CN107788013A - Drink water purifying disinfectant and preparation method thereof - Google Patents
Drink water purifying disinfectant and preparation method thereof Download PDFInfo
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- CN107788013A CN107788013A CN201711144183.4A CN201711144183A CN107788013A CN 107788013 A CN107788013 A CN 107788013A CN 201711144183 A CN201711144183 A CN 201711144183A CN 107788013 A CN107788013 A CN 107788013A
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- sodium chlorite
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/12—Iodine, e.g. iodophors; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of drink water purifying disinfectant and preparation method thereof, wherein disinfectant includes:Water, citric acid, hydrogen peroxide, sodium chlorite, disodium hydrogen phosphate, silver nitrate, surfactant, polyhexamethylene guanidine propionate, chitosan, KI.Technical scheme does not produce any harmful DBPs substantially, the carcinogenic generation such as haloform can be significantly reduced, there is no corrosivity, biomembrane that can be effectively in eliminating equipment pipe network, can significantly reduce the maintenance cost of pipeline and equipment, have highly stable chemical property, period of storage is grown, high temperature resistant, do not decompose in the sun, it is optimal to the antivirus effect of drinking water.
Description
Technical field
The invention belongs to water-treatment technology field, and in particular to a kind of drink water purifying disinfectant.
Background technology
The disinfectant generally used in drinking water field mainly has chlorination, chloramines disinfection, disinfection by chlorine dioxide, ozone to disappear
Poison, disinfection by ultraviolet light etc..But above-mentioned disinfectant all there is it is certain the defects of, for the demand to persistence disinfecting power,
Only chlorhexidine-containing disinfectant and chloramines disinfection agent can be used in secondary sterilization, but the use of these disinfectants simultaneously generate again it is harmful
DBPs, and the yield of accessory substance with drinking water in the distribution system of water supply extension of period of storage and increase.Study table
Bright, in many drinking water plants, the DBPs such as about more than 50% haloform generates in distribution system of water supply system.
There are a variety of DBPs to be included in sanitary standard for drinking water by countries in the world and the World Health Organization and monitored.
Therefore, how while effectively being disinfected to drinking water reduce DBPs yield increasingly by
Concern.
The content of the invention
In view of the problems of prior art, the present invention provides a kind of drink water purifying disinfectant.
In order to solve the above technical problems, technical scheme proposed by the present invention is as follows:A kind of drink water purifying disinfectant, including
The component of following parts by weight:The parts by weight of water 80~100, the parts by weight of citric acid 40~60, the parts by weight of hydrogen peroxide 30~50, chlorous acid
The parts by weight of sodium 25~45, the parts by weight of disodium hydrogen phosphate 20~30, the parts by weight of silver nitrate 15~30, the weight of surfactant 10~20
Part, the parts by weight of polyhexamethylene guanidine propionate 5~15, the parts by weight of chitosan 1~5, the parts by weight of KI 1~5.
According to drink water purifying disinfectant provided by the invention and preparation method thereof, inventor has carried out substantial amounts of group early stage
Point and dosage screening experiment, be found surprisingly that, technical scheme does not produce any harmful sterilization by-product substantially
Thing, the carcinogenic generation such as haloform can be significantly reduced, without corrosivity, biology that can be effectively in eliminating equipment pipe network
Film, the maintenance cost of pipeline and equipment can be significantly reduced, there is highly stable chemical property, period of storage is grown, high temperature resistant,
Do not decomposed under sunlight, it is optimal to the antivirus effect of drinking water.
In addition, drink water purifying disinfectant according to the above embodiment of the present invention and preparation method thereof, can also have such as
Additional technical characteristic down:
According to the example of the present invention, the water is 80 parts by weight, and the citric acid is 40 parts by weight, the hydrogen peroxide
For 30 parts by weight, the sodium chlorite is 25 parts by weight, and the disodium hydrogen phosphate is 20 parts by weight, and the silver nitrate is 15 weights
Part is measured, the surfactant is 10 parts by weight, and the polyhexamethylene guanidine propionate is 5 parts by weight, and the chitosan is 1 weight
Part, the KI is 1 parts by weight.
