CN107746654A - A kind of preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating - Google Patents
A kind of preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating Download PDFInfo
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- CN107746654A CN107746654A CN201711036498.7A CN201711036498A CN107746654A CN 107746654 A CN107746654 A CN 107746654A CN 201711036498 A CN201711036498 A CN 201711036498A CN 107746654 A CN107746654 A CN 107746654A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Abstract
The invention provides a kind of preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating, comprise the following steps：(1) host A preparation：Modifying epoxy resin by organosilicon and dispersant are first added into solvent by formula ratio, after stirring, sequentially add conductive titanium dioxide, CNT, graphene and polyaniline, after being uniformly dispersed, it is placed in grinder and grinds, fineness of grind is less than or equal to 20 microns, ground mill base is placed in clean stirred tank, defoamer, levelling agent, delustering agent and surface modifier are sequentially added under agitation, are stirred, are then filtered and packaged as host A after well mixed；(2) curing agent B preparation：Amine hardener is weighed by formula ratio, is filtered and packaged as curing agent B.Polyaniline epoxy organosilicon graphene heat radiation coating of the present invention has high-heating radiation rate, high thermal conductivity and low-heat resistance, while has polyaniline and epoxy organosilicon characteristic concurrently, has stronger practical value.
Description
Technical field
The invention belongs to chemical industry, energy field, is led more particularly, to a kind of radiating of polyaniline epoxy organosilicon graphene quiet
The preparation method of electrocoating paint.
Background technology
Modern electronic equipment is increasingly becoming the highly integrated system of High Density Packaging, and this causes the heat flow density day of product
Become and become big.Such as the heat-sinking capability deficiency of fruit product, part and circuit temperature rise, and will make equipment thermal deformation and thermal failure, shadow
Ring the performance to electronic product and life-span.In the industry fields such as metallurgy, petrochemical industry, ceramics, medicine, various industrial pots are often related to
The bodies of heater such as stove, station boiler, flame furnace, its heat dispersion are most important to the safety of personnel and the reliability service of equipment.Therefore,
How to improve the heat dispersion of electronics industry and other field turns into the important topic for promoting industrial progress.
The content of the invention
In view of this, the present invention is directed to propose a kind of preparation of polyaniline epoxy organosilicon graphene radiating static conductive coating
Method, the defects of to overcome prior art, the radiating static conductive coating heat resistance of preparation, electric conductivity, antiseptic property, radiating
Performance is superior to common epoxy static conducting coating, and there is wide applicability and can be widely applied value.
To reach above-mentioned purpose, the technical proposal of the invention is realized in this way：
A kind of preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating, comprises the following steps：
(1) host A preparation：Modifying epoxy resin by organosilicon and dispersant, stirring are first added into solvent by formula ratio
After uniformly, conductive titanium dioxide, CNT, graphene and polyaniline are sequentially added, after being uniformly dispersed, is placed in grinder and grinds
Mill, fineness of grind are less than or equal to 20 microns, ground mill base are placed in clean stirred tank, add successively under agitation
Enter defoamer, levelling agent, delustering agent and surface modifier, stirred after being well mixed to 30 microns of fineness, then bag filter
Dress is host A；
(2) curing agent B preparation：Amine hardener is weighed by formula ratio, is filtered and packaged as curing agent B；
(3) host A and curing agent B is 2-8 according to quality proportioning：1 ratio carry out with paint, then stir evenly produce it is poly-
Aniline epoxy organosilicon graphene radiating static conductive coating.
Preferably, the host A includes each component of following percetage by weight：Epoxy silicone resin 43.0~
48.0%, dispersant 1.4~2.0%, conductive titanium dioxide 20.0~38.0%, graphene 0.02~0.04%, CNT 0.5
~0.8%, defoamer 0.2~1.0%, levelling agent 0.2~1.0%, polyaniline 0.2~1.0%, surface modifier 2.0~
6.0%, diluent 8.0~28.0%；The mass percent sum of each component is 100%.
Preferably, the host A includes each component of following percetage by weight：Epoxy silicone resin 45.5%, disperse
Agent 1.7%, conductive titanium dioxide 29.8%, graphene 0.03%, CNT 0.3%, defoamer 0.25%, levelling agent
0.25%, polyaniline 0.6%, surface modifier 2.5%, diluent 19.07%.
