CN107767982A - A kind of online washer of nuclear power facility primary Ioops radioactive pollution and method - Google Patents

A kind of online washer of nuclear power facility primary Ioops radioactive pollution and method Download PDF

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Publication number
CN107767982A
CN107767982A CN201711008420.4A CN201711008420A CN107767982A CN 107767982 A CN107767982 A CN 107767982A CN 201711008420 A CN201711008420 A CN 201711008420A CN 107767982 A CN107767982 A CN 107767982A
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CN
China
Prior art keywords
decontamination
detergent
tank
circulation
agitation tank
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Pending
Application number
CN201711008420.4A
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Chinese (zh)
Inventor
臧晗宇
陈家坚
陈博
金伟
刘勇
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SHENYANG ZHONGKE CORROSION CONTROL ENGINEERING Co Ltd
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SHENYANG ZHONGKE CORROSION CONTROL ENGINEERING Co Ltd
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Priority to CN201711008420.4A priority Critical patent/CN107767982A/en
Publication of CN107767982A publication Critical patent/CN107767982A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04Treating liquids
    • G21F9/06Processing
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04Treating liquids
    • G21F9/20Disposal of liquid waste
    • G21F9/22Disposal of liquid waste by storage in a tank or other container

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Monitoring And Testing Of Nuclear Reactors (AREA)

Abstract

The present invention relates to a kind of online washer of nuclear power facility primary Ioops radioactive pollution and method, belongs to the decontamination field that nuclear industry radwaste minimizes.The equipment is made up of detergent system, circulation decontamination system, circulation line etc., (I) circulation washer is established according to field condition, reasonable Arrangement decontamination Agitation Tank, detergent tank and connection associated cyclic pipeline facilities at the scene, and the pipeline of washer is connected with the primary coolant circuit pipe of nuclear power facility, and carry out installation and debugging;(II) each component and solvent of detergent are added into detergent tank, after stirring fully, circulation decontamination is carried out to the primary Ioops pipeline of nuclear power facility;(III) after circulation decontamination terminates, the solvent in circulation decontamination system is neutralized, circulation decontamination system cleaned with clear water.The present invention has the features such as detersive efficiency is high, saving decontamination cost, and toxic and harmful gas, and easily recovery and the processing of the waste water after decontamination need not be produced in decontamination process.

