 part.
It should be noted that the glass transition temperature of the soft propene acid resin is 80 DEG C；The hard acrylic resin
Glass transition temperature is 105 DEG C.
The specific implementation for the aqueous laser thin-film material that the application provides, referring also to following embodiments.
Embodiment 1
Step S110, weighs 15 parts of deionized waters and 12.5 parts of absolute ethyl alcohol, adds into reactor；
Step S120, weighs 5 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S130, weighs 50 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S140, weighs 15 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S150,30-100 minutes, dispersion machine is closed, obtains 1# samples.
Embodiment 2
Step S210, weighs 15 parts of deionized waters and 10 parts of absolute ethyl alcohol, adds into reactor；
Step S220, weighs 3 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S230, weighs 40 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S240, weighs 10 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S250,30-100 minutes, dispersion machine is closed, obtains 2# samples.
Embodiment 3
Step S310, weighs 15 parts of deionized waters and 12.5 parts of absolute ethyl alcohol, adds into reactor；
Step S320, weighs 5 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S330, weighs 40 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S340, weighs 15 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S350,30-100 minutes, dispersion machine is closed, obtains 3# samples.
Embodiment 4
Step S410, weighs 15 parts of deionized waters and 15 parts of absolute ethyl alcohol, adds into reactor；
Step S420, weighs 7 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S430, weighs 40 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S440, weighs 20 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S450,30-100 minutes, dispersion machine is closed, obtains 4# samples.
Embodiment 5
Step S510, weighs 15 parts of deionized waters and 10 parts of absolute ethyl alcohol, adds into reactor；
Step S520, weighs 5 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S530, weighs 50 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S540, weighs 20 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S550,30-100 minutes, dispersion machine is closed, obtains 5# samples.
Embodiment 6
Step S610, weighs 15 parts of deionized waters and 12.5 parts of absolute ethyl alcohol, adds into reactor；
Step S620, weighs 7 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S630, weighs 50 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S640, weighs 10 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S650,30-100 minutes, dispersion machine is closed, obtains 6# samples.
Embodiment 7
Step S710, weighs 15 parts of deionized waters and 15 parts of absolute ethyl alcohol, adds into reactor；
Step S720, weighs 3 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S730, weighs 50 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S740, weighs 15 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S750,30-100 minutes, dispersion machine is closed, obtains 7# samples.
Embodiment 8
Step S810, weighs 15 parts of deionized waters and 10 parts of absolute ethyl alcohol, adds into reactor；
Step S820, weighs 7 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S830, weighs 60 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S840, weighs 15 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S850,30-100 minutes, dispersion machine is closed, obtains 8# samples.
Embodiment 9
Step S910, weighs 15 parts of deionized waters and 12.5 parts of absolute ethyl alcohol, adds into reactor；
Step S920, weighs 3 parts of diethylene glycols, adds into reactor, starts dispersion machine, is started with 500-600r/min
It is scattered；
Step S930, weighs 60 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds extremely
Reactor；
Step S940, weighs 20 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S950,30-100 minutes, dispersion machine is closed, obtains 9# samples.
Embodiment 10
Step S1010, weighs 15 parts of deionized waters and 15 parts of absolute ethyl alcohol, adds into reactor；
Step S1020, weighs 5 parts of diethylene glycols, adds into reactor, starts dispersion machine, is opened with 500-600r/min
Begin scattered；
Step S1030, weighs 60 parts of acrylic resins, including soft propene acid resin and hard acrylic resin, adds
To reactor；
Step S1040, weighs 10 parts of water-based wax emulsions, 2 parts of wetting agents and 0.2 part of defoamer, adds into reactor；
After step S1050,30-100 minutes, dispersion machine is closed, obtains 10# samples.
