CN107736349A - A kind of composition of the amino acid of peptide containing benzene and flumetralim - Google Patents
A kind of composition of the amino acid of peptide containing benzene and flumetralim Download PDFInfo
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- CN107736349A CN107736349A CN201710785639.9A CN201710785639A CN107736349A CN 107736349 A CN107736349 A CN 107736349A CN 201710785639 A CN201710785639 A CN 201710785639A CN 107736349 A CN107736349 A CN 107736349A
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- flumetralim
- amino acid
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- benzene
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the groups —CO—N< and, both being directly attached by their carbon atoms to the same carbon skeleton, e.g. H2N—NH—CO—C6H4—COOCH3; Thio-analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
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- Pest Control & Pesticides (AREA)
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Abstract
The invention discloses a kind of composition containing benzene peptide amino acid and flumetralim and its application, is made up of the first active component benzene peptide amino acid, the second active component flumetralim and auxiliary agent, the weight ratio of the first active component and the second active component is 1:40~40:1, content sum is the 1%~60% of the composition total weight.This composition can be configured to suspending agent, aqueous emulsion, missible oil, aqua, soluble concentrate, wettable powder, water dispersible granules, the microemulsion agriculturally allowed.Instant component is reasonable, and the inhibition, topping effect and citrus control shoot effect to crops axillary bud are good, and its suckering, topping and citrus control shoot effect are not the simple superposition of each component activity, compared with existing unitary agent, there is significant synergistic effect.Said composition can improve crop yield simultaneously, improve crop quality, dosage be reduced, to crop safety.
Description
Technical field
The present invention relates to a kind of composition, by the first active component benzene peptide amino acid, the second active component flumetralim and help
Agent forms, and belongs to technical field of compounded pesticide.
Background technology
Benzene peptide amino acid, chemical name are o- (- N- benzoyls) benzoic acid.Benzene peptide amino acid has bioactivity for one kind
Plant growth regulator, by foliage-spray, can immerse in plant rapidly, promote nutriment to be adjusted to colored growing point
It is dynamic, pollinated beneficial to inseminating, have and induce bud into flower result, and the maturity period can be done sth. in advance, induce single fringe fruit to expand, tool is bright
Aobvious flower and fruit protecting effect；Physiology and preharvest drop are prevented, the natural maturity phase can shift to an earlier date 5~7 days.
Flumetralim, English name prime, it is called maleic Min, dinitroanilines.Flumetralim is contact and office
Portion's absorbability plant growth retardent, it is absorbed by plants soon, effect is rapid, main to influence enzyme system function in plant, increases
Chlorophyll and protein content.Suppress the growth of tobacco lateral bud, 2 hours after dispenser, no rain can take effect, and have one to prevention mosaic disease
Determine effect.
Applicant is had found through experiment, and the different benzene peptide amino acid of the mechanism of action is compounded with flumetralim, is had following excellent
Point and beneficial effect：Using compound scheme, suckering activity is improved, synergistic effect is notable；Citrus control shoot positive effect, synergistic effect
Significantly；Crop yield and quality are improved, to crop safety；Exempt to pinch, reduce workload；Reduce dosage and times for spraying, drop
Low cost accounting.
The content of the invention
It is an object of the invention to provide a kind of component is reasonable, active high, the citrus control shoot positive effect of suckering, synergistic effect
Significantly, crop yield and quality can be improved, drug cost is low and to the combination containing benzene peptide amino acid and flumetralim of crop safety
Thing.
Another object of the present invention is to provide the combination dosage form containing benzene peptide amino acid and flumetralim.
It is still another object of the present invention to provide application of the above-mentioned composition on tobacco, cotton and citrus.
To achieve the above object, the technical scheme is that so solving：
A kind of composition containing benzene peptide amino acid and flumetralim, it is characterised in that
（1）First active component：Benzene peptide amino acid；
（2）Second active component：Flumetralim；
The weight of first active component and the second active component ratio is 1:40~40:1, content sum is the composition total weight
1%~60%.
