CN107726729A - A kind of liquefied natural gas condensation method and device again - Google Patents

A kind of liquefied natural gas condensation method and device again Download PDF

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Publication number
CN107726729A
CN107726729A CN201610656334.3A CN201610656334A CN107726729A CN 107726729 A CN107726729 A CN 107726729A CN 201610656334 A CN201610656334 A CN 201610656334A CN 107726729 A CN107726729 A CN 107726729A
Authority
CN
China
Prior art keywords
lng
gas
bog
condenser pipe
pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610656334.3A
Other languages
Chinese (zh)
Inventor
王以斌
李战杰
常征
何建明
王文昊
何龙辉
李津
王惠勤
杜富国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Engineering Group Co Ltd
Sinopec Luoyang Guangzhou Engineering Co Ltd
Original Assignee
Sinopec Luoyang Petrochemical Engineering Corp
Sinopec Engineering Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sinopec Luoyang Petrochemical Engineering Corp, Sinopec Engineering Group Co Ltd filed Critical Sinopec Luoyang Petrochemical Engineering Corp
Priority to CN201610656334.3A priority Critical patent/CN107726729A/en
Publication of CN107726729A publication Critical patent/CN107726729A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022Hydrocarbons, e.g. natural gas
    • F25J1/0025Boil-off gases "BOG" from storages
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/004Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

The invention discloses a kind of liquefied natural gas condensation method and device again.The condensation method again is:BOG from house steward BOG enters horizontal condenser pipe after being mixed after compression with the LNG from LNG low-pressure manifolds, and mixing contact is carried out in the form of multiphase flow through the upset of multiple gas-liquid, condenses recovery BOG, condenses the LNG after recovery BOG and enters surge tank progress gas-liquid separation;Described condensing unit again is mainly made up of horizontal condenser pipe and surge tank, and with being connected in the middle part of surge tank, horizontal condenser pipe is mainly alternately formed by connecting horizontal condenser pipe by gas-liquid turner and condensation straight pipe.This invention simplifies the controlling unit for condensing link again and eliminating complexity of LNG receiving stations technique, security and economic benefit that LNG receiving stations operate are improved.

