CN107775191A - Reserve type lithium battery liquid storage bottle laser seal method - Google Patents
Reserve type lithium battery liquid storage bottle laser seal method Download PDFInfo
- Publication number
- CN107775191A CN107775191A CN201710913764.3A CN201710913764A CN107775191A CN 107775191 A CN107775191 A CN 107775191A CN 201710913764 A CN201710913764 A CN 201710913764A CN 107775191 A CN107775191 A CN 107775191A
- Authority
- CN
- China
- Prior art keywords
- liquid storage
- storage bottle
- laser
- bottle
- thionyl chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/21—Bonding by welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/70—Auxiliary operations or equipment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B33/00—Manufacture of ammunition; Dismantling of ammunition; Apparatus therefor
Abstract
A kind of liquid storage bottle laser seal method.Using a CO2Laser-beam welding machine is in glove box, and using argon gas as protective gas, laser seal is carried out to liquid storage bottle.Laser welding program has been worked out, has formulated that thionyl chloride solution is filling, the operating procedure of liquid storage bottle closure.This method has that effect is good, and qualification rate is high, free of contamination feature.Liquid storage bottle laser seal method of the present invention preferably meets the technical requirements of small size liquid storage bottle.
Description
Technical field
The invention belongs to Small-Caliber Ammunition Fuze Technology field, more particularly to a kind of reserve type lithium battery liquid storage bottle laser envelope
Mouth method.
Background technology
Currently, ammunition fuze field is developed towards electronic direction, and electronic fuse needs the energy, therefore just must be equipped with to draw
Believe the power supply of power supply, i.e. fuze power supply.Lithium-thionyl chloride battery is a kind of typical non-aqueous electrodeless electrolyte solution power supply, is had
Standby small volume, in light weight, low temperature performance well higher than energy, the characteristics of power-on time is long, be Small-Caliber Ammunition preferable fuse electricity
Source.As reserve type battery, generally thionyl chloride solution is sealed in liquid storage bottle, isolated with lithium.Need to break during galvanic action
Liquid storage bottle is opened, thionyl chloride is contacted with lithium, produces chemical reaction, generates electric current.Thionyl chloride solution low boiling point (70~80
DEG C), high volatility, chance water electrode, which easily reacts, generates sulfuric acid and hydrochloric acid, and corrosivity is strong, and generally use vial carries as liquid storage
Body.The sealing of vial is the minor diameter bottleneck by being heated at high temperature vial, makes what the glass melting of bottleneck was realized together.
Now welded frequently with acetylene flame, acetylene flame welding liquid storage bottle has the disadvantage that:1st, the region of heating is larger, and welding temperature is low, glass
Glass fusing time is grown, and the easily heated volatilization of thionyl chloride solution and water vapor in air reaction are rotten;2nd, in order to avoid thionyl chloride
The heated volatilization of solution, go bad, heating zone causes the liquid storage bottle height after sealing higher away from thionyl chloride solution is needed.And osculum
Small volume of footpath ammunition fuze itself, inner components quantity up to dozens of, liquid storage bottle is also one of Fuze Components, and this will
Ask the volume of liquid storage bottle the smaller the better.Traditional flame sealing technology, small size liquid storage bottle technical requirements are not reached.
The content of the invention
The purpose of the present invention is exactly to overcome the shortcomings of above-mentioned background technology, proposes a kind of reserve type lithium battery liquid storage bottle
Laser seal method.
A kind of reserve type lithium battery liquid storage bottle laser seal method involved in the present invention, it is comprised the following steps that:
1) CO is opened2Laser-beam welding machine general supply, " driving " key on pressing operation panel, connect cooling system, laser
The power switches such as device, rotation gas cylinder valve connect argon gas, and the time is about 5 minutes;
2) " jerk " switch is discharged, after the completion for the treatment of PLC control system self-test, laser is opened, presses " correction " key, use feux rouges
" rising ", " decline " button are by focus lamp and workpiece to good;
3) water content in latex examination gloves case, if water content is not up to standard, is cleaned to casing;
4) thionyl chloride solution, liquid storage bottle, syringe, tweezers, medical rubber glove, the paper of bottle sealing will be distributed into
Towel etc. is successively put into glove box by glove box transfer chamber;
5) reaffirm whether the water content in glove box is up to standard, then thionyl chloride solution is injected by syringe and stored up
Liquid bottle, 0.15~0.2ml of injection volume, and the electrolyte of spilling is sucked with paper handkerchief, it is placed on after syringe use on paper handkerchief;
6) liquid storage bottle after splendid attire is placed on workbench special tooling according to the laser welding program of setting and carries out trying to add
Laser current is adjusted for work, sealing quality visually, and the sealing of remaining liquid storage bottle is completed after steady quality;
7) after sealing, by the liquid storage bottle sealed, used syringe, thionyl chloride solution empty bottle, paper handkerchief etc.
