CN107735473A - Packaging plastic for solar opto-electronic board - Google Patents

Packaging plastic for solar opto-electronic board Download PDF

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Publication number
CN107735473A
CN107735473A CN201780001758.9A CN201780001758A CN107735473A CN 107735473 A CN107735473 A CN 107735473A CN 201780001758 A CN201780001758 A CN 201780001758A CN 107735473 A CN107735473 A CN 107735473A
Authority
CN
China
Prior art keywords
packaging plastic
weight
electronic board
solar opto
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201780001758.9A
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Chinese (zh)
Inventor
朱桂林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Jiayida Electrical Appliances Co Ltd
Original Assignee
Suzhou Jiayida Electrical Appliances Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Jiayida Electrical Appliances Co Ltd filed Critical Suzhou Jiayida Electrical Appliances Co Ltd
Publication of CN107735473A publication Critical patent/CN107735473A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J179/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
    • C09J179/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C09J179/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/204Applications use in electrical or conductive gadgets use in solar cells
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Photovoltaic Devices (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

This case discloses a kind of packaging plastic for solar opto-electronic board, includes the material of following parts by weight:The parts by weight of polyethyl methacrylate 50;The parts by weight of polyimides 50;The parts by weight of ethylene acrylic hydroxyl ethyl ester copolymer 1 0~12;The parts by weight of polyethylene glycol 5~6 and the parts by weight of sodium oxalate 2~3.This case improves the weather resistance of packaging plastic by introducing polyimides in polyethyl methacrylate system;Simultaneously, ethylene acrylic hydroxyl ethyl ester copolymer, polyethylene glycol and sodium oxalate are as Aided Modification auxiliary agent, the weatherability and stability for improving packaging plastic can not only be cooperateed with, adhesion strength of the packaging plastic when being exposed to outdoor for a long time can also be effectively improved, reduce the packaging plastic influence to light transmittance in itself, ensure the generating efficiency and service life of photovoltaic panel.

Description

Packaging plastic for solar opto-electronic board
Technical field
The present invention relates to one kind to encapsulate PUR, and in particular to one kind is used to bond in solar opto-electronic board assembly technology The packaging plastic of safety glass and cell piece.
Background technology
In solar energy photovoltaic panel, power generation main body is crystalline silicon battery plate, in order to protect this cell piece, it is necessary in battery Transparent safety glass is covered once on piece, and connect this safety glass and cell piece is exactly packaging plastic.In the prior art, Mainly using EVA resin as this encapsulation PUR, but EVA exposes jaundice easy to aging in atmosphere, can influence light transmittance, from And influence generating efficiency, also, when being exposed to for a long time in air, EVA and safety glass, cell piece adhesion strength also can be significantly Decline, so as to influence the life-span of photovoltaic board component.
The content of the invention
In view of the deficiencies of the prior art, it is an object of the invention to provide a kind of encapsulation for solar opto-electronic board Glue, it has high light transmittance, excellent resistance to ag(e)ing, weatherability and high bond strength.
Technical scheme is summarized as follows:
A kind of packaging plastic for solar opto-electronic board, include the material of following parts by weight:
Preferably, the described packaging plastic for solar opto-electronic board, wherein, the ethylene-acrylic acid hydroxyl ethyl ester is total to In polymers, the content of vinyl monomer is 33~35wt%, and remaining is Vinyl Acetate Monomer.
Preferably, the described packaging plastic for solar opto-electronic board, wherein, the ethylene-acrylic acid hydroxyl ethyl ester is total to The number-average molecular weight of polymers is 16000~20000g/mol.
Preferably, the described packaging plastic for solar opto-electronic board, wherein, the number of the polyethyl methacrylate Average molecular weight is 30000~35000g/mol.
Preferably, the described packaging plastic for solar opto-electronic board, wherein, the number-average molecular weight of the polyimides For 23000~26000g/mol.
Preferably, the described packaging plastic for solar opto-electronic board, wherein, the number-average molecular weight of the polyethylene glycol For 4000~5000g/mol.
Preferably, the described packaging plastic for solar opto-electronic board, wherein, include the oxygen of 0.2~0.3 parts by weight Change barium.
Preferably, the described packaging plastic for solar opto-electronic board, wherein, include the oxygen of 0.2~0.3 parts by weight Change magnesium.
The beneficial effects of the invention are as follows:This case is improved by introducing polyimides in polyethyl methacrylate system The weather resistance of packaging plastic;Meanwhile ethylene-acrylic acid hydroxyl ethyl ester copolymer, polyethylene glycol and sodium oxalate are as Aided Modification Auxiliary agent, it can not only cooperate with the weatherability and stability for improving packaging plastic, moreover it is possible to effectively improve packaging plastic and be exposed to family for a long time Adhesion strength when outer, reduce the packaging plastic influence to light transmittance in itself, ensure the generating efficiency and service life of photovoltaic panel.
Embodiment
With reference to embodiment, the present invention is described in further detail, to make those skilled in the art with reference to specification Word can be implemented according to this.
This case proposes the packaging plastic for solar opto-electronic board of an embodiment, includes the material of following parts by weight:
Wherein, in ethylene-acrylic acid hydroxyl ethyl ester copolymer, the content of vinyl monomer is preferably 33~35wt%, and remaining is Vinyl Acetate Monomer.
Wherein, the number-average molecular weight of ethylene-acrylic acid hydroxyl ethyl ester copolymer is preferably 16000~20000g/mol.
Wherein, the number-average molecular weight of polyethyl methacrylate is preferably 30000~35000g/mol.Wherein, polyamides is sub- The number-average molecular weight of amine is preferably 23000~26000g/mol.
Wherein, the number-average molecular weight of polyethylene glycol is preferably 4000~5000g/mol.
Wherein, it may preferably further comprise the barium monoxide of 0.2~0.3 parts by weight.
Wherein, it may preferably further comprise the magnesia of 0.2~0.3 parts by weight.
Table one lists the concrete composition and its performance parameter of the packaging plastic of different embodiments:
Table one
* limit tolerance time of ultraviolet irradiation/25W, 20 DEG C refer to:At 20 DEG C, irradiate, encapsulate under 25W UV intensity Glue meets non-yellowing, does not harden, does not ftracture, the adhesion strength range of decrease is less than the 5% most long irradiation time that can bear.Following table is same.
Table two lists the concrete composition and its performance parameter of the packaging plastic of different comparative examples:
Table two
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited In specific details.