Description

A kind of liquefied natural gas condensation method and device again
Technical field
The present invention relates to a kind for the treatment of technology of natural gas vaporization gas (BOG), specifically, is related to a kind of liquefaction day Right gas (LNG) condensation method and device again.
Background technology
Liquefied natural gas receiving station is the terminal link in LNG industry chain, is received from LNG ship liquefied natural gas and through storage Deposit, regasify after be conveyed to downstream user, due to the operating of pump, environment leakage heat and unload the displacement of ship time in receiving station's system Effect, equipment pipe cold insulation etc. can all cause the liquefied natural gas gasifying under extremely low temperature (- 162 DEG C) to produce boil-off gas (BOG).
LNG receiving stations BOG recovery processing techniques mainly include directly compression it is outer it is defeated with LNG is condensed into by after-condenser after Pressurization, gasification are simultaneously outer defeated, and the directly outer defeated technique of compression needs defeated pipe network outside the supporting low-voltage customer in downstream or low pressure, and domestic Defeated pipe network is generally high pressure pipe network and lacks related supporting industry outside the downstream of LNG receiving stations, therefore all using condensing work again Skill handles BOG gases, and foreign countries are also frequently with this technique.
For LNG boil-off gas using when condensing recovery process again, after-condenser is the capital equipment in process system, is entirely being connect Receive in the operation of station and play the central role taken over from the past and set a new course for the future, its major function is mainly that BOG and LNG provide enough times of contact Promote BOG to be condensed into LNG with space and ensure the inlet pressure of high-pressure pump as the inlet buffer of LNG high-pressure pumps, then The Stress control of condenser involves the Collaborative Control of the multi-parameters such as liquid level, pressure, temperature, flow and to ensure high pressure pump inlet Pressure stability, control mode is complex and control effect is not ideal enough.
The content of the invention
Control mode is complex and the dissatisfactory technical problem of control effect in order to solve existing for prior art, this Invention provides a kind of liquefied natural gas condensation method and device again.
Condensation method comprises the following steps liquefied natural gas provided by the invention again:
1) horizontal condenser pipe is entered after the BOG from house steward BOG mixes with the LNG from LNG low-pressure manifolds after compression;
2) BOG and LNG entered in horizontal condenser pipe is in horizontal condenser pipe through gas-liquid is overturn with multiphase twice or repeatedly Manifold formula carries out mixing contact, to promote BOG condensation to reclaim;
3) LNG after condensation recovery BOG enters surge tank progress gas-liquid separation after leaving horizontal condenser pipe, isolates not Solidifying gas is discharged into house steward BOG, and the LNG after separating fixed gas is discharged by surge tank outlet at bottom.
Present invention also offers a kind of liquefied natural gas after-condenser device, and the device is mainly by horizontal condenser pipe and surge tank Composition, with being connected in the middle part of surge tank, horizontal condenser pipe is mainly alternately connected horizontal condenser pipe by gas-liquid turner and condensation straight pipe Form.
The gas-liquid turner is overall in a tubular form, is mainly made up of shell and upset blade, and shell is pipe, overturns blade It is fixed on inner wall of tube shell.
Described upset blade is in 180 ° of helical forms, and its diameter is equal to shell internal diameter, the seamed edge of upset blade rear and front end It is parallel to each other, seamed edge length is equal to upset blade diameter, and the strip blade that upset blade is equal to shell internal diameter by width rotates Formed after 180 °, the state arrangement that upset blade is horizontal in shell with plane where the seamed edge of rear and front end, upset Blade will divide into two helical channels inside shell.
The shell internal diameter that the length of the upset blade is 2~3 times, gas-liquid turner can use flange with condensation straight pipe Connection can also use welding manner.
As improved plan, described horizontal condenser pipe porch is provided with entrance expansion tube, entrance expansion tube can To relax impact of the material to horizontal condenser pipe.
In operation, the BOG from house steward BOG is mixed the device of the present invention with the LNG from LNG low-pressure manifolds after compression Enter horizontal condenser pipe after conjunction, in horizontal condenser pipe, fluid-mixing fluid (BOG is principal phase) and lower floor fluid (LNG at the middle and upper levels For principal phase) just inverted after 180 ° of two helical ducts upset of gas-liquid turner respectively, (BOG is top fluid Principal phase) lower floor is come, lower floor's fluid (LNG is principal phase) comes upper strata, serves the effect for being sufficiently mixed gas-liquid two-phase;Work as BOG With LNG multiphase flow in condensation straight pipe because Action of Gravity Field recovers after proper flow again by next gas-liquid turner Upset, is sufficiently mixed gas-liquid two-phase again, and BOG passes through twice with LNG multiphase flow or multiple upset mixes, and BOG is obtained Arrived it is sufficient condensation recovery, condensation recovery BOG after LNG enter surge tank carry out gas-liquid separation, the fixed gas isolated by Atmospheric valve at the top of surge tank is discharged into house steward BOG, and the LNG after separating fixed gas is discharged by surge tank outlet at bottom.
Advantages of the present invention is cold again using duct type innovatively to propose a kind of duct type condensation method and device again Solidifying mode carries out BOG condensation recovery, sets gas-liquid turner in the duct, is overturn by multiple gas-liquid, be BOG and LNG Provide enough times of contact and space, BOG is sufficiently mixed with LNG, be greatly promoted BOG condensation recovery, by Level condensation pipe end is that the entrance of LNG high-pressure pumps sets surge tank to ensure that the inlet pressure of LNG high-pressure pumps is stable, is simplified LNG receiving stations technique condense again link and eliminate complexity controlling unit, improve LNG receiving stations operation security and Economic benefit.
Brief description of the drawings
Fig. 1 is the structural representation of condensing unit again of the invention;
Fig. 2 is the structural representation of gas-liquid turner in Fig. 1;
Fig. 3 is the structural representation that blade is overturn in Fig. 2;
Fig. 4 is the dimensional structure diagram of Fig. 3 upset blades.
In figure:1- entrance expansion tubes, 2- condensation straight pipes, 3- gas-liquid turners, 4- surge tanks, 5- shells, 6- upset blades, 7- front ends seamed edge, 8- rear ends seamed edge.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention will be further described.
Referring to Fig. 1, liquefied natural gas after-condenser device of the invention is mainly by entrance expansion tube 1, condensation straight pipe 2, gas-liquid Turner 3 and surge tank 4 form, and wherein alternately connection forms horizontal condenser pipe for gas-liquid turner 3 and condensation straight pipe 2, horizontal cold Solidifying Guan Yiyi sections condensation straight pipe is connected with the middle part of surge tank 4, and gas-liquid turner 3 can be connected with condensation straight pipe 2 using flange Welding manner can also be used.
Referring to Fig. 2~4, gas-liquid turner is overall in a tubular form, is mainly made up of shell 5 and upset blade 6, and shell 5 is circle Pipe;Blade 6 is overturn by being fixedly welded on the inwall of shell 5, in 180 ° of helical forms, its diameter is equal to the internal diameter of shell 5, overturns leaf The front end seamed edge 7 and rear end seamed edge 8 of piece 6 are parallel to each other, and seamed edge length is equal to the upset diameter of blade 6, and upset blade 6 is by width etc. Formed after the strip blade of shell internal diameter rotates 180 °, upset blade 6 is in shell with front end seamed edge 7 and rear end seamed edge 8 The state arrangement that place plane is horizontal, upset blade 6 will divide into two helical channels inside shell.
During operation, the BOG from house steward BOG is expanding through entrance after being mixed after compression with the LNG from LNG low-pressure manifolds The cushioning effect of pipe 1 enters horizontal condenser pipe, passes sequentially through the condensation straight pipe 2 being alternately arranged and gas-liquid turner 3, fluid-mixing Fluid (BOG is principal phase) passes through two helical ducts of gas-liquid turner 3 with lower floor's fluid (LNG is principal phase) respectively at the middle and upper levels Just inverted after 180 ° of upsets, top fluid (BOG is principal phase) comes lower floor, and lower floor's fluid (LNG is principal phase) is come Layer, serves the effect for being sufficiently mixed gas-liquid two-phase;BOG passes through twice with LNG multiphase flow or multiple upset mixes, BOG Sufficient condensation recovery has been obtained, the LNG after recovery BOG has been condensed and carries out gas-liquid separation, the fixed gas isolated into surge tank 4 House steward BOG is discharged into by surge tank top exit, the LNG after separating fixed gas is discharged by surge tank outlet at bottom.