Successively taken out by glove box transfer chamber;
8) " driving " key is closed, presses rapid stop key, disconnects the power supplys such as cooling system, laser, closes air door, is disconnected
CO2Laser-beam welding machine general supply;
9) liquid storage bottle for having sealed completion is immersed in hot water, hot water temperature is 80~90 DEG C, observes the sulfurous of its storage
Whether solution of acid chloride reacts with water, takes out the liquid storage bottle not reacted after 5~10 minutes, is used after being dried with paper handkerchief
PH test paper is detected.Certified products, which are put into special container, to be put neatly.
The reserve type lithium battery liquid storage bottle laser seal method of the present invention, highly low, liquid storage bottle closure after liquid storage bottle closure
Qualification rate is high, pollution-free, and the thionyl chloride solution of storage can meet small size liquid storage bottle technical requirements without going bad in liquid storage bottle.
Brief description of the drawings
The laser-beam welding machine figure that Fig. 1 is in glove box;
Fig. 2 sky liquid storage bottle schematic diagrames;
Liquid storage bottle after Fig. 3 encapsulation electrolyte.
Embodiment
The present invention is further described with reference to the accompanying drawings and examples.
Embodiment
Reserve type lithium battery liquid storage bottle laser seal method involved by the present embodiment, using a CO2Laser-beam welding machine
In glove box, using argon gas as protective gas, as shown in figure 1, carrying out laser seal to liquid storage bottle.Empty liquid storage bottle such as Fig. 2 institutes
Show, encapsulate the liquid storage bottle after electrolyte as shown in figure 3, laser welding program is shown in Table 1.
The laser welding program of table 1
Reserve type lithium battery liquid storage bottle laser seal method involved by the present embodiment, lithium battery liquid storage are that thionyl chloride is molten
Liquid, the concrete operation step of liquid storage bottle closure are as follows:
1) CO is opened2Laser-beam welding machine general supply, " driving " key on pressing operation panel, connect cooling system, laser
The power switches such as device, rotation gas cylinder valve connect argon gas, and the time is about 5 minutes;
2) " jerk " switch is discharged, after the completion for the treatment of PLC control system self-test, laser is opened, presses " correction " key, use feux rouges
" rising ", " decline " button are by focus lamp and workpiece to good;
3) water content in latex examination gloves case, if water content is not up to standard, is cleaned to casing;
4) thionyl chloride solution, liquid storage bottle, syringe, tweezers, medical rubber glove, the paper of bottle sealing will be distributed into
Towel etc. is successively put into glove box by glove box transfer chamber;
5) reaffirm whether the water content in glove box is up to standard, then thionyl chloride solution is injected by syringe and stored up
Liquid bottle, 0.15~0.2ml of injection volume, and the electrolyte of spilling is sucked with paper handkerchief, it is placed on after syringe use on paper handkerchief;
6) liquid storage bottle after splendid attire is placed on workbench special tooling according to the laser welding program of setting and carries out trying to add
Laser current is adjusted for work, sealing quality visually, and the sealing of remaining liquid storage bottle is completed after steady quality;
7) after sealing, by the liquid storage bottle sealed, used syringe, thionyl chloride solution empty bottle, paper handkerchief etc.
Successively taken out by glove box transfer chamber;
8) " driving " key is closed, presses rapid stop key, disconnects the power supplys such as cooling system, laser, closes air door, is disconnected
CO2Laser-beam welding machine general supply;
9) liquid storage bottle for having sealed completion is immersed in hot water (temperature is 80~90 DEG C), observes the thionyl chloride of its storage
Whether solution reacts with water, takes out the liquid storage bottle not reacted after 5~10 minutes, is tried after being dried with paper handkerchief using PH
Paper is detected.Certified products, which are put into special container, to be put neatly.
By the application of above-described embodiment, the height after liquid storage bottle closure is low, and liquid storage bottle closure qualification rate is high, pollution-free,
The thionyl chloride solution of storage can meet small size liquid storage bottle technical requirements without going bad in liquid storage bottle.
