CN107676180A - A kind of compression carbon dioxide energy-storage system of double underground gas storage rooms - Google Patents

A kind of compression carbon dioxide energy-storage system of double underground gas storage rooms Download PDF

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Publication number
CN107676180A
CN107676180A CN201710964845.6A CN201710964845A CN107676180A CN 107676180 A CN107676180 A CN 107676180A CN 201710964845 A CN201710964845 A CN 201710964845A CN 107676180 A CN107676180 A CN 107676180A
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carbon dioxide
energy
storage
storage system
compression
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CN201710964845.6A
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Inventor
何青
郝银萍
刘辉
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North China Electric Power University
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North China Electric Power University
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Priority to CN201710964845.6A priority Critical patent/CN107676180A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
    • F02C6/14Gas-turbine plants having means for storing energy, e.g. for meeting peak loads
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D15/00Adaptations of machines or engines for special use; Combinations of engines with devices driven thereby
    • F01D15/10Adaptations for driving, or combinations with, electric generators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • F01K25/10Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
    • F01K25/103Carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
    • F02C6/18Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/10Geothermal energy

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The invention discloses a kind of new energy-storage system, the system is using carbon dioxide as working media, mainly including compressor(Group), expansion turbine(Unit), underground gas storage room, heat exchanger, choke valve, the capital equipment such as cooler.Underground gas storage room is served as using saline groundwater floor, store carbon dioxide, the high-pressure carbon dioxide in high-pressure gas room can be heated so as to save the storage heater in energy-storage system using underground geothermal;In view of environmental protection effect, CO2 emission is avoided into air, the compression carbon dioxide energy-storage system uses two underground gas storage rooms, the supercritical carbon dioxide of one high-pressure gas room storage compressor release, the carbon dioxide of another low pressure air storage chamber storage expansion turbine release, so that compression carbon dioxide energy-storage system forms the energy-storage system of a closing.To sum up, the system serves as underground gas storage room to store carbon dioxide using saline groundwater floor, does not produce pollutant in the process of running, reaches economical, the benefit of environmental protection and energy-conservation.Described compression carbon dioxide energy-storage system is as shown in Figure 1.

Description

A kind of compression carbon dioxide energy-storage system of double underground gas storage rooms
Technical field
The invention belongs to compress carbon dioxide energy-storage system field, the salt water layer at more particularly to a kind of underground different depth Each act as the compression carbon dioxide energy-storage system of high and low pressure air storage chamber.
Background technology
At present, compressed air energy storage technology is born in the 1970s, being a kind of more ripe, the feasible big rule of development Mould energy storage technology.Its course of work is:In low power consumption, compressor utilizes the sky in unnecessary electric energy compressed atmosphere environment Gas, convert electrical energy into the interior energy of air and be stored in air storage chamber, in peak of power consumption, the pressure-air in air storage chamber is released Release, expansion turbine is entered after heating and is done work, electric energy is converted into by generator.
Compressed-air energy-storage system has been subjected to domestic and international scientific research institution and the highest attention of personnel, but up to the present Still without large-scale business application, now there was only German Huntorf energy-accumulating power stations and U.S.'s McIntosh energy storage electricity in the world To stand and enter comercial operation mode phases, compressed air energy storage technology has that cost of investment is low, capacity big the advantages of waiting, but due to being There is the shortcomings of operational efficiency is low, and energy storage density is low, discharges carbon dioxide greenhouse gas in system operation, therefore limit compression in itself The further development of air energy storage technology.
The present invention proposes a kind of knot to solve the problems, such as that energy storage density is low as starting point in existing compressed air energy storage technology Close the compression carbon dioxide energy-storage system of double underground gas storage rooms of compressed air energy storage technology and carbon dioxide physical property advantage.
Carbon dioxide geologic sequestration refers to carbon dioxide compression injecting underground fluid or porous rock containing fluid constructs In, such as natural gas, oil, deep salt water layer etc..Research shows that China's saline groundwater layer distribution area is wide, and it is big to seal space up for safekeeping, It is most potential carbon dioxide sequestration place, therefore, the storage by the use of underground gas storage room as compression carbon dioxide energy-storage system Air chamber has stronger feasibility.
