CN107698970A - A kind of nylon resin alloy for having high rigidity high intensity and hydrolysis - Google Patents
A kind of nylon resin alloy for having high rigidity high intensity and hydrolysis Download PDFInfo
- Publication number
- CN107698970A CN107698970A CN201711006215.4A CN201711006215A CN107698970A CN 107698970 A CN107698970 A CN 107698970A CN 201711006215 A CN201711006215 A CN 201711006215A CN 107698970 A CN107698970 A CN 107698970A
- Authority
- CN
- China
- Prior art keywords
- hydrolysis
- nylon resin
- agent
- resin alloy
- high intensity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses a kind of nylon resin alloy for having high rigidity high intensity and hydrolysis, and it is made up of the raw material of following weight fraction：0~1 part of 40~60 parts of nylon 66 resin, 5~10 parts of nylon 6 resin, 25~45 parts of alkali-free glass fibre, 1~4 part of antioxidant, 0.5~2 part of hydrolysis-resisting agent, 1~5 part of Stiffening agent, 0.5~2 part of lubricant, 0.5~2 part of heat stabilizer and other auxiliary agents.The nylon resin alloy that the present invention has makes raw material abundance, and cost is low, and intensity is high, while has outstanding rigidity and hydrolytic resistance, and the joint that alternative copper is used for water heater makes, and does not readily conduct heat, safe.
Description
Technical field
The present invention relates to nylon alloy technical field, in particular it relates to a kind of Buddhist nun for having high rigidity high intensity and hydrolysis
Imperial resin alloy.
Background technology
In daily life, water heater is essential household appliances.And because copper is not easy to get rusty, quality is soft, hardness is high
Property be often used as connecting the joint of water heater and water pipe.But it is fast using copper sleeve heat conduction, easily human body is caused to scald, weight
Tenor is high, while copper metal price is high, causes production cost height.
So we need badly, a kind of cost is low, hardness is high and the material of hydrolysis substitutes copper and is used to prepare joint.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of nylon resin conjunction for having high rigidity high intensity and hydrolysis
Gold.
A kind of nylon resin alloy for having high rigidity high intensity and hydrolysis disclosed by the invention, it is by following weight fraction
Raw material composition：
According to an embodiment of the present invention, it also includes：0.5~1 part of surface conditioning agent.
According to an embodiment of the present invention, antioxidant includes：Antioxidant 1010 and antioxidant 168, wherein pressing
Weight fraction calculates both：Antioxidant 1010 is 0.5~1 part, and antioxidant 168 is 0.5~1 part.
According to an embodiment of the present invention, hydrolysis-resisting agent is BRUGGOLEN H3337/H3347.
According to an embodiment of the present invention, Stiffening agent is maleic anhydride inoculated polypropylene.
According to an embodiment of the present invention, lubricant includes：White oil, paraffin, stearic acid, stearmide, oleamide,
One or both of erucyl amide and two or more compositions.
According to an embodiment of the present invention, heat stabilizer includes：Organic tin compound and metal soap compound
In one kind.
According to an embodiment of the present invention, other auxiliary agents include：Nucleator, chain extender, brightener, brightening agent, plasticising
Agent, eliminating smell agent and the therein one or two kinds of and two or more composition of antitack agent.
According to an embodiment of the present invention, surface conditioning agent includes：Aluminate coupling agent, aluminium titanium composite coupler and
One kind in silane coupler.
The present invention is different from the effective of prior art and is：The nylon resin alloy that the present invention has makes raw material abundance,
Cost is low, and intensity is high, while has outstanding rigidity and hydrolytic resistance, and the joint that alternative copper is used for water heater makes, and
Do not readily conduct heat, it is safe.
Brief description of the drawings
Accompanying drawing described herein is used for providing further understanding of the present application, forms the part of the application, this Shen
Schematic description and description please is used to explain the application, does not form the improper restriction to the application.In the accompanying drawings：
Fig. 1 is using the performance table of comparisons of two kinds of different nylon resin this products in embodiment one.
