CN107687094A - A kind of spinning sizing agent and preparation method thereof - Google Patents
A kind of spinning sizing agent and preparation method thereof Download PDFInfo
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- CN107687094A CN107687094A CN201710881000.0A CN201710881000A CN107687094A CN 107687094 A CN107687094 A CN 107687094A CN 201710881000 A CN201710881000 A CN 201710881000A CN 107687094 A CN107687094 A CN 107687094A
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- parts
- sizing agent
- spinning sizing
- lecithin
- polyethylene glycol
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/273—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having epoxy groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a kind of spinning sizing agent, including following components：Pure glue, sodium carboxymethyl starch, methacrylic acid, silica, polyethylene glycol, lecithin, PAM, polyglycerolmethacrylate, ammonium xylene sulfonate and trimesic acid.Its preparation method is that first pure glue and sodium carboxymethyl starch are scattered in hot water, it is stirred, add silica, polyethylene glycol, lecithin, methacrylic acid, PAM and ammonium xylene sulfonate are added after being stirred, heating stirring, is eventually adding polyglycerolmethacrylate and trimesic acid, ethyl acetate is added dropwise under stirring, continue to stir after being added dropwise, concentration obtains spinning sizing agent.The slurry of the present invention adds sodium carboxymethyl starch, polyethylene glycol and lecithin in pure glue, is effectively improved the physical property of slurry, the resistance to flexibility of gained slurry, can extensive use in production up to 1489 times.
Description
Technical field
The invention belongs to textile weaving field, and in particular to a kind of spinning sizing agent and preparation method thereof.
Background technology
During woven, warp thread will bear multi-drawing, bending and rubbing action.Warp thread during in order to reduce weaving
Fluffing and broken end, non-twist, low twist chemical fibre and mixed yarn are made to be required for starching during warp thread.The slurry that starching is selected needs full
The certain requirement of foot:1）Fiber is not chemically reacted, does not damage the original performance of yarn；2) there is stronger adhesion to fiber
And film forming；3) there are appropriate viscosity and permeability；4) stable performance is unlikely to deteriorate；5) film forming is preferable, and serous coat should be soft,
It is non-blocking, it is not likely to produce electrostatic；6) it is easy to desizing when concise, and the post processings such as dyeing, stamp is had no adverse effects；7) select
Slurry answers that source is wide, cost is low, size mixing, starching it is simple and convenient, in traditional production practices, conventional slurry include starch,
Polyvinyl alcohol (PVA) and acrylic acid, with deepening continuously for research, the good novel slurry of many starch finishing effects is continuously developed
Out.
In currently used slurry, starch size good film-forming property is strong with natural fiber affinity, is easy to desizing, is weaving
The main pulp component of sizing；But starch size slashing strength is inadequate, not wear-resisting, and it is inadequate with polyester fiber affinity.Poly- second
Enol slurry serous coat strength is big, and pliability is good, and slurry fluidity is good；But polyvinyl alcohol is difficult to desizing, and due to polyethylene
Alcohol is difficult to degrade, and is easily caused white ambient pollution, European Union, which has made laws, to prohibit the use of.The chemical constitution of polyester pulp and terylene phase
Seemingly, therefore it is strong with washing fiber affinity, is particularly suitable for use in contain and washs fiber, and its desizing is easy；But polyester pulp neutral and
It is degradable under alkalescence condition, hydrolyzed in mashing off and sizing process, cause sizing intensity to decline, limit polyester pulp
Using.Meanwhile the mechanical performance after starching disposed slurry film forming also has much room for improvement.
The content of the invention
It is an object of the invention to provide a kind of spinning sizing agent and preparation method thereof, gained slurry has excellent physical
Energy.
A kind of spinning sizing agent, include the component of following parts by weight：Pure glue 8-12 parts, sodium carboxymethyl starch 3-8 parts, methyl-prop
Olefin(e) acid 2-4 parts, -3 parts of silica 1, polyethylene glycol 2-5 parts, lecithin 1-3 parts, PAM 1-2 parts, polymethyl
Acid glyceride 0.5-1 parts, ammonium xylene sulfonate 0.3-0.8 parts and trimesic acid 4-8 parts.