A kind of composition containing benzene peptide amino acid and flumetralim of the present invention is according to well known to those skilled in the art of the present technique
The preparation formulation that method can be prepared is suspending agent, aqueous emulsion, missible oil, aqua, soluble concentrate, wettable powder, water-dispersible grain
Agent, microemulsion.
To suspending agent, workable auxiliary agent has：Dispersant such as polycarboxylate, lignosulfonates, alkyl naphthalene formaldehyde condensation
Thing sulfonate, alkylphenol-polyethenoxy base ether phosphate, alkylphenol-polyethenoxy base ether sulfonate, phenethyl phenol polyoxyethylene groups
Ether phosphate, alkyl polyoxyethylene ether sulfonate, polyoxyethylene polyoxypropylene base ether block copolymers, pull open powder, dodecyl
It is one or more in polyoxyethylene ether phosphate；Wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, benzene second
Base phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, alkylnaphthalene sulfonate, alkylphenol-formaldehyde resin polyoxy
Vinethene, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer are one or more；Thickener such as xanthans, polyethylene
It is one or more in alcohol, bentonite, aluminium-magnesium silicate, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose；Preservative is such as
It is one or more in formaldehyde, benzoic acid, sodium benzoate, potassium sorbate, OIT；Defoamer such as silicone oil, silicone chemical combination
One or more in thing, C10-20 saturated fat acid compounds, C8-10 aliphatic alcohols, hexanol, butanol, octanol；Antifreezing agent
Such as one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, sorbierite, urea, inorganic salts；Water is deionization
Water.
To aqueous emulsion, workable auxiliary agent has：Emulsifying agent such as Nonyl pheno（EO=10）Ether phosphate, triphen second
Base phenol polyoxyethylene phosphonate, Nongru-700 #（Common name：Alkyl phenol formaldehyde resin polyoxyethylene ether）, agriculture breast 2201#, this
Disk -60#（Common name：Span60）, Tween-60 #（Common name：Polyoxyethylene sorbitan stearic acid
Ester）、TX-10（Common name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601（Common name：Triphenoethyl benzene phenol polyoxypropylene gathers
Oxygen ethylene block polymer）, it is agriculture breast 600#, one or more in agriculture breast 400#；Solvent such as dimethylbenzene, toluene, cyclohexanone, solvent
Oil（The trade mark：S-150、S-180、S-200）It is one or more；Stabilizer such as triphenyl phosphite, epoxychloropropane, epoxy soybean
It is one or more in oil；It is one or more in antifreezing agent such as ethylene glycol, propane diols, glycerine, urea, inorganic salts such as sodium chloride；
It is one or more in thickener such as xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate；Preservative such as formaldehyde, benzoic acid, benzene first
One or more in sour sodium, water is deionized water.
To missible oil, workable auxiliary agent has：Emulsifying agent is selected from calcium dodecyl benzene sulfonate（Agriculture breast 500#）, Nongru-700 #,
Agriculture breast 2201, this disk -60#, emulsifying agent T-60（Common name：Anhydrous sorbitol single-hard ester acid ester APEO）、TX-10（It is logical
With name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601#, agriculture breast 600#, the one or more in agriculture breast 400# etc.；Solvent selects
From dimethylbenzene, solvent naphtha（S-150、S-180、S-200）, toluene, biodiesel, one kind or more in methylated vegetable oil etc.
Kind；One or more of the cosolvent in ethyl acetate, methanol, dimethylformamide, cyclohexanone, acetone, MEK etc.；Surely
Determine one or more of the agent in triphenyl phosphite, epoxychloropropane, aceticanhydride etc..
To aqua, workable auxiliary agent has：Emulsifying agent such as calcium dodecyl benzene sulfonate, alkylphenol-formaldehyde resin polyoxyethylene
Ether, agriculture breast 2201#, sorbitan monostearate, sorbitan monostearate APEO, octyl phenol polyoxyethylene
（10）Ether, AEO, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, agriculture breast 600#, agriculture breast 400#, dodecane
One or more in base dimethyl benzyl ammonium chloride etc.；Water is deionized water.