Embodiment
Multiple embodiments of the present invention, as clearly stated, the details in many practices will be disclosed with schema below
It will be explained in the following description.It should be appreciated, however, that the details in these practices is not applied to limit the present invention.Also
It is to say, in some embodiments of the present invention, the details in these practices is non-essential.In addition, for the sake of simplifying schema,
Some known usual structures will illustrate it in a manner of simply illustrative in the drawings with component.
It is to be appreciated that the directional instruction (such as up, down, left, right, before and after ...) of institute is only used in the embodiment of the present invention
In explaining the relative position relation under a certain particular pose (as shown in drawings) between each part, motion conditions etc., if should
When particular pose changes, then directionality instruction also correspondingly changes therewith.
In addition, in the present invention such as relating to the description of " first ", " second " etc. be only used for describe purpose, not especially censure
The meaning of order or cis-position, also it is not used to limit the present invention, its component described with constructed term just for the sake of difference
Or operation, and it is not intended that indicating or implying its relative importance or the implicit number for indicating indicated technical characteristic
Amount.Thus, " first " is defined, at least one this feature can be expressed or be implicitly included to the feature of " second ".It is in addition, each
Technical scheme between individual embodiment can be combined with each other, but must can be implemented as base with those of ordinary skill in the art
Plinth, it will be understood that the combination of this technical scheme is not present when the combination appearance of technical scheme is conflicting or can not realize,
Also not within the protection domain of application claims.
Embodiment one：
Fraction takes by weight：47 parts of nylon 66 resins, 6 parts of nylon 6 resins, 40 parts of alkali-free glass fibres, by 0.8 part of antioxygen
Agent 1010 and 0.6 part of antioxidant 168 compound the antioxidant formed, 1 part of BRUGGOLEN H3337/H3347,1 part of Malaysia
Anhydride-grafted polypropylene, 1 part of paraffin, 1 part of tetraphenyltin, 0.8 part of aluminium titanium composite coupler and 0.8 part of other auxiliary agent, will be upper
The paramount several mixers of all material addition for stating removing alkali-free glass fibre are stirred 5~10 minutes, then pass through twin-screw
Extruder is extruded, and alkali-free glass fibre is added in extrusion, is prepared into the Buddhist nun of tool high rigidity high intensity and hydrolysis
Imperial resin alloy.Wherein, above-mentioned nylon 66 resin sorting also can be to influenceing tool high rigidity high intensity of the invention and hydrolysis
Nylon resin alloy property, in the present embodiment, nylon 66 resin uses Du Pont PA66, but is not restricted to aforesaid way, please
With reference to shown in figure 1, it is the properties of product table of comparisons, understands that this product possesses more outstanding amount with respect to existing product by the table of comparisons
Rigidity, intensity and hydrolytic resistance.
Embodiment two：
Fraction takes by weight：45 parts of nylon 66 resins, 8 parts of nylon 6 resins, 40 parts of alkali-free glass fibres, by 0.5 part of antioxygen
Agent 1010 and 0.5 part of antioxidant 168 compound antioxidant, 0.8 part of BRUGGOLEN H3337/H3347, the 1 portion of horse formed
Maleic anhydride grafted polypropylene, 0.8 part of stearmide, 2 parts of tetraphenyltins, 0.8 part of silane coupler and 1 part of other auxiliary agent, will
Above-mentioned removing alkali-free glass fibre all material adds paramount several mixers and is stirred 5~10 minutes, and then by double
Screw extruder is extruded, and alkali-free glass fibre is added in extrusion, is prepared into tool high rigidity high intensity and hydrolysis
Nylon resin alloy.
The upper only embodiments of the present invention, are not intended to limit the invention.For those skilled in the art
For, the present invention can have various modifications and variations.All any modifications made in spirit and principles of the present invention, it is equal
Replace, improve etc., it all should be included within scope of the presently claimed invention.
Claims (9)
1. a kind of nylon resin alloy for having high rigidity high intensity and hydrolysis, it is characterised in that it is by following weight fraction
Raw material form：
40~60 parts of nylon 66 resin；
5~10 parts of nylon 6 resin；
25~45 parts of alkali-free glass fibre；
1~4 part of antioxidant；
0.5~2 part of hydrolysis-resisting agent；
1~5 part of Stiffening agent；
0.5~2 part of lubricant；
0.5~2 part of heat stabilizer；And
0~1 part of other auxiliary agents.