Claims (7)

1. a kind of liquefied natural gas condensation method again, it is characterised in that comprise the following steps:
1) horizontal condenser pipe is entered after the BOG from house steward BOG mixes with the LNG from LNG low-pressure manifolds after compression;
2) overturn into the BOG in horizontal condenser pipe and LNG in horizontal condenser pipe through obtaining multiple gas-liquid twice with multiphase manifold Formula carries out mixing contact, to promote BOG condensation to reclaim;
3) LNG after condensation recovery BOG enters surge tank progress gas-liquid separation, the fixed gas isolated after leaving horizontal condenser pipe House steward BOG is discharged into, the LNG after separating fixed gas is discharged by surge tank outlet at bottom.
A kind of 2. liquefied natural gas after-condenser device, it is characterised in that:Mainly it is made up of horizontal condenser pipe and surge tank, it is horizontal cold With being connected in the middle part of surge tank, horizontal condenser pipe is mainly alternately formed by connecting solidifying pipe by gas-liquid turner and condensation straight pipe.
3. device according to claim 2, it is characterised in that:The gas-liquid turner is overall in a tubular form, mainly by shell With upset blade composition, shell is pipe, and upset blade is fixed on inner wall of tube shell.
4. device according to claim 3, it is characterised in that:The upset blade is in 180 ° of helical forms, and its diameter is equal to Shell internal diameter, the seamed edge of upset blade rear and front end are parallel to each other, and seamed edge length is equal to upset blade diameter, and upset blade is by width Degree is formed after rotating 180 ° equal to the strip blade of shell internal diameter, and upset blade is in shell with flat where the seamed edge of rear and front end The state arrangement that face is horizontal, upset blade will divide into two helical channels inside shell.
5. the device according to claim 3 or 4, it is characterised in that:The shell that the length of the upset blade is 2~3 times Internal diameter.
6. device according to claim 2, it is characterised in that:The gas-liquid turner is connected with condensation straight pipe using flange Or using welding manner.
7. device according to claim 2, it is characterised in that:It is expanding that the horizontal condenser pipe porch is provided with entrance Pipe.
CN201610656334.3A 2016-08-11 2016-08-11 A kind of liquefied natural gas condensation method and device again Pending CN107726729A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115282744A (en) * 2022-08-04 2022-11-04 合肥科安设备安装有限公司 Natural gas recovery device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1971197A (en) * 2005-11-23 2007-05-30 三星电子株式会社 Piping for heat exchanger and refrigerating system using same
CN101881549A (en) * 2010-06-25 2010-11-10 华南理工大学 Re-condensation reclaiming system for evaporated gas of liquefied natural gas receiving station and reclaiming method thereof
CN104034122A (en) * 2013-03-04 2014-09-10 中国石化工程建设有限公司 System and method for re-condensing boil off gas (BOG) of liquefied natural gas
CN104321581A (en) * 2011-12-02 2015-01-28 氟石科技公司 LNG boiloff gas recondensation configurations and methods
CN104913196A (en) * 2015-07-07 2015-09-16 中国海洋石油总公司 BOG (boil-off gas) treatment process and device under normal operation condition of LNG (liquefied natural gas) receiving station
CN205027154U (en) * 2015-09-22 2016-02-10 江苏中圣压力容器装备制造有限公司 Novel flash distillation vapour aftercooling congeals heat exchanger

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1971197A (en) * 2005-11-23 2007-05-30 三星电子株式会社 Piping for heat exchanger and refrigerating system using same
CN101881549A (en) * 2010-06-25 2010-11-10 华南理工大学 Re-condensation reclaiming system for evaporated gas of liquefied natural gas receiving station and reclaiming method thereof
CN104321581A (en) * 2011-12-02 2015-01-28 氟石科技公司 LNG boiloff gas recondensation configurations and methods
CN104034122A (en) * 2013-03-04 2014-09-10 中国石化工程建设有限公司 System and method for re-condensing boil off gas (BOG) of liquefied natural gas
CN104034122B (en) * 2013-03-04 2016-02-10 中国石化工程建设有限公司 A kind of natural gas vaporization gas condenser system and method again
CN104913196A (en) * 2015-07-07 2015-09-16 中国海洋石油总公司 BOG (boil-off gas) treatment process and device under normal operation condition of LNG (liquefied natural gas) receiving station
CN205027154U (en) * 2015-09-22 2016-02-10 江苏中圣压力容器装备制造有限公司 Novel flash distillation vapour aftercooling congeals heat exchanger

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115282744A (en) * 2022-08-04 2022-11-04 合肥科安设备安装有限公司 Natural gas recovery device

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Application publication date: 20180223