To soluble concentrate, workable auxiliary agent has：Emulsifying agent such as Nongru-700 #（Common name：Alkylphenol-formaldehyde resin polyoxy
Vinethene）, agriculture breast 2201#, this disk -60#（Common name：Span60）, Tween-60 #（Common name：Polyoxy second
Alkene Span60）、TX-10（Common name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601#（Common name：Three
Phenethyl phenol polyoxyethylene polyoxypropylene block polymer）, agriculture breast 600#, the one or more in agriculture breast 400#；Solvent is such as
One or more in methanol, ethanol, acetone, cyclohexanone, dimethylformamide, dimethyl sulfoxide (DMSO), 1-METHYLPYRROLIDONE；Surely
Determine the one or more in agent such as triphenyl phosphite, triphenyl phosphate, epoxychloropropane.
To wettable powder, workable auxiliary agent has：Dispersant such as polycarboxylate, lignosulfonates, polyoxyethylene gather
Oxypropylene group ether block copolymers, alkyl naphthalene formaldehyde condensate sulfonates, alkylphenol-polyethenoxy base ether phosphate, poly alkyl alcohol
One or more in oxygen ethene ether phosphate, alkylphenol-polyethenoxy base ether sulfonate etc.；Wetting agent such as alkyl sulfate, alkane
One or more in base sulfonate, alkylnaphthalene sulfonate etc.；Filler such as ammonium sulfate, urea, sucrose, glucose, diatomite, height
One or more in ridge soil, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, clay etc..
To water dispersible granules, workable auxiliary agent has：Dispersant such as polycarboxylate（TERSPERSE2700、T36、GY-D06
Deng）, it is lignosulfonates, one or more in alkylnaphthalene sulfonate；Wetting agent such as alkyl sulfate, alkylsulfonate, naphthalene sulphur
It is one or more in hydrochlorate；In disintegrant such as ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and its derivative, bentonite
It is one or more；One kind in binding agent such as starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose
It is or a variety of；Filler such as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, clay is one or more.
To microemulsion, workable auxiliary agent has：Emulsifying agent is selected from calcium dodecyl benzene sulfonate（Agriculture breast 500#）, agriculture breast
700#, agriculture breast 2201, this disk-60#, polysorbate60-#, TX-10, agriculture breast 1601（Common name：Phenethyl phenol polyoxyethylene polyoxy
Propylene ether）, agriculture breast 600#, agriculture breast 400#；Assistant for emulsifying agent is selected from methanol, isopropanol, n-butanol, ethanol；Solvent be selected from cyclohexanone,
1-METHYLPYRROLIDONE, dimethylbenzene, toluene, solvent naphtha（The trade mark：S-150、S-180、S-200）；Stabilizer is selected from phosphorous acid three
Phenyl ester, epoxychloropropane；Water is deionized water.
Instant component is reasonable, and suckering activity is high, and citrus control shoot positive effect, synergistic effect is notable, can improve and make produce
Amount and quality, drug cost is low, good to crop safety, meets the security requirement of pesticidal preparations.
Embodiment
In order to which the present invention is better described, present invention is described further with reference to embodiment, in formula
Percentage is weight percentage.
Example of formulations 1
5% benzene peptide amino acid, 10% flumetralim, 8% phenethyl phenol polyoxyethylene groups ether phosphate, 4% alkylphenol-formaldehyde resin is weighed to gather
Oxygen vinethene, 0.3% carboxyethyl cellulose, 0.3% xanthans, 4% polyethylene glycol, 0.05% potassium sorbate, 0.1% octanol, deionization
Water adds to 100% parts by weight.Above-mentioned raw materials are blended, and high speed shear disperses 30min, are sanded with sand mill to particle diameter D90 and are less than 10
15% benzene peptide amino acid flumetralim suspending agent is made after μm.