Description

A kind of online washer of nuclear power facility primary Ioops radioactive pollution and method
Technical field
The present invention relates to the decontamination technology field that nuclear industry radwaste minimizes, and in particular to a kind of nuclear power facility one The online washer of loop radioactive pollution and method.
Background technology
With the high speed development of China's nuclear industry, the nuclear power generating sets of construction are also more and more, due in nuclear-power reactor In running, reactor in-core will necessarily produce and accumulate radionuclide, and radionuclide is led to by Main Coolant therewith Cross primary Ioops system and take relevant system to, cause the radioactive pollution of system and equipment.Before reactor dismantling, in order to reduce The radiation field intensity of Work places, operating personnel's exposure dosage is reduced, reduce waste category, reduced reactor decommissioning process and give up Thing yield, clean dirt need to be carried out to primary Ioops system.
Foreign countries start from the 1970s for the developmental research of one loop of nuclear power station decontamination technology.At present, widely use The softening of low concentration of detergent learns decontamination process and instead of initial concentrated solution decontamination process, and decontamination is conceived to decontamination factor It is high, low to matrix material rate of corrosion, produce secondary amount of waste is few, temperature is low, speed is fast etc..In order to achieve the above object, it is chemical Decontamination process develops towards redox multistep processes, and the research of domestic this aspect is also in the starting stage.
At present, common decontamination method has mechanical decontamination (including high-speed jet, supercritical ultrasonics technology etc.), chemical decontamination, electrification The methods of learning decontamination, laser decontamination and melting decontamination, the process that these methods are applied at the scene cuts both ways.
The content of the invention
It is an object of the invention to provide a kind of online washer of nuclear power facility primary Ioops radioactive pollution and method, uses The apparatus and method carry out decontamination to nuclear power facility primary Ioops, have the features such as detersive efficiency is high, saving decontamination cost, decontamination Toxic and harmful gas will not be produced in journey, and easily recovery and processing, the apparatus and method have filled up existing to the waste water after decontamination The blank of the online decontamination technology of nuclear power facility.
To achieve the above object, the technical solution adopted in the present invention is as follows:
A kind of online washer of nuclear power facility primary Ioops radioactive pollution, the equipment include decontamination agent storage device, followed Ring decontamination system and external system;Wherein:
Decontamination agent storage device:For storing detergent, including detergent tank, support frame and liquid level gauge with a scale;It is described For detergent tank on support frame, the top of detergent tank is provided with dosing mouth, and liquid level gauge with a scale is set in detergent tank and is stirred Device is mixed, liquid level gauge with a scale is used for the amount for measuring solution in detergent tank, and agitating device is used to enter material in detergent tank Row stirring;
Circulate decontamination system:Including dosing pump, decontamination Agitation Tank, electric heater, glass plate liquid level gauge and circulation line;Institute State decontamination Agitation Tank by pipeline I with the bottom of detergent tank to be connected, pipeline I is provided with dosing pump;Open dosing pump, decontamination Material in agent tank enters in decontamination Agitation Tank;Electric heater and glass plate liquid level gauge are provided with the decontamination Agitation Tank;Institute The material stated in decontamination Agitation Tank is circulated by circulation line between decontamination Agitation Tank and external system;
External system:Including reaction vessel A and reaction vessel B.
The top of the decontamination Agitation Tank is provided with exhaust outlet and water supplement port, and the bottom of decontamination Agitation Tank sets sewage draining exit, gone The side middle and lower part of dirty Agitation Tank sets sample tap and waste water car interface, the opposite side of decontamination Agitation Tank by circulation line with it is outer System is connected.
