CN107724061A - A kind of multi-functional anti-ultraviolet finishing agent and preparation method thereof - Google Patents
A kind of multi-functional anti-ultraviolet finishing agent and preparation method thereof Download PDFInfo
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- CN107724061A CN107724061A CN201710913820.3A CN201710913820A CN107724061A CN 107724061 A CN107724061 A CN 107724061A CN 201710913820 A CN201710913820 A CN 201710913820A CN 107724061 A CN107724061 A CN 107724061A
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- parts
- finishing agent
- functional anti
- ultraviolet finishing
- ultraviolet
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- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 73
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 53
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 241000219357 Cactaceae Species 0.000 claims abstract description 21
- 229920001661 Chitosan Polymers 0.000 claims abstract description 21
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 21
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910021538 borax Inorganic materials 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 21
- 239000001540 sodium lactate Substances 0.000 claims abstract description 21
- 229940005581 sodium lactate Drugs 0.000 claims abstract description 21
- 235000011088 sodium lactate Nutrition 0.000 claims abstract description 21
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 21
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 21
- 235000003417 Plumeria rubra f acutifolia Nutrition 0.000 claims abstract description 20
- 244000040691 Plumeria rubra f. acutifolia Species 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 20
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 20
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 20
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 20
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000001301 oxygen Substances 0.000 claims abstract description 9
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 235000019441 ethanol Nutrition 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 14
- 238000007664 blowing Methods 0.000 claims description 7
- 238000005538 encapsulation Methods 0.000 claims description 7
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- 125000005233 alkylalcohol group Chemical group 0.000 claims 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 230000008859 change Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 206010015150 Erythema Diseases 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000321 erythema Toxicity 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 201000009030 Carcinoma Diseases 0.000 description 1
- 206010056474 Erythrosis Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 244000046101 Sophora japonica Species 0.000 description 1
- 235000010586 Sophora japonica Nutrition 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 208000007442 rickets Diseases 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000007920 subcutaneous administration Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
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- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- D06M2200/30—Flame or heat resistance, fire retardancy properties
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Abstract
The invention discloses a kind of multi-functional anti-ultraviolet finishing agent and preparation method thereof, the multi-functional anti-ultraviolet finishing agent is made up of the raw material of following parts by weight：57 parts of nano zine oxide, 35 parts of magnesium hydroxide, 12 parts of triethanolamine, 10 20 parts of ethanol, 5 10 parts of modified polyorganosiloxane, 35 parts of ammonium chloride, 35 parts of sodium acid carbonate, 5 10 parts of Pagodatree Flower, 35 parts of cactus powder, 35 parts of borax, 35 parts of chitosan, 5 10 parts of sodium lactate, 35 parts of AEO, 30 40 parts of deionized water.After the multi-functional anti-ultraviolet finishing agent application fabric of the present invention, the ultraviolet ray transmissivity of fabric is no more than 4%, and limited oxygen index is more than 28%, and Wind-proof, moisture-permeability excellent performance is soft.The multi-functional anti-ultraviolet finishing agent manufacturing process of the present invention is simple to operation, and low in raw material price is easily obtained, and nontoxic, and human body is not stimulated, and volatility is low, and the fabric after arrangement its toughness, intensity are substantially unaffected.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relates to a kind of multi-functional anti-ultraviolet finishing agent and its system
Preparation Method.