Example of formulations 2
Weigh 14% benzene peptide amino acid, 8% flumetralim, 4% sodium lignin sulfonate, 2% Negel, 0.4% carboxyethyl cellulose,
5% propane diols, 0.01% formaldehyde, 1% hexanol, deionized water add to 100% parts by weight.Above-mentioned raw materials are blended, and high speed shear is disperseed
30min, it is sanded with sand mill after being less than 10 μm to particle diameter D90 and 22% benzene peptide amino acid flumetralim suspending agent is made.
Example of formulations 3
Weigh 15% benzene peptide amino acid, 5% flumetralim, 4% agriculture breast 2201#, 5% thermally coupled distillation columns, 5% cyclohexanone, 3%
Solvent naphtha S-180,1% epoxychloropropane, 5% sodium chloride, 0.2% polyvinyl alcohol, 0.5% benzoic acid, deionized water add to 100% weight
Measure part.Above-mentioned raw materials are blended, and 20% benzene peptide amino acid flumetralim aqueous emulsion is made in high speed shearing emulsification.
Example of formulations 4
Weigh 12% benzene peptide amino acid, 6% flumetralim, 8% agriculture breast TX-10#, 2% Nonyl pheno（EO=10）Ether phosphate, 4%
Triphenoethyl benzene phenol polyethenoxy ether phosphate, 2% this disk -60#, 5% toluene, 1% epoxychloropropane, 2% urea, 0.2% polyethylene
Alcohol, 0.5% formaldehyde, deionized water add to 100% parts by weight.Above-mentioned raw materials are blended, and 18% benzene peptamine is made in high speed shearing emulsification
Sour flumetralim aqueous emulsion.
Example of formulations 5
10% benzene peptide amino acid, 10% flumetralim, 5% agriculture breast 500#, 2%TX-10,1% agriculture breast 1601#, 8% ethyl acetate are weighed, biology
Diesel oil adds to 100% parts by weight.Above-mentioned raw materials are blended, and 20% benzene peptide amino acid flumetralim missible oil is made in stirring and dissolving afterwards completely.
Example of formulations 6
Weigh 6% benzene peptide amino acid, 4% flumetralim, 4% agriculture breast 500#, 2%TX-10,4% agriculture breast 1601#, 7% ethyl acetate, biological bavin
Oil adds to 100% parts by weight.Above-mentioned raw materials are blended, and 10% benzene peptide amino acid flumetralim missible oil is made in stirring and dissolving afterwards completely.
Example of formulations 7
10% benzene peptide amino acid, 5% flumetralim, 4% agriculture breast 1601# are weighed, deionized water adds to 100% parts by weight.Above-mentioned raw materials are through mixed
Close, 15% benzene peptide amino acid flumetralim aqua is made in stirring and dissolving afterwards completely.
Example of formulations 8
8% benzene peptide amino acid, 12% flumetralim, 2% agriculture breast 2201#, 3% Nongru-700 # are weighed, deionized water adds to 100% parts by weight.On
It is blended to state raw material, 20% benzene peptide amino acid flumetralim aqua is made in stirring and dissolving afterwards completely.
Example of formulations 9
Weigh 10% benzene peptide amino acid, 15% flumetralim, 1% agriculture breast 500#, 4%TX-10,2% agriculture breast 1601#, 1% epoxychloropropane, 10%
1-METHYLPYRROLIDONE, cyclohexanone add to 100% parts by weight.Above-mentioned raw materials are blended, and 25% benzene peptide is made in stirring and dissolving afterwards completely
Amino acid flumetralim soluble concentrate.
Example of formulations 10
7% benzene peptide amino acid, 8% flumetralim, 3%TX-10,2% agriculture breast 1601#, 20% dimethylformamide are weighed, acetone adds to 100%
Parts by weight.Above-mentioned raw materials are blended, and 15% benzene peptide amino acid flumetralim soluble concentrate is made in stirring and dissolving afterwards completely.
