CN103681006B - molecular sieve acid control device - Google Patents
molecular sieve acid control device Download PDFInfo
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- CN103681006B CN103681006B CN201210320151.6A CN201210320151A CN103681006B CN 103681006 B CN103681006 B CN 103681006B CN 201210320151 A CN201210320151 A CN 201210320151A CN 103681006 B CN103681006 B CN 103681006B
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Abstract
The invention discloses molecular sieve acid control device, it includes molecular sieve, control acid tube and politef base, it is bottleneck that one end of control acid tube is provided with the junction of horn mouth and horn mouth and pipe shaft, molecular sieve is fixing in the flask neck by fluid sealant, and the bottom surface of politef base is provided with the envelope acid mouth connected with through hole.The invention has the beneficial effects as follows: volatilize in capacitor protector body when achieving ageing or the isolation of the Working electrolyte that overflows and capacitor case, reduce the Working electrolyte impact on insulator, serve and prevent capacitor product shell from polluting and corrosion, protect the effect of insulator, thus ensure that stability and the reliability of capacitor product, simultaneously, the electrolyte gas being trapped in control acid tube again condenses into solution and passes back in shell, thus avoid secondary acid filling, be conducive to the fixing quantity of electrolyte, decrease the waste of electrolyte, save the manufacturing cost of finished product, and there is simple in construction, feature easy to use.
Description
Technical field
The present invention relates to molecular sieve acid control device, before particularly relating to a kind of high energy mixed capacitor sealing, during ageing, prevent work
Make the molecular sieve acid control device of electrolyte splash or overflow or evaporation, belong to electrolysis condenser manufacturing technology field.
Background technology
Tantalum capacitor normally can work under conditions of variations in temperature is violent, and its volume is little, capacity big, than
Big more than 2 times of the capacitance of other capacitors of same volume, plays important work to miniaturization of electronic products development and performance boost
With.Tantalum electrochemical capacitor is mainly used in the circuit that alminium electrolytic condenser performance parameter is difficult to meet requirement, as required electric capacity volume
Little, temperature range width, frequency characteristic and impedance operator require aviation that height, product stability and reliability requirement are high, civilian whole
Dynamo-electric road etc..High energy mixing tantalum ultracapacitor has the features such as volume is little, running voltage is high, capacitance is big, as novel
Free of contamination energy-storage travelling wave tube, be widely used in the military of the fields such as impulse circuit, wave filter, communication apparatus, medical instrument and
In civil electrical and electronic equipment, particularly can provide power for vehicle electronics, the development of electric automobile can be promoted,
The pollution to environment of the tail gas of minimizing motor vehicle emission, therefore has market prospect widely.The capacitance of high energy mixing tantalum capacitor
Scope 3300～200000 μ F, in current liquid tantalum capacitor, it is achieved that the capacitance of high unit volume.
In electrolysis condenser technology of preparing, ageing is requisite screening technology.Ageing refers to the tantalum electricity assembled
Electrolysis condenser is placed under certain ambient temperature, applies a certain voltage more than rated capacitor value, the electricity to product continuously
Parameter carries out repairing and eliminating the technological measure of the product that can not repair.By this PROCESS FOR TREATMENT, not only can repair because of
Former procedures (such as assembling etc.) and the oxide-film that damages, make the performance of capacitor tend towards stability, and can also reject those and have
The product that open defect, leakage current are excessive, compressive resistance is low, improves the reliability of capacitor.Technique for ageing is divided into sealing ageing
With opening ageing two ways.From the point of view of high energy mixing tantalum capacitor, if using sealing ageing mode, high energy mixing tantalum electricity
The anodic wick of container (＜ 100 DEG C) under the conditions of higher temperatures can carry out selfreparing to the defect on anode oxide film, is repairing
During Working electrolyte generation chemical reaction discharge gas, and the vaporization of Working electrolyte so that capacitor internal gas pressure
Rising causes shell dilatancy, even makes outer casing rupture cause product rejection.So current high energy mixing tantalum capacitor
Ageing uses opening ageing mode；Experiment proves that opening ageing can significantly reduce product leakage current value, avoid puncturing and carrying
High qualification rate.But opening ageing there is problems in that (1) during opening ageing, tantalum anode fuse is under the function of current
Heating and high temperature aging condition itself Working electrolyte is seethed with excitement, so that from the electrolyte inlet of capacitor surface
Overflow and the shell of polluted product；(2) due to heat effect, the volatilization of a small amount of electrolyte becomes gas, the electrolyte meeting evaporated
Accelerate ageing stove, the corrosion of aging clamp；(3) close to anode exit of the electrolyte overflowed and the electrolyte evaporated
Sealed insulator has strong corrosiveness thus destroys the sealing of insulator, can directly contribute electricity during product later stage work
Solve liquid leakage phenomenon, thus cause capacitor failure.At present, the main technique form for opening ageing is to stick at acid-filling mouth
With hygroscopic paper tape, paper tape still cannot be avoided the outflow of sulphuric acid, more can not stop the volatilization of sulphuric acid.(4) when stopping
Only after ageing, after stopping ageing, electrolyte will run off greatly, not only cause waste, more seriously product
The meeting out of control of Inner electrolysis liquid measure causes particular product performance parameters big ups and downs.
