CN107663303A - A kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch - Google Patents
A kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch Download PDFInfo
- Publication number
- CN107663303A CN107663303A CN201610610877.1A CN201610610877A CN107663303A CN 107663303 A CN107663303 A CN 107663303A CN 201610610877 A CN201610610877 A CN 201610610877A CN 107663303 A CN107663303 A CN 107663303A
- Authority
- CN
- China
- Prior art keywords
- incipient scorch
- oil
- small primer
- fitting method
- antiscorching agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch, calculate in parts by weight, including butadiene-styrene rubber 90, nitrile rubber 10, sulphur 0.4 0.5, captax 0.1 0.2, zinc oxide 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5 2.5, calcium carbonate 10 20, clay 20 40, pine tar 5, dibutyl ester 15, dark substitute 5, carbon black 20, antiscorching agent YG 1 0.2 0.4, antiscorching agent PVI 0.1 0.5.With the small primer of formula production, its oil resistance is preferable, and cost is relatively low, adapts to contact the operating environment of oils, and suitable for the protection of oil operations, and process is not susceptible to incipient scorch phenomenon, can greatly improve the security of sizing material processing.
Description
Technical field
The present invention relates to rubber overshoes manufacturing field, is related to the small primer formula of footwear, more particularly to a kind of patch that can prevent incipient scorch
The small primer of legal oil-resistant shoe.
Background technology
Shoes made of General Purpose Rubber material, its small primer are usually that natural rubber adds synthetic rubber, use range is wide,
Cost is low, but because natural rubber and fluid medium solubility parameter are not greatly different enough, causes small primer oil resistivity poor, therefore,
Conventional small primer formula can not be used for the protection boots for contacting oils.
Incipient scorch is a kind of sizing material prevulcanization phenomenon, produce incipient scorch the reason for have：Mismate, such as vulcanizing agent, accelerator
Dosage is too many；Misoperation, as roller temperature is too high, too early add Sulfur or add vulcanizing agent after mixing time it is oversize.It is kneaded uneven
Cause vulcanizing agent and accelerator concentration of local；It is improper that sizing material cooling is parked.Such as park too long, holding area temperature is too high or air
Circulation etc., when there is incipient scorch phenomenon, sizing material is rough, and pitted skin plasticity reduces, and size occurs in sizing material surface when serious
The particle not waited.
Because summer temperature is higher, easily causes oil-resistant shoe vamp rubber and incipient scorch phenomenon occurs when being kneaded and machining, make
Scrapped into sizing material.
The content of the invention
The purpose of the present invention is in view of the shortcomings of the prior art, and to provide a kind of fitting method oil-resistant shoe that can prevent incipient scorch and use
Small primer, with the small primer of formula production, its oil resistance is preferable, and cost is relatively low, adapts to the operating environment of oil resistant, is applicable
In the protection of oil resistant operation, and process is not susceptible to incipient scorch phenomenon, can greatly improve the security of sizing material processing.
Realizing the technical scheme of the object of the invention is：
A kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch, is calculated in parts by weight, including
Butadiene-styrene rubber 90, nitrile rubber 10, sulphur 0.4-0.5, captax 0.1-0.2, zinc oxide 5, magnesia 4, stearic acid
1.5th, antioxidant D 1.5-2.5, calcium carbonate 10-20, clay 20-40, pine tar 5, dibutyl ester 15, dark substitute 5, carbon black 20, anti-
Burnt agent YG-1 0.2-0.4, antiscorching agent PVI 0.1-0.5.
The advantage of the invention is that：It is combined using butadiene-styrene rubber and nitrile rubber, rubber and fluid medium solubility parameter
Great disparity, there is preferable oil resistivity；Softening agent is based on dibutyl ester, and with part pine tar, dark substitute；Filler calcium carbonate,
Clay dosage suitably increases, and contributes to anti-swelling；State of cure (vulcanization) improves, and crosslink density is high, and oil-resistant effect is preferable.Given birth to the formula
Its oil resistance of the small primer of production is preferable, and cost is relatively low, adapts to contact the operating environment of oils, suitable for the anti-of oil operations
Shield.Gum base ingredients prevent the generation of incipient scorch phenomenon using antiscorching agent YG-1 and antiscorching agent PVI combinations, are produced with the formula small
Primer is not susceptible to incipient scorch phenomenon, can greatly improve the security of sizing material processing.Antiscorching agent PVI is for being already subjected to high fever simultaneously
Or the sizing material for having slight incipient scorch has reactivation, the process safety of sizing material can be further improved, is avoided because of temperature rise, roller
The too high loss for causing sizing material incipient scorch of temperature.
Embodiment
Present invention is further elaborated below by embodiment, but is not limitation of the invention.
A kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch, is calculated in parts by weight, including
Butadiene-styrene rubber 90, nitrile rubber 10, sulphur 0.4-0.5, captax 0.1-0.2, zinc oxide 5, magnesia 4, stearic acid
1.5th, antioxidant D 1.5-2.5, calcium carbonate 10-20, clay 20-40, pine tar 5, dibutyl ester 15, dark substitute 5, carbon black 20, anti-
Burnt agent YG-1 0.2-0.4, antiscorching agent PVI 0.1-0.5.
Embodiment：
A kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch, is calculated in parts by weight, including
It is butadiene-styrene rubber 90, nitrile rubber 10, sulphur 0.45, captax 0.15, zinc oxide 5, magnesia 4, stearic acid 1.5, anti-
It is old agent D 1.9, calcium carbonate 15, clay 30, pine tar 5, dibutyl ester 15, dark substitute 5, carbon black 20, antiscorching agent YG-1 0.3, anti-
Burnt agent PVI 0.3.
Preparation method：
The rubber of formula ratio is added in banbury and is kneaded completely, stearic acid, carbon black, accelerator is then added and is mixed in mill
Refining is complete, and age resistor, plasticizer, filler, the antiscorching agent for adding formula ratio continue to be kneaded completely, are eventually adding sulphur mixing
Completely.
Claims (2)
1. a kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch, is calculated in parts by weight, including：Butadiene-styrene rubber 90, fourth
Nitrile rubber 10, sulphur 0.4-0.5, captax 0.1-0.2, zinc oxide 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5-
2.5th, calcium carbonate 10-20, clay 20-40, pine tar 5, dibutyl ester 15, dark substitute 5, carbon black 20, antiscorching agent YG-1 0.2-
0.4th, antiscorching agent PVI 0.1-0.5.
2. the small primer of the fitting method oil-resistant shoe according to claim 1 that can prevent incipient scorch, it is characterised in that according to weight
Part is measured to calculate, including：It is butadiene-styrene rubber 90, nitrile rubber 10, sulphur 0.45, captax 0.15, zinc oxide 5, magnesia 4, hard
Resin acid 1.5, antioxidant D 1.9, calcium carbonate 15, clay 30, pine tar 5, dibutyl ester 15, dark substitute 5, carbon black 20, antiscorching agent
YG-1 0.3, antiscorching agent PVI 0.3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610610877.1A CN107663303A (en) | 2016-07-29 | 2016-07-29 | A kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610610877.1A CN107663303A (en) | 2016-07-29 | 2016-07-29 | A kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107663303A true CN107663303A (en) | 2018-02-06 |
Family
ID=61114744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610610877.1A Withdrawn CN107663303A (en) | 2016-07-29 | 2016-07-29 | A kind of small primer of fitting method oil-resistant shoe that can prevent incipient scorch |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107663303A (en) |
-
2016
- 2016-07-29 CN CN201610610877.1A patent/CN107663303A/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180206 |