CN107778761A - A kind of product of rubber and plastic mechanical property modifying agent - Google Patents

A kind of product of rubber and plastic mechanical property modifying agent Download PDF

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Publication number
CN107778761A
CN107778761A CN201711173259.6A CN201711173259A CN107778761A CN 107778761 A CN107778761 A CN 107778761A CN 201711173259 A CN201711173259 A CN 201711173259A CN 107778761 A CN107778761 A CN 107778761A
Authority
CN
China
Prior art keywords
parts
rubber
product
mechanical property
modifying agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711173259.6A
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Chinese (zh)
Inventor
方文学
詹小兵
方揆民
李明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Million Square Pipe Industry Group Co Ltd
Original Assignee
Anhui Million Square Pipe Industry Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Million Square Pipe Industry Group Co Ltd filed Critical Anhui Million Square Pipe Industry Group Co Ltd
Priority to CN201711173259.6A priority Critical patent/CN107778761A/en
Publication of CN107778761A publication Critical patent/CN107778761A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L59/00Compositions of polyacetals; Compositions of derivatives of polyacetals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of product of rubber and plastic mechanical property modifying agent, is made up of by weight the following raw material:20 25 parts of butyral resin, 15 18 parts of polyacrylate, 15 20 parts of natural rubber, 35 parts of polyethylene, 36 parts of silane coupler, 5 12 parts of carboxylic acid compound, 46 parts of water reducer, 36 parts of epoxide, 37 parts of phosphite ester, 15 parts of toughener, 36 parts of plasticiser, 25 parts of anti-wear agent, 13 parts of fire retardant.The product of rubber and plastic mechanical property modifying agent of the present invention, not only nontoxic, good weatherability, with preferable stability, being applied to the finished product for going to obtain in product of rubber and plastic has preferable fire resistance, anti-wear performance, tensile resistance and intensity, and for a long time in hot environment still be able to keep good mechanical performance, be unlikely to deteriorate it is impaired, service life is grown, and has very strong practical value.