Geothermic gradient also turns into " low temperature gradients ", and it is defined as on along the normal of geoisothermal to the direction in the earth's core, single Apart from the increased numerical value of interior temperature institute, geothermic gradient value is usually 30 DEG C/km for position.As 2-3km under carbon dioxide storage, its Geothermal energy heating high-pressure carbon dioxide can be utilized, so as to save the storage heater in original compression carbon dioxide energy-storage system.
To ensure that the carbon dioxide in energy-storage system is not discharged into atmospheric environment, the present invention uses two underground gas storages Room, the supercritical carbon dioxide of a high-pressure gas room storage compressor release, a low pressure air storage chamber storage expansion turbine are released The carbon dioxide put, so that compression carbon dioxide energy-storage system forms the energy-storage system of a closing, not to Environment release temperature Room gas, reach the purpose of environmental protection.
The content of the invention
The purpose of the present invention is to disclose a kind of compression carbon dioxide energy-storage system of double underground gas storage rooms, using carbon dioxide Instead of air as acting working medium, solve the problems, such as that energy storage density is low, while use the salt water layer of underground different depth as two Carbonoxide air storage chamber, high-pressure carbon dioxide is heated using geothermal energy, save the storage heater of energy-storage system, and the system is done work Working medium carbon dioxide recycling, therefore the system can solve the problems, such as that energy-storage system energy storage density is low, while reach economical, ring Protect, efficient purpose.
To reach above-mentioned purpose, technical solution of the invention is:A kind of compression carbon dioxide of double underground gas storage rooms Energy-storage system, including carbon dioxide energy-storage units and carbon dioxide releasing unit, it is characterised in that:
-- the carbon dioxide energy-storage units include be sequentially connected by pipeline underground low-voltage air storage chamber, cooler, choke valve, Compressor(Group), high-pressure gas room, wherein:Compressor(Group)Outlet is connected with the import of high-pressure gas room;
-- the carbon dioxide releasing unit include be sequentially connected by pipeline high-pressure gas room, choke valve, regenerator, expansion Turbine(Unit);
-- the carbon dioxide releasing unit includes regenerator, wherein:The heat accumulation side-entrance of the regenerator and expansion turbine(Machine Group)Outlet is connected, and outlet side is connected with underground low-voltage air storage chamber import;The regenerator hot side import goes out with high-pressure gas room Choke valve at mouthful is connected, regenerator hot side outlet and expansion turbine(Unit)Import is connected;
-- the carbon dioxide energy-storage system compressor(Group)With expansion turbine(Unit)It is connected by electric generator/electric motor;
-- the compression carbon dioxide energy-storage system of double underground gas storage rooms stores carbon dioxide using saline groundwater floor, respectively The high and low pressure air storage chamber of the system is served as using the salt water layer at the different depth of underground, using underground geothermal energy, to heat Carbon dioxide in high-pressure gas room, complete the acting process of energy-storage system.
The compression carbon dioxide energy-storage system of described a kind of double underground gas storage rooms, to ensure the titanium dioxide in energy-storage system Carbon is not discharged into atmospheric environment, and the system uses two underground gas storage rooms, a high-pressure gas room storage compressor release Supercritical carbon dioxide, the carbon dioxide of low pressure air storage chamber storage expansion turbine release, so that compression carbon dioxide Energy-storage system forms the energy-storage system of a closing, not to Environment release greenhouse gases, reaches environmentally friendly purpose.
A kind of compression carbon dioxide energy-storage system of described double underground gas storage rooms, consider shadow of the geothermic gradient to air storage chamber Ring, the carbon dioxide temperature of low pressure reservoir outlet can be higher, and to reduce compressor wasted work, cooler is placed on into low pressure gas storage Room exit is lowered into the carbon dioxide temperature of suction port of compressor.
A kind of compression carbon dioxide energy-storage system of described double underground gas storage rooms, the two of high and low pressure air storage chamber memory storage Its pressure can gradually reduce with release process during carbonoxide discharges again, in order to ensure to enter compressor and expansion turbine Pressure carbon dioxide be definite value, ensure that suction port of compressor and expansion turbine enter using the mode of choke valve decompression in recycling The pressure of mouth is steady state value.