The circulation line includes pipeline II and pipeline III, and one end of pipeline II is connected to the bottom of decontamination Agitation Tank, separately One end is divided into the bottom of two branch roads, two branch road difference coupled reaction device A and reactor B;One end of pipeline III is connected to The top of dirty Agitation Tank, the other end are divided into the top of two branch roads, two branch road difference coupled reaction device A and reactor B.
The pipeline II is provided with thermometer and circulating pump, and the both sides of circulating pump respectively set a pressure gauge on pipeline II; Connecting test pipeline section on the pipeline III.
The detergent tank and decontamination Agitation Tank use acid-alkali-corrosive-resisting material.
The online decontamination method of nuclear power facility primary Ioops radioactive pollution carried out using the equipment, is comprised the following steps:
(1) online washer is connected with primary coolant circuit pipe, then adds decontamination into detergent tank from dosing mouth Each raw material components of agent, open agitating device and stir 20~40min, detergent is obtained when being well mixed to each raw material;
(2) dosing pump is opened, the detergent in detergent tank is injected into decontamination Agitation Tank, is started in decontamination Agitation Tank Electric heater, end-point temperature is determined according to field condition;
(3) decontamination is circulated:After temperature of charge in Agitation Tank to be decontaminated reaches assigned temperature, open the circulation pump, make decontamination Agent is circulated by circulation line between decontamination Agitation Tank and external system;By adjust the power output of circulating pump come Adjust the fluid flow in circulation line;
(4) after circulation decontamination terminates, pH adjusting agent, and open the circulation pump is added into decontamination Agitation Tank, decontamination will be circulated PH value in system is adjusted to neutrality;Then (waste water car interface row will be opened in the display device by discharge of wastewater to nuclear power station Put);
(5) clear water is injected in decontamination Agitation Tank, open the circulation pump in circulation decontamination system to carrying out wash cycles 1~2 It is secondary.
In above-mentioned steps (1), more sub-sampling detection pH value in whipping process, up to pH stable to constant value.
In above-mentioned steps (2), the end-point temperature is 40-50 DEG C.
In above-mentioned steps (3), after open the circulation pump, every 4~6min carries out one cycle decontamination system in preceding half an hour Liquid sampling in system, and the radioactive dosage analysis synchronized is tested with pH, and the end of circulation decontamination is determined according to analysis result Point.
In above-mentioned steps (3), the sample tap set from the test pipeline section of circulation line samples, and samples the radioactivity in liquid When dosage and pH value of solution no longer rise, that is, regard as decontamination terminal.
Advantages of the present invention and beneficial effect are:
1st, traditional offline decontamination is higher by irradiation dose to personnel, and when being removed to loop, workload is huge, Easily form substantial amounts of radioaerosol and other solid waste, add personnel, environment by irradiation potential safety hazard.
2nd, the mode combined is wanted invention applies chemical decontamination method and online decontamination cycles device, to nuclear power facility one Loop carries out chemical cycle decontamination, can greatly reduce decontamination time and decontamination cost, and the detergent used is inorganization Compound, reduce the difficulty of later stage Spent Radioactive water process.
3rd, the present invention has necessarily perspective in principle and field practice, and inorganic detergent has been selected in decontamination process Agent and corrosion inhibiter, while decontamination is carried out to nuclear power metal structure is crucial, protected using corrosion inhibiter by the metallic conduit of decontamination, Decontamination process is simple to operate, without the plant equipment of complexity, while equipment and technique after improvement, can equally apply and its The online decontamination engineering of his pipeline.
Brief description of the drawings
Fig. 1 is the online washer structural representation of nuclear power facility primary Ioops radioactive pollution of the present invention.