Description

A kind of product of rubber and plastic mechanical property modifying agent
Technical field
The present invention relates to a kind of rubber and plastics auxiliaries, specifically a kind of product of rubber and plastic mechanical property modifying agent.
Background technology
In automobile industry, Automobile Plastic Rubber accessory species is various, such as rain brush, seal fitting, damping air spring circle, tooth form The place to use of cutting belt etc., different products and accessory is different to the mechanical property requirements of rubber and plastic accessory, and due to automobile The long-term lossy product grown for the update cycle, and all in hot operation state, this is just right in many places in use Accessory require it is very high, from the performance such as intensity, fire resistance, low-temperature resistance, stretch-proof, high temperature resistance, wear-resistant for have it is certain It is required that this applied to the mechanical property modifying agent in rubber and plastic accessory also just to having further high standards.
It is a kind of to be worth research dedicated for improving the exploitation of the mechanical property modifying agent of Automobile Plastic Rubber accessory article.
The content of the invention
The invention provides a kind of product of rubber and plastic mechanical property modifying agent, to solve above-mentioned technical problem.
A kind of product of rubber and plastic mechanical property modifying agent, it is made up of by weight the following raw material:Butyral resin 20-25 parts, gather Acrylate 15-18 parts, natural rubber 15-20 parts, polyethylene 3-5 parts, silane coupler 3-6 parts, carboxylic acid compound 5-12 Part, water reducer 4-6 parts, epoxide 3-6 parts, phosphite ester 3-7 parts, toughener 1-5 parts, plasticiser 3-6 parts, anti-wear agent 2- 5 parts, fire retardant 1-3 parts.
Preferably, a kind of product of rubber and plastic mechanical property modifying agent, it is made up of by weight the following raw material:Butyral resin 22.5 Part, 16.5 parts of polyacrylate, 17.5 parts of natural rubber, 4 parts of polyethylene, 4.5 parts of silane coupler, carboxylic acid compound 8.5 Part, 5 parts of water reducer, 4.5 parts of epoxide, 5 parts of phosphite ester, 3 parts of toughener, 4.5 parts of plasticiser, 3.5 parts of anti-wear agent, resistance Fire 2 parts of agent.
Preferably, the epoxide is one kind in expoxy propane, epoxy silicon oil, epoxychloropropane.
Preferably, the carbon atom number of the carboxylic acid compound is not less than 6.
Preferably, the toughener is haloflex.
Preferably, the plasticiser is environment-friendlyplasticizer plasticizer.
Preferably, silicone oil is not less than 20% in the anti-wear agent.
Preferably, the fire retardant is antimony oxide.
Beneficial effects of the present invention:
The beneficial effects of the invention are as follows:The product of rubber and plastic mechanical property modifying agent of the present invention, not only nontoxic, weatherability It is good, there is preferable stability, be applied to the finished product for going to obtain in product of rubber and plastic have preferable fire resistance, anti-wear performance, Tensile resistance and intensity, and still be able to keep good mechanical performance in hot environment for a long time, be unlikely to deteriorate impaired, make With long lifespan, there is very strong practical value.
Embodiment
Embodiments of the invention are described in detail below, but what the present invention can be defined by the claims and cover Multitude of different ways is implemented.
Below by way of specific embodiment, the present invention will be described in detail.
Embodiment 1
A kind of product of rubber and plastic mechanical property modifying agent, it is made up of by weight the following raw material:20 parts of butyral resin, polypropylene 15 parts of acid esters, 15 parts of natural rubber, 3 parts of polyethylene, 3 parts of silane coupler, 5 parts of carboxylic acid compound, 4 parts of water reducer, epoxy 3 parts of compound, 3 parts of phosphite ester, 1 part of toughener, 3 parts of plasticiser, 2 parts of anti-wear agent, 1 part of fire retardant.
Wherein, the epoxide is one kind in expoxy propane, epoxy silicon oil, epoxychloropropane;The carboxylic acids The carbon atom number of compound is not less than 6;The toughener is haloflex;The plasticiser is environment-friendlyplasticizer plasticizer;Institute State silicone oil in anti-wear agent and be not less than 20%;The fire retardant is antimony oxide.
Embodiment 2
A kind of product of rubber and plastic mechanical property modifying agent, it is made up of by weight the following raw material:22.5 parts of butyral resin, poly- third 16.5 parts of olefin(e) acid ester, 17.5 parts of natural rubber, 4 parts of polyethylene, 4.5 parts of silane coupler, 8.5 parts of carboxylic acid compound, diminishing 5 parts of agent, 4.5 parts of epoxide, 5 parts of phosphite ester, 3 parts of toughener, 4.5 parts of plasticiser, 3.5 parts of anti-wear agent, fire retardant 2 Part.
Wherein, the epoxide is one kind in expoxy propane, epoxy silicon oil, epoxychloropropane;The carboxylic acids The carbon atom number of compound is not less than 6;The toughener is haloflex;The plasticiser is environment-friendlyplasticizer plasticizer;Institute State silicone oil in anti-wear agent and be not less than 20%;The fire retardant is antimony oxide.
Embodiment 3
A kind of product of rubber and plastic mechanical property modifying agent, it is made up of by weight the following raw material:25 parts of butyral resin, polypropylene 18 parts of acid esters, 20 parts of natural rubber, 5 parts of polyethylene, 6 parts of silane coupler, 12 parts of carboxylic acid compound, 6 parts of water reducer, epoxy 6 parts of compound, 7 parts of phosphite ester, 5 parts of toughener, 6 parts of plasticiser, 5 parts of anti-wear agent, 3 parts of fire retardant.
Wherein, the epoxide is one kind in expoxy propane, epoxy silicon oil, epoxychloropropane;The carboxylic acids The carbon atom number of compound is not less than 6;The toughener is haloflex;The plasticiser is environment-friendlyplasticizer plasticizer;Institute State silicone oil in anti-wear agent and be not less than 20%;The fire retardant is antimony oxide.
The embodiments of the present invention described above are not intended to limit the scope of the present invention, any in the present invention Spirit and principle within the modifications, equivalent substitutions and improvements made etc., should be included in the claim protection model of the present invention Within enclosing.