Example of formulations 11
Weigh 30% benzene peptide amino acid, 5% flumetralim, 6% polyoxyethylene polyoxypropylene base ether block copolymers, 4% sodium lignin sulfonate,
3% Negel, fine particle calcium carbonate are filled up to 100% parts by weight.Above-mentioned raw materials are blended, ultra micro air-flow crushing, hybrid technique step
Suddenly it is prepared into 35% benzene peptide amino acid flumetralim wettable powder.
Example of formulations 12
Weigh 20% benzene peptide amino acid, 10% flumetralim, 4% polyoxyethylene polyoxypropylene base ether block copolymers, 5% alkylnaphthalene sulfonate
Formaldehyde condensation products, 3% lauryl sodium sulfate, talcum powder are filled up to 100% parts by weight.Above-mentioned raw materials are blended, ultra micro air-flow
Crush, hybrid technique step is prepared into 30% benzene peptide amino acid flumetralim wettable powder.
Example of formulations 13
Weigh 10% benzene peptide amino acid, 40% flumetralim, 8% sodium lignin sulfonate, 3% polycarboxylate T36,4% lauryl sodium sulfate,
3% sodium alkyl sulfonate, attapulgite add to 100% parts by weight.The method i.e. mixing of the frequent regulation water intaking dispersible granule of above-mentioned raw materials,
Ultra micro air-flow crushing, mixing, granulation step produce 50% benzene peptide amino acid flumetralim water dispersible granules.
Example of formulations 14
Weigh 25% benzene peptide amino acid, 15% flumetralim, 5% polycarboxylate T36,2% sodium lignin sulfonate, 5% Nekal BX（Dibutyl
Sodium naphthalene sulfonate）, 2% lauryl sodium sulfate, talcum powder adds to 100% parts by weight.The frequent regulation water intaking dispersible granule of above-mentioned raw materials
Method be that mixing, ultra micro air-flow crushing, mixing, granulation step produce 40% benzene peptide amino acid flumetralim water dispersible granules.
Example of formulations 15
Weigh 4% benzene peptide amino acid, 8% flumetralim, 5% agriculture breast 1601,3% agriculture breast 400#, 5% dimethylbenzene, 3% solvent naphtha S-200,3% first
Alcohol, 1% epoxychloropropane, through dissolving completely and being well mixed, deionized water adds to 100% parts by weight, and 12% benzene peptide is made after stirring
Amino acid flumetralim microemulsion.
Example of formulations 16
Weigh 8% benzene peptide amino acid, 6% flumetralim, 4% agriculture breast 600#, 3% this disk -60#, 5% dimethylbenzene, 4% solvent naphtha S-150,1% second
Alcohol, 1% triphenyl phosphite, through dissolving completely and being well mixed, deionized water adds to 100% parts by weight, and 14% benzene is made after stirring
Peptide amino acid flumetralim microemulsion.
Biological Examples 1：Tobacco axillary bud inhibition is tested.
In May, 2016 has carried out example of formulations 1 in Jimo City of Shandong Province crossdrift town（15% benzene peptide amino acid flumetralim hangs
Floating agent）, example of formulations 3（20% benzene peptide amino acid flumetralim aqueous emulsion）, example of formulations 5（20% benzene peptide amino acid flumetralim
Missible oil）, example of formulations 7（15% benzene peptide amino acid flumetralim aqua）Suppress the field test of tobacco axillary bud growth.
Experiment is located at Jimo City crossdrift town, and practice ground is Plain plot, and soil is leaching dynamics.Tobacco bred is
NC89, transplanting on May 27, line-spacing 100cm, spacing in the rows 30cm.Test medicine and extension rate are shown in Table 1, separately set blank control, often locate
4 repetitions are managed, per plot area 50m2, totally 28 cells, random district's groups arrange.
At the full center of field 1/2, the flowers are in blossom puts, top length in more than 20cm when pinched, and extract and all be longer than 2cm's
Axillary bud.Dispenser is carried out using cup leaching method immediately after topping, every plant is 20ml with amount of liquid medicine.
Investigation and statistical method：Take per cell at 3 points, 10 plants every, respectively investigate bud number of once living within 2,4,6 weeks after administration
（More than 2cm）, adopt bud living when last time is investigated and weigh.