A kind of compression carbon dioxide energy-storage system of described double underground gas storage rooms, carbon dioxide is exported according to expansion turbine State, when expansion turbine outlet temperature and pressure less than carbon dioxide critical outlet temperature and pressure (T c=304.55K,P c=7.38MPa) when, carbon dioxide now is in critical-cross carbon dioxide state, the Trans-critical cycle being stored in low pressure air storage chamber Carbon dioxide, its temperature, pressure is relatively low, cause thermal energy storage process compression ratio and exoergic process expansion ratio it is larger, therefore storing up Compression process need to use multi-stage compression, cascade EDFA in energy system, and expansion process need to use multiple expansion, reheat in stage.
A kind of compression carbon dioxide energy-storage system of described double underground gas storage rooms, carbon dioxide is exported according to expansion turbine State, when expansion turbine outlet temperature and pressure higher than carbon dioxide critical outlet temperature and pressure (T c=304.55K,P c=7.38MPa) when, carbon dioxide now is in supercritical carbon dioxide state, is stored in overcritical in low pressure air storage chamber Carbon dioxide, its temperature and pressure is higher, and the compression ratio of thermal energy storage process and the expansion ratio of exoergic process are smaller, therefore are storing up Single stage compress and single-stage expansion can be only needed in system.
A kind of compression carbon dioxide energy-storage system of described double underground gas storage rooms, takes the salt water layer at the different depth of underground Underground high and low pressure air storage chamber is done respectively, and wherein underground high-voltage air storage chamber depth will be at least the 1.5-2.5 of low pressure air storage chamber depth Times.
The innovative point of the present invention has following three features:First, using saline groundwater layer resource, as the energy-storage system Underground gas storage room;Second, using the geothermal energy at underground gas storage layer depth, the carbon dioxide in underground high-voltage air storage chamber is heated, from And the original storage heater of energy-storage system can be saved;3rd, the acting working medium of the system is carbon dioxide, the circulation for system Work, not to Environment release greenhouse gases, has environmental benefit.
Brief description of the drawings
Fig. 1 is a kind of compression carbon dioxide energy-storage system schematic diagram of double underground gas storage rooms.
Fig. 1(a)It is a kind of Trans-critical cycle compression carbon dioxide energy-storage system schematic diagram using double underground gas storage rooms.
Fig. 1(b)It is a kind of overcritical compression carbon dioxide energy-storage system schematic diagram using double underground gas storage rooms.
Label in figure
Such as Fig. 1, wherein:
1- compressors;2- electric generator/electric motors;3- expansion turbines;4- heaters;5- regenerators;6- choke valves 1;7- undergrounds are high Press air storage chamber;8- underground low-voltage air storage chambers;9- coolers;10- choke valves 2.
Embodiment
The invention provides a kind of compression carbon dioxide energy-storage system of double underground gas storage rooms, below in conjunction with the accompanying drawings and specifically The present invention is described further for embodiment.
The present invention can be based on the system and realize, its concrete structure such as Fig. 1(a)It is shown, with expansion turbine exit two The state of carbonoxide is exemplified by critical-cross carbon dioxide state:The system is by compressor 1, compressor set 2, compressor set 3, level Between cooler 4, interstage cooler 5, electric generator/electric motor 6, expansion turbine unit 7, expansion turbine unit 8, reheat in stage device 9, Regenerator 10, choke valve 11, underground high-voltage air storage chamber 12, underground low-voltage air storage chamber 13, cooler 14, choke valve 15 form, tool Body operating process is:
Such as Fig. 1(a)It is shown, in thermal energy storage process, i.e. in the low power consumption stage, using unnecessary electric energy, low pressure air storage chamber will be stored in Carbon dioxide in 13 is after cooler 14 is cooled to environment temperature, after being depressured by choke valve 15, into compressor set 1,2,3 Multi-stage compression and the process of interstage cooler 4 and 5 are carried out, injection high-pressure gas room 12 is deposited after being compressed into supercritical carbon dioxide Storage;In exoergic process, i.e., peak of power consumption stage, the carbon dioxide being stored in high-pressure gas room 12 are depressured by choke valve 11 Enter the waste heat that regenerator 10 absorbs expansion process discharge afterwards, expansion work, exhaust are carried out subsequently into first order expansion turbine 7 Heating up process is completed into heater 9, second level expansion turbine 8 is entered back into and carries out expansion work, subsequently into regenerator The carbon dioxide of 10 pairs of high-pressure gas room releases heats, and releases the carbon dioxide injection low pressure air storage chamber 13 after waste heat and enters Row storage.
