CN107759861A - A kind of preparation method of wear-resistant anti-skidding deceleration carrying material - Google Patents
A kind of preparation method of wear-resistant anti-skidding deceleration carrying material Download PDFInfo
- Publication number
- CN107759861A CN107759861A CN201711068753.6A CN201711068753A CN107759861A CN 107759861 A CN107759861 A CN 107759861A CN 201711068753 A CN201711068753 A CN 201711068753A CN 107759861 A CN107759861 A CN 107759861A
- Authority
- CN
- China
- Prior art keywords
- parts
- wear
- carrying material
- self
- river sand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/267—Magnesium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Tires In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of preparation method of wear-resistant anti-skidding deceleration carrying material, belong to deceleration strip preparing technical field.The present invention utilizes butadiene-styrene rubber and fluorosioloxane rubber,The vulcanization epoxy glue with wearability is formed in sulfidation,Carbon black and molybdenum disulfide are added into vulcanization epoxy glue,Wherein carbon black has certain chemism,Wear away smaller,Molybdenum disulfide can form rough layer in rubber surface,Contain abundant hardness silica using river sand,Using silane coupler to river sand powder modification,By itself and vegetable oil and the blending fermentation of biogas slurry microorganism,It is subsequently added into carborundum and magnesium carbonate with certain anti-wear performance,At high temperature,It is melted in vulcanizate,Continue to deceleration strip material surface sprayed glass fiber,So that glass fibre viscosity is attached to deceleration strip fiber surface,Wherein deceleration carrying material is squeezed into ridge design shape,Reach skidproof effect to a certain extent,So as to improve the non-skid property of deceleration carrying material,With extensive prospect of the application.
Description
Technical field
The invention discloses a kind of preparation method of wear-resistant anti-skidding deceleration carrying material, belongs to deceleration strip technology of preparing neck
Domain.
Background technology
Deceleration strip be mounted in make on highway by vehicle deceleration means of transportation, shape is generally strip, also a little
Shape, material is mainly rubber, and it is metal also to have, typically alternate to cause vision attention with yellow black.With traffic thing
The development of industry, the level of highway in China construction are obviously improved, and auto industry is also in fast development, so driving speed
Degree becomes increasingly faster, and traffic safety problem also becomes increasingly severe.It is therefore desirable to effectively control driving speed
Degree, road accident rate is reduced, this just needs to install some forced deceleration facilities on road surface to reach the mesh of limitation road speed
's.Deceleration strip makes road surface somewhat arch upward to reach vehicle deceleration purpose, be generally located on highway road junction, industrial and mining enterprises, school, live
Residence cell entry etc. needs the section that vehicle deceleration goes slowly and easily triggers the section of traffic accident, be for reductor motor-car,
The novel traffic Special safety of non-motor vehicle running velocity is set.Deceleration strip largely reduces the accident of each traffic main artery mouth
Occur, be the new exclusive facility of traffic safety.Automobile is not only safe under steam but also plays buffer deceleration purpose, improves traffic road
The safety of mouth.
Deceleration strip is to realize what is slowed down by influenceing the driving psychology of driver.When vehicle passes through deceleration strip with higher speed
When, violent vibration can pass to driver from tire via vehicle body and seat, and vertical curve can produce a vertical direction
Acceleration, producing strong physiological stimulation includes vibratory stimulation and visual stimulus and Psychological stimulation.Physiological stimulation promotes to drive
Sail people and produce strong sticky feeling, and Psychological stimulation has then deepened the dangerous doubt of driver, reduce further driving
The sense of security of the people to road environment.Under normal circumstances, driver thinks that non-comfort is bigger, and vehicle safety is smaller, i.e.,
The sense of security is smaller.Therefore, the setting of deceleration strip can reduce the desired value of the sense of driver's traffic safety and riding comfort, promote to drive
Sail people and select relatively low desired speed.Under desired speed guidance, driver will actively drive vehicle with relatively low road speed
Approach and pass through deceleration strip.Preferable deceleration strip must assure that vehicle by when will not occur to lose control of one's vehicle, important safety part
The unsafe conditions such as fracture will not be produced, higher traveling and safety of structure should be possessed.Common deceleration carrying material is present resistance at present
The defects of grinding poor-performing and poor non-skid property, therefore, invent a kind of wear-resistant anti-skidding deceleration carrying material and be is prepared by deceleration strip
Technical field has positive effect.