Summary of the invention
It is an object of the invention to provide the molecular sieve acid control device of a kind of simple in construction, low cost, good stability, at height
Working electrolyte splash or overflow or volatilization can be prevented during ageing before mixed capacitor sealing, tantalum capacitor shell and close can be protected
Sealed insulator, from polluting and the effect of corrosion, is avoided that secondary acid filling simultaneously, reduces waste the holding capacitor device of electrolyte
Electrolyte inside amount is consistent, saves manufacturing cost and holding properties of product are stable and parameter is uniform.
It is an object of the invention to be achieved through the following technical solutions: molecular sieve acid control device, it includes molecular sieve, control
Acid tube and politef base, the pipe shaft of control acid tube is straight tube, one end of control acid tube be provided with horn mouth and horn mouth with
The junction of pipe shaft is bottleneck, and bottleneck is to contract, and molecular sieve is fixing in the flask neck by fluid sealant, on politef base
Having the through hole running through base, control acid tube is arranged on politef base and connects with through hole, politef base
Bottom surface is provided with the envelope acid mouth connected with through hole, and envelope acid mouth is inverted cone-shaped.
Described molecular sieve isThe molecular sieve of rank.
Described envelope acid mouth buckle closure is on the electrolyte inlet of capacitor.
The beneficial effects of the present invention is: the Working electrolyte volatilizing in capacitor protector body when achieving ageing or overflowing
With the isolation of capacitor case, reduce the Working electrolyte impact on insulator, serve and prevent capacitor product shell dirty
Dye and corrosion, protect the effect of insulator, thus ensure that stability and the reliability of capacitor product, be trapped in meanwhile
Electrolyte gas in control acid tube again condenses into solution and passes back in shell, thus avoids secondary acid filling, decreases electrolysis
The waste of liquid and maintain the constant of electrolyte content, saves the manufacturing cost of finished product and maintains the performance of product, and having
There are simple in construction, feature easy to use.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention；
Fig. 2 is the use view of the present invention.
Wherein, 1-molecular sieve, 2-fluid sealant, 3-controls acid tube, 301-horn mouth, 302-bottleneck, 303-pipe shaft, 4-polytetrafluoro
Ethylene base, 401-through hole, 5-envelope acid mouth, 6-capacitor anode, 7-electrolyte inlet, 8-capacitor, 9-sealing insulator.
Detailed description of the invention
Further describe technical scheme below in conjunction with the accompanying drawings, but claimed scope is not limited to institute
State.
Such as Fig. 1, molecular sieve acid control device, it includes molecular sieve 1, control acid tube 3 and politef base 4, control
The pipe shaft 303 of acid tube 3 is straight tube, and one end of control acid tube 3 is provided with the junction of horn mouth 301 and horn mouth 301 and pipe shaft 303
For bottleneck 302, bottleneck 302 is fixed in bottleneck 302, on politef base 4 by fluid sealant 2 to contract, molecular sieve 1
Having the through hole 401 running through base, control acid tube 3 is arranged on politef base 4 and connects with through hole 401, polytetrafluoroethyl-ne
The bottom surface of alkene base 4 is provided with the envelope acid mouth 5 connected with through hole 401, and envelope acid mouth 5 is in inverted cone-shaped.
Described molecular sieve 1 isThe molecular sieve of rank, the gas molecule diameter control of the electrolyte i.e. volatilized
System is 4 × 10-10M～16 × 10-10Between m, it is ensured that the electrolyte gas of volatilization is adsorbed effectively by molecular sieve 1.
Described envelope acid mouth 5 buckle closure is on the electrolyte inlet 7 of capacitor 8.
Such as Fig. 2, the sealing insulator 9 of capacitor 8 is provided with electrolyte inlet 7, by the envelope of molecular sieve acid control device
Acid mouth 5 buckle closure is on electrolyte inlet 7.During ageing, the positive pole of power supply is connected with capacitor anode 6 lead-out wire, and power supply is born
Pole is connected with the negative outside wire of capacitor, and being applied with voltage can carry out ageing to product.
Before capacitor 8 carries out opening technique for ageing, with fixture, control acid tube 3 is tightly secured on capacitor 8, envelope acid
Mouth 5 buckle closures are placed in ageing stove after electrolyte inlet 7.When ambient temperature raises, and the acid in capacitor 8 cavity is heated excessive
Going out, produce the electrolyte gas of volatilization simultaneously, the electrolyte of spilling all rests in control acid tube 3, and the electrolysis produced of volatilizing
Liquid gas major part is trapped in control acid tube 3, therefore directly can be isolated with capacitor 8 shell by the electrolyte overflowed, not cause
The pollution of tantalum case surface, and the isolation electrolyte pollution to sealing insulator 9 completely, can be detained major part in control acid tube 3 and wave
Electricity solution liquid gas, thus avoid the gas molecule catalyzed corrosion effect to sintering furnace, and isolated electrolyte gas pair
The corrosiveness of sealing insulator 9.