Claims (1)
- A kind of 1. reserve type lithium battery liquid storage bottle laser seal method, it is characterized in that this method comprises the following steps that:1) CO is opened2Laser-beam welding machine general supply, " driving " key on pressing operation panel, connect the electricity such as cooling system, laser Source switch, rotation gas cylinder valve connect argon gas, and the time is about 5 minutes;2) discharge " jerk " switch, after the completion for the treatment of PLC control system self-test, open laser, press " correction " key, with feux rouges with " rising ", " decline " button are by focus lamp and workpiece to good;3) water content in latex examination gloves case, if water content is not up to standard, is cleaned to casing;4) thionyl chloride solution, liquid storage bottle, syringe, tweezers, medical rubber glove, the paper handkerchief etc. of bottle sealing will be distributed into Successively it is put into by glove box transfer chamber in glove box;5) reaffirm whether the water content in glove box is up to standard, and thionyl chloride solution then is injected into liquid storage by syringe Bottle, 0.15~0.2ml of injection volume, and the electrolyte of spilling is sucked with paper handkerchief, it is placed on after syringe use on paper handkerchief;6) liquid storage bottle after splendid attire is placed on workbench special tooling according to the laser welding program of setting and carries out examination processing, root Laser current is adjusted according to the sealing quality of range estimation, the sealing of remaining liquid storage bottle is completed after steady quality;7) after sealing, the liquid storage bottle sealed, used syringe, thionyl chloride solution empty bottle, paper handkerchief etc. are passed through Glove box transfer chamber is successively taken out;8) " driving " key is closed, presses rapid stop key, disconnects the power supplys such as cooling system, laser, closes air door, disconnects CO2Swash Photocoagulator general supply;9) liquid storage bottle for having sealed completion is immersed in hot water, hot water temperature is 80~90 DEG C, observes the thionyl chloride of its storage Whether solution reacts with water, takes out the liquid storage bottle not reacted after 5~10 minutes, is tried after being dried with paper handkerchief using PH Paper is detected.Certified products, which are put into special container, to be put neatly.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710913764.3A CN107775191A (en) | 2017-09-30 | 2017-09-30 | Reserve type lithium battery liquid storage bottle laser seal method |
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CN201710913764.3A CN107775191A (en) | 2017-09-30 | 2017-09-30 | Reserve type lithium battery liquid storage bottle laser seal method |
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CN201710913764.3A Pending CN107775191A (en) | 2017-09-30 | 2017-09-30 | Reserve type lithium battery liquid storage bottle laser seal method |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109494384A (en) * | 2018-10-18 | 2019-03-19 | 重庆长安工业(集团)有限责任公司 | A kind of chemical reserve battery |
CN112935568A (en) * | 2021-02-04 | 2021-06-11 | 大族激光科技产业集团股份有限公司 | Application of infrared laser on vaccine bottle sealing hole |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105377783A (en) * | 2013-05-10 | 2016-03-02 | 康宁股份有限公司 | Laser welding transparent glass sheets using low melting glass or thin absorbing films |
CN106112261A (en) * | 2016-08-01 | 2016-11-16 | 中国核动力研究设计院 | In a kind of quartz glass capillary, filled gold belongs to the long packaging technology of control and auxiliary mould thereof |
CN206105151U (en) * | 2016-09-12 | 2017-04-19 | 中山市镭通激光科技有限公司 | Microelectronic device packaging welding machine |
CN206122901U (en) * | 2016-08-22 | 2017-04-26 | 成都超迈光电科技有限公司 | Laser welding packaging hardware based on under atmosphere protective strip spare |
-
2017
- 2017-09-30 CN CN201710913764.3A patent/CN107775191A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105377783A (en) * | 2013-05-10 | 2016-03-02 | 康宁股份有限公司 | Laser welding transparent glass sheets using low melting glass or thin absorbing films |
CN106112261A (en) * | 2016-08-01 | 2016-11-16 | 中国核动力研究设计院 | In a kind of quartz glass capillary, filled gold belongs to the long packaging technology of control and auxiliary mould thereof |
CN206122901U (en) * | 2016-08-22 | 2017-04-26 | 成都超迈光电科技有限公司 | Laser welding packaging hardware based on under atmosphere protective strip spare |
CN206105151U (en) * | 2016-09-12 | 2017-04-19 | 中山市镭通激光科技有限公司 | Microelectronic device packaging welding machine |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109494384A (en) * | 2018-10-18 | 2019-03-19 | 重庆长安工业(集团)有限责任公司 | A kind of chemical reserve battery |
CN112935568A (en) * | 2021-02-04 | 2021-06-11 | 大族激光科技产业集团股份有限公司 | Application of infrared laser on vaccine bottle sealing hole |
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Application publication date: 20180309 |