Background technology
It is ultraviolet that ultraviolet (ultraviolet rays abbreviation UV) is divided into long wave ultraviolet (UV-A, 320-400nm), medium wave
Line (UV-B, 280-320nm) and short wave ultraviolet (UV-C, 200-280nm).UV-B effect is 1000 times of UV-A, summer
Mildew mainly due to UV-B effect, veins beneath the skin absorb UV-B after can cause expansion make erythrosis produce erythema, sternly
It can be inflamed during weight.It can also equally have influence on subcutaneous elastomer, skin is followed the string, and form coarse wrinkle,
UB-C has certain bactericidal action as a kind of stronger ultraviolet, but also harmful.Generally speaking, ultraviolet C can not
Ground is reached, but due to the raising of fluorinated volume in air in recent years, the UV-B and C for reaching ground are consequently increased.According to the study
Show, appropriate ultraviolet is beneficial to human body：It can promote the synthesis of vitamin D, have inhibitory action to rickets, and have
There is sterilization.But excessive ultraviolet is extremely harmful to human body, and it can not only increase human body melanin, make skin
Skin aging, it is serious skin is got blister, erythema, or even can also cause cutaneum carcinoma.
Anti-uv finishing is by strengthening fabric to the reflection of the absorbability of ultraviolet or enhancing fabric to ultraviolet
Ability reduces the transit dose of ultraviolet.After multi-functional anti-uv finishing, ultraviolet is absorbed fabric by fabric, therefore thoroughly
The ultraviolet quantity for crossing fabric is greatly reduced, and has good multifunctional protection to act on to human body.Arranged by ultra-violet absorber,
The light aging of fiber, the fastness to light of dyed fabric also can all substantially improve, so multifunctional protection effect is many, use
Way and many-side.
The transmitance of the fabric ultraviolet by anti-uv finishing in the market is 3% or so, washing fastness
Difference, and the feel of the fabric script after arranging, the performance such as ventilative is changed, therefore is found a kind of high performance multi-functional
Anti-ultraviolet finishing agent is current urgent problem.
The content of the invention
It is an object of the invention to provide a kind of multi-functional anti-ultraviolet finishing agent and preparation method, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：Nano zine oxide 5-7 parts, hydrogen
Magnesia 3-5 parts, triethanolamine 1-2 parts, ethanol 10-20 parts, modified polyorganosiloxane 5-10 parts, ammonium chloride 3-5 parts, sodium acid carbonate
3-5 parts, Pagodatree Flower 5-10 parts, cactus powder 3-5 parts, borax 3-5 parts, chitosan 3-5 parts, sodium lactate 5-10 parts, fat
Alcohol APEO 3-5 parts, deionized water 30-40 parts.
Preferably, the ethanol in described multi-functional anti-ultraviolet finishing agent is absolute ethyl alcohol, and purity is pure to analyze.
Preferably, described multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：It is nano oxidized
5 parts of zinc, 3 parts of magnesium hydroxide, 1 part of triethanolamine, 10 parts of ethanol, 5 parts of modified polyorganosiloxane, 3 parts of ammonium chloride, 3 parts of sodium acid carbonate,
5 parts of Pagodatree Flower, 3 parts of cactus powder, 3 parts of borax, 3 parts of chitosan, 5 parts of sodium lactate, 3 parts of AEO, go
30 parts of ionized water.
Preferably, described multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：It is nano oxidized
6 parts of zinc, 4 parts of magnesium hydroxide, 1.5 parts of triethanolamine, 15 parts of ethanol, 8 parts of modified polyorganosiloxane, 4 parts of ammonium chloride, sodium acid carbonate 4
Part, 8 parts of Pagodatree Flower, 4 parts of cactus powder, 4 parts of borax, 4 parts of chitosan, 8 parts of sodium lactate, 4 parts of AEO,
35 parts of deionized water.
Preferably, described multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：It is nano oxidized
7 parts of zinc, 5 parts of magnesium hydroxide, 2 parts of triethanolamine, 20 parts of ethanol, 10 parts of modified polyorganosiloxane, 5 parts of ammonium chloride, sodium acid carbonate 5
Part, 10 parts of Pagodatree Flower, 5 parts of cactus powder, 5 parts of borax, 5 parts of chitosan, 10 parts of sodium lactate, AEO 5
Part, 40 parts of deionized water.