The content of the invention
The technical problems to be solved by the invention：It is poor and anti-skidding to there is anti-wear performance for current common deceleration carrying material
A kind of the defects of poor-performing, there is provided preparation method of wear-resistant anti-skidding deceleration carrying material.
In order to solve the above technical problems, the present invention is using technical scheme as described below：
A kind of preparation method of wear-resistant anti-skidding deceleration carrying material, it is characterised in that specifically preparation process is：
（1）Butadiene-styrene rubber, fluorosioloxane rubber and sulphur are put into kneading machine and are kneaded, obtains self-control vulcanization epoxy glue；
（2）100 mesh sieves are crossed after weighing the grinding of 10~30g river sands, collect sieving river sand powder, sieving river sand powder and silane is even
Join agent KH-570 to mix, obtain mixture, beet oil and mixture with mixture quality 6% will be poured into mixture
In the fermentation tank of the bed-silt of quality 0.6%, it is sealed by fermentation, after fermentation ends, takes out tunning, use deionized water rinsing
Tunning, remove the removal of impurity, naturally dry, as modified river sand powder；
（3）Pyrophillite and cullet are put into kiln and melted, founds to obtain fused solution, after excluding bubble, is transported to porous leakage
Wire drawing in plate, as makes glass fibre by oneself, and self-control glass fibre, titanate coupling agent 201 and peach gum are mixed, mixed
Compound 1, it is put into the beaker of the deionized water equipped with 1~3 times of 1 mass of mixture, the heating stirring in water bath with thermostatic control, after stirring
Insulation is stood, and obtains modified self-control glass fibre；
（4）Count in parts by weight, weigh self-control vulcanization epoxy glue, modified river sand powder, modified self-control glass fibre, charcoal respectively
Black, molybdenum disulfide, sulfur dichloride and deionized water mixing be placed in stirring reaction in mixer, then add carborundum, magnesium carbonate and
Calcium carbonate, continue insulation and mix, obtain mixed slurry, mixed slurry is poured into mould, be placed in extruding in extruder
Shaping, obtains deceleration strip body of material, is finally putting into calender and extrudes ridge design, naturally cool to room temperature, discharges, you can
Wear-resistant anti-skidding deceleration carrying material is made.
Step（1）The mass ratio of described butadiene-styrene rubber, fluorosioloxane rubber and sulphur is 3：2：1, melting temperature be 120~
160 DEG C, mixing time is 1~2h.
Step（2）Described milling time is 6~8min, the mass ratio of sieve river sand powder and Silane coupling reagent KH-570
For 4：1, mixing time is 10~12min, and fermentation temperature is 35~45 DEG C, and fermentation time is 9~11 days.
Step（3）Described pyrophillite and the mass ratio of cullet are 2：1, melting temperature is 1400~1600 DEG C, melting
Time is 2~4h, and wire drawing rotating speed is 2400~3000r/min, the matter of self-control glass fibre, titanate coupling agent 201 and peach gum
Amount is than being 3：1：1, mixing time is 6~8min, and whipping temp is 55~75 DEG C, and mixing time is 20~30min, time of repose
For 2~4h.
Step（4）Described meter in parts by weight, 20~30 parts of self-control vulcanization epoxy glues, 12~16 parts of modifications are weighed respectively
River sand powder, 14~16 parts of modified self-control glass fibres, 4~6 parts of carbon blacks, 3~5 parts of molybdenum disulfide, 1~3 part of sulfur dichloride, 12
~16 parts of deionized waters, 2~4 parts of carborundum, 1~3 part of magnesium carbonate and 2~4 parts of calcium carbonate, reaction temperature are 140~160 DEG C,
Reaction time is 16~20min, and mixing time is 1~2h, and die size is 800mm × 300mm × 6mm, extrusion temperature 160
~180 DEG C, squeeze pressure is 16~24MPa, and it is 65~75 DEG C to extrude temperature.