In figure:1 dosing mouth;2 detergent tanks;3 support frames;4 liquid level gauges with a scale;5 dosing pumps;6 exhaust outlets;7 decontaminations are matched somebody with somebody Flow container;8 sample taps;9 waste water car interfaces;10 sewage draining exits;11 electric heaters;12 water supplement ports;13 test pipeline sections;14 glass plate liquid levels Meter;15 thermometers;16 pressure gauge A;17 circulating pumps;18 pressure gauge B;19- reaction vessels A;20- reaction vessels B;21- pipelines I; 22- pipelines II;23- pipelines III.
Embodiment
The present invention is described in detail below in conjunction with accompanying drawing.
The present invention is the online washer of nuclear power facility primary Ioops radioactive pollution and method, and the structure of the equipment is as schemed Shown in 1.The equipment includes decontamination agent storage device, circulation decontamination system and external system;Each several part concrete structure is as follows:
(1) decontamination agent storage device:Including detergent tank 2, support frame 3 and liquid level gauge with a scale 4;The detergent tank 2 On support frame 3, the top of detergent tank 2 is provided with dosing mouth 1, sets liquid level gauge 4 with a scale and stirring to fill in detergent tank 2 Put;
(2) decontamination system is circulated:Including dosing pump 5, decontamination Agitation Tank 7, electric heater 11, the and of glass plate liquid level gauge 14 Circulation line;The decontamination Agitation Tank 7 is connected by pipeline I 21 with the bottom of detergent tank 2, and pipeline I 21 is provided with dosing Pump 5;Electric heater 11, agitating device and glass plate liquid level gauge 14 are provided with the decontamination Agitation Tank 7, passes through glass plate liquid level gauge Liquid level in 14 pairs of decontamination Agitation Tanks 7 is tested, and the liquid in decontamination Agitation Tank 7 can be added by electric heater 11 Heat, have the characteristics that to heat up.The liquid in decontamination Agitation Tank 7 is stirred by agitating device;The decontamination Agitation Tank 7 Top be provided with exhaust outlet 6 and water supplement port 12, exhaust outlet 6 is beneficial to the discharge of waste gas in circulation decontamination operation, and water supplement port 12 is beneficial to Box house cleans.The bottom of decontamination Agitation Tank sets sewage draining exit 10, and sewage draining exit 10 is easy to discharge caused miscellaneous during decontamination Matter.
The side middle and lower part of decontamination Agitation Tank 7 sets sample tap 8 and waste water car interface 9, and sample tap 8 is easy to monitoring in real time to go Liquid component in dirty Agitation Tank 7, waste water car interface 9 are used for the discharge of waste liquid after decontamination.The opposite side of decontamination Agitation Tank passes through Circulation line is connected with external system.The external system includes reaction vessel A19 and reaction vessel B20.
The circulation line includes pipeline II 22 and pipeline III 23, and one end of pipeline II 22 is connected to decontamination Agitation Tank 7 Bottom, the other end are divided into the bottom of two branch roads, two branch road difference coupled reaction device A19 and reactor B 20;Pipeline III 23 One end is connected to the top of decontamination Agitation Tank 7, and the other end is divided into two branch roads, two branch roads difference coupled reaction device A19 and anti- Answer device B20 top.
The pipeline II 22 is provided with thermometer 15 and circulating pump 17, and the both sides of circulating pump 17 are set respectively on pipeline II 22 Pressure gauge A16 and pressure gauge B18;Connecting test pipeline section 13 on the pipeline III 23.The decontamination Agitation Tank 7 passes through circulation line Connect the entrance of circulating pump 17 and decontamination and return liquid, be easy to by the detergent that detergent tank 2 is sent be delivered to external system (reaction vessel A, Reaction vessel B) carry out circulation decontamination.
The detergent tank and decontamination Agitation Tank of the equipment use acid-alkali-corrosive-resisting material.The bottom of detergent tank 2 and support Connected mode between frame is welding, can ensure that the medicaments such as decontamination host, aggressive agent, sustained release agent uniformly mix with water, real When monitor detergent ingredient.In addition, the dosing pump 5 that the exit design of detergent tank 2 has acid and alkali-resistance characteristic (connects with pipeline for flange Connect), for conveying the decontamination medicament prepared to decontamination Agitation Tank 7.The flow and lift of dosing pump 5, according to decontamination system The size and elevation of water capacity, can voluntarily be selected.
