CN107778577A - A kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch - Google Patents
A kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch Download PDFInfo
- Publication number
- CN107778577A CN107778577A CN201610775824.5A CN201610775824A CN107778577A CN 107778577 A CN107778577 A CN 107778577A CN 201610775824 A CN201610775824 A CN 201610775824A CN 107778577 A CN107778577 A CN 107778577A
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- CN
- China
- Prior art keywords
- rubber
- oil
- incipient scorch
- fitting method
- neoprene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/10—Footwear characterised by the material made of rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch, calculate in parts by weight, including butadiene-styrene rubber 60 80, nitrile rubber 40 20, neoprene 1.5, sulphur 0.4 0.5, captax 0.1 0.2, zinc oxide 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5 2.5, calcium carbonate 40 50, clay 10, pine tar 25, dibutyl ester 15, dark substitute 25, carbon black 10, antiscorching agent YG 1 0.2 0.4.It is combined using butadiene-styrene rubber and butyronitrile, neoprene, there is preferable oil resistivity;Filler calcium carbonate dosage suitably increases, and contributes to anti-swelling.With the vamp rubber of formula production, its oil resistance is preferable, and cost is relatively low, adapts to the operating environment of oil resistant, and suitable for the protection of oil resistant operation, and process is not susceptible to incipient scorch phenomenon, can greatly improve the security of sizing material processing.
Description
Technical field
The present invention relates to rubber overshoes manufacturing field, is related to footwear vamp rubber formula, more particularly to a kind of fitting for being not easy incipient scorch
Method oil-resistant shoe vamp rubber.
Background technology
Shoes made of General Purpose Rubber material, its vamp rubber are usually that natural rubber adds synthetic rubber, use range is wide,
Cost is low, but because natural rubber and fluid medium solubility parameter are not greatly different enough, causes vamp rubber oil resistivity poor, therefore,
Conventional vamp rubber formula can not be used for the protection boots for contacting oils.
Incipient scorch is a kind of sizing material prevulcanization phenomenon, produce incipient scorch the reason for have:Mismate, such as vulcanizing agent, accelerator
Dosage is too many;Misoperation, as roller temperature is too high, too early add Sulfur or add vulcanizing agent after mixing time it is oversize.It is kneaded uneven
Cause vulcanizing agent and accelerator concentration of local;It is improper that sizing material cooling is parked.Such as park too long, holding area temperature is too high or air
Circulation etc., when there is incipient scorch phenomenon, sizing material is rough, and pitted skin plasticity reduces, and size occurs in sizing material surface when serious
The particle not waited.
Because summer temperature is higher, easily causes oil-resistant shoe vamp rubber and incipient scorch phenomenon occurs when being kneaded and machining, make
Scrapped into sizing material.
The content of the invention
The purpose of the present invention is in view of the shortcomings of the prior art, and to provide a kind of fitting method oil-resistant shoe footwear for being not easy incipient scorch
Face glue, with the vamp rubber of formula production, its oil resistance is preferable, and cost is relatively low, adapts to the operating environment of oil resistant, is applied to
The protection of oil resistant operation, and process is not susceptible to incipient scorch phenomenon, can greatly improve the security of sizing material processing.
Realizing the technical scheme of the object of the invention is:
A kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch, is calculated in parts by weight, including
Butadiene-styrene rubber 60-80, nitrile rubber 40-20, neoprene 1.5, sulphur 0.4-0.5, captax 0.1-0.2, oxidation
Zinc 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5-2.5, calcium carbonate 40-50, clay 10, pine tar 2-5, dibutyl ester 15,
Dark substitute 2-5, carbon black 10, antiscorching agent YG-1 0.2-0.4.
The advantage of the invention is that:It is combined using butadiene-styrene rubber and butyronitrile, neoprene, rubber and fluid medium solubility
Parameter great disparity, has preferable oil resistivity;Softening agent is based on dibutyl ester, and with part pine tar, dark substitute;Filler carbonic acid
Calcium dosage suitably increases, and contributes to anti-swelling;State of cure (vulcanization) improves, and crosslink density is high, and oil-resistant effect is preferable.Produced with the formula
Vamp rubber its oil resistance it is preferable, cost is relatively low, adapts to contact the operating environment of oils, suitable for the anti-of oil operations
Shield.Gum base ingredients prevent the generation of incipient scorch phenomenon using antiscorching agent YG-1, with the formula produce oil-resistant shoe with vamp rubber not
Incipient scorch phenomenon easily occurs, the security of sizing material processing can be greatly improved.Avoid the sizing material incipient scorch caused by temperature rise, roller temperature are too high
Loss.
Embodiment
Present invention is further elaborated below by embodiment, but is not limitation of the invention.
A kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch, is calculated in parts by weight, including
Butadiene-styrene rubber 60-80, nitrile rubber 40-20, neoprene 1.5, sulphur 0.4-0.5, captax 0.1-0.2, oxidation
Zinc 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5-2.5, calcium carbonate 40-50, clay 10, pine tar 2-5, dibutyl ester 15,
Dark substitute 2-5, carbon black 10, antiscorching agent YG-1 0.2-0.4.
Embodiment:
A kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch, is calculated in parts by weight, including
Butadiene-styrene rubber 70, nitrile rubber 30, neoprene 1.5, sulphur 0.45, captax 0.15, zinc oxide 5, magnesia 4,
Stearic acid 1.5, antioxidant D 2.0, calcium carbonate 45, clay 10, pine tar 4, dibutyl ester 15, dark substitute 4, carbon black 10, antiscorching agent
YG-1 0.3。
Preparation method:
The rubber of formula ratio is added in banbury and is kneaded completely, stearic acid, carbon black, accelerator is then added and is mixed in mill
Refining is complete, and the age resistor, plasticizer, filler for adding formula ratio continue to be kneaded completely, and it is complete to be eventually adding sulphur mixing.
Claims (2)
1. a kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch, is calculated in parts by weight, including
Butadiene-styrene rubber 60-80, nitrile rubber 40-20, neoprene 1.5, sulphur 0.4-0.5, captax 0.1-0.2, oxidation
Zinc 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5-2.5, calcium carbonate 40-50, clay 10, pine tar 2-5, dibutyl ester 15,
Dark substitute 2-5, carbon black 10, antiscorching agent YG-1 0.2-0.4.
2. the fitting method oil-resistant shoe vamp rubber according to claim 1 for being not easy incipient scorch, it is characterised in that according to parts by weight
Calculate, including
Butadiene-styrene rubber 70, nitrile rubber 30, neoprene 1.5, sulphur 0.45, captax 0.15, zinc oxide 5, magnesia 4,
Stearic acid 1.5, antioxidant D 2.0, calcium carbonate 45, clay 10, pine tar 4, dibutyl ester 15, dark substitute 4, carbon black 10, antiscorching agent
YG-1 0.3。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610775824.5A CN107778577A (en) | 2016-08-31 | 2016-08-31 | A kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610775824.5A CN107778577A (en) | 2016-08-31 | 2016-08-31 | A kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107778577A true CN107778577A (en) | 2018-03-09 |
Family
ID=61450516
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610775824.5A Pending CN107778577A (en) | 2016-08-31 | 2016-08-31 | A kind of fitting method oil-resistant shoe vamp rubber for being not easy incipient scorch |
Country Status (1)
Country | Link |
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CN (1) | CN107778577A (en) |
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2016
- 2016-08-31 CN CN201610775824.5A patent/CN107778577A/en active Pending
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Legal Events
Date | Code | Title | Description |
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PB01 | Publication | ||
PB01 | Publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180309 |
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WD01 | Invention patent application deemed withdrawn after publication |