Compared with other method, advantageous effects are the present invention：
The present invention utilizes butadiene-styrene rubber and fluorosioloxane rubber, the vulcanization epoxy glue with wearability is formed in sulfidation, to sulphur
Changing addition carbon black and molybdenum disulfide, wherein carbon black in epoxy glue has certain chemism, and its surface-active point is more, is being kneaded
Easy and rubber molecule reacts to form network structure in sulfidation, vulcanizate intensity increase, so as to improve the wear-resisting of deceleration strip
Property, in high temperature system, with the increase of molybdenum disulfide dosage, the molybdenum disulphide particles for playing increasing mill flour milling are increased,
Interface shear strength between vulcanizate and mill part is bigger, and abrasion are smaller, and molybdenum disulfide can form rough layer in rubber surface, carry
High skin-friction force and hysteresis effect, so that coefficient of friction significantly improves, so as to improve the wearability of deceleration carrying material, then
Contain abundant hardness silica using river sand, using silane coupler to river sand powder modification, by itself and vegetable oil and
The blending fermentation of biogas slurry microorganism, plant oil decomposition is produced into lipophile ester group using microorganism, and made in the self-crosslinking of microorganism
With lower so that ester group is grafted to river sand surface, the compatibility of river sand and high polymer is enhanced, improves the resistance to of deceleration carrying material again
Performance is ground, carborundum and magnesium carbonate with certain anti-wear performance is subsequently added into, at high temperature, is melted in vulcanizate, makes it
Anti-wear performance and non-skid property further improve, further improve deceleration carrying material anti-wear performance and non-skid property, continue to
Deceleration strip material surface sprayed glass fiber, glass fibre is carried out by titanate coupling agent and tool sticking peach gum common
It is modified so that glass fibre is adhered to deceleration strip fiber surface, promotes the degree of roughness on its surface to improve, then the carrying material that will slow down
Ridge design shape is squeezed into, reaches skidproof effect to a certain extent, so as to improve the non-skid property of deceleration carrying material, is had
Extensive prospect of the application.
Embodiment
It is 3 in mass ratio：2：1 is put into butadiene-styrene rubber, fluorosioloxane rubber and sulphur in kneading machine, is mixed at 120~160 DEG C
1~2h is refined, obtains self-control vulcanization epoxy glue, weighs after 10~30g river sands grind 6~8min and crosses 100 mesh sieves, collect sieving river sand
Powder, it is 4 in mass ratio by sieving river sand powder and Silane coupling reagent KH-570：1 mixes 10~12min, is mixed
Thing, the fermentation tank of the bed-silt of beet oil and mixture quality 0.6% with mixture quality 6% will be poured into mixture
In, it is sealed by fermentation 9~11 days under conditions of being 35~45 DEG C in temperature, after fermentation ends, takes out tunning, use deionized water
Tunning is rinsed, goes the removal of impurity, naturally dry, as modified river sand powder, is in mass ratio 2：1 by pyrophillite and cullet
2~4h of melting in 1400~1600 DEG C of kiln is put into, founds to obtain fused solution, after excluding bubble, is transported in porous bushing,
The wire drawing in the case where rotating speed is 2400~3000r/min, as makes glass fibre by oneself, is in mass ratio 3：1：1 will self-control glass fibre,
Titanate coupling agent 201 and peach gum mix 6~8min, obtain mixture 1, are put into equipped with 1~3 times of 1 mass of mixture
In the beaker of deionized water, 20~30min of heating stirring in 55~75 DEG C of water bath with thermostatic control, 2~4h of insulation standing after stirring,
Modified self-control glass fibre is obtained, is counted in parts by weight, weighs 20~30 parts of self-control vulcanization epoxy glues, 12~16 parts of modifications respectively
River sand powder, 14~16 parts of modified self-control glass fibres, 4~6 parts of carbon blacks, 3~5 parts of molybdenum disulfide, 1~3 part of sulfur dichloride and
12~16 parts of deionized water mixing are placed in mixer, 16~20min of stirring reaction at 140~160 DEG C, then add 2~4 parts
Carborundum, 1~3 part of magnesium carbonate and 2~4 parts of calcium carbonate, continue insulation and mix 1~2h, mixed slurry is obtained, by mixing slurry
Material is poured into the mould that size is 800mm × 300mm × 6mm, is placed in extruder, is 160~180 DEG C, pressure in temperature
For extrusion forming under 16~24MPa, deceleration strip body of material is obtained, is finally putting into 65~75 DEG C of calender and extrudes concavo-convex flower
Line, room temperature is naturally cooled to, discharged, you can wear-resistant anti-skidding deceleration carrying material is made.