2. the nylon resin alloy of tool high rigidity high intensity according to claim 1 and hydrolysis, it is characterised in that it is also
Including：0.5~1 part of surface conditioning agent.
3. the nylon resin alloy of tool high rigidity high intensity according to claim 1 and hydrolysis, it is characterised in that described
Antioxidant includes：Antioxidant 1010 and antioxidant 168, wherein fraction calculates both respectively by weight：
0.5~1 part of antioxidant 1010；
168 0.5~1 part of antioxidant.
4. the nylon resin alloy of tool high rigidity high intensity according to claim 1 and hydrolysis, it is characterised in that：It is described
Hydrolysis-resisting agent is BRUGGOLEN H3337/H3347.
5. the nylon resin alloy of tool high rigidity high intensity according to claim 1 and hydrolysis, it is characterised in that described
Stiffening agent is maleic anhydride inoculated polypropylene.
6. the nylon resin alloy of tool high rigidity high intensity according to claim 1 and hydrolysis, it is characterised in that described
Lubricant includes：One or both of white oil, paraffin, stearic acid, stearmide, oleamide, erucyl amide and two kinds with
On composition.
7. the nylon resin alloy of tool high rigidity high intensity according to claim 1 and hydrolysis, it is characterised in that described
Heat stabilizer includes：One kind in organic tin compound or metal soap compound.
8. the nylon resin alloy of tool high rigidity high intensity according to claim 1 and hydrolysis, it is characterised in that described
Other auxiliary agents include：Nucleator, chain extender, brightener, brightening agent, plasticizer, eliminating smell agent, antitack agent one or two therein
And two or more composition.
9. the nylon resin alloy of tool high rigidity high intensity according to claim 2 and hydrolysis, it is characterised in that described
Surface conditioning agent includes：One kind in aluminate coupling agent, aluminium titanium composite coupler and silane coupler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711006215.4A CN107698970A (en) | 2017-10-25 | 2017-10-25 | A kind of nylon resin alloy for having high rigidity high intensity and hydrolysis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711006215.4A CN107698970A (en) | 2017-10-25 | 2017-10-25 | A kind of nylon resin alloy for having high rigidity high intensity and hydrolysis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107698970A true CN107698970A (en) | 2018-02-16 |
Family
ID=61182320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711006215.4A Pending CN107698970A (en) | 2017-10-25 | 2017-10-25 | A kind of nylon resin alloy for having high rigidity high intensity and hydrolysis |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107698970A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109111734A (en) * | 2018-07-24 | 2019-01-01 | 东莞市创永佳新材料有限公司 | Hydrolysis, anti-anti-icing fluid nylon add fiber material and preparation method thereof and device |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044903A (en) * | 2012-12-26 | 2013-04-17 | 安徽科聚新材料有限公司 | Hydrolysis-resistant nylon composite material and preparation method thereof |
| CN103102684A (en) * | 2013-02-20 | 2013-05-15 | 合肥杰事杰新材料股份有限公司 | Weather-proof and hydrolysis-resistant continuous glass fiber reinforced polyamide composite material and its preparation method |
| CN103113737A (en) * | 2012-10-08 | 2013-05-22 | 天津戈瑞德新材料科技有限公司 | Glass fiber reinforced and hydrolysis-resistant nylon PA (Polyethylene) 6/PA66 composite material and preparation method thereof |
| CN104861649A (en) * | 2015-05-21 | 2015-08-26 | 广东威林工程塑料有限公司 | High-temperature-resistant nylon material for high-humidity and high-pressure environment and preparation method of high-temperature-resistant nylon material |
| CN106280436A (en) * | 2016-08-31 | 2017-01-04 | 广东顺德顺炎新材料股份有限公司 | A kind of hydrolysis PA material and preparation method thereof |
| CN106317867A (en) * | 2015-06-18 | 2017-01-11 | 合肥杰事杰新材料股份有限公司 | Low-fiber exposure hydrolysis-resistant continuous glass fiber reinforced polyamide composite material and preparation method thereof |
-
2017