A kind of preparation method of multi-functional anti-ultraviolet finishing agent, is comprised the following steps that：
(1) deionized water 30-40 parts are added in a kettle, and rise temperature is to 60-70 DEG C；
(2) modified polyorganosiloxane 5-10 parts, magnesium hydroxide 3-5 parts, AEO 3-5 parts, 500- are added
1000 revs/min, stir 20-30 minutes；
(3) first by nano zine oxide 5-7 parts, triethanolamine 1-2 parts, ethanol 10-20 parts, with ultrasonic disperse, ultrasonic power
For 500-1000W, ultrasonic time is 20-30 minutes；
(4) solution of step (3) is added in the solution of step (2), 500-1000 revs/min, 10-20 points of stirring
Clock；
(5) be cooled to 30-40 DEG C, add ammonium chloride 3-5 parts, sodium acid carbonate 3-5 parts, borax 3-5 parts, chitosan 3-5 parts,
Sodium lactate 5-10 parts, Pagodatree Flower 5-10 parts, cactus powder 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；
(6) stirring is closed down, the multi-functional anti-ultraviolet finishing agent of the liquid prepared；
(7) stand and be cooled to the multi-functional anti-ultraviolet finishing agent of liquid in stirred tank less than 20 DEG C, blowing encapsulation, be made into
Product.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, after multi-functional anti-ultraviolet finishing agent application fabric of the invention, the ultraviolet ray transmissivity of fabric is no more than
4%, limited oxygen index is more than 28%, and Wind-proof, moisture-permeability excellent performance is soft.
2nd, multi-functional anti-ultraviolet finishing agent manufacturing process of the invention is simple to operation, and low in raw material price easily obtains,
And it is nontoxic, human body is not stimulated, volatility is low, the fabric after arrangement its toughness, color and luster, feel, intensity and color fastness base
This is unaffected.
3rd, mutual compatibility, synergy between various raw materials used in multi-functional anti-ultraviolet finishing agent of the invention, jointly
The excellent product of component property.
4th, multi-functional anti-ultraviolet finishing agent of the invention absorbs the wave-length coverage broadness of ultraviolet, works well.
5th, multi-functional anti-ultraviolet finishing agent of the invention is water-fastness and dry-cleans, and to light, thermally and chemically product are stable.
6th, multi-functional anti-ultraviolet finishing agent of the invention is in application process, absorbs not yellowing after ultraviolet, does not produce
Poisonous gas or solid matter.
7th, technique is simplified, safe operation is simple, is easy to industrialized production.
8th, multi-functional anti-ultraviolet finishing agent construction is simple of the invention, can by impregnating, spraying, roller coat etc. applied
Add, production efficiency improves.
9th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：Nano oxygen
Change zinc 5-7 parts, magnesium hydroxide 3-5 parts, triethanolamine 1-2 parts, ethanol 10-20 parts, modified polyorganosiloxane 5-10 parts, ammonium chloride 3-
5 parts, sodium acid carbonate 3-5 parts, Pagodatree Flower 5-10 parts, cactus powder 3-5 parts, borax 3-5 parts, chitosan 3-5 parts, sodium lactate
5-10 parts, AEO 3-5 parts, deionized water 30-40 parts.
Present invention also offers a kind of preparation method of multi-functional anti-ultraviolet finishing agent, comprise the following steps that：
(1) deionized water 30-40 parts are added in a kettle, and rise temperature is to 60-70 DEG C；
(2) modified polyorganosiloxane 5-10 parts, magnesium hydroxide 3-5 parts, AEO 3-5 parts, 500- are added
1000 revs/min, stir 20-30 minutes；
(3) first by nano zine oxide 5-7 parts, triethanolamine 1-2 parts, ethanol 10-20 parts, with ultrasonic disperse, ultrasonic power
For 500-1000W, ultrasonic time is 20-30 minutes；
(4) solution of step (3) is added in the solution of step (2), 500-1000 revs/min, 10-20 points of stirring
Clock；
(5) be cooled to 30-40 DEG C, add ammonium chloride 3-5 parts, sodium acid carbonate 3-5 parts, borax 3-5 parts, chitosan 3-5 parts,
Sodium lactate 5-10 parts, Pagodatree Flower 5-10 parts, cactus powder 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；
(6) stirring is closed down, the multi-functional anti-ultraviolet finishing agent of the liquid prepared；
(7) stand and be cooled to the multi-functional anti-ultraviolet finishing agent of liquid in stirred tank less than 20 DEG C, blowing encapsulation, be made into
Product.