Preferably, the curing agent B is amine hardener；Preferably, curing agent B is aliphatic cyclic amine, polyamide, phenolic aldehyde amine, ring
It is more than one or both of oxygen amine additives, fatty amine.
Preferably, the epoxy silicone resin is the modifying epoxy resin by organosilicon of Degussa.
Preferably, the dispersant is the BYK-161 of German BYK companies；Described conductive titanium dioxide is FT-300, is stone
Original production.
Preferably, the defoamer is the BYK-051 of German BYK companies；Described levelling agent is German BYK companies
BYK-354。
Preferably, the CNT for Chinese Academy of Sciences Chengdu it is organic TNHC.
Preferably, the surface modifier is the BYK-3700 of German BYK companies.
Preferably, the graphene is the XTJL-201 of Tianjin Xi Teng Science and Technology Ltd.s；The polyaniline is An Huiku
The conductivity type polyaniline of your bioengineering Co., Ltd.
Epoxy silicone resin is coating resin weather-proof, that heat resistance is very strong, and painting can be greatly improved in polyaniline resin
The heat radiation value and electric conductivity of material, graphene and CNT can further speed up the transmission of heat, conductive titanium dioxide tool
There is the effect of heat-resisting, weather-proof and conductive and heat-conductive, polyaniline, CNT, graphene and conductive titanium dioxide are in internal fluid
Ultimately form the full three-dimensional net structure distribution of point (polyaniline, conductive titanium white)+line (CNT)+plane (graphene).
Relative to prior art, a kind of polyaniline epoxy organosilicon graphene radiating static conductive coating of the present invention
Preparation method has the advantage that：
A kind of preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating of the present invention, epoxy have
Machine silicones is to be condensed the polyorganosiloxane resin of certain low molecule amount and bisphenol A epoxide resin under catalyst action
Resin, because it contains silicon and epoxy component, the higher heat resistance of the relatively strong hardness of the product is caused, polyaniline is due to molecule
Both contain oxidized and reduced in structure, and containing two kinds of mixed state, have the conductive proton of doping in addition, so as in metal
Electronic energy caused by base material corrosion bottom anode is delivered to a bed boundary above by the polyaniline of conduction, runs into oxygen and water becomes
Into OH-, concentration difference and electronics the supply limited source of oxygen, separate anode reaction and cathode reaction, so as to help metal bottom
Material is passivated, and generation is similar to Fe3O4Fine and close passivation layer, so as to improve antiseptic property.CNT, graphene, conductive titanium white
Powder is respectively provided with good electric conductivity, and these three raw material thermal stabilities are excellent, served in film system is applied skeleton and
Bridge beam action.
A kind of preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating of the present invention, epoxy have
Machine silicon tree has combination property more more preferable than conventional resins, separately using polyaniline, CNT, graphene as the basic of additive
Composition, the full three-dimensional network distribution of line-face-body is finally formd in internal fluid, thermal conductivity and thermal emissivity rate is improved, is lifted
The radiating efficiency and its combination property of heat radiation coating, have a stronger practical value.
The preparation method of polyaniline epoxy organosilicon graphene heat radiation coating of the present invention, the coating of preparation have height
Thermal emissivity rate, high thermal conductivity and low-heat resistance, while have polyaniline and epoxy organosilicon characteristic concurrently, i.e., from peace and quiet, acid and alkali-resistance, surpass
Strong electric conductivity and extremely strong heat resistance, there is stronger practical value.
Embodiment
In addition to being defined, technical term used has universal with those skilled in the art of the invention in following examples
The identical meanings of understanding.Test reagent used, is routine biochemistry reagent unless otherwise specified in following examples；It is described
Experimental method, it is conventional method unless otherwise specified.
The present invention is described in detail with reference to embodiment.
Embodiment 1
Polyaniline epoxy organosilicon graphene radiates static conductive coating, including host A and curing agent B, the host A and solid
Agent B weight ratio is 3:1；The host A includes each component of following percetage by weight：Epoxy silicone resin 43.0%,
Dispersant 1.4%, conductive titanium dioxide 24.4%, graphene 0.02%, CNT 0.2%, defoamer 0.34%, levelling agent
0.44%, polyaniline 0.2%, surface modifier 2.0%, diluent 28.0%.
