CN107675480A - A kind of method that directional water guiding fabric is obtained using corona treatment - Google Patents
A kind of method that directional water guiding fabric is obtained using corona treatment Download PDFInfo
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- CN107675480A CN107675480A CN201710949571.3A CN201710949571A CN107675480A CN 107675480 A CN107675480 A CN 107675480A CN 201710949571 A CN201710949571 A CN 201710949571A CN 107675480 A CN107675480 A CN 107675480A
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- Prior art keywords
- fabric
- plasma
- water guiding
- corona treatment
- directional water
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
Abstract
The invention provides a kind of method that directional water guiding fabric is obtained using corona treatment, fabric is pre-processed with inert gas plasma first；Then with oxygen gas plasma to carrying out surface activation process to fabric；Plasma-coated processing finally is applied to fabric one side with hexamethyldisiloxane steam.The present invention is pre-processed by inert gas to fabric face, instead of the cleaning link of fabric early stage, is advantageously reduced water resources consumption, is reduced waste water, the efficient combination of coating after being also beneficial to, so as to reduce cost of material；Handled by oxygen gas plasma, active group is formed in fabric face, be advantageous to hexamethyldisiloxane steam in coating procedure and form chemical bond with fabric face under plasma jet, improve the fastness and wash durability of coating；This method technique is simple, energy-saving and water-saving, and the fabric obtained has that directional water guiding is good, permeability is excellent, comfortableness is high, good endurance etc. a little.
Description
Technical field
The present invention relates to a kind of method that directional water guiding fabric is obtained using corona treatment, belong to functions of textile fabrics
Finishing technique field.
Background technology
Traditional cotton, hair, silk, fiber crops or the pure spinning of viscose rayon or blend fabric have preferable hydrophilic, hygroscopicity, and
It is wide material sources, cheap, but after substantial amounts of moisture and sweat accumulation, the obvious discomfort of human body can be given.To meet
The demand for the functional fabrics such as people are good to comfortableness, water guide is ventilative, directional water guiding fabric is welcomed by the people, and lifting is natural
The directional water guiding performance of fabric has important practicality and researching value.
At present, the method for obtaining directional water guiding fabric mainly has structural approach and the class of chemical method two.Structural approach is main
It is the directional water guiding that fabric is realized by configuring different fibrous raw materials；Such method is often using hydrophobic chemical fibre and hydrophilic
Fiber is combined.Chemical method mainly constructs two asymmetric parents in face of fabric by various chemical treatments and finishing technique
Hydrophobicity, the wicking differential water pressures between two surfaces are caused so as to realize that the water of orientation conducts.It is but more using fluorine-containing change at present
Compound carries out the hydrophobic treatment of one side to fabric, exists to the health of human body potentially hazardous.In addition, using printing coating
Method, scraper coating, spray water-repelling agent and realize determining for fabric using the methods of electrostatic spinning to carry out fabric face arrangement
To transmissibility.However, most hydrophobic treatment has the problems such as coat fastness is low, water-wash resistance is poor, fabric is had a strong impact on
Using effect.
Coating processes therefore, present in the existing method for obtaining directional water guiding fabric are complicated, coat fastness is low,
The problems such as water-wash resistance is poor, uneven to fabric surface treatments, it is that those skilled in the art are eager to solve.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of technique is simple, environment-friendly, fastness to washing is high, fabric face
The method that processing uniformly obtains directional water guiding fabric using corona treatment.
In order to solve the above-mentioned technical problem, determined the technical scheme is that providing one kind using corona treatment
To the method for water guide fabric, it is characterised in that this method is made up of following 3 steps：
Step 1：Fabric is pre-processed with inert gas plasma；
Step 2：With oxygen gas plasma to carrying out surface activation process to fabric；
Step 3：Plasma-coated processing is applied to fabric one side with hexamethyldisiloxane steam.
Preferably, in the step 1 and step 2, plasma type is low-voltage capacitor discharge plasma.
Preferably, in the step 1, inert gas is one or more of combinations in helium, argon gas, xenon.
Preferably, in the step 1, inert gas plasma processing electric discharge air pressure vacuum is 1 × 10-2Mbar~3
×10-2Mbar, discharge power are 100W~150W, and processing time is 2min~3min.
Preferably, in the step 2, oxygen gas plasma processing electric discharge air pressure vacuum is 2 × 10-2Mbar~4 × 10-2Mbar, discharge power are 100W~150W, and processing time is 3min~5min.