According to the example of the present invention, the water is 85 parts by weight, and the citric acid is 45 parts by weight, the hydrogen peroxide
For 35 parts by weight, the sodium chlorite is 30 parts by weight, and the disodium hydrogen phosphate is 23 parts by weight, and the silver nitrate is 18 weights
Part is measured, the surfactant is 13 parts by weight, and the polyhexamethylene guanidine propionate is 8 parts by weight, and the chitosan is 2 weight
Part, the KI is 2 parts by weight.
According to the example of the present invention, the water is 90 parts by weight, and the citric acid is 50 parts by weight, the hydrogen peroxide
For 40 parts by weight, the sodium chlorite is 40 parts by weight, and the disodium hydrogen phosphate is 27 parts by weight, and the silver nitrate is 23 weights
Part is measured, the surfactant is 16 parts by weight, and the polyhexamethylene guanidine propionate is 12 parts by weight, and the chitosan is 3 weights
Part is measured, the KI is 3 parts by weight.
According to the example of the present invention, the water is 100 parts by weight, and the citric acid is 60 parts by weight, the dioxygen
Water is 50 parts by weight, and the sodium chlorite is 45 parts by weight, and the disodium hydrogen phosphate is 30 parts by weight, and the silver nitrate is 30 weights
Part is measured, the sodium chlorite is 20 parts by weight, and the polyhexamethylene guanidine propionate is 15 parts by weight, and the chitosan is 5 weight
Part, the KI is 5 parts by weight.
In addition, present invention also offers a kind of preparation method of drink water purifying disinfectant, comprise the following steps:(1) with
Parts by weight meter, weigh the raw material for standby;(2) with ready citric acid, sodium chlorite, polyhexamethylene guanidine propionate and appropriate
Water has configured pH cushioning liquid;(3) silver nitrate solution is added into buffer solution to be well mixed, add chitosan, mix and produce.
The advantages of above additional aspect, will be set forth in part in the description, and partly will become bright from the following description
It is aobvious, or recognized by the practice of the present invention.
Embodiment
Embodiment one
A kind of drink water purifying disinfectant, include the component of following parts by weight:Water is 80 parts by weight, and citric acid is 40 weight
Part, hydrogen peroxide is 30 parts by weight, and sodium chlorite is 25 parts by weight, and disodium hydrogen phosphate is 20 parts by weight, and silver nitrate is 15 parts by weight,
Surfactant is 10 parts by weight, and polyhexamethylene guanidine propionate is 5 parts by weight, and chitosan is 1 parts by weight, and KI is 1 weight
Part.
Embodiment two
A kind of drink water purifying disinfectant, include the component of following parts by weight:Water is 85 parts by weight, and citric acid is 45 weight
Part, hydrogen peroxide is 35 parts by weight, and sodium chlorite is 30 parts by weight, and disodium hydrogen phosphate is 23 parts by weight, and silver nitrate is 18 parts by weight,
Surfactant is 13 parts by weight, and polyhexamethylene guanidine propionate is 8 parts by weight, and chitosan is 2 parts by weight, and KI is 2 weight
Part.
Embodiment three
A kind of drink water purifying disinfectant, include the component of following parts by weight:Water is 90 parts by weight, and citric acid is 50 weight
Part, hydrogen peroxide is 40 parts by weight, and sodium chlorite is 40 parts by weight, and disodium hydrogen phosphate is 27 parts by weight, and silver nitrate is 23 parts by weight,
Surfactant is 16 parts by weight, and polyhexamethylene guanidine propionate is 12 parts by weight, and chitosan is 3 parts by weight, and KI is 3 weight
Part.
Example IV
A kind of drink water purifying disinfectant, include the component of following parts by weight:Water is 100 parts by weight, and citric acid is 60 weights
Part is measured, hydrogen peroxide is 50 parts by weight, and sodium chlorite is 45 parts by weight, and disodium hydrogen phosphate is 30 parts by weight, and silver nitrate is 30 weight
Part, sodium chlorite is 20 parts by weight, and polyhexamethylene guanidine propionate is 15 parts by weight, and chitosan is 5 parts by weight, and KI is 5 weights
Measure part.