Preferably, the silica is nano silicon.
Preferably, the polyethylene glycol is polyethylene glycol-800.
Preferably, the lecithin is hydrophilic liquid lecithin.
The preparation method of above-mentioned spinning sizing agent, step are as follows：
Step 1, pure glue and sodium carboxymethyl starch are scattered in hot water, are stirred, then add silica, poly- second two
Alcohol, lecithin, mixture one is obtained after being stirred；
Step 2, methacrylic acid is added in mixture one, adds PAM and ammonium xylene sulfonate, be warming up to 50-
60 DEG C, 40-60 minutes are stirred, obtain mixture two；
Step 3, polyglycerolmethacrylate and trimesic acid are added in mixture two, acetic acid is added dropwise under stirring
Ethyl ester, continue to stir 60-90 minutes after being added dropwise, be concentrated into solid content 60-70%, obtain spinning sizing agent.
Preferably, the temperature of hot water is 60-65 DEG C in step 1.
Preferably, the addition mass fraction of hot water is 60-70 parts in step 1.
Preferably, the addition mass fraction of ethyl acetate is 2-5 parts in step 3.
The slurry of the present invention adds sodium carboxymethyl starch, polyethylene glycol and lecithin in pure glue, is effectively improved slurry
Physical property, the resistance to flexibility of gained slurry, can extensive uses in production up to 1489 times.
Embodiment
Embodiment 1
A kind of spinning sizing agent, include the component of following parts by weight：Pure 8 parts of glue, 3 parts of sodium carboxymethyl starch, 2 parts of methacrylic acid,
Silica 1 part, 2 parts of polyethylene glycol, 1 part of lecithin, 1 part of PAM, 0.5 part of polyglycerolmethacrylate, diformazan
4 parts of 0.3 part of ammonium benzene sulfonate and trimesic acid.
Wherein, the silica is nano silicon；The polyethylene glycol is polyethylene glycol-800；The lecithin
For hydrophilic liquid lecithin.
The preparation method of above-mentioned spinning sizing agent, step are as follows：
Step 1, pure glue and sodium carboxymethyl starch are scattered in hot water, are stirred, then add silica, poly- second two
Alcohol, lecithin, mixture one is obtained after being stirred；
Step 2, methacrylic acid is added in mixture one, adds PAM and ammonium xylene sulfonate, be warming up to 50-
60 DEG C, 40-60 minutes are stirred, obtain mixture two；
Step 3, polyglycerolmethacrylate and trimesic acid are added in mixture two, acetic acid is added dropwise under stirring
Ethyl ester, continue to stir 60-90 minutes after being added dropwise, be concentrated into solid content 60-70%, obtain spinning sizing agent.
Wherein, the temperature of hot water is 60-65 DEG C in step 1, and the addition mass fraction of hot water is 60 parts.Second in step 3
The addition mass fraction of acetoacetic ester is 2 parts.
Embodiment 2
A kind of spinning sizing agent, include the component of following parts by weight：Pure 9 parts of glue, 5 parts of sodium carboxymethyl starch, 3 parts of methacrylic acid,
21 parts of silica, 3 parts of polyethylene glycol, 2 parts of lecithin, 1.3 parts of PAM, 0.7 part of polyglycerolmethacrylate, two
6 parts of 0.4 part of ammonium tosylate and trimesic acid.
Wherein, the silica is nano silicon；The polyethylene glycol is polyethylene glycol-800；The lecithin
For hydrophilic liquid lecithin.
The preparation method of above-mentioned spinning sizing agent, step are as follows：
Step 1, pure glue and sodium carboxymethyl starch are scattered in hot water, are stirred, then add silica, poly- second two
Alcohol, lecithin, mixture one is obtained after being stirred；
Step 2, methacrylic acid is added in mixture one, adds PAM and ammonium xylene sulfonate, be warming up to 50-
60 DEG C, 40-60 minutes are stirred, obtain mixture two；
Step 3, polyglycerolmethacrylate and trimesic acid are added in mixture two, acetic acid is added dropwise under stirring
Ethyl ester, continue to stir 60-90 minutes after being added dropwise, be concentrated into solid content 60-70%, obtain spinning sizing agent.