Example 1
It is 3 in mass ratio：2：1 is put into butadiene-styrene rubber, fluorosioloxane rubber and sulphur in kneading machine, is kneaded 1h at 120 DEG C, obtains
Self-control vulcanization epoxy glue, 100 mesh sieves are crossed after weighing 10g river sands grinding 6min, collect sieving river sand powder, by the river sand powder that sieves
It is 4 in mass ratio with Silane coupling reagent KH-570：1 mixes 10min, obtains mixture, will be poured into mixture with mixed
It is close under conditions of temperature is 35 DEG C in the fermentation tank of the beet oil of compound quality 6% and the bed-silt of mixture quality 0.6%
Seal ferment 9 days, after fermentation ends, tunning is taken out, with deionized water rinsing tunning, go the removal of impurity, naturally dry, i.e.,
It is in mass ratio 2 for modified river sand powder：Pyrophillite and cullet are put into 1400 DEG C of kiln and melt 2h by 1, found to obtain
Fused solution, after excluding bubble, it is transported in porous bushing, the wire drawing in the case where rotating speed is 2400r/min, as makes glass fibre by oneself,
It is 3 in mass ratio：1：Self-control glass fibre, titanate coupling agent 201 and peach gum are mixed 6min by 1, obtain mixture 1,
It is put into the beaker of the deionized water equipped with 1 times of 1 mass of mixture, the heating stirring 20min in 55 DEG C of water bath with thermostatic control, stirring
Insulation stands 2h afterwards, obtains modified self-control glass fibre, counts in parts by weight, weighs 20 parts of self-control vulcanization epoxy glues, 12 respectively
Part modified river sand powder, 14 parts of modified self-control glass fibres, 4 parts of carbon blacks, 3 parts of molybdenum disulfide, 1 part of sulfur dichloride and 12 parts go from
Sub- water mixing is placed in mixer, the stirring reaction 16min at 140 DEG C, then adds 2 parts of carborundum, 1 part of magnesium carbonate and 2 parts of carbon
Sour calcium, continue insulation and mix 1h, obtain mixed slurry, it is 800mm × 300mm × 6mm's that mixed slurry is poured into size
In mould, it is placed in extruder, the extrusion forming in the case where temperature is 160 DEG C, pressure is 16MPa, obtains deceleration strip body of material,
It is finally putting into 65 DEG C of calender and extrudes ridge design, naturally cool to room temperature, discharge, you can wear-resistant anti-skidding is made and slows down
Carrying material.