Comparative example one
Citric acid and hydrogen peroxide are not used, remaining composition is identical with embodiment one.
Comparative example two
Silver nitrate is not used, remaining composition is identical with embodiment one.
Measure of merit
The haloform of each embodiment and comparative example of drink water purifying disinfectant by the present invention and preparation method thereof
Tested etc. harmful substance reduced rate (with compared with dosage chlorination), sterilization efficiency enhancing rate, test result such as following table:
Harmful substance reduced rate (%) | Sterilization efficiency enhancing rate (%) | |
Embodiment one | 8.7 | 10.30 |
Embodiment two | 9.2 | 9.98 |
Embodiment three | 9.8 | 10.77 |
Example IV | 10.1 | 10.20 |
Comparative example one | 4.3 | 5.38 |
Comparative example two | 3.9 | 4.93 |
Understand that the disinfectant of technical scheme does not produce any harmful sterilization by-product substantially with reference to above-mentioned data
Thing, the carcinogenic generation such as haloform can be significantly reduced, without corrosivity, biology that can be effectively in eliminating equipment pipe network
Film, the maintenance cost of pipeline and equipment can be significantly reduced, there is highly stable chemical property, period of storage is grown, and high temperature resistant is right
The antivirus effect of drinking water is optimal.
Although embodiments of the invention have been shown and described above, it is to be understood that above-described embodiment is example
Property, it is impossible to limitation of the present invention is interpreted as, one of ordinary skill in the art within the scope of the invention can be to above-mentioned
Embodiment is changed, changed, replacing and modification.
Claims (6)
1. a kind of drink water purifying disinfectant, it is characterised in that include the component of following parts by weight:The parts by weight of water 80~100, lemon
The parts by weight of lemon acid 40~60, the parts by weight of hydrogen peroxide 30~50, the parts by weight of sodium chlorite 25~45, the weight of disodium hydrogen phosphate 20~30
Part, the parts by weight of silver nitrate 15~30, the parts by weight of surfactant 10~20, the parts by weight of polyhexamethylene guanidine propionate 5~15, shell gather
Sugared 1~5 parts by weight, the parts by weight of KI 1~5.
2. drink water purifying disinfectant according to claim 1, it is characterised in that the water is 80 parts by weight, the lemon
Lemon acid is 40 parts by weight, and the hydrogen peroxide is 30 parts by weight, and the sodium chlorite is 25 parts by weight, and the disodium hydrogen phosphate is 20
Parts by weight, the silver nitrate are 15 parts by weight, and the surfactant is 10 parts by weight, and the polyhexamethylene guanidine propionate is 5
Parts by weight, the chitosan are 1 parts by weight, and the KI is 1 parts by weight.
3. drink water purifying disinfectant according to claim 1, it is characterised in that the water is 85 parts by weight, the lemon
Lemon acid is 45 parts by weight, and the hydrogen peroxide is 35 parts by weight, and the sodium chlorite is 30 parts by weight, and the disodium hydrogen phosphate is 23
Parts by weight, the silver nitrate are 18 parts by weight, and the surfactant is 13 parts by weight, and the polyhexamethylene guanidine propionate is 8
Parts by weight, the chitosan are 2 parts by weight, and the KI is 2 parts by weight.
4. drink water purifying disinfectant according to claim 1, it is characterised in that the water is 90 parts by weight, the lemon
Lemon acid is 50 parts by weight, and the hydrogen peroxide is 40 parts by weight, and the sodium chlorite is 40 parts by weight, and the disodium hydrogen phosphate is 27
Parts by weight, the silver nitrate are 23 parts by weight, and the surfactant is 16 parts by weight, and the polyhexamethylene guanidine propionate is 12
Parts by weight, the chitosan are 3 parts by weight, and the KI is 3 parts by weight.
