CN107687097A - 用无机含硫还原剂制备抗紫外羊毛织物 - Google Patents
用无机含硫还原剂制备抗紫外羊毛织物 Download PDFInfo
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- 210000002268 wool Anatomy 0.000 title claims abstract description 45
- 239000004744 fabric Substances 0.000 title claims abstract description 33
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 14
- 239000011593 sulfur Substances 0.000 title claims abstract description 14
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000002105 nanoparticle Substances 0.000 claims abstract description 20
- 239000006166 lysate Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000011787 zinc oxide Substances 0.000 claims abstract description 14
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 229920000151 polyglycol Polymers 0.000 claims abstract description 7
- 239000010695 polyglycol Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004202 carbamide Substances 0.000 claims abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 2
- 235000015424 sodium Nutrition 0.000 claims 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 8
- 102000004169 proteins and genes Human genes 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 2
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- 241001494479 Pecora Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 229960003067 cystine Drugs 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 238000005411 Van der Waals force Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Abstract
本发明提供了一种使用无机含硫还原剂制备抗紫外羊毛织物的方法,该方法包括如下步骤:(1)溶解液的制备:将无机含硫还原剂、尿素和十二烷基硫酸钠溶解到水中,然后加入氧化锌纳米粒子,剧烈搅拌下得到分散有氧化锌纳米粒子的溶解液;(2)将羊毛织物在步骤(1)所得的溶解液中多次浸轧;(3)将浸轧后的羊毛织物在红外线下辐照;(4)将辐照后的羊毛织物浸渍于聚乙二醇溶液中凝固,然后水洗、烘干。本制备技术简单易行,成本低廉,对羊毛织物的强力损伤小,不改变羊毛纤维表面性能,氧化锌纳米粒子在羊毛织物上具有良好的牢度;本制备过程中未使用任何粘合剂,无毒无害。
Description
技术领域
本发明涉及一种功能织物的制备方法,尤其是一种使用无机含硫还原剂制备抗紫外羊毛织物的方法。
背景技术
将纳米粒子引入纺织纤维中,可以制备得到功能性纤维材料。目前将纳米粒子引入羊毛纤维的制备方法很多,如:吸附法,溶胶凝胶法,层层组装法,涂层法等。然而,吸附法通过主要通过分子间范德华力和离子键力使纳米粒子吸附到羊毛纤维表面,水洗牢度较低;溶胶凝胶法和层层组装法的工艺过程较长,且较难控制;涂层法是利用粘合剂将纳米粒子粘合到羊毛纤维表面,降低了羊毛纤维对人体的亲肤性。