Wherein, the temperature of hot water is 60-65 DEG C in step 1, and the addition mass fraction of hot water is 65 parts.Second in step 3
The addition mass fraction of acetoacetic ester is 3 parts.
Embodiment 3
A kind of spinning sizing agent, include the component of following parts by weight：Pure 10 parts of glue, 6 parts of sodium carboxymethyl starch, 3 parts of methacrylic acid,
2 parts of silica, 4 parts of polyethylene glycol, 2 parts of lecithin, 2 parts of PAM, 0.7 part of polyglycerolmethacrylate, diformazan
6 parts of 0.6 part of ammonium benzene sulfonate and trimesic acid.
Wherein, the silica is nano silicon；The polyethylene glycol is polyethylene glycol-800；The lecithin
For hydrophilic liquid lecithin.
The preparation method of above-mentioned spinning sizing agent, step are as follows：
Step 1, pure glue and sodium carboxymethyl starch are scattered in hot water, are stirred, then add silica, poly- second two
Alcohol, lecithin, mixture one is obtained after being stirred；
Step 2, methacrylic acid is added in mixture one, adds PAM and ammonium xylene sulfonate, be warming up to 50-
60 DEG C, 40-60 minutes are stirred, obtain mixture two；
Step 3, polyglycerolmethacrylate and trimesic acid are added in mixture two, acetic acid is added dropwise under stirring
Ethyl ester, continue to stir 60-90 minutes after being added dropwise, be concentrated into solid content 60-70%, obtain spinning sizing agent.
Wherein, the temperature of hot water is 60-65 DEG C in step 1, and the addition mass fraction of hot water is 67 parts.Second in step 3
The addition mass fraction of acetoacetic ester is 4 parts.
Embodiment 4
A kind of spinning sizing agent, include the component of following parts by weight：Pure 12 parts of glue, 8 parts of sodium carboxymethyl starch, 4 parts of methacrylic acid,
3 parts of silica, 5 parts of polyethylene glycol, 3 parts of lecithin, 2 parts of PAM, 1 part of polyglycerolmethacrylate, dimethylbenzene
8 parts of 0.8 part of ichthyodin and trimesic acid.
Wherein, the silica is nano silicon；The polyethylene glycol is polyethylene glycol-800；The lecithin
For hydrophilic liquid lecithin.
The preparation method of above-mentioned spinning sizing agent, step are as follows：
Step 1, pure glue and sodium carboxymethyl starch are scattered in hot water, are stirred, then add silica, poly- second two
Alcohol, lecithin, mixture one is obtained after being stirred；
Step 2, methacrylic acid is added in mixture one, adds PAM and ammonium xylene sulfonate, be warming up to 50-
60 DEG C, 40-60 minutes are stirred, obtain mixture two；
Step 3, polyglycerolmethacrylate and trimesic acid are added in mixture two, acetic acid is added dropwise under stirring
Ethyl ester, continue to stir 60-90 minutes after being added dropwise, be concentrated into solid content 60-70%, obtain spinning sizing agent.
Wherein, the temperature of hot water is 60-65 DEG C in step 1, and the addition mass fraction of hot water is 70 parts.Second in step 3
The addition mass fraction of acetoacetic ester is 5 parts.
The gained of embodiment 1 to 4 slurry is subjected to quantitative measurement, the fracture strength of gained slurry is in 40.08N/mm2, fracture
Elongation is 168.5%, is worn away as 0.19mg/cm2, resistance to flexibility is 1489 times, hydroscopicity 9.8%.
Claims (8)
1. a kind of spinning sizing agent, it is characterised in that include the component of following parts by weight：Pure glue 8-12 parts, sodium carboxymethyl starch 3-8
It is part, methacrylic acid 2-4 parts, -3 parts of silica 1, polyethylene glycol 2-5 parts, lecithin 1-3 parts, PAM 1-2 parts, poly-
Glyceral methacrylate 0.5-1 parts, ammonium xylene sulfonate 0.3-0.8 parts and trimesic acid 4-8 parts.