5. drink water purifying disinfectant according to claim 1, it is characterised in that the water is 100 parts by weight, the lemon
Lemon acid is 60 parts by weight, and the hydrogen peroxide is 50 parts by weight, and the sodium chlorite is 45 parts by weight, and the disodium hydrogen phosphate is 30
Parts by weight, the silver nitrate are 30 parts by weight, and the sodium chlorite is 20 parts by weight, and the polyhexamethylene guanidine propionate is 15 weights
Part is measured, the chitosan is 5 parts by weight, and the KI is 5 parts by weight.
6. a kind of preparation method of drink water purifying disinfectant according to claim 1, it is characterised in that including following step
Suddenly:(1) in parts by weight, the raw material for standby is weighed;(2) with ready citric acid, sodium chlorite, propanoic acid polyhexamethylene
Guanidine and suitable quantity of water have configured pH cushioning liquid;(3) silver nitrate solution is added into buffer solution to be well mixed, add chitosan,
Mix and produce.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711144183.4A CN107788013A (en) | 2017-11-17 | 2017-11-17 | Drink water purifying disinfectant and preparation method thereof |
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CN201711144183.4A CN107788013A (en) | 2017-11-17 | 2017-11-17 | Drink water purifying disinfectant and preparation method thereof |
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CN107788013A true CN107788013A (en) | 2018-03-13 |
Family
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CN201711144183.4A Withdrawn CN107788013A (en) | 2017-11-17 | 2017-11-17 | Drink water purifying disinfectant and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107996605A (en) * | 2018-03-22 | 2018-05-08 | 中山市榄商置业发展有限公司 | A kind of solid sterilizing new material and preparation method thereof |
CN111328804A (en) * | 2020-04-08 | 2020-06-26 | 刘水平 | Disinfectant for water treatment and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1103628A (en) * | 1993-12-11 | 1995-06-14 | 李圭白 | Drinking water purifying technique with compound permanganate medicament |
CN1703958A (en) * | 2004-05-26 | 2005-12-07 | 韩国友 | Highly efficient broad spectrum disinfectant, its preparation method and application |
CN101574087A (en) * | 2008-05-05 | 2009-11-11 | 铜陵高聚生物科技有限公司 | Polyhexamethylene guanidine propionate disinfectant and preparation method thereof |
CN103891773A (en) * | 2014-04-21 | 2014-07-02 | 成都科宏达科技有限公司 | Sterilizing agent and preparation method thereof |
CN105836860A (en) * | 2016-05-30 | 2016-08-10 | 柴海林 | Stable hydrogen perioxide sanitizer and application thereof in drinking water sanitization |
-
2017
- 2017-11-17 CN CN201711144183.4A patent/CN107788013A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1103628A (en) * | 1993-12-11 | 1995-06-14 | 李圭白 | Drinking water purifying technique with compound permanganate medicament |
CN1703958A (en) * | 2004-05-26 | 2005-12-07 | 韩国友 | Highly efficient broad spectrum disinfectant, its preparation method and application |
CN101574087A (en) * | 2008-05-05 | 2009-11-11 | 铜陵高聚生物科技有限公司 | Polyhexamethylene guanidine propionate disinfectant and preparation method thereof |
CN103891773A (en) * | 2014-04-21 | 2014-07-02 | 成都科宏达科技有限公司 | Sterilizing agent and preparation method thereof |
CN105836860A (en) * | 2016-05-30 | 2016-08-10 | 柴海林 | Stable hydrogen perioxide sanitizer and application thereof in drinking water sanitization |
Non-Patent Citations (3)
Title |
---|
严莲荷: "《水处理药剂及配方手册》", 31 January 2004, 中国石化出版社 * |
环境保护部化学品登记中心: "《国外重点环境管理化学品及其筛选技术》", 31 December 2011, 中国环境科学出版社 * |
蒋建新等: "《功能性多糖胶开发与应用》", 31 January 2013, 中国轻工业出版社 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107996605A (en) * | 2018-03-22 | 2018-05-08 | 中山市榄商置业发展有限公司 | A kind of solid sterilizing new material and preparation method thereof |
CN111328804A (en) * | 2020-04-08 | 2020-06-26 | 刘水平 | Disinfectant for water treatment and preparation method thereof |
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Application publication date: 20180313 |