Inhibition computational methods：
Suckering rate（%）=[（Check plot work bud number-treatment region work bud number）/ check plot work bud number] × 100
Bud inhibition effect（%）=[（Check plot work bud fresh weight-treatment region work bud fresh weight)/check plot work bud fresh weight] × 100
The benzene peptide amino acid of table 1 is compounded to tobacco axillary bud inhibition with flumetralim
The benzene peptide amino acid of table 2 compounds the influence to tobacco production and quality with flumetralim
As can be seen from the above data, above-mentioned 4 example of formulations dilute the suckering rate after 500 times and fresh weight bud inhibition effect is bright
The aobvious suckering that 300 times are diluted higher than 20% benzene peptamine aqueous acid dilution agent of comparison medicament, 400 times, 125 g/l flumetralim missible oil
Rate and fresh weight bud inhibition effect.After dispenser 6 weeks, complex preparation suckering rate and fresh weight bud inhibition effect are more than 80%, and the suppression of single dose
Bud rate is respectively 32.6% and 60.5%, and fresh weight bud inhibition effect is respectively 38.0% and 65.5%, illustrates that benzene peptide amino acid is answered with flumetralim
It is high with rear suckering activity, there is significant synergistic function.Meanwhile complex preparation can improve the quality and yield of tobacco.
Security survey, observed during experiment, tobacco growing safety, no poisoning phenomenon occur all reagent agents.
Biological Examples 2：Cotton axillary bud inhibition is tested and topping effect test.
In May, 2016 has carried out example of formulations 9 in Jining City in Shandong Province Jinxiang County（25% benzene peptide amino acid flumetralim can
Solution）, example of formulations 11（35% benzene peptide amino acid flumetralim wettable powder）, example of formulations 13（50% benzene peptamine
Sour flumetralim water dispersible granules）, example of formulations 15（12% benzene peptide amino acid flumetralim microemulsion）Suppress cotton axillary bud growth
And the field test of topping effect.
Experiment is located at Jinxiang County of Jining City, and experiment physical features is flat, and soil is moisture soil.Cotton variety is that Shandong cotton grinds No. 37, April
Open field live broadcast on the 21st, line-spacing 75cm, spacing in the rows 25cm.Test medicine and extension rate are shown in Table 2, separately set blank control, often handle 4 times
Repeat, per plot area 30m2, totally 28 cells, random district's groups arrange.Normally pinched preceding 5d in cotton for the first time, even spraying
Processing.Second, 20d even sprayings are handled after dispenser first.
Investigation and statistical method：Radix investigation is carried out before second of dispenser, it is every per cell using the point sampling of diagonal 5
Point chooses representational 6 plants of fixed points from middle 3 rows, records bud number living（More than 2cm）, adopt bud living when last time is investigated and claim
Weight.
Inhibition computational methods：
Suckering rate（%）=[（Check plot work bud number-treatment region work bud number）/ check plot work bud number] × 100
Bud inhibition effect（%）=[（Check plot work bud fresh weight-treatment region work bud fresh weight)/check plot work bud fresh weight] × 100
The benzene peptide amino acid of table 3 is compounded to cotton axillary bud inhibition with flumetralim
As can be seen from the above data, above-mentioned 4 example of formulations dilute the suckering after 500 times, 700 times, 1000 times, 300 times
Rate and fresh weight bud inhibition effect will be apparently higher than 400 times, the 125 g/l flumetralims of benzene peptamine aqueous acid dilution agent of comparison medicament 20%
Missible oil dilutes 300 times of suckering rate and fresh weight bud inhibition effect.After 2nd dispenser 20d, complex preparation suckering rate and fresh weight suckering effect
Fruit is more than 80%, and the suckering rate of single dose is respectively 34.6% and 65.4%, and fresh weight bud inhibition effect is respectively 39.2% He
69.1%, illustrate that benzene peptide amino acid and suckering activity after flumetralim compounding are high, there is significant synergistic function.