The detection data of the sample to the 1# that embodiment 10 is prepared to 10# of above-described embodiment 1 are as shown in table 1：
Table 1
From above technical scheme, aqueous laser thin-film material provided by the embodiments of the present application, including：Acrylic resin
40-60 parts；10-15 parts of ethanol；Water-based wax emulsion 10-20 parts；3-7 parts of diethylene glycol；1-3 parts of wetting agent；Defoamer 0.1-0.3
Part；10-20 parts of water；The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid tree
Fat is 0-5 parts, and the hard acrylic resin is 0-1 parts.The application also provides a kind of preferred solution, 50 parts of acrylic resin；
12.5 parts of ethanol；Water-based 15 parts of wax emulsion；5 parts of diethylene glycol；2 parts of wetting agent；0.2 part of defoamer；15 parts of water.The application provides
Aqueous laser thin-film material, film-formation result is good, and adhesion is strong, wear-resisting, more it is essential that the aqueous laser thin-film material is free of
Organic solvent, green non-pollution.
It is required that those skilled in the art can be understood that the technology in the embodiment of the present invention can add by software
The mode of general hardware platform realize.Based on such understanding, the technical solution in the embodiment of the present invention substantially or
Say that the part to contribute to the prior art can be embodied in the form of software product, which can deposit
Storage is in storage medium, such as ROM/RAM, magnetic disc, CD, including some instructions are used so that computer equipment (can be with
Be personal computer, server, either network equipment etc.) perform some part institutes of each embodiment of the present invention or embodiment
The method stated.
In this specification between each embodiment identical similar part mutually referring to.Especially for embodiment 1-
For 10, since it is substantially similar to embodiment of the method, so description is fairly simple, related part is referring in embodiment of the method
Explanation.
Invention described above embodiment is not intended to limit the scope of the present invention..
Claims (10)
- A kind of 1. aqueous laser thin-film material, it is characterised in that including：The acrylic resin includes soft propene acid resin and hard acrylic resin, wherein, the soft propene acid resin is 0-5 Part, the hard acrylic resin is 0-1 parts.
- 2. material according to claim 1, it is characterised in that the material includes：
- 3. material according to claim 2, it is characterised in that the material includes：
- 4. according to claim 1-3 any one of them materials, it is characterised in that the soft propene acid resin is 0 part.
- 5. according to claim 1-3 any one of them materials, it is characterised in that the hard acrylic resin is 0 part.
- 6. according to claim 1-3 any one of them materials, it is characterised in that the soft propene acid resin is 5 parts, described hard Acrylic resin is 1 part.
- 7. according to claim 1-3 any one of them materials, it is characterised in that the gamma transition temperature of the soft propene acid resin Spend for 80 DEG C.
- 8. according to claim 1-3 any one of them materials, it is characterised in that the gamma transition temperature of the hard acrylic resin Spend for 105 DEG C.
- 9. according to claim 1-3 any one of them materials, it is characterised in that the main component of the water-based wax emulsion is water Property Tissuemat E.
- 10. according to claim 1-3 any one of them materials, it is characterised in that defoamer is the defoamer without organosilicon.
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| CN201711251492.1A CN107936725A (en) | 2017-12-01 | 2017-12-01 | A kind of aqueous laser thin-film material |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168637A (en) * | 2006-10-23 | 2008-04-30 | 吴达文 | Water highlight high conglutination-resistance printing gloss oil and its preparation method and application |
| CN103555180A (en) * | 2013-11-19 | 2014-02-05 | 三友（天津）高分子技术有限公司 | Water-based laser transfer coating for wine bottle glass baking paper, and preparation method thereof |
-
2017
- 2017-12-01 CN CN201711251492.1A patent/CN107936725A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168637A (en) * | 2006-10-23 | 2008-04-30 | 吴达文 | Water highlight high conglutination-resistance printing gloss oil and its preparation method and application |
| CN103555180A (en) * | 2013-11-19 | 2014-02-05 | 三友（天津）高分子技术有限公司 | Water-based laser transfer coating for wine bottle glass baking paper, and preparation method thereof |
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Application publication date: 20180420 |