2. spinning sizing agent according to claim 1, it is characterised in that silica is nano silicon.
3. spinning sizing agent according to claim 1, it is characterised in that polyethylene glycol is polyethylene glycol-800.
4. spinning sizing agent according to claim 1, it is characterised in that lecithin is hydrophilic liquid lecithin.
5. the preparation method of the spinning sizing agent described in claim 1, it is characterised in that step is as follows：
Step 1, pure glue and sodium carboxymethyl starch are scattered in hot water, are stirred, then add silica, poly- second two
Alcohol, lecithin, mixture one is obtained after being stirred；
Step 2, methacrylic acid is added in mixture one, adds PAM and ammonium xylene sulfonate, be warming up to 50-
60 DEG C, 40-60 minutes are stirred, obtain mixture two；
Step 3, polyglycerolmethacrylate and trimesic acid are added in mixture two, acetic acid is added dropwise under stirring
Ethyl ester, continue to stir 60-90 minutes after being added dropwise, be concentrated into solid content 60-70%, obtain spinning sizing agent.
6. the preparation method of spinning sizing agent according to claim 5, it is characterised in that the temperature of hot water is in step 1
60-65℃。
7. the preparation method of spinning sizing agent according to claim 5, it is characterised in that the addition quality of hot water in step 1
Number is 60-70 parts.
8. the preparation method of spinning sizing agent according to claim 5, it is characterised in that the addition of ethyl acetate in step 3
Mass fraction is 2-5 parts.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710881000.0A CN107687094A (en) | 2017-09-26 | 2017-09-26 | A kind of spinning sizing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710881000.0A CN107687094A (en) | 2017-09-26 | 2017-09-26 | A kind of spinning sizing agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107687094A true CN107687094A (en) | 2018-02-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710881000.0A Pending CN107687094A (en) | 2017-09-26 | 2017-09-26 | A kind of spinning sizing agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111041865A (en) * | 2019-11-11 | 2020-04-21 | 浙江森马服饰股份有限公司 | Production process of breathable printed fabric |
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| CN101597356A (en) * | 2009-06-26 | 2009-12-09 | 东华大学 | High-performance modified nano silicon/acrylic size and preparation method thereof |
| CN101831805A (en) * | 2010-04-14 | 2010-09-15 | 宜兴市军达浆料科技有限公司 | Textile size and preparation method thereof |
| CN102086601A (en) * | 2010-12-25 | 2011-06-08 | 浙江新澳纺织股份有限公司 | Woolen sweater printing method |
| CN104558600A (en) * | 2013-10-21 | 2015-04-29 | 乐凯华光印刷科技有限公司 | Nitrogen-containing multi-degree-of-functionality acrylate resin as well as preparation method and application thereof |
-
2017
- 2017-09-26 CN CN201710881000.0A patent/CN107687094A/en active Pending
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| CN101008153A (en) * | 2007-01-29 | 2007-08-01 | 许盛英 | Attapulgite spinning slurry adjuvant |
| CN101597356A (en) * | 2009-06-26 | 2009-12-09 | 东华大学 | High-performance modified nano silicon/acrylic size and preparation method thereof |
| CN101831805A (en) * | 2010-04-14 | 2010-09-15 | 宜兴市军达浆料科技有限公司 | Textile size and preparation method thereof |
| CN102086601A (en) * | 2010-12-25 | 2011-06-08 | 浙江新澳纺织股份有限公司 | Woolen sweater printing method |
| CN104558600A (en) * | 2013-10-21 | 2015-04-29 | 乐凯华光印刷科技有限公司 | Nitrogen-containing multi-degree-of-functionality acrylate resin as well as preparation method and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111041865A (en) * | 2019-11-11 | 2020-04-21 | 浙江森马服饰股份有限公司 | Production process of breathable printed fabric |
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Application publication date: 20180213 |