CN107778571A - A kind of fitting method oil-resistant shoe foxing glue that can prevent incipient scorch - Google Patents

Abstract

The invention discloses a kind of fitting method oil-resistant shoe foxing glue that can prevent incipient scorch, calculate in parts by weight, including butadiene-styrene rubber 60 80, nitrile rubber 40 20, neoprene 1.5, sulphur 0.4 0.5, captax 0.1 0.2, zinc oxide 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5 2.5, calcium carbonate 40 50, clay 15, pine tar 25, dibutyl ester 15, dark substitute 25, the resins 24 of RX 80, carbon black 5, antiscorching agent YG 1 0.2 0.4, antiscorching agent PVI 0.1 0.5.It is combined using butadiene-styrene rubber and butyronitrile, neoprene, there is preferable oil resistivity；Filler calcium carbonate dosage suitably increases, and contributes to anti-swelling.With the foxing glue of formula production, its oil resistance is preferable, and cost is relatively low, adapts to the operating environment of oil resistant, and suitable for the protection of oil resistant operation, and process is not susceptible to incipient scorch phenomenon, can greatly improve the security of sizing material processing.

Description

A kind of fitting method oil-resistant shoe foxing glue that can prevent incipient scorch

Technical field

The present invention relates to rubber overshoes manufacturing field, is related to footwear foxing glue formula, more particularly to a kind of patch that can prevent incipient scorch Legal oil-resistant shoe foxing glue.

Background technology

Shoes made of General Purpose Rubber material, its foxing glue are usually that natural rubber adds synthetic rubber, use range is wide, Cost is low, but because natural rubber and fluid medium solubility parameter are not greatly different enough, causes foxing glue oil resistivity poor, therefore, Conventional foxing glue formula can not be used for the protection boots for contacting oils.

Incipient scorch is a kind of sizing material prevulcanization phenomenon, produce incipient scorch the reason for have：Mismate, such as vulcanizing agent, accelerator Dosage is too many；Misoperation, as roller temperature is too high, too early add Sulfur or add vulcanizing agent after mixing time it is oversize.It is kneaded uneven Cause vulcanizing agent and accelerator concentration of local；It is improper that sizing material cooling is parked.Such as park too long, holding area temperature is too high or air Circulation etc., when there is incipient scorch phenomenon, sizing material is rough, and pitted skin plasticity reduces, and size occurs in sizing material surface when serious The particle not waited.

Because summer temperature is higher, easily causes oil-resistant shoe foxing glue and incipient scorch phenomenon occurs when being kneaded and machining, make Scrapped into sizing material.

The content of the invention

The purpose of the present invention is in view of the shortcomings of the prior art, and to provide a kind of fitting method oil-resistant shoe that can prevent incipient scorch and use Foxing glue, with the foxing glue of formula production, its oil resistance is preferable, and cost is relatively low, adapts to the operating environment of oil resistant, is applicable In the protection of oil resistant operation, and process is not susceptible to incipient scorch phenomenon, can greatly improve the security of sizing material processing.

Realizing the technical scheme of the object of the invention is：

A kind of fitting method oil-resistant shoe foxing glue, is calculated in parts by weight, including

Butadiene-styrene rubber 60-80, nitrile rubber 40-20, neoprene 1.5, sulphur 0.4-0.5, captax 0.1-0.2, oxidation Zinc 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5-2.5, calcium carbonate 40-50, clay 15, pine tar 2-5, dibutyl ester 15, Dark substitute 2-5, RX-80 resin 2-4, carbon black 5, antiscorching agent YG-1 0.2-0.4, antiscorching agent PVI 0.1-0.5.

The advantage of the invention is that：It is combined using butadiene-styrene rubber and butyronitrile, neoprene, rubber and fluid medium solubility Parameter great disparity, has preferable oil resistivity；Softening agent is based on dibutyl ester, and with part pine tar, dark substitute；Filler carbonic acid Calcium dosage suitably increases, and contributes to anti-swelling；State of cure (vulcanization) improves, and crosslink density is high, and oil-resistant effect is preferable.Produced with the formula Foxing glue its oil resistance it is preferable, cost is relatively low, adapts to contact the operating environment of oils, suitable for the anti-of oil operations Shield.Gum base ingredients prevent the generation of incipient scorch phenomenon using antiscorching agent YG-1 and antiscorching agent PVI combinations, are enclosed with what the formula produced Bar glue is not susceptible to incipient scorch phenomenon, can greatly improve the security of sizing material processing.Antiscorching agent PVI is for being already subjected to high fever simultaneously Or the sizing material for having slight incipient scorch has reactivation, the process safety of sizing material can be further improved, is avoided because of temperature rise, roller The too high loss for causing sizing material incipient scorch of temperature.

Embodiment

Present invention is further elaborated below by embodiment, but is not limitation of the invention.

A kind of fitting method oil-resistant shoe foxing glue that can prevent incipient scorch, is calculated in parts by weight, including

Butadiene-styrene rubber 60-80, nitrile rubber 40-20, neoprene 1.5, sulphur 0.4-0.5, captax 0.1-0.2, oxidation Zinc 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5-2.5, calcium carbonate 40-50, clay 15, pine tar 2-5, dibutyl ester 15, Dark substitute 2-5, RX-80 resin 2-4, carbon black 5, antiscorching agent YG-1 0.2-0.4, antiscorching agent PVI 0.1-0.5.

Embodiment：

A kind of fitting method oil-resistant shoe foxing glue that can prevent incipient scorch, is calculated in parts by weight, including

Butadiene-styrene rubber 70, nitrile rubber 30, neoprene 1.5, sulphur 0.45, captax 0.15, zinc oxide 5, magnesia 4, Stearic acid 1.5, antioxidant D 2.0, calcium carbonate 45, clay 15, pine tar 3, dibutyl ester 15, dark substitute 4, RX-80 resins 3, charcoal Black 5, antiscorching agent YG-1 0.3, antiscorching agent PVI 0.3.

Preparation method：

The rubber of formula ratio is added in banbury and is kneaded completely, stearic acid, carbon black, accelerator is then added and is mixed in mill Refining is complete, and the age resistor, plasticizer, filler for adding formula ratio continue to be kneaded completely, and it is complete to be eventually adding sulphur mixing.

Claims (2)

1. a kind of fitting method oil-resistant shoe foxing glue that can prevent incipient scorch, is calculated in parts by weight, including

Butadiene-styrene rubber 60-80, nitrile rubber 40-20, neoprene 1.5, sulphur 0.4-0.5, captax 0.1-0.2, oxidation Zinc 5, magnesia 4, stearic acid 1.5, antioxidant D 1.5-2.5, calcium carbonate 40-50, clay 15, pine tar 2-5, dibutyl ester 15, Dark substitute 2-5, RX-80 resin 2-4, carbon black 5, antiscorching agent YG-1 0.2-0.4, antiscorching agent PVI 0.1-0.5.

2. the fitting method oil-resistant shoe foxing glue according to claim 1 that incipient scorch can be prevented, it is characterised in that according to weight Part calculates, including

Butadiene-styrene rubber 70, nitrile rubber 30, neoprene 1.5, sulphur 0.45, captax 0.15, zinc oxide 5, magnesia 4, Stearic acid 1.5, antioxidant D 2.0, calcium carbonate 45, clay 15, pine tar 3, dibutyl ester 15, dark substitute 4, RX-80 resins 3, charcoal Black 5, antiscorching agent YG-1 0.3, antiscorching agent PVI 0.3.