Claims (8)

1. a kind of product of rubber and plastic mechanical property modifying agent, it is characterised in that be made up of by weight the following raw material:Butyral resin 20-25 parts, polyacrylate 15-18 parts, natural rubber 15-20 parts, polyethylene 3-5 parts, silane coupler 3-6 parts, carboxylic acids Compound 5-12 parts, water reducer 4-6 parts, epoxide 3-6 parts, phosphite ester 3-7 parts, toughener 1-5 parts, plasticiser 3-6 Part, anti-wear agent 2-5 parts, fire retardant 1-3 parts.
2. product of rubber and plastic mechanical property modifying agent according to claim 1, it is characterised in that by the following raw material by weight Composition:22.5 parts of butyral resin, 16.5 parts of polyacrylate, 17.5 parts of natural rubber, 4 parts of polyethylene, silane coupler 4.5 Part, 8.5 parts of carboxylic acid compound, 5 parts of water reducer, 4.5 parts of epoxide, 5 parts of phosphite ester, 3 parts of toughener, plasticiser 4.5 parts, 3.5 parts of anti-wear agent, 2 parts of fire retardant.
3. product of rubber and plastic mechanical property modifying agent according to claim 1 or 2, it is characterised in that the epoxide For one kind in expoxy propane, epoxy silicon oil, epoxychloropropane.
4. product of rubber and plastic mechanical property modifying agent according to claim 1 or 2, it is characterised in that the carboxylic acids chemical combination The carbon atom number of thing is not less than 6.
5. product of rubber and plastic mechanical property modifying agent according to claim 1 or 2, it is characterised in that the toughener is chlorine Change polyethylene.
6. product of rubber and plastic mechanical property modifying agent according to claim 1 or 2, it is characterised in that the plasticiser is ring Protect shape agent.
7. product of rubber and plastic mechanical property modifying agent according to claim 1 or 2, it is characterised in that silicon in the anti-wear agent Oil content is not less than 20%.
8. product of rubber and plastic mechanical property modifying agent according to claim 1 or 2, it is characterised in that the fire retardant is three Aoxidize two antimony.
CN201711173259.6A 2017-11-22 2017-11-22 A kind of product of rubber and plastic mechanical property modifying agent Pending CN107778761A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711173259.6A CN107778761A (en) 2017-11-22 2017-11-22 A kind of product of rubber and plastic mechanical property modifying agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711173259.6A CN107778761A (en) 2017-11-22 2017-11-22 A kind of product of rubber and plastic mechanical property modifying agent

Publications (1)

Publication Number Publication Date
CN107778761A true CN107778761A (en) 2018-03-09

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CN201711173259.6A Pending CN107778761A (en) 2017-11-22 2017-11-22 A kind of product of rubber and plastic mechanical property modifying agent

Country Status (1)

Country Link
CN (1) CN107778761A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105295413A (en) * 2015-11-11 2016-02-03 苏州国泰科技发展有限公司 Modifier for mechanical properties of rubber-plastic product
CN105419375A (en) * 2015-11-11 2016-03-23 苏州国泰科技发展有限公司 Preparation method of rubber and plastic product mechanical property modifier
CN105566934A (en) * 2016-01-29 2016-05-11 安徽以诺木塑板材科技有限公司 Reinforced wood-plastic plate
CN105566931A (en) * 2016-01-29 2016-05-11 安徽以诺木塑板材科技有限公司 Wood-plastic composite board

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105295413A (en) * 2015-11-11 2016-02-03 苏州国泰科技发展有限公司 Modifier for mechanical properties of rubber-plastic product
CN105419375A (en) * 2015-11-11 2016-03-23 苏州国泰科技发展有限公司 Preparation method of rubber and plastic product mechanical property modifier
CN105566934A (en) * 2016-01-29 2016-05-11 安徽以诺木塑板材科技有限公司 Reinforced wood-plastic plate
CN105566931A (en) * 2016-01-29 2016-05-11 安徽以诺木塑板材科技有限公司 Wood-plastic composite board

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Application publication date: 20180309

RJ01 Rejection of invention patent application after publication