Meanwhile, the electrolyte gas of volatilization is adsorbed by molecular sieve 1, so spreading limited, therefore the overwhelming majority is retained in
In control acid tube 3.After stopping ageing, after ageing stove Temperature fall, the electrolyte gas being trapped in control acid tube 3 coagulates again
Form solution to pass back in shell, thus avoid secondary acid filling.
Therefore the device using present invention design can more effectively reduce the waste of electrolyte and maintain capacitor electrolysis
Liquid measure constant, save the manufacturing cost of finished product and maintain stablizing of capacitor performance, it is to avoid the technique ring of secondary acid filling
Joint.
Claims (3)
1. molecular sieve acid control device, it is characterised in that: it includes molecular sieve (1), control acid tube (3) and politef base
(4), the pipe shaft (303) of control acid tube (3) is straight tube, and one end of control acid tube (3) is provided with horn mouth (301) and horn mouth (301)
Being bottleneck (302) with the junction of pipe shaft (303), bottleneck (302) is fixed on by fluid sealant (2) to contract, molecular sieve (1)
In bottleneck (302), politef base (4) having the through hole (401) running through base, control acid tube (3) is arranged on polytetrafluoro
Ethylene base (4) is upper and connect with through hole (401), and the bottom surface of politef base (4) is provided with and connects with through hole (401)
Envelope acid mouth (5), envelope acid mouth (5) is in inverted cone-shaped；
The using method of described molecular sieve acid control device: before capacitor (8) carries out opening technique for ageing, will control acid with fixture
Pipe (3) is tightly secured on capacitor (8), and envelope acid mouth (5) buckle closure is placed in ageing stove after electrolyte inlet (7), when
Ambient temperature raises, and the acid in capacitor (8) cavity is heated spilling, produces the electrolyte gas of volatilization, the electrolysis of spilling simultaneously
Liquid all rests in control acid tube (3), and the electrolyte gas major part produced of volatilizing is trapped in control acid tube (3), therefore may be used
Directly the electrolyte overflowed is isolated with capacitor (8) shell, do not cause the pollution of tantalum case surface, and completely cut off electrolyte completely
Pollution to sealing insulator (9), can be detained the electrolyte gas of major part volatilization, thus avoid gas in control acid tube (3)
The molecule catalyzed corrosion effect to sintering furnace, and isolated the electrolyte gas corrosiveness to sealing insulator (9).
Molecular sieve acid control device the most according to claim 1, it is characterised in that: described molecular sieve (1) is
The molecular sieve of rank.
Molecular sieve acid control device the most according to claim 1, it is characterised in that: described envelope acid mouth (5) buckle closure is at electric capacity
On the electrolyte inlet (7) of device (8).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210320151.6A CN103681006B (en) | 2012-08-31 | 2012-08-31 | molecular sieve acid control device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210320151.6A CN103681006B (en) | 2012-08-31 | 2012-08-31 | molecular sieve acid control device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103681006A CN103681006A (en) | 2014-03-26 |
| CN103681006B true CN103681006B (en) | 2016-12-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210320151.6A Active CN103681006B (en) | 2012-08-31 | 2012-08-31 | molecular sieve acid control device |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110226866A (en) * | 2019-05-31 | 2019-09-13 | 深圳市微笑地球控股有限公司 | Cup |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2364556Y (en) * | 1998-06-25 | 2000-02-16 | 郑京和 | Full-enclosed lead-acid accumulator |
| JP2006324015A (en) * | 2005-05-17 | 2006-11-30 | Toyo Seikan Kaisha Ltd | Sealing compound for battery |
| CN201523049U (en) * | 2009-11-06 | 2010-07-07 | 卧龙电气集团股份有限公司 | Acid-proof gas-passing cover for internal formation of storage battery |
| CN202094240U (en) * | 2011-05-30 | 2011-12-28 | 风帆股份有限公司 | Reflux exhaust device for preventing overflow of electrolyte formed by storage battery |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005041747B4 (en) * | 2005-09-02 | 2020-03-12 | Bayerische Motoren Werke Aktiengesellschaft | Process for reducing emissions by gaseous decomposition products of an electrolyte in motor vehicles and device for carrying out the process |
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- 2012-08-31 CN CN201210320151.6A patent/CN103681006B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2364556Y (en) * | 1998-06-25 | 2000-02-16 | 郑京和 | Full-enclosed lead-acid accumulator |
| JP2006324015A (en) * | 2005-05-17 | 2006-11-30 | Toyo Seikan Kaisha Ltd | Sealing compound for battery |
| CN201523049U (en) * | 2009-11-06 | 2010-07-07 | 卧龙电气集团股份有限公司 | Acid-proof gas-passing cover for internal formation of storage battery |
| CN202094240U (en) * | 2011-05-30 | 2011-12-28 | 风帆股份有限公司 | Reflux exhaust device for preventing overflow of electrolyte formed by storage battery |
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| Publication number | Publication date |
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| CN103681006A (en) | 2014-03-26 |
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