Preferably, in the step 3, the same of plasma-coated processing is applied to fabric one side with hexamethyldisiloxane steam
When, apply in fabric another side and protect.
It is highly preferred that in the step 3, fabric another side is by taping or film is protected.
Preferably, in the step 3, hexamethyldisiloxane steam applies the electric discharge of plasma-coated processing to fabric one side
Air pressure vacuum is 1 × 10-1Mbar~2 × 10-1Mbar, discharge power are 100W~150W, processing time be 2.5min~
3.5min。
Preferably, the fabric is the knitted fabric or woven fabric of the pure spinning or blending of cotton, hair, silk, fiber crops or viscose rayon.Should
Fabric has preferable hydrophily.
Using plasma of the present invention handles fabric face, makes the molecule grafted moiety bond strength of fiber surface in fabric
High, water-fastness and good endurance, and cost is low；Although using hypobaric vacuum environment, single garment is completely suitable for
The directional water guiding arrangement of cloth, it is adapted to directional water guiding to require high, the wet comfortableness of the biography high, cloth of quality better eager to excel in whatever one does.
Compared with prior art, the present invention has the advantages that：
1st, fabric face is pre-processed by inert gas, instead of the cleaning link of fabric early stage, advantageously reduced
Water resources consumption, reduce waste water, the efficient combination of coating after being also beneficial to, so as to reduce cost of material；
2nd, handled by oxygen gas plasma, form active group in fabric face, be advantageous to hexamethyl in coating procedure
Two silicon ether steam form chemical bond under plasma jet with fabric face, improve the fastness and wash durability of coating；
3rd, this method technique is simple, energy-saving and water-saving, and the fabric obtained has that directional water guiding is good, permeability is excellent,
Comfortableness height, good endurance etc. are a little.This method is suitable to promote the exploitation for directional water guiding fabric on a large scale.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of method that directional water guiding pure cotton plain fabric is obtained using corona treatment, is comprised the following steps：
(1) vacuum for setting reaction environment is 2 × 10-2Mbar, using the argon plasma of 110W power, to fabric
Implement 3min pretreatment to remove surface impurity and greasy dirt etc.；
(2) 3 × 10-2Under mbar vacuum, using the oxygen gas plasma under 100W discharge powers to entering to fabric
Row surface activation process, processing time are arranged to 3min；
(3) hexamethyldisiloxane steam is used 1 × 10 after oxygen gas plasma processing-1Mbar vacuum and 100W electric discharge
Plasma-coated processing 3min is applied to fabric in the plasma jet of power, obtains directional water guiding fabric, gained orientation is led
The contact angle of the hydrophobic one side of water pure cotton plain fabric is 150.0 °, and the water droplet wet fabric time is more than 2400 seconds；And fixed
When dripping upper water droplet to the one side of water guide fabric, contact angle is less than 90 °, and the water droplet wet fabric time is less than 3 seconds.It is moreover, prepared
Two surfaces of directional water guiding pure cotton plain fabric when dripping respectively, lower surface can only be oriented to from the upper surface of fabric, and
It is unable to lower surface and is oriented to upper surface.Compared to original untreated pure cotton plain fabric, untreated pure cotton plain fabric
The contact angle on upper and lower surface is respectively less than 90 °, and water droplet can be oriented to lower surface from the upper surface of fabric, can also be led from lower surface
To upper surface.
Wherein, it is another in fabric when described hexamethyldisiloxane steam applies plasma-coated processing to fabric one side
Face is pasted with fabric face with the adhesive tape of homalographic, is advantageous to protect another side fabric not influenceed by coating.
Embodiment 2
A kind of method that directional water guiding llama plain fabric is obtained using corona treatment, including following step
Suddenly：
(1) vacuum for setting reaction environment is 3 × 10-2Mbar, using the helium gas plasma of 100W power, to fabric
Implement 2min pretreatment to remove surface impurity and greasy dirt etc.；
(2) 2 × 10-2Under mbar vacuum, using the oxygen gas plasma under 125W discharge powers to entering to fabric
Row surface activation process, processing time are arranged to 5min；
(3) hexamethyldisiloxane steam is used 2 × 10 after oxygen gas plasma processing-1Mbar vacuum and 110W electric discharge
Plasma-coated processing 3min is applied to fabric in the plasma jet of power, obtains directional water guiding fabric.Gained orientation is led
The contact angle of the hydrophobic one side of water llama plain fabric is 152.0 °, and the water droplet wet fabric time is more than 2400 seconds；And
In water droplet in the one side drop of directional water guiding fabric, contact angle is less than 90 °, and the water droplet wet fabric time is less than 4 seconds.Moreover, institute
When two surfaces of directional water guiding llama plain fabric of preparation are dripped respectively, under can only being oriented to from the upper surface of fabric
Surface, and be unable to lower surface and be oriented to upper surface.Compared to original untreated llama plain fabric, untreated cotton wool mixes
The contact angle for spinning the upper and lower surface of plain fabric is respectively less than 90 °, and water droplet can be oriented to lower surface from the upper surface of fabric,
Upper surface can be oriented to from lower surface.