Embodiment 1
The invention discloses a kind of multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：Nano oxygen
Change 5 parts of zinc, 3 parts of magnesium hydroxide, 1 part of triethanolamine, 10 parts of ethanol, 5 parts of modified polyorganosiloxane, 3 parts of ammonium chloride, sodium acid carbonate 3
Part, 5 parts of Pagodatree Flower, 3 parts of cactus powder, 3 parts of borax, 3 parts of chitosan, 5 parts of sodium lactate, 3 parts of AEO,
30 parts of deionized water.
Present invention also offers a kind of preparation method of multi-functional anti-ultraviolet finishing agent, comprise the following steps that：
(1) 30 parts of deionized water is added in a kettle, and rise temperature is to 60 DEG C；
(2) 5 parts of modified polyorganosiloxane, 3 parts of magnesium hydroxide, 3 parts of AEO are added, 500 revs/min, is stirred
Mix 20 minutes；
(3) first by 5 parts of nano zine oxide, 1 part of triethanolamine, 10 parts of ethanol, with ultrasonic disperse, ultrasonic power 500W,
Ultrasonic time is 20 minutes；
(4) solution of step (3) is added in the solution of step (2), 500 revs/min, stirred 10 minutes；
(5) be cooled to 30 DEG C, add 3 parts of ammonium chloride, 3 parts of sodium acid carbonate, 3 parts of borax, 3 parts of chitosan, 5 parts of sodium lactate,
5 parts of Pagodatree Flower, 3 parts of cactus powder, 500 revs/min, stir 30 minutes；
(6) stirring is closed down, the multi-functional anti-ultraviolet finishing agent of the liquid prepared；
(7) stand and be cooled to the multi-functional anti-ultraviolet finishing agent of liquid in stirred tank less than 20 DEG C, blowing encapsulation, be made into
Product.
Embodiment 2
The invention discloses a kind of multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：Nano oxygen
Change 6 parts of zinc, 4 parts of magnesium hydroxide, 1.5 parts of triethanolamine, 15 parts of ethanol, 8 parts of modified polyorganosiloxane, 4 parts of ammonium chloride, sodium acid carbonate
4 parts, 8 parts of Pagodatree Flower, 4 parts of cactus powder, 4 parts of borax, 4 parts of chitosan, 8 parts of sodium lactate, AEO 4
Part, 35 parts of deionized water.
Present invention also offers a kind of preparation method of multi-functional anti-ultraviolet finishing agent, comprise the following steps that：
(1) 35 parts of deionized water is added in a kettle, and rise temperature is to 65 DEG C；
(2) 8 parts of modified polyorganosiloxane, 4 parts of magnesium hydroxide, 4 parts of AEO are added, 800 revs/min, is stirred
Mix 25 minutes；
(3) first by 6 parts of nano zine oxide, 1.5 parts of triethanolamine, 15 parts of ethanol, with ultrasonic disperse, ultrasonic power is
800W, ultrasonic time are 25 minutes；
(4) solution of step (3) is added in the solution of step (2), 900 revs/min, stirred 15 minutes；
(5) 35 DEG C are cooled to, adds 4 parts of chlorination, 4 parts of sodium acid carbonate, 4 parts of borax, 4 parts of chitosan, 8 parts of sodium lactate, Chinese scholartree
Pollen end 8 parts, 4 parts of cactus powder, are stirred 25 minutes by 800 revs/min；
(6) stirring is closed down, the multi-functional anti-ultraviolet finishing agent of the liquid prepared；
(7) stand and be cooled to the multi-functional anti-ultraviolet finishing agent of liquid in stirred tank less than 20 DEG C, blowing encapsulation, be made into
Product.