Use the said equipment nuclear power facility primary Ioops radioactive pollution is carried out the process of online decontamination for:According to live feelings Condition establishes circulation washer, at the scene the facility such as reasonable Arrangement decontamination Agitation Tank, detergent tank and connection associated cyclic pipeline, And the pipeline of washer is connected with the primary coolant circuit pipe of nuclear power facility, and carry out installation and debugging.After debugging is good, to decontamination In agent tank add detergent each component and solvent, stirring fully after, according to corresponding operational procedure to nuclear power facility one Circuit lines carry out circulation decontamination.After circulation decontamination terminates, the solvent in circulation decontamination system is neutralized, with clear water to following Ring decontamination system is cleaned.
Embodiment 1:
The present embodiment is that nuclear power facility primary Ioops radioactive pollution carries out online decontamination, is comprised the following steps that:
(1) online washer is connected with primary coolant circuit pipe, then adds decontamination into detergent tank from dosing mouth Each raw material components of agent, open agitating device and stir 20~40min, detergent is obtained when being well mixed to each raw material;
(2) dosing pump is opened, the detergent in detergent tank is injected into decontamination Agitation Tank, is started in decontamination Agitation Tank Electric heater, end-point temperature is determined according to field condition;
(3) decontamination is circulated:After temperature of charge in Agitation Tank to be decontaminated reaches assigned temperature, open the circulation pump, make decontamination Agent is circulated by circulation line between decontamination Agitation Tank and external system;By adjust the power output of circulating pump come Adjust the fluid flow in circulation line;
(4) after circulation decontamination terminates, appropriate pH adjusting agent, and open the circulation pump is added into decontamination Agitation Tank, will be followed PH value in ring decontamination system is adjusted to neutrality;Then (will open waste water car to connect in the display device of discharge of wastewater to nuclear power station Mouth discharge);
(5) clear water is injected in decontamination Agitation Tank, open the circulation pump in circulation decontamination system to carrying out wash cycles 1~2 It is secondary.
In above-mentioned steps (1), more sub-sampling detection pH value in whipping process, up to pH stable to constant value.
In above-mentioned steps (2), the end-point temperature is 40-50 DEG C.
In above-mentioned steps (3), after open the circulation pump, every 4~6min carries out one cycle decontamination system in preceding half an hour Liquid sampling in system, and the radioactive dosage analysis synchronized is tested with pH, and the end of circulation decontamination is determined according to analysis result Point.
In above-mentioned steps (3), the sample tap set from the test pipeline section of circulation line samples, and samples the radioactivity in liquid When dosage and pH value of solution no longer rise, that is, regard as decontamination terminal.
Embodiment result shows that the present invention is online to being carried out inside nuclear power facility primary Ioops using chemical cycle decontamination method Decontamination is circulated, the working time of field personnel is greatly reduced relative to offline decontamination, reduces staff and is irradiated Dosage, protect the safety of personnel, the public and environment.
The principal character and technological merit of the present invention is shown above, and there is low reagent cost, Preparation equipment and processing side The advantages such as method is simple, processing cost is low.The present invention is not limited to the above embodiments, is not departing from cardinal principle of the present invention and examination On the premise of agent scope, various changes and modifications of the present invention are possible, and these changes and improvements both fall within this claimed hair In bright scope.