The benzene peptide amino acid of table 4 is compounded to cotton topping effect with flumetralim
Remarks：In table 4, normal 50 tests of blow-of-cottons cotton boll are chosen.
As can be seen from the above data, after the 2nd dispenser 20d, above-mentioned 4 example of formulations dilute 500 times, 700 times,
Cotton plant height after 1000 times, 300 times will it is obvious it is short in 400 times of the benzene peptamine aqueous acid dilution agent of comparison medicament 20%, 125 grams/
Rise the plant height that flumetralim missible oil dilutes 300 times.Complex preparation seed cotton heavy, Single boll weight, seed refer to, bolling rate and per mu yield are above pair
According to single dose and blank control group, illustrate that benzene peptide amino acid and effect of being pinched after flumetralim compounding are good, there is significant Synergistic to make
With.
Security survey, observed during experiment, cotton growth safety, no poisoning phenomenon occur all reagent agents.
Biological Examples 3：Citrus control shoot is tested.
In May, 2017 is carried out 20% benzene peptide amino acid SL+12.5 fluorine sections in Guangxi province Guilin City Yanshan District Hui Xian towns Zhou Jia villages
Amine EC compounds the field test to citrus control shoot effect.
Experimental field outdoor plantation citrus throughout the year, the age of the age of tree 4,100 plants/acre of density, the average tip of citrus are about 2.72cm.Investigation
Method carries out corresponding singling with reference to citrus control summer shoot standard and determines tip investigation.Cell each all investigate by 3 strain numbers of processing, every plant of tree
6 summer shoots of fixed point investigation after administration investigated and collected evidence by growth length, and 18 summer shoots are investigated in each processing altogether, are given birth to by summer shoot
Long length vs carry out medicine assessment.
Drug effect computational methods：Summer shoot growth length before summer shoot growth length-medicine after citrus summer shoot growth=medicine
Inhibition (%)=[1- (tip is grown after tip length × treatment region medicine before the medicine of check plot) ÷（Tip length × control before treatment region medicine
The tip is grown after area's medicine）]×100
The benzene peptide amino acid of table 5 is with 10 days after flumetralim compound medicine to citrus control shoot result of the test
As can be seen from the above data, flumetralim single dose or its complex preparation are used in citrus summer shoot about 2.72cm to the citrus summer
The tip is respectively provided with certain inhibitory action.Other flumetralim is more than flumetralim or benzene with benzene peptide amino acid compounding to the positive effect of citrus control shoot
The effect of peptide amino acid single dose, synergistic effect are obvious.
Use technical proposal：Because citrus summer shoot can carry out nutrient competition in growth course with citrus young fruit, so as to lead
Citrus young fruit subalimentation is caused to cause to fall fruit.And citrus summer shoot growth period is citrus thanks to colored 15-20 days citruses summer shoot and start to give birth to
It is long, so when be optimal citrus summer shoot control time.When summer shoot grows about 0-3cm, answered using benzene peptide amino acid and flumetralim
Preparaton carries out controlling citrus summer shoot 1 time, is used the 2nd time after 12-15 days, can effectively suppress the growth of citrus summer shoot.By making
With the program, there is certain inhibitory action to citrus summer shoot, when citrus summer shoot is slow-growing, tip nutrition gradually decreases.So as to
Have the function that citrus fruit retention indirectly using citrus young fruit nutritional sufficiency.Morning or crop in afternoon should be selected in without dew during spray in addition
Water spray is advisable, and notices that whole strain sprinkling is uniform, avoids drain spray.
Points for attention：1）Citrus control shoot fruit retention is a part for fruit retention scheme, during which should coordinate corresponding and rich water quality management
With the farming operations such as girdling, reach the purpose of optimal fruit retention.2）During dispenser, as citrus summer shoot 4cm or during more than 4cm,
It is recommended that directly erase 4cm and above summer shoot, then carry out dispenser control citrus summer shoot.