Embodiment 3
The invention discloses a kind of multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：Nano oxygen
Change 7 parts of zinc, 5 parts of magnesium hydroxide, 2 parts of triethanolamine, 20 parts of ethanol, 10 parts of modified polyorganosiloxane, 5 parts of ammonium chloride, sodium acid carbonate 5
Part, 10 parts of Pagodatree Flower, 5 parts of cactus powder, 5 parts of borax, 5 parts of chitosan, 10 parts of sodium lactate, AEO 5
Part, 40 parts of deionized water.
Present invention also offers a kind of preparation method of multi-functional anti-ultraviolet finishing agent, comprise the following steps that：
(1) 40 parts of deionized water is added in a kettle, and rise temperature is to 70 DEG C；
(2) 10 parts of modified polyorganosiloxane of addition, 5 parts of magnesium hydroxide, 5 parts of AEO, 1000 revs/min,
Stirring 30 minutes；
(3) first by 7 parts of nano zine oxide, 2 parts of triethanolamine, 20 parts of ethanol, with ultrasonic disperse, ultrasonic power 1000W,
Ultrasonic time is 30 minutes；
(4) solution of step (3) is added in the solution of step (2), 1000 revs/min, stirred 20 minutes；
(5) be cooled to 40 DEG C, add 5 parts of ammonium chloride, 5 parts of sodium acid carbonate, 5 parts of borax, 5 parts of chitosan, 10 parts of sodium lactate,
10 parts of Pagodatree Flower, 5 parts of cactus powder, 1000 revs/min, stir 30 minutes；
(6) stirring is closed down, the multi-functional anti-ultraviolet finishing agent of the liquid prepared；
(7) stand and be cooled to the multi-functional anti-ultraviolet finishing agent of liquid in stirred tank less than 20 DEG C, blowing encapsulation, be made into
Product.
Embodiment 4
The invention discloses a kind of multi-functional anti-ultraviolet finishing agent, according to parts by weight, including following components：Nano oxygen
Change 7 parts of zinc, 5 parts of magnesium hydroxide, 2 parts of triethanolamine, 15 parts of ethanol, 5 parts of modified polyorganosiloxane, 4 parts of ammonium chloride, sodium acid carbonate 4
Part, 10 parts of Pagodatree Flower, 4 parts of cactus powder, 4 parts of borax, 4 parts of chitosan, 8 parts of sodium lactate, AEO 4
Part, 30 parts of deionized water.
Present invention also offers a kind of preparation method of multi-functional anti-ultraviolet finishing agent, comprise the following steps that：
(1) 30 parts of deionized water is added in a kettle, and rise temperature is to 65 DEG C；
(2) 5 parts of modified polyorganosiloxane, 5 parts of magnesium hydroxide, 4 parts of AEO are added, 1000 revs/min, is stirred
Mix 20 minutes；
(3) first by 7 parts of nano zine oxide, 2 parts of triethanolamine, 15 parts of ethanol, with ultrasonic disperse, ultrasonic power 800W,
Ultrasonic time is 25 minutes；
(4) solution of step (3) is added in the solution of step (2), 900 revs/min, stirred 20 minutes；
(5) be cooled to 35 DEG C, add 4 parts of ammonium chloride, 4 parts of sodium acid carbonate, 4 parts of borax, 4 parts of chitosan, 8 parts of sodium lactate,
10 parts of Pagodatree Flower, 4 parts of cactus powder, 1000 revs/min, stir 30 minutes；
(6) stirring is closed down, the multi-functional anti-ultraviolet finishing agent of the liquid prepared；
(7) stand and be cooled to the multi-functional anti-ultraviolet finishing agent of liquid in stirred tank less than 20 DEG C, blowing encapsulation, be made into
Product.