The curing agent is aliphatic cyclic amine.
The epoxy silicone resin is the modifying epoxy resin by organosilicon of Degussa.
The dispersant is the BYK-161 of German BYK companies；Described conductive titanium dioxide is FT-300, is stone original production.
The defoamer is the BYK-051 of German BYK companies；Described levelling agent is the BYK-354 of German BYK companies.
The CNT for Chinese Academy of Sciences Chengdu it is organic TNHC.
The surface modifier is the BYK-3700 of German BYK companies.
The graphene is the XTJL-201 of Tianjin Xi Teng Science and Technology Ltd.s.
The polyaniline is the conductivity type polyaniline of Anhui Ku Er bioengineering Co., Ltd.
The method for preparing above-mentioned polyaniline epoxy organosilicon graphene radiating static conductive coating：
(1) host A preparation：Modifying epoxy resin by organosilicon and dispersant, stirring are first added into solvent by formula ratio
After uniformly, conductive titanium dioxide, CNT, graphene and polyaniline are sequentially added, after being uniformly dispersed, is placed in grinder and grinds
Mill, fineness of grind are less than 20 microns, ground mill base are placed in clean stirred tank, sequentially adds defoaming under agitation
Agent, levelling agent, delustering agent and surface modifier, after being well mixed stirring to below 30 microns of fineness, then filter and package as
Host A；
(2) curing agent B preparation：Amine hardener is weighed by formula ratio, is filtered and packaged as curing agent B；
(3) host A and curing agent B is 3 according to quality proportioning：1 ratio with paint, then stir evenly and produce polyphenyl
Amine epoxy organosilicon graphene radiating static conductive coating.
Radiating effect contrast test：
Test method：The fin for taking two blocks of aluminium alloys to make, size are 100mm × 50mm × 15mm, and fin number is 6
Piece.The heat radiation coating of one piece of spraying the present embodiment, another piece does not spray any heat radiation coating.Distinguish at the above-mentioned two fin back side
10WLED chips are connected, and are connected to composition LED test system on D.C. regulated power supply, it is stand-by.In LED chip and fin
It is upper to connect thermocouple probe respectively, record each channel temperature data after experiment is started.Test temperature is 25 DEG C of room temperature.Test knot
Fruit is shown in Table 1：
The embodiment 1 of table 1 and blank example coating radiating contrast test result (25 DEG C of initial temperature)
It can be clearly seen from table 1, the chip temperature rise after spraying is obvious slower than the chip temperature rise not sprayed, from chip
Temperature approach is at 1 DEG C or so after can be seen that the spraying coating of embodiment 1 with the fin temperature difference, and the temperature difference maximum not sprayed reaches
To 11.2 DEG C.Chip and the chip final temperature that does not spray reduce about 10 DEG C after spraying, illustrate after spraying system radiating ability compared with
By force, so as to reduce the temperature of LED chip, overall radiating efficiency is improved.
Embodiment 2
Polyaniline epoxy organosilicon graphene radiates static conductive coating, including host A and curing agent B, the host A and solid
Agent B weight ratio is 5:1；The host A includes each component of following percetage by weight：Epoxy silicone resin 45.5%,
Dispersant 1.7%, conductive titanium dioxide 29.8%, graphene 0.03%, CNT 0.3%, defoamer 0.25%, levelling agent
0.25%, polyaniline 0.6%, surface modifier 2.5%, diluent 19.07%.
The curing agent is phenolic aldehyde amine.
The epoxy silicone resin is the modifying epoxy resin by organosilicon of Degussa.
The dispersant is the BYK-161 of German BYK companies；Described conductive titanium dioxide is FT-300, is stone original production.
The defoamer is the BYK-051 of German BYK companies；Described levelling agent is the BYK-354 of German BYK companies.
The CNT for Chinese Academy of Sciences Chengdu it is organic TNHC.
The surface modifier is the BYK-3700 of German BYK companies.
The graphene is the XTJL-201 of Tianjin Xi Teng Science and Technology Ltd.s.