Example 2
It is 3 in mass ratio：2：1 is put into butadiene-styrene rubber, fluorosioloxane rubber and sulphur in kneading machine, is kneaded 1.5h at 140 DEG C, obtains
Vulcanize epoxy glue to self-control, cross 100 mesh sieves after weighing 20g river sands grinding 7min, collect sieving river sand powder, by the river sand powder that sieves
End and Silane coupling reagent KH-570 are 4 in mass ratio：1 mixes 11min, obtains mixture, is carried being poured into mixture
In the fermentation tank of the beet oil of mixture quality 6% and the bed-silt of mixture quality 0.6%, under conditions of temperature is 40 DEG C
It is sealed by fermentation 10 days, after fermentation ends, takes out tunning, with deionized water rinsing tunning, go the removal of impurity, dry in the air naturally
Dry, as modified river sand powder, is in mass ratio 2：Pyrophillite and cullet are put into 1500 DEG C of kiln and melt 3h by 1, are melted
Fused solution is made, after excluding bubble, is transported in porous bushing, the wire drawing in the case where rotating speed is 2400~3000r/min, is certainly
Glass fibre processed, it is in mass ratio 3：1：Self-control glass fibre, titanate coupling agent 201 and peach gum are mixed 7min by 1, are obtained
To mixture 1, it is put into the beaker of the deionized water equipped with 2 times of 1 mass of mixture, the heating stirring in 65 DEG C of water bath with thermostatic control
25min, insulation standing 3h after stirring, modified self-control glass fibre is obtained, is counted in parts by weight, weigh 25 parts of self-control vulcanizations respectively
Epoxy glue, 14 parts of modified river sand powder, 15 parts of modified self-control glass fibres, 5 parts of carbon blacks, 4 parts of molybdenum disulfide, 2 parts of sulfur dichloride
It is placed in 14 parts of deionized water mixing in mixer, the stirring reaction 18min at 150 DEG C, then adds 3 parts of carborundum, 2 parts of carbonic acid
Magnesium and 3 parts of calcium carbonate, continue insulation mix 1.5h, obtain mixed slurry, by mixed slurry pour into size for 800mm ×
In 300mm × 6mm mould, it is placed in extruder, the extrusion forming in the case where temperature is 170 DEG C, pressure is 20MPa, is subtracted
Speed belt body of material, it is finally putting into 70 DEG C of calender and extrudes ridge design, naturally cool to room temperature, discharge, you can is made
Wear-resistant anti-skidding deceleration carrying material.
Example 3
It is 3 in mass ratio：2：1 is put into butadiene-styrene rubber, fluorosioloxane rubber and sulphur in kneading machine, is kneaded 2h at 160 DEG C, obtains
Self-control vulcanization epoxy glue, 100 mesh sieves are crossed after weighing 30g river sands grinding 8min, collect sieving river sand powder, by the river sand powder that sieves
It is 4 in mass ratio with Silane coupling reagent KH-570：1 mixes 12min, obtains mixture, will be poured into mixture with mixed
It is close under conditions of temperature is 45 DEG C in the fermentation tank of the beet oil of compound quality 6% and the bed-silt of mixture quality 0.6%
Seal ferment 11 days, after fermentation ends, tunning is taken out, with deionized water rinsing tunning, go the removal of impurity, naturally dry,
As modified river sand powder, is in mass ratio 2：Pyrophillite and cullet are put into 1600 DEG C of kiln and melt 4h by 1, are melted into
To fused solution, after excluding bubble, it is transported in porous bushing, the wire drawing in the case where rotating speed is 3000r/min, as makes glass fibers by oneself
Dimension, is in mass ratio 3：1：Self-control glass fibre, titanate coupling agent 201 and peach gum are mixed 8min by 1, obtain mixture
1, it is put into the beaker of the deionized water equipped with 3 times of 1 mass of mixture, heating stirring 30min, is stirred in 75 DEG C of water bath with thermostatic control
Insulation stands 4h after mixing, and obtains modified self-control glass fibre, counts in parts by weight, weigh respectively 30 parts of self-control vulcanization epoxy glues,
16 parts of modified river sand powder, 16 parts of modified self-control glass fibres, 6 parts of carbon blacks, 5 parts of molybdenum disulfide, 3 parts of sulfur dichloride and 16 parts are gone
Ionized water mixing is placed in mixer, the stirring reaction 20min at 160 DEG C, then adds 4 parts of carborundum, 3 parts of magnesium carbonate and 4 parts
Calcium carbonate, continue insulation and mix 2h, obtain mixed slurry, it is 800mm × 300mm × 6mm that mixed slurry is poured into size
Mould in, be placed in extruder, the extrusion forming in the case where temperature is 180 DEG C, pressure is 24MPa, obtain deceleration strip material blank
Body, it is finally putting into 75 DEG C of calender and extrudes ridge design, naturally cool to room temperature, discharge, you can wear-resistant anti-skidding is made
Deceleration carrying material.