The present invention can be based on the system and realize, its concrete structure such as Fig. 1(b)It is shown, with expansion turbine exit two The state of carbonoxide is exemplified by supercritical carbon dioxide state:The system is saturating by compressor 1, electric generator/electric motor 2, expansion Flat 3, heater 4, regenerator 5, choke valve 6, underground high-voltage air storage chamber 7, underground low-voltage air storage chamber 8, cooler 9, choke valve 10 Composition, specific operation process are:
Such as Fig. 1(b)It is shown, in thermal energy storage process, i.e. in the low power consumption stage, low pressure air storage chamber 8 will be stored in using unnecessary electric energy In carbon dioxide after cooler 9 is cooled to environment temperature, by choke valve 10 be depressured after, be compressed into compressor 1 Into supercritical carbon dioxide, it is then injected into high-pressure gas room 6 and is stored;In exoergic process, i.e. in the peak of power consumption stage, store Carbon dioxide in high-pressure gas room 7, which enters after the decompression of choke valve 6 in regenerator 5, to be absorbed more than expansion process discharge Heat, then enter expansion turbine 3 after the heating of heater 4 and carry out expansion work, subsequently into regenerator 5 to high-pressure gas room The carbon dioxide of release is heated, and is released and is stored in the carbon dioxide injection low pressure air storage chamber 8 after waste heat.
The embodiment above of the present invention is that the present invention will be described, is not limited the invention.Claim Claimed spirit and scope are indicated, and above-mentioned explanation does not pay the scope of the present invention all.Therefore, exist Any change in claims of the present invention suitable implication and scope, should be construed as being included in the scope of claims It is interior.

Claims (6)

1. a kind of compression carbon dioxide energy-storage system of double underground gas storage rooms, including energy-storage units and releasing unit, its feature exist In,
-- the carbon dioxide energy-storage units include be sequentially connected by pipeline underground low-voltage air storage chamber, cooler, choke valve, Compressor(Group), high-pressure gas room, wherein:Compressor(Group)Outlet is connected with the import of high-pressure gas room;
-- the carbon dioxide releasing unit include be sequentially connected by pipeline high-pressure gas room, choke valve, regenerator, expansion Turbine(Unit);
-- the carbon dioxide releasing unit includes regenerator, wherein:The heat accumulation side-entrance of the regenerator and expansion turbine(Machine Group)Outlet is connected, and outlet side is connected with underground low-voltage air storage chamber import;The regenerator hot side import goes out with high-pressure gas room Choke valve at mouthful is connected, regenerator hot side outlet and expansion turbine(Unit)Import is connected;
-- the carbon dioxide energy-storage system compressor(Group)With expansion turbine(Unit)It is connected by electric generator/electric motor;
-- the compression carbon dioxide energy-storage system of double underground gas storage rooms stores carbon dioxide using saline groundwater floor, respectively The high and low pressure air storage chamber of the system is served as using the salt water layer at the different depth of underground, using underground geothermal energy, to heat Carbon dioxide in high-pressure gas room, complete the acting process of energy-storage system.
A kind of 2. compression carbon dioxide energy-storage system of double underground gas storage rooms according to claims 1, it is characterised in that To ensure that the carbon dioxide in energy-storage system is not discharged into atmospheric environment, the present invention uses two underground gas storage rooms, a height Press the supercritical carbon dioxide of air storage chamber storage compressor release, the titanium dioxide of a low pressure air storage chamber storage expansion turbine release Carbon, so that compression carbon dioxide energy-storage system forms the energy-storage system of a closing, not to Environment release greenhouse gases, reach The purpose of environmental protection.
A kind of 3. compression carbon dioxide energy-storage system of double underground gas storage rooms according to claims 1, it is characterised in that Because in underground gas storage room, influence of the geothermic gradient to air storage chamber, the carbon dioxide temperature of low pressure reservoir outlet can be higher, In order to reduce compressor wasted work, cooler is placed at low pressure reservoir outlet to be lowered into the carbon dioxide of suction port of compressor Temperature.