Claims (10)

  1. A kind of 1. online washer of nuclear power facility primary Ioops radioactive pollution, it is characterised in that:The equipment is stored up including detergent Cryopreservation device, circulation decontamination system and external system;Wherein:
    Decontamination agent storage device:For storing detergent, including detergent tank, support frame and liquid level gauge with a scale;The decontamination For agent tank on support frame, the top of detergent tank is provided with dosing mouth, sets liquid level gauge with a scale and stirring to fill in detergent tank Put, liquid level gauge with a scale is used for the amount for measuring solution in detergent tank, and agitating device is used to stir material in detergent tank Mix;
    Circulate decontamination system:Including dosing pump, decontamination Agitation Tank, electric heater, glass plate liquid level gauge and circulation line;It is described to go Dirty Agitation Tank is connected by pipeline I with the bottom of detergent tank, and pipeline I is provided with dosing pump;Open dosing pump, detergent tank Interior material enters in decontamination Agitation Tank;Electric heater and glass plate liquid level gauge are provided with the decontamination Agitation Tank;It is described to go Material in dirty Agitation Tank is circulated by circulation line between decontamination Agitation Tank and external system;
    External system:Including reaction vessel A and reaction vessel B.
  2. 2. the online washer of nuclear power facility primary Ioops radioactive pollution according to claim 1, it is characterised in that:It is described The top of decontamination Agitation Tank is provided with exhaust outlet and water supplement port, and the bottom of decontamination Agitation Tank sets sewage draining exit, and the one of decontamination Agitation Tank Side middle and lower part sets sample tap and waste water car interface, the opposite side of decontamination Agitation Tank to be connected by circulation line with external system.
  3. 3. the online washer of nuclear power facility primary Ioops radioactive pollution according to claim 2, it is characterised in that:It is described Circulation line includes pipeline II and pipeline III, and one end of pipeline II is connected to the bottom of decontamination Agitation Tank, and the other end is divided into two The bottom of branch road, two branch road difference coupled reaction device A and reactor B;One end of pipeline III is connected to the upper of decontamination Agitation Tank Portion, the other end are divided into the top of two branch roads, two branch road difference coupled reaction device A and reactor B.
  4. 4. the online washer of nuclear power facility primary Ioops radioactive pollution according to claim 3, it is characterised in that:It is described Pipeline II is provided with thermometer and circulating pump, and the both sides of circulating pump respectively set a pressure gauge on pipeline II;On the pipeline III Connecting test pipeline section.
  5. 5. the online washer of nuclear power facility primary Ioops radioactive pollution according to claim 1, it is characterised in that:It is described Detergent tank and decontamination Agitation Tank use acid-alkali-corrosive-resisting material.
  6. 6. the online decontamination method of nuclear power facility primary Ioops radioactive pollution carried out using equipment described in claim 1, its feature It is:This method comprises the following steps:
    (1) online washer is connected with primary coolant circuit pipe, detergent is then added into detergent tank from dosing mouth Each raw material components, open agitating device and stir 20~40min, detergent is obtained when being well mixed to each raw material;
    (2) dosing pump is opened, the detergent in detergent tank is injected into decontamination Agitation Tank, starts the electricity in decontamination Agitation Tank Heater, end-point temperature is determined according to field condition;
    (3) decontamination is circulated:After temperature of charge in Agitation Tank to be decontaminated reaches assigned temperature, open the circulation pump, lead to detergent Circulation line is crossed to be circulated between decontamination Agitation Tank and external system;Adjusted by adjusting the power output of circulating pump Fluid flow in circulation line;
    (4) after circulation decontamination terminates, pH adjusting agent, and open the circulation pump is added into decontamination Agitation Tank, decontamination system will be circulated Interior pH value is adjusted to neutrality;Then by the display device by discharge of wastewater to nuclear power station;
    (5) clear water is injected in decontamination Agitation Tank, open the circulation pump in circulation decontamination system to carrying out wash cycles 1~2 time.
  7. 7. the online decontamination method of nuclear power facility primary Ioops radioactive pollution carried out using equipment described in claim 6, its feature It is:In step (1), more sub-sampling detection pH value in whipping process, up to pH stable to constant value.
  8. 8. the online decontamination method of nuclear power facility primary Ioops radioactive pollution carried out using equipment described in claim 6, its feature It is:In step (2), the end-point temperature is 40-50 DEG C.
  9. 9. the online decontamination method of nuclear power facility primary Ioops radioactive pollution carried out using equipment described in claim 6, its feature It is:In step (3), after open the circulation pump, every 4~6min carries out liquid in one cycle decontamination system in preceding half an hour Sampling, and the radioactive dosage analysis synchronized is tested with pH, and the terminal of circulation decontamination is determined according to analysis result.
  10. 10. the online decontamination method of nuclear power facility primary Ioops radioactive pollution carried out using equipment described in claim 9, its feature It is:In step (3), the sampling of the sample tap that is set from the test pipeline section of circulation line, sample radioactive dosage in liquid and When pH value of solution no longer rises, that is, regard as decontamination terminal.
CN201711008420.4A 2017-10-25 2017-10-25 A kind of online washer of nuclear power facility primary Ioops radioactive pollution and method Pending CN107767982A (en)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN108597628A (en) * 2018-05-22 2018-09-28 广东核电合营有限公司 A kind of radiation protection method for Spent Fuel Pool dilatation
CN110959183A (en) * 2018-05-11 2020-04-03 原子能股份公司 Device for electrochemical decontamination of metal radioactive wastes
CN115641979A (en) * 2022-10-26 2023-01-24 核工业北京化工冶金研究院 Chemical method online decontamination device and decontamination method for pipeline

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JPH06214098A (en) * 1993-01-20 1994-08-05 Toshiba Corp Chemical decontamination device
JPH08136696A (en) * 1994-11-14 1996-05-31 Toshiba Corp Chemical decontamination method for inside of reactor facility system
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110959183A (en) * 2018-05-11 2020-04-03 原子能股份公司 Device for electrochemical decontamination of metal radioactive wastes
CN110959183B (en) * 2018-05-11 2023-12-01 原子能股份公司 Electrochemical decontamination device for metal radioactive waste
CN108597628A (en) * 2018-05-22 2018-09-28 广东核电合营有限公司 A kind of radiation protection method for Spent Fuel Pool dilatation
CN115641979A (en) * 2022-10-26 2023-01-24 核工业北京化工冶金研究院 Chemical method online decontamination device and decontamination method for pipeline

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Application publication date: 20180306