- 2017-10-25 CN CN201711006215.4A patent/CN107698970A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103113737A (en) * | 2012-10-08 | 2013-05-22 | 天津戈瑞德新材料科技有限公司 | Glass fiber reinforced and hydrolysis-resistant nylon PA (Polyethylene) 6/PA66 composite material and preparation method thereof |
| CN103044903A (en) * | 2012-12-26 | 2013-04-17 | 安徽科聚新材料有限公司 | Hydrolysis-resistant nylon composite material and preparation method thereof |
| CN103102684A (en) * | 2013-02-20 | 2013-05-15 | 合肥杰事杰新材料股份有限公司 | Weather-proof and hydrolysis-resistant continuous glass fiber reinforced polyamide composite material and its preparation method |
| CN104861649A (en) * | 2015-05-21 | 2015-08-26 | 广东威林工程塑料有限公司 | High-temperature-resistant nylon material for high-humidity and high-pressure environment and preparation method of high-temperature-resistant nylon material |
| CN106317867A (en) * | 2015-06-18 | 2017-01-11 | 合肥杰事杰新材料股份有限公司 | Low-fiber exposure hydrolysis-resistant continuous glass fiber reinforced polyamide composite material and preparation method thereof |
| CN106280436A (en) * | 2016-08-31 | 2017-01-04 | 广东顺德顺炎新材料股份有限公司 | A kind of hydrolysis PA material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109111734A (en) * | 2018-07-24 | 2019-01-01 | 东莞市创永佳新材料有限公司 | Hydrolysis, anti-anti-icing fluid nylon add fiber material and preparation method thereof and device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105802173B (en) | A kind of delustring halogen-free flame retardant PC/ABS alloy material and preparation method thereof | |
| CN101205332B (en) | High-gloss nano barium sulfate reinforced polypropylene resin composition | |
| CN101113225A (en) | ABS composite material | |
| CN103232649A (en) | High-impact high-surface hardness polymer alloy and preparation method thereof | |
| CN103044774B (en) | Car water kettle hydrolysis glass fiber reinforced polypropylene composite material and preparation technology thereof | |
| CN101314659A (en) | Heat-proof type high-gloss reinforced polypropylene and preparation method thereof | |
| CN103387711A (en) | High gloss and scratch resistant polypropylene resins and preparation method thereof | |
| CN105086283A (en) | High-fluidity and flame-retardant PVC/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof | |
| CN104693596A (en) | Scraping-resistant polypropylene resin and preparation method thereof | |
| CN106977911A (en) | A kind of high-gloss scraping-resistant daiamid composition and preparation method thereof | |
| CN107698970A (en) | A kind of nylon resin alloy for having high rigidity high intensity and hydrolysis | |
| CN110684337A (en) | High-performance scratch-resistant polyamide/polyphenyl ether composite material and preparation method thereof | |
| CN106117954A (en) | A kind of oil resistant, low temperature resistant regeneration ABS/PBT alloy material | |
| CN106700387A (en) | Flame-retardant master batch, preparation method and application of master batch to flame-retardant PC and alloy materials | |
| KR20170063159A (en) | Polybutyleneterephthalate Resin Composition and Moded Article Produed with the Same | |
| CN107815054A (en) | A kind of PA composites and preparation method thereof with low water absorption, strong thermal conductivity | |
| CN108342056A (en) | PC/PBT alloys and products thereof | |
| CN104277326A (en) | Ageing-resistant plastic pipe | |
| CN103524997A (en) | Modified ABS hollow glass bead filling material | |
| CN106317753A (en) | Heat-resistant ABS resin composition for improving chemical resistance | |
| CN109575431A (en) | A kind of high-intensitive, modified polypropylene material of high tenacity and preparation method thereof | |
| CN104403199A (en) | Extrusion-grade highly filled polypropylene composite material and preparation method thereof | |
| CN105623246A (en) | Impact-resistant high-rigidity polyamide composite material and preparation method thereof | |
| CN111393764B (en) | High-toughness high-strength PVC pipe material | |
| CN106147007A (en) | A kind of enhancing, scraping-resistant polypropylene material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180216 |