A kind of 4. compression carbon dioxide energy-storage system of double underground gas storage rooms according to claims 1, it is characterised in that High and low pressure air storage chamber memory storage carbon dioxide during release its pressure can gradually be reduced with release process, be Ensure that the pressure carbon dioxide into compressor and expansion turbine be definite value, in systems using the mode of choke valve decompression Ensure that the inlet pressure of compressor and expansion turbine is constant.
A kind of 5. compression carbon dioxide energy-storage system of double underground gas storage rooms according to claims 1, when saturating in expansion Carbon dioxide after the completion of flat acting is subcritical state, then in compression process, it is necessary to carry out multi-stage compression, cascade EDFA, Expansion work process is, it is necessary to carry out multiple expansion, cascade EDFA, therefore needs in respective process to use cooler and heating respectively Device.
A kind of 6. compression carbon dioxide energy-storage system of double underground gas storage rooms according to claims 1, when saturating in expansion The carbon dioxide put down after finishing work(is supercriticality, then without cooler and heater.
CN201710964845.6A 2017-10-17 2017-10-17 A kind of compression carbon dioxide energy-storage system of double underground gas storage rooms Pending CN107676180A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108547673A (en) * 2018-02-28 2018-09-18 上海柯来浦能源科技有限公司 A kind of Ke using ambient heat power generation is come pumping system
CN109667633A (en) * 2019-01-07 2019-04-23 苏州欧拉透平机械有限公司 Energy output system and method applied to urea plant
CN110345044A (en) * 2019-07-05 2019-10-18 华北电力大学 A kind of compression carbon dioxide energy-storage system that double underground gas storage rooms are recycled with heat accumulation
CN114084569A (en) * 2021-11-12 2022-02-25 长沙理工大学 Method for storing energy by compressing carbon dioxide in deep aquifer carbon dioxide geological storage
CN114810259A (en) * 2022-06-23 2022-07-29 西安热工研究院有限公司 Interstage air extraction backflow gravity compressed air energy storage system and energy storage method
CN115306500A (en) * 2022-08-03 2022-11-08 哈尔滨工业大学 Transcritical compressed carbon dioxide energy storage system and operation method thereof
CN115653824A (en) * 2022-11-16 2023-01-31 河南大学 Tidal energy compressed air energy storage device and method utilizing underground aquifer
CN116388405A (en) * 2023-06-07 2023-07-04 势加透博(河南)能源科技有限公司 System and method for integrating carbon dioxide seal and energy storage power generation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
HUI LIU ETAL: "Thermodynamic analysis of a compressed carbon dioxide energy storage system using two saline aquifers at different depths as storage reservoirs", 《ENERGY CONVERSION AND MANAGEMENT》 *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108547673A (en) * 2018-02-28 2018-09-18 上海柯来浦能源科技有限公司 A kind of Ke using ambient heat power generation is come pumping system
CN109667633A (en) * 2019-01-07 2019-04-23 苏州欧拉透平机械有限公司 Energy output system and method applied to urea plant
CN109667633B (en) * 2019-01-07 2024-03-19 苏州欧拉透平机械有限公司 Energy output system and method applied to urea device
CN110345044A (en) * 2019-07-05 2019-10-18 华北电力大学 A kind of compression carbon dioxide energy-storage system that double underground gas storage rooms are recycled with heat accumulation
CN114084569A (en) * 2021-11-12 2022-02-25 长沙理工大学 Method for storing energy by compressing carbon dioxide in deep aquifer carbon dioxide geological storage
CN114084569B (en) * 2021-11-12 2023-11-21 长沙理工大学 Method for developing compressed carbon dioxide energy storage on deep aquifer carbon dioxide geological storage
CN114810259A (en) * 2022-06-23 2022-07-29 西安热工研究院有限公司 Interstage air extraction backflow gravity compressed air energy storage system and energy storage method
CN115306500A (en) * 2022-08-03 2022-11-08 哈尔滨工业大学 Transcritical compressed carbon dioxide energy storage system and operation method thereof
CN115653824A (en) * 2022-11-16 2023-01-31 河南大学 Tidal energy compressed air energy storage device and method utilizing underground aquifer
CN116388405A (en) * 2023-06-07 2023-07-04 势加透博(河南)能源科技有限公司 System and method for integrating carbon dioxide seal and energy storage power generation
CN116388405B (en) * 2023-06-07 2023-08-29 势加透博(河南)能源科技有限公司 System and method for integrating carbon dioxide seal and energy storage power generation

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