Comparative example
With the wear-resistant anti-skidding deceleration carrying material of Changzhou company as a comparison case
By the wear-resistant anti-skidding deceleration carrying material progressive in wear-resistant anti-skidding deceleration carrying material produced by the present invention and comparative example
It can detect, shown under testing result：
1st, method of testing：
Abrasive size test is detected using abrasive grain machinery instrument, and abrasive size is bigger, and anti-wear performance is higher；
Wear-resisting revolution method of testing：According to national standard, the deceleration strip in example 1~3 and comparative example is surveyed with 180 mesh sand paper
Examination, every 500 conversion, one, sand paper.Measure last wear-resisting revolution；
Anti-skid factor test is detected by the standards of GB/T 26542.
Table 1
| Test event | Example 1 | Example 2 | Example 3 | Comparative example |
| Abrasive size（Mesh） | 232 | 241 | 250 | 150 |
| Wear-resisting revolution（r） | 9650 | 9700 | 9800 | 6500 |
| Anti-skid factor（Level） | 0.7 | 0.8 | 0.9 | 0.5 |
It can be seen from data in table 1, wear-resistant anti-skidding deceleration strip material abrasive material particle diameter produced by the present invention is big, and wear-resisting revolution is high,
Reach 9800 turns, anti-wear performance is good, and anti-skid factor reaches 0.9 grade, and non-skid property is good, has broad application prospects.
Claims (5)
1. a kind of preparation method of wear-resistant anti-skidding deceleration carrying material, it is characterised in that specifically preparation process is：
（1）Butadiene-styrene rubber, fluorosioloxane rubber and sulphur are put into kneading machine and are kneaded, obtains self-control vulcanization epoxy glue；
（2）100 mesh sieves are crossed after weighing the grinding of 10~30g river sands, collect sieving river sand powder, sieving river sand powder and silane is even
Join agent KH-570 to mix, obtain mixture, beet oil and mixture with mixture quality 6% will be poured into mixture
In the fermentation tank of the bed-silt of quality 0.6%, it is sealed by fermentation, after fermentation ends, takes out tunning, use deionized water rinsing
Tunning, remove the removal of impurity, naturally dry, as modified river sand powder；
（3）Pyrophillite and cullet are put into kiln and melted, founds to obtain fused solution, after excluding bubble, is transported to porous leakage
Wire drawing in plate, as makes glass fibre by oneself, and self-control glass fibre, titanate coupling agent 201 and peach gum are mixed, mixed
Compound 1, it is put into the beaker of the deionized water equipped with 1~3 times of 1 mass of mixture, the heating stirring in water bath with thermostatic control, after stirring
Insulation is stood, and obtains modified self-control glass fibre；
（4）Count in parts by weight, weigh self-control vulcanization epoxy glue, modified river sand powder, modified self-control glass fibre, charcoal respectively
Black, molybdenum disulfide, sulfur dichloride and deionized water mixing be placed in stirring reaction in mixer, then add carborundum, magnesium carbonate and
Calcium carbonate, continue insulation and mix, obtain mixed slurry, mixed slurry is poured into mould, be placed in extruding in extruder
Shaping, obtains deceleration strip body of material, is finally putting into calender and extrudes ridge design, naturally cool to room temperature, discharges, you can
Wear-resistant anti-skidding deceleration carrying material is made.