The polyaniline is the conductivity type polyaniline of Anhui Ku Er bioengineering Co., Ltd.
The method for preparing above-mentioned polyaniline epoxy organosilicon graphene radiating static conductive coating：
(1) host A preparation：Modifying epoxy resin by organosilicon and dispersant, stirring are first added into solvent by formula ratio
After uniformly, conductive titanium dioxide, CNT, graphene and polyaniline are sequentially added, after being uniformly dispersed, is placed in grinder and grinds
Mill, fineness of grind are less than 20 microns, ground mill base are placed in clean stirred tank, sequentially adds defoaming under agitation
Agent, levelling agent, delustering agent and surface modifier, after being well mixed stirring to below 30 microns of fineness, then filter and package as
Host A；
(2) curing agent B preparation：Amine hardener is weighed by formula ratio, is filtered and packaged as curing agent B；
(3) host A and curing agent B is 5 according to quality proportioning：1 ratio with paint, then stir evenly and produce polyphenyl
Amine epoxy organosilicon graphene radiating static conductive coating.
Radiating effect contrast test：
Test method：The fin for taking two blocks of aluminium alloys to make, size are 100mm × 50mm × 15mm, and fin number is 6
Piece.The heat radiation coating of one piece of spraying the present embodiment, another piece does not spray any heat radiation coating.Distinguish at the above-mentioned two fin back side
10WLED chips are connected, and are connected to composition LED test system on D.C. regulated power supply, it is stand-by.In LED chip and fin
It is upper to connect thermocouple probe respectively, record each channel temperature data after experiment is started.Test temperature is 25 DEG C of room temperature, during test
Between 25min.Test result is shown in Table 2：
The embodiment 2 of table 2 and blank example heat radiation coating contrast test result
From Table 2, it can be seen that after 25min spray the coating of embodiment 2 chip compared with more original chip temperature,
10.3 DEG C are reduced, illustrates that the addition system radiating ability of embodiment 2 is stronger, the temperature difference of embodiment 2 is 1 DEG C or so, and in comparative example
The temperature difference is up to 11 DEG C, illustrates to add CNT, graphene in most preferred embodiment as additive, can form in the coating
The full three-dimensional network distribution of " point-line-face ", has high thermal conductivity and thermal emissivity rate.The radiating of the heat radiation coating of most preferred embodiment
System has more preferable infrared radiant energy, temperature caused by chip is radiate with higher efficiency, so as to reduce LED chip
Temperature, improve the radiating efficiency and service life of product facility, there is extensive practical value.
Embodiment 3
Polyaniline epoxy organosilicon graphene radiates static conductive coating, including host A and curing agent B, the host A and solid
Agent B weight ratio is 7:1；The host A includes each component of following percetage by weight：Epoxy silicone resin 48%, point
Powder 2.0%, conductive titanium dioxide 30.0%, graphene 0.04%, CNT 0.4%, defoamer 0.3%, levelling agent
0.3%, polyaniline 0.6%, surface modifier 3.0%, diluent 15.36%.
The curing agent is phenolic aldehyde amine.
The epoxy silicone resin is the modifying epoxy resin by organosilicon of Degussa.
The dispersant is the BYK-161 of German BYK companies；Described conductive titanium dioxide is FT-300, is stone original production.
The defoamer is the BYK-051 of German BYK companies；Described levelling agent is the BYK-354 of German BYK companies.
The CNT for Chinese Academy of Sciences Chengdu it is organic TNHC.
The surface modifier is the BYK-3700 of German BYK companies.
The graphene is the XTJL-201 of Tianjin Xi Teng Science and Technology Ltd.s.
The polyaniline is the conductivity type polyaniline of Anhui Ku Er bioengineering Co., Ltd.
The method for preparing above-mentioned polyaniline epoxy organosilicon graphene radiating static conductive coating：
(1) host A preparation：Modifying epoxy resin by organosilicon and dispersant, stirring are first added into solvent by formula ratio
After uniformly, conductive titanium dioxide, CNT, graphene and polyaniline are sequentially added, after being uniformly dispersed, is placed in grinder and grinds
Mill, fineness of grind are less than 20 microns, ground mill base are placed in clean stirred tank, sequentially adds defoaming under agitation
Agent, levelling agent, delustering agent and surface modifier, after being well mixed stirring to below 30 microns of fineness, then filter and package as
Host A；
(2) curing agent B preparation：Amine hardener is weighed by formula ratio, is filtered and packaged as curing agent B；
(3) host A and curing agent B is 7 according to quality proportioning：1 ratio with paint, then stir evenly and produce polyphenyl
Amine epoxy organosilicon graphene radiating static conductive coating.