Test case
4 pieces of identical fabrics are put into the multi-functional anti-ultraviolet finishing agent solution of embodiment 1,2,3,4 and padded, passed through
Two leachings two are rolled, and then heat to 100-110 DEG C of prebake, then are dried at 130-150 DEG C, are then cleaned with 50 DEG C of hot water, finally
With cold water flush, dried after cleaning, 4 pieces of cloth with multi-functional ultraviolet resistance can be obtained.Test result is as follows：
| Embodiment | Ultraviolet ray transmissivity (%) | Limited oxygen index (%) |
| 1 | 4 | 28 |
| 2 | 3 | 30 |
| 3 | 1 | 32 |
| 4 | 2 | 31 |
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (6)
- A kind of 1. multi-functional anti-ultraviolet finishing agent, it is characterised in that：The multi-functional anti-ultraviolet finishing agent includes following weight Measure the raw material of number：Nano zine oxide 5-7 parts, magnesium hydroxide 3-5 parts, triethanolamine 1-2 parts, ethanol 10-20 parts, modified poly- silicon Oxygen alkane 5-10 parts, ammonium chloride 3-5 parts, sodium acid carbonate 3-5 parts, Pagodatree Flower 5-10 parts, cactus powder 3-5 parts, borax 3-5 Part, chitosan 3-5 parts, sodium lactate 5-10 parts, AEO 3-5 parts, deionized water 30-40 parts.
- 2. multi-functional anti-ultraviolet finishing agent according to claim 1, it is characterised in that：The ethanol is absolute ethyl alcohol, Purity is pure to analyze.
- 3. multi-functional anti-ultraviolet finishing agent according to claim 1, it is characterised in that：According to parts by weight, including with Lower component：5 parts of nano zine oxide, 3 parts of magnesium hydroxide, 1 part of triethanolamine, 10 parts of ethanol, 5 parts of modified polyorganosiloxane, ammonium chloride 3 Part, 3 parts of sodium acid carbonate, 5 parts of Pagodatree Flower, 3 parts of cactus powder, 3 parts of borax, 3 parts of chitosan, 5 parts of sodium lactate, poly alkyl alcohol 3 parts of oxygen vinethene, 30 parts of deionized water.
- 4. multi-functional anti-ultraviolet finishing agent according to claim 1, it is characterised in that：According to parts by weight, including with Lower component：6 parts of nano zine oxide, 4 parts of magnesium hydroxide, 1.5 parts of triethanolamine, 15 parts of ethanol, 8 parts of modified polyorganosiloxane, chlorination 4 parts of ammonium, 4 parts of sodium acid carbonate, 8 parts of Pagodatree Flower, 4 parts of cactus powder, 4 parts of borax, 4 parts of chitosan, 8 parts of sodium lactate, fat 4 parts of alcohol APEO, 35 parts of deionized water.
- 5. multi-functional anti-ultraviolet finishing agent according to claim 1, it is characterised in that：According to parts by weight, including with Lower component：7 parts of nano zine oxide, 5 parts of magnesium hydroxide, 2 parts of triethanolamine, 20 parts of ethanol, 10 parts of modified polyorganosiloxane, ammonium chloride 5 parts, 5 parts of sodium acid carbonate, 10 parts of Pagodatree Flower, 5 parts of cactus powder, 5 parts of borax, 5 parts of chitosan, 10 parts of sodium lactate, fat 5 parts of alcohol APEO, 40 parts of deionized water.