A kind of 2. preparation method of wear-resistant anti-skidding deceleration carrying material according to claim 1, it is characterised in that：Step
（1）The mass ratio of described butadiene-styrene rubber, fluorosioloxane rubber and sulphur is 3：2：1, melting temperature is 120~160 DEG C, mixing time
For 1~2h.
A kind of 3. preparation method of wear-resistant anti-skidding deceleration carrying material according to claim 1, it is characterised in that：Step
（2）Described milling time is 6~8min, and the mass ratio of sieving river sand powder and Silane coupling reagent KH-570 is 4：1, during stirring
Between be 10~12min, fermentation temperature is 35~45 DEG C, and fermentation time is 9~11 days.
A kind of 4. preparation method of wear-resistant anti-skidding deceleration carrying material according to claim 1, it is characterised in that：Step
（3）Described pyrophillite and the mass ratio of cullet are 2：1, melting temperature is 1400~1600 DEG C, and the melting time is 2~4h,
Wire drawing rotating speed is 2400~3000r/min, and the mass ratio of self-control glass fibre, titanate coupling agent 201 and peach gum is 3：1：1,
Mixing time is 6~8min, and whipping temp is 55~75 DEG C, and mixing time is 20~30min, and time of repose is 2~4h.
A kind of 5. preparation method of wear-resistant anti-skidding deceleration carrying material according to claim 1, it is characterised in that：Step
（4）Described meter in parts by weight, 20~30 parts of self-control vulcanization epoxy glues, 12~16 parts of modified river sand powder, 14 are weighed respectively
~16 parts of modified self-control glass fibres, 4~6 parts of carbon blacks, 3~5 parts of molybdenum disulfide, 1~3 part of sulfur dichloride, 12~16 parts go from
Sub- water, 2~4 parts of carborundum, 1~3 part of magnesium carbonate and 2~4 parts of calcium carbonate, reaction temperature are 140~160 DEG C, and the reaction time is
16~20min, mixing time are 1~2h, and die size is 800mm × 300mm × 6mm, and extrusion temperature is 160~180 DEG C, is squeezed
Pressure pressure is 16~24MPa, and it is 65~75 DEG C to extrude temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711068753.6A CN107759861A (en) | 2017-11-03 | 2017-11-03 | A kind of preparation method of wear-resistant anti-skidding deceleration carrying material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711068753.6A CN107759861A (en) | 2017-11-03 | 2017-11-03 | A kind of preparation method of wear-resistant anti-skidding deceleration carrying material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107759861A true CN107759861A (en) | 2018-03-06 |
Family
ID=61273029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711068753.6A Pending CN107759861A (en) | 2017-11-03 | 2017-11-03 | A kind of preparation method of wear-resistant anti-skidding deceleration carrying material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107759861A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485286A (en) * | 2018-03-30 | 2018-09-04 | 胡果青 | A kind of preparation method of antibacterial damp-proof floor wax |
| CN109280233A (en) * | 2018-10-15 | 2019-01-29 | 浙江鼎天交通设施有限公司 | Speed-reducing rubber band and preparation method thereof |
| CN114837107A (en) * | 2021-01-30 | 2022-08-02 | 金浩 | Resistance type deceleration strip and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804258A (en) * | 2015-04-21 | 2015-07-29 | 青岛承天伟业机械制造有限公司 | Rubber gasket |
| CN106279842A (en) * | 2016-08-28 | 2017-01-04 | 肖丽燕 | A kind of beidellite modified styrene butadiene rubber metallic composite panel and preparation method thereof |
| CN106633248A (en) * | 2016-12-28 | 2017-05-10 | 德轮橡胶股份有限公司 | Wear-resistant anti-aging tire rubber material |
| CN106832472A (en) * | 2015-12-04 | 2017-06-13 | 张美玲 | A kind of flame retardant rubber |
-
2017
- 2017-11-03 CN CN201711068753.6A patent/CN107759861A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804258A (en) * | 2015-04-21 | 2015-07-29 | 青岛承天伟业机械制造有限公司 | Rubber gasket |