Radiating effect contrast test：
Test method：The fin for taking two blocks of aluminium alloys to make, size are 100mm × 50mm × 15mm, and fin number is 6
Piece.The heat radiation coating of one piece of spraying the present embodiment, another piece does not spray any heat radiation coating.Distinguish at the above-mentioned two fin back side
10WLED chips are connected, and are connected to composition LED test system on D.C. regulated power supply, it is stand-by.In LED chip and fin
It is upper to connect thermocouple probe respectively, record each channel temperature data after experiment is started.Test temperature is 25 DEG C of room temperature, during test
Between 25min.Test result is shown in Table 3：
The embodiment 3 of table 3 and blank example heat radiation coating contrast test result
From table 3 it is observed that after 25min spray the coating of embodiment 3 chip compared with more original chip temperature,
7.6 DEG C are reduced, illustrates that addition most preferred embodiment system radiating ability is stronger, the temperature difference of embodiment 3 is 2 DEG C or so, and comparative example
The middle temperature difference is up to 11.5 DEG C, illustrates to add CNT, graphene, polyaniline in most preferred embodiment as additive, can be
The full three-dimensional network distribution of " point-line-face " is formd in coating, there is high thermal conductivity and thermal emissivity rate.Most preferred embodiment dissipates
The cooling system of hot coating has more preferable thermal radiation capability, and temperature caused by chip is radiate with higher efficiency, from
And the temperature of LED chip is reduced, the radiating efficiency and service life of product facility are improved, there is extensive practical value.
After testing, other performances of embodiment 1-3 are as follows：
To sum up, the epoxy silicone resin selected by the present invention, has combination property more more preferable than conventional resins, separately will be poly-
The basic composition of aniline, CNT, graphene as additive, the full three-dimensional of line-face-body is finally formd in internal fluid
Network distribution, thermal conductivity and thermal emissivity rate are improved, improve the radiating efficiency and its combination property of heat radiation coating, had stronger
Practical value.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.
Claims (10)
1. a kind of preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating, comprises the following steps：
(1) host A preparation：Modifying epoxy resin by organosilicon and dispersant are first added into solvent by formula ratio, is stirred
Afterwards, conductive titanium dioxide, CNT, graphene and polyaniline are sequentially added, after being uniformly dispersed, is placed in grinder and grinds, grind
Grinding rate is less than or equal to 20 microns, and ground mill base is placed in clean stirred tank, sequentially adds disappear under agitation
Infusion, levelling agent, delustering agent and surface modifier, after being well mixed below stirring to 30 microns of fineness, then filter and package i.e.
For host A；
(2) curing agent B preparation：Amine hardener is weighed by formula ratio, is filtered and packaged as curing agent B；
(3) host A and curing agent B is 2-8 according to quality proportioning：1 ratio with paint, then stir evenly and produce polyaniline
Epoxy organosilicon graphene radiating static conductive coating.
A kind of 2. preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating, it is characterised in that：The host A
Include each component of following percetage by weight：Epoxy silicone resin 43.0~48.0%, dispersant 1.4~2.0%, conductive titanium
White powder 20.0~38.0%, graphene 0.02~0.04%, CNT 0.5~0.8%, defoamer 0.2~1.0%, levelling
Agent 0.2~1.0%, polyaniline 0.2~1.0%, surface modifier 2.0~6.0%, diluent 8.0~28.0%；Each component
Mass percent sum is 100%.
3. the preparation method of polyaniline epoxy organosilicon graphene radiating static conductive coating according to claim 2, it is special
Sign is：The host A includes each component of following percetage by weight：Epoxy silicone resin 45.5%, dispersant 1.7%,
Conductive titanium dioxide 29.8%, graphene 0.03%, CNT 0.3%, defoamer 0.25%, levelling agent 0.25%, polyaniline
0.6%, surface modifier 2.5%, diluent 19.07%.