Claims (8)

1. a kind of packaging plastic for solar opto-electronic board, include the material of following parts by weight:
2. the packaging plastic according to claim 1 for solar opto-electronic board, it is characterised in that the ethylene-acrylic acid In hydroxyl ethyl ester copolymer, the content of vinyl monomer is 33~35wt%, and remaining is Vinyl Acetate Monomer.
3. the packaging plastic according to claim 1 for solar opto-electronic board, it is characterised in that the ethylene-acrylic acid The number-average molecular weight of hydroxyl ethyl ester copolymer is 16000~20000g/mol.
4. the packaging plastic according to claim 1 for solar opto-electronic board, it is characterised in that the polymethylacrylic acid The number-average molecular weight of ethyl ester is 30000~35000g/mol.
5. the packaging plastic according to claim 1 for solar opto-electronic board, it is characterised in that the number of the polyimides Average molecular weight is 23000~26000g/mol.
6. the packaging plastic according to claim 1 for solar opto-electronic board, it is characterised in that the number of the polyethylene glycol Average molecular weight is 4000~5000g/mol.
7. the packaging plastic according to claim 1 for solar opto-electronic board, it is characterised in that also including 0.2~0.3 weight Measure the barium monoxide of part.
8. the packaging plastic according to claim 7 for solar opto-electronic board, it is characterised in that also including 0.2~0.3 weight Measure the magnesia of part.
CN201780001758.9A 2017-06-01 2017-06-01 Packaging plastic for solar opto-electronic board Pending CN107735473A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2017/086810 WO2018218594A1 (en) 2017-06-01 2017-06-01 Packaging adhesive for solar photovoltaic board

Publications (1)

Publication Number Publication Date
CN107735473A true CN107735473A (en) 2018-02-23

Family

ID=61220309

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780001758.9A Pending CN107735473A (en) 2017-06-01 2017-06-01 Packaging plastic for solar opto-electronic board

Country Status (2)

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CN (1) CN107735473A (en)
WO (1) WO2018218594A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018218594A1 (en) * 2017-06-01 2018-12-06 苏州佳亿达电器有限公司 Packaging adhesive for solar photovoltaic board
CN114989748A (en) * 2022-07-05 2022-09-02 苏州地枢新材料科技有限公司 Adhesive for mounting luminous floor tiles and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1124754A (en) * 1995-03-23 1996-06-19 张福增 Flash set adhesive and its preparing process
CN101275059A (en) * 2007-03-28 2008-10-01 刘萍 Heat-resistant strippable micro-viscous pressure-sensitive adhesive film and preparation thereof
CN104745109A (en) * 2015-04-16 2015-07-01 中天光伏材料有限公司 White EVA adhesive film for photovoltaic module encapsulation
CN106010422A (en) * 2016-06-29 2016-10-12 龚灿锋 Binding agent for assembling solar panel

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5352716A (en) * 1992-12-16 1994-10-04 Ecostar International, L.P. Degradable synthetic polymeric compounds
JP2005036077A (en) * 2003-07-18 2005-02-10 Sumitomo Chemical Co Ltd Adhesive film
JP6427947B2 (en) * 2014-05-15 2018-11-28 凸版印刷株式会社 Gas barrier packaging materials
WO2018218594A1 (en) * 2017-06-01 2018-12-06 苏州佳亿达电器有限公司 Packaging adhesive for solar photovoltaic board

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1124754A (en) * 1995-03-23 1996-06-19 张福增 Flash set adhesive and its preparing process
CN101275059A (en) * 2007-03-28 2008-10-01 刘萍 Heat-resistant strippable micro-viscous pressure-sensitive adhesive film and preparation thereof
CN104745109A (en) * 2015-04-16 2015-07-01 中天光伏材料有限公司 White EVA adhesive film for photovoltaic module encapsulation
CN106010422A (en) * 2016-06-29 2016-10-12 龚灿锋 Binding agent for assembling solar panel

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018218594A1 (en) * 2017-06-01 2018-12-06 苏州佳亿达电器有限公司 Packaging adhesive for solar photovoltaic board
CN114989748A (en) * 2022-07-05 2022-09-02 苏州地枢新材料科技有限公司 Adhesive for mounting luminous floor tiles and preparation method and application thereof

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Application publication date: 20180223