Wherein, it is another in fabric when described hexamethyldisiloxane steam applies plasma-coated processing to fabric one side
Face is pasted with fabric face with the film of homalographic, is advantageous to protect another side fabric not influenceed by coating.
Embodiment 3
A kind of method that directional water guiding pure wool latitude jersey is obtained using corona treatment, is comprised the following steps：
(1) vacuum for setting reaction environment is 1 × 10-2Mbar, using the argon plasma of 150W power, to fabric
Implement 2min pretreatment to remove surface impurity and greasy dirt etc.；
(2) 2 × 10-2Under mbar vacuum, using the oxygen gas plasma under 110W discharge powers to entering to fabric
Row surface activation process, processing time are arranged to 4min；
(3) hexamethyldisiloxane steam is used 1.5 × 10 after oxygen gas plasma processing-1Mbar vacuum and 150W is put
Plasma-coated processing 2.5min is applied to fabric in the plasma jet of electrical power, obtains directional water guiding fabric.Gained is determined
Contact angle to the hydrophobic one side of water guide pure wool latitude jersey is 135.0 °, and water droplet diffusion time is more than 2400 seconds；And fixed
When the one side of guide liquid drugs injection fabric drips upper water droplet, contact angle is less than 90 °, and water droplet diffusion time is less than 3 seconds.It is moreover, prepared
When two surfaces of directional water guiding knitted fabric are dripped respectively, lower surface can only be oriented to from the upper surface of fabric, and be unable to lower surface
It is oriented to upper surface.Compared to original untreated knitted fabric, the contact angle on the upper and lower surface of untreated knitted fabric is respectively less than 90 °,
And water droplet can be oriented to lower surface from the upper surface of fabric, upper surface can also be oriented to from lower surface.
Wherein, it is another in fabric when described hexamethyldisiloxane steam applies plasma-coated processing to fabric one side
Face is pasted with fabric face with the adhesive tape of homalographic, is advantageous to protect another side fabric not influenceed by coating.
Embodiment 4
A kind of method that directional water guiding linen-cotton twill woven thing is obtained using corona treatment, is comprised the following steps：
(1) vacuum for setting reaction environment is 2 × 10-2Mbar, using the argon plasma of 125W power, to fabric
Implement 3min pretreatment to remove surface impurity and greasy dirt etc.；
(2) 4 × 10-2Under mbar vacuum, using the oxygen gas plasma under 150W discharge powers to entering to fabric
Row surface activation process, processing time are arranged to 5min；
(3) hexamethyldisiloxane steam is used 1 × 10 after oxygen gas plasma processing-1Mbar vacuum and 130W electric discharge
Plasma-coated processing 3.5min is applied to fabric in the plasma jet of power, obtains directional water guiding fabric.Gained orients
The contact angle of the hydrophobic one side of water guide linen-cotton twill woven thing is 149.0 °, and water droplet diffusion time is more than 2400 seconds；And orienting
When the one side of water guide fabric drips upper water droplet, contact angle is less than 90 °, and water droplet diffusion time is less than 5 seconds.Moreover, prepared orientation
When two surfaces of water guide fabric are dripped respectively, lower surface can only be oriented to from the upper surface of fabric, and be unable to lower surface and be oriented to
Surface.Compared to original untreated fabric, the contact angle on the upper and lower surface of untreated fabric is respectively less than 90 °, and water droplet can be from
The upper surface of fabric is oriented to lower surface, can also be oriented to upper surface from lower surface.
Wherein, it is another in fabric when described hexamethyldisiloxane steam applies plasma-coated processing to fabric one side
Face is pasted with fabric face with the adhesive tape of homalographic, is advantageous to protect another side fabric not influenceed by coating.
It is described above, only presently preferred embodiments of the present invention, it is not any to the present invention in form and substantial limitation,
It should be pointed out that for those skilled in the art, on the premise of