- 6. the preparation method of any described multi-functional anti-ultraviolet finishing agent in a kind of 1-5 using the claims, it is special Sign is：Comprise the following steps that：Step 1, deionized water 30-40 parts are added in a kettle, and rise temperature is to 60-70 DEG C；Step 2, modified polyorganosiloxane 5-10 parts, magnesium hydroxide 3-5 parts, AEO 3-5 parts, 500-1000 are added Rev/min, stir 20-30 minutes；Step 3, first by nano zine oxide 5-7 parts, triethanolamine 1-2 parts, ethanol 10-20 parts, with ultrasonic disperse, ultrasonic power is 500-1000W, ultrasonic time are 20-30 minutes；Step 4, the solution of step 3 is added in the solution of step 2,500-1000 revs/min, stirs 10-20 minutes；Step 5, be cooled to 30-40 DEG C, add ammonium chloride 3-5 parts, sodium acid carbonate 3-5 parts, borax 3-5 parts, chitosan 3-5 parts, Sodium lactate 5-10 parts, Pagodatree Flower 5-10 parts, cactus powder 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；Step 6, stirring is closed down, the multi-functional anti-ultraviolet finishing agent of the liquid prepared；Step 7, stand and be cooled to the multi-functional anti-ultraviolet finishing agent of liquid in stirred tank less than 20 DEG C, blowing encapsulation, be made into Product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108625156A (en) * | 2018-05-16 | 2018-10-09 | 盐城工学院 | A kind of preparation method of uvioresistant and anti-electromagnetic-radiation multifunctional textile product |
| CN108677522A (en) * | 2018-05-16 | 2018-10-19 | 盐城工学院 | A kind of uvioresistant, flame-retardant multifunctional coated fabric finishing agent and finishing technique |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103726318A (en) * | 2012-10-16 | 2014-04-16 | 青岛道合生物科技有限公司 | Flame-retardant finishing agent special for textile |
| CN104437403A (en) * | 2014-11-13 | 2015-03-25 | 蚌埠德美过滤技术有限公司 | Cactus-containing antibacterial and anti-radiation activated carbon filtering material and preparation method thereof |
| CN104530851A (en) * | 2014-12-17 | 2015-04-22 | 谭树隆 | Multifunctional surface treating agent and use method thereof |
| CN104805680A (en) * | 2015-04-28 | 2015-07-29 | 武汉纺织大学 | Preparation method of functional fabric |
| CN105671969A (en) * | 2016-01-25 | 2016-06-15 | 苏州印丝特纺织数码科技有限公司 | Modified siloxane softening agent for spinning and preparation method of modified siloxane softening agent for spinning |
-
2017
- 2017-09-30 CN CN201710913820.3A patent/CN107724061A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103726318A (en) * | 2012-10-16 | 2014-04-16 | 青岛道合生物科技有限公司 | Flame-retardant finishing agent special for textile |
| CN104437403A (en) * | 2014-11-13 | 2015-03-25 | 蚌埠德美过滤技术有限公司 | Cactus-containing antibacterial and anti-radiation activated carbon filtering material and preparation method thereof |
| CN104530851A (en) * | 2014-12-17 | 2015-04-22 | 谭树隆 | Multifunctional surface treating agent and use method thereof |
| CN104805680A (en) * | 2015-04-28 | 2015-07-29 | 武汉纺织大学 | Preparation method of functional fabric |
| CN105671969A (en) * | 2016-01-25 | 2016-06-15 | 苏州印丝特纺织数码科技有限公司 | Modified siloxane softening agent for spinning and preparation method of modified siloxane softening agent for spinning |
Non-Patent Citations (2)
| Title |
|---|
| 夏建明主编: "《染整助剂及其应用》", 30 September 2013, 中国纺织出版社 * |
| 王昌涛等编著: "《化妆品植物添加剂的开发和应用》", 30 April 2013, 中国轻工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108625156A (en) * | 2018-05-16 | 2018-10-09 | 盐城工学院 | A kind of preparation method of uvioresistant and anti-electromagnetic-radiation multifunctional textile product |
| CN108677522A (en) * | 2018-05-16 | 2018-10-19 | 盐城工学院 | A kind of uvioresistant, flame-retardant multifunctional coated fabric finishing agent and finishing technique |
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Application publication date: 20180223 |