Security survey, observed during experiment, each citrus tender tip, climax leaves and fruit of handling is normal, does not occur leaf roll, falls leaf
Phenomena such as falling fruit, experiment safety occur without poisoning phenomenon.
In summary, composition of the invention is to use two kinds of active components compound scheme, and its activity is not that each component is lived
Property simple superposition, compared with existing unitary agent, there is obvious bud inhibition effect and control shoot effect, synergistic effect is notable, prevent
Cost reduction is controlled, to crop safety, meets the security requirement of pesticidal preparations.
Claims (6)
1. the composition of a kind of amino acid of peptide containing benzene and flumetralim, it is characterised in that lived by the first active component benzene peptide amino acid, second
Property composition flumetralim and auxiliary agent composition, the weight ratio of the first active component and the second active component is 1:40~40:1.
2. the composition of the amino acid of peptide containing benzene and flumetralim according to claim 1, it is characterised in that the first active component and
The weight ratio of two active components is 1:20~20:1.
3. the composition of the amino acid of peptide containing benzene according to claim 1 or claim 2 and flumetralim, it is characterised in that the first active component
With the second active component content sum be the composition total weight 1%~60%.
4. the composition of the amino acid of peptide containing benzene according to claim 1 or claim 2 and flumetralim, it is characterised in that the first active component
With the second active component content sum be the composition total weight 5%~50%.
5. the composition of the amino acid of peptide containing benzene and flumetralim according to claim 1, it is characterised in that the combination dosage form is
Suspending agent, aqueous emulsion, missible oil, aqua, soluble concentrate, wettable powder, water dispersible granules, microemulsion.
6. the composition of the amino acid of peptide containing benzene and flumetralim is suppressing crops axillary bud growth, topping, mandarin orange according to claim 1
Purposes on tangerine control shoot, increase crop yield and raising crop quality.
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| CN201710017979.7A CN106857514A (en) | 2017-01-11 | 2017-01-11 | A kind of composition of the amino acid of peptide containing benzene and flumetralim |
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| CN201710785639.9A Pending CN107736349A (en) | 2017-01-11 | 2017-09-04 | A kind of composition of the amino acid of peptide containing benzene and flumetralim |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108812661A (en) * | 2018-08-28 | 2018-11-16 | 陕西上格之路生物科学有限公司 | Application of the composition containing flumetralim and triazole bactericidal agent in crop control shoot sprout inhibition |
| CN111248198A (en) * | 2018-11-30 | 2020-06-09 | 陕西汤普森生物科技有限公司 | Plant regulating composition containing flumetralin |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109744237A (en) * | 2017-11-06 | 2019-05-14 | 陕西美邦药业集团股份有限公司 | A kind of synergistic composition containing Duraset |
| CN109430266A (en) * | 2018-12-29 | 2019-03-08 | 四川国光农化股份有限公司 | A kind of plant growth regualting composition, preparation and its application |
| CN115669651A (en) * | 2022-11-18 | 2023-02-03 | 南京太化化工有限公司 | Flumetralin suspending agent and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101828548A (en) * | 2010-05-28 | 2010-09-15 | 上海交通大学 | Flumetralin-containing aqueous emulsion composition and preparation method thereof |
-
2017
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101828548A (en) * | 2010-05-28 | 2010-09-15 | 上海交通大学 | Flumetralin-containing aqueous emulsion composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 郑先福等: "《植物生长调节剂应用技术》", 30 September 2009, 中国农业大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108812661A (en) * | 2018-08-28 | 2018-11-16 | 陕西上格之路生物科学有限公司 | Application of the composition containing flumetralim and triazole bactericidal agent in crop control shoot sprout inhibition |
| CN108812661B (en) * | 2018-08-28 | 2021-03-23 | 陕西上格之路生物科学有限公司 | Application of composition containing flumetralin and triazole bactericide in crop tip control and bud inhibition |
| CN111248198A (en) * | 2018-11-30 | 2020-06-09 | 陕西汤普森生物科技有限公司 | Plant regulating composition containing flumetralin |
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| CN106857514A (en) | 2017-06-20 |
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