4. the preparation method of the polyaniline epoxy organosilicon graphene radiating static conductive coating according to Claims 2 or 3, its
It is characterised by：The curing agent B is amine hardener；Preferably, curing agent B is that aliphatic cyclic amine, polyamide, phenolic aldehyde amine, epoxy amine add
Into more than one or both of thing, fatty amine.
5. the preparation method of the polyaniline epoxy organosilicon graphene radiating static conductive coating according to Claims 2 or 3, its
It is characterised by：The epoxy silicone resin is the modifying epoxy resin by organosilicon of Degussa.
6. the preparation method of the polyaniline epoxy organosilicon graphene radiating static conductive coating according to Claims 2 or 3, its
It is characterised by：The dispersant is the BYK-161 of German BYK companies；Described conductive titanium dioxide is FT-300, is that stone is primary
Production.
7. the preparation method of the polyaniline epoxy organosilicon graphene radiating static conductive coating according to Claims 2 or 3, its
It is characterised by：The defoamer is the BYK-051 of German BYK companies；Described levelling agent is the BYK-354 of German BYK companies.
8. the preparation method of the polyaniline epoxy organosilicon graphene radiating static conductive coating according to Claims 2 or 3, its
It is characterised by：The CNT for Chinese Academy of Sciences Chengdu it is organic TNHC.
9. the preparation method of the polyaniline epoxy organosilicon graphene radiating static conductive coating according to Claims 2 or 3, its
It is characterised by：The surface modifier is the BYK-3700 of German BYK companies.
10. the preparation method of the polyaniline epoxy organosilicon graphene radiating static conductive coating according to Claims 2 or 3,
It is characterized in that：The graphene is the XTJL-201 of Tianjin Xi Teng Science and Technology Ltd.s；The polyaniline is Anhui Ku Ersheng
The conductivity type polyaniline of thing Engineering Co., Ltd.
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| CN109181533A (en) * | 2018-09-20 | 2019-01-11 | 张芸 | A kind of preparation method of the high heat radiation coating of electric appliance |
| CN111019462A (en) * | 2019-12-27 | 2020-04-17 | 常州纳欧新材料科技有限公司 | Polypropylene-oriented conductive primer and preparation method thereof |
| CN111218143A (en) * | 2018-12-17 | 2020-06-02 | 中国科学院理化技术研究所 | Boron nitride/graphene composite material, preparation thereof, surface protective coating composition comprising same and application |
| CN113980450A (en) * | 2021-12-26 | 2022-01-28 | 大连中沐化工有限公司 | High-temperature-resistant antistatic composition |
| CN115286976A (en) * | 2022-06-21 | 2022-11-04 | 南京长江涂料有限公司 | Long-acting protective water-based novolac epoxy static conductive coating and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181533A (en) * | 2018-09-20 | 2019-01-11 | 张芸 | A kind of preparation method of the high heat radiation coating of electric appliance |
| CN111218143A (en) * | 2018-12-17 | 2020-06-02 | 中国科学院理化技术研究所 | Boron nitride/graphene composite material, preparation thereof, surface protective coating composition comprising same and application |
| CN111218143B (en) * | 2018-12-17 | 2022-07-29 | 中国科学院理化技术研究所 | Boron nitride/graphene composite material, preparation thereof, surface protective coating composition comprising same and application |
| CN111019462A (en) * | 2019-12-27 | 2020-04-17 | 常州纳欧新材料科技有限公司 | Polypropylene-oriented conductive primer and preparation method thereof |
| CN113980450A (en) * | 2021-12-26 | 2022-01-28 | 大连中沐化工有限公司 | High-temperature-resistant antistatic composition |
| CN115286976A (en) * | 2022-06-21 | 2022-11-04 | 南京长江涂料有限公司 | Long-acting protective water-based novolac epoxy static conductive coating and preparation method thereof |
| CN115286976B (en) * | 2022-06-21 | 2023-11-21 | 南京长江涂料有限公司 | Long-acting protective water-based phenolic epoxy static conductive paint and preparation method thereof |
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Application publication date: 20180302 |