羊毛角蛋白是一种富含胱氨酸的蛋白质,胱氨酸中的二硫键是分子间相互交联,构成稳定的网状结构,是羊毛蛋白不溶于水的本质原因。无机含硫还原剂可以将二硫键还原成巯基,已经广泛用于羊毛角蛋白的溶解。
发明内容
本发明所要解决的技术问题是,针对以上现有技术存在的缺点,提出一种使用无机含硫还原剂制备抗紫外羊毛织物的方法。该制备技术简单易行,成本低廉,对羊毛织物的强力损伤小,不改变羊毛纤维表面性能,氧化锌纳米粒子在羊毛织物上具有良好的牢度;该制备过程中未使用任何粘合剂,无毒无害。
为了实现上述目的,本发明采取的解决方案为:一种使用无机含硫还原剂制备抗紫外羊毛织物的方法,其特征在于包括以下步骤:
(1)溶解液的制备:将无机含硫还原剂、尿素和十二烷基硫酸钠溶解到水中,然后加入氧化锌纳米粒子,剧烈搅拌下得到分散有氧化锌纳米粒子的溶解液;
(2)将羊毛织物在步骤(1)所得的溶解液中多次浸轧;
(3)将浸轧后的羊毛织物在红外线下辐照10-30min;
(4)将辐照后的羊毛织物浸渍于聚乙二醇溶液中凝固,然后水洗、烘干。
本发明的有益效果在于,(1)采用浸轧法使有限的无机含硫还原剂主要分布于羊毛纤维的表面,短时间的红外线辐照只能对羊毛纤维表面进行部分溶解,而不会损伤羊毛纤维内部,减小对羊毛纤维及织物物理机械性能的损伤;(2)在羊毛纤维表面部分溶解的羊毛蛋白形成蛋白质浓溶液,对纳米粒子具有粘附作用;(3)羊毛纤维表面形成的蛋白质浓溶液在聚乙二醇溶液中重新凝固,起到对纳米粒子的粘合、包裹作用;(4)制备过程中未使用任何粘合剂,无毒无害。
具体实施方式
下文将结合具体实施例详细描述本发明。应当注意的是,下述实施例中描述的技术特征或者技术特征的组合不应当被认为是孤立的,它们可以被相互组合从而达到更好的技术效果。
实施例1
(1)溶解液的制备:将8g硫化钠、20g尿素和2g十二烷基硫酸钠溶解到水中,形成100g混合溶液,然后加入0.1g氧化锌纳米粒子,剧烈搅拌下得到分散有氧化锌纳米粒子的溶解液;
(2)将羊毛织物在步骤(1)所得的溶解液中多次浸轧,轧余率为70%;
(3)将浸轧后的羊毛织物在300w红外线下辐照15min;
(4)将辐照后的羊毛织物浸渍于聚乙二醇溶液(质量分数为8%)中凝固10min,然后水洗、烘干。
实施例2
(1)溶解液的制备:将7g焦亚硫酸钠、30g尿素和2g十二烷基硫酸钠溶解到水中,形成100g混合溶液,然后加入0.3g氧化锌纳米粒子,剧烈搅拌下得到分散有氧化锌纳米粒子的溶解液;
(2)将羊毛织物在步骤(1)所得的溶解液中多次浸轧,轧余率为80%;
(3)将浸轧后的羊毛织物在100w红外线下辐照20min;
(4)将辐照后的羊毛织物浸渍于聚乙二醇溶液(质量分数为12%)中凝固10min,然后水洗、烘干。
实施例3
(1)溶解液的制备:将5g亚硫酸氢钠、40g尿素和3g十二烷基硫酸钠溶解到水中,形成100g混合溶液,然后加入0.7g氧化锌纳米粒子,剧烈搅拌下得到分散有氧化锌纳米粒子的溶解液;
(2)将羊毛织物在步骤(1)所得的溶解液中多次浸轧,轧余率为90%;
(3)将浸轧后的羊毛织物在150w红外线下辐照25min;
(4)将辐照后的羊毛织物浸渍于聚乙二醇溶液(质量分数为10%)中凝固10min,然后水洗、烘干。
本文虽然已经给出了本发明的一些实施例,但是本领域的技术人员应当理解,在不脱离本发明精神的情况下,可以对本文的实施例进行改变。上述实施例只是示例性的,不应以本文的实施例作为本发明权利范围的限定。
Claims (2)
1.一种使用无机含硫还原剂制备抗紫外羊毛织物的方法,其特征在于,包括如下步骤:
(1)溶解液的制备:将无机含硫还原剂、尿素和十二烷基硫酸钠溶解到水中,然后加入氧化锌纳米粒子,剧烈搅拌下得到分散有氧化锌纳米粒子的溶解液;
(2)将羊毛织物在步骤(1)所得的溶解液中多次浸轧;
(3)将浸轧后的羊毛织物在红外线下辐照10-30min;
(4)将辐照后的羊毛织物浸渍于聚乙二醇溶液中凝固,然后水洗、烘干。
2.根据权利要求1所述的一种使用无机含硫还原剂制备抗紫外羊毛织物的方法,其特征在于:无机含硫还原剂为硫化钠、亚硫酸氢钠、焦亚硫酸钠等。
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CN115679680A (zh) * | 2022-11-11 | 2023-02-03 | 江南大学 | 一种高白度防缩毛织物的制备方法 |
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