| CN106832472A (en) * | 2015-12-04 | 2017-06-13 | 张美玲 | A kind of flame retardant rubber |
| CN106279842A (en) * | 2016-08-28 | 2017-01-04 | 肖丽燕 | A kind of beidellite modified styrene butadiene rubber metallic composite panel and preparation method thereof |
| CN106633248A (en) * | 2016-12-28 | 2017-05-10 | 德轮橡胶股份有限公司 | Wear-resistant anti-aging tire rubber material |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485286A (en) * | 2018-03-30 | 2018-09-04 | 胡果青 | A kind of preparation method of antibacterial damp-proof floor wax |
| CN109280233A (en) * | 2018-10-15 | 2019-01-29 | 浙江鼎天交通设施有限公司 | Speed-reducing rubber band and preparation method thereof |
| CN109280233B (en) * | 2018-10-15 | 2021-07-20 | 浙江鼎天交通设施股份有限公司 | Rubber deceleration strip and preparation method thereof |
| CN114837107A (en) * | 2021-01-30 | 2022-08-02 | 金浩 | Resistance type deceleration strip and preparation method thereof |
| CN114837107B (en) * | 2021-01-30 | 2023-11-28 | 金浩 | Resistance type deceleration strip and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107759861A (en) | A kind of preparation method of wear-resistant anti-skidding deceleration carrying material | |
| CN112175418B (en) | Modified white carbon black, preparation method thereof and masterbatch | |
| CN102558627B (en) | Preparation method of white carbon black modified styrene-butadiene rubber facing green tires and product thereof | |
| CN104761761A (en) | High-toughness nanofiber-reinforced rubber-base 3D printing material and preparation method thereof | |
| CN105710983B (en) | A kind of rubber wet method compounding process for premixing atomization and remixing | |
| CN108129695B (en) | Preparation method of functional white carbon black for green tire | |
| CN104262700A (en) | Preparation method of silicon dioxide graft graphene oxide/rubber composite material | |
| CN104479181A (en) | Novel adhesion promoting system tire belt ply and preparation method thereof | |
| CN103435861B (en) | Tire transition layer and preparation method thereof | |
| CN101475714A (en) | Preparation of oil-extended montmorillonite-extended latex coprecipitation rubber | |
| CN104419023A (en) | Abrasion and pierce proof low-resistance tire rubber compound and preparation method thereof | |
| CN102718993B (en) | Rubber nano composite material for bead filler of tire and preparation method for rubber nano composite material | |
| CN104760469B (en) | Tire of the double formulation composition of a kind of tread cap and preparation method thereof and equipment | |
| CN106366386B (en) | The ultralow tread rubber composition for rolling resistance, high wet-sliding resistant riding radial tire | |
| CN104059251A (en) | Mosaic-type color tire rubber material combination and preparation method thereof | |
| CN103275365A (en) | Ionic liquid modified carbon black-white carbon black double-phase particle filling natural rubber and preparation method thereof | |
| CN107099064A (en) | A kind of solid tyre rubber and preparation method | |
| CN114395276A (en) | Janus structure carbon black and preparation method thereof | |
| CN113150413A (en) | Liquid-containing reclaimed rubber conveyer belt cover rubber material and preparation method thereof | |
| CN103073761B (en) | Production method of tire tread with low rolling resistance | |
| CN109776917B (en) | Multilayer enhanced high-strength asphalt anti-rutting agent with industrial solid waste powder as central core | |
| CN1397586A (en) | Process for preparing coiled water-proof polyolefine material | |
| CN104419021A (en) | Tire rubber compound with strong viscosity, anti-aging and low resistance | |
| CN114921002B (en) | Winter tire tread rubber with hard lamellar structure metal salt, mixing method thereof and tire | |
| CN113651332B (en) | Preparation method of high-performance white carbon black based on styrene-butadiene rubber reinforcement |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180306 |
|
| RJ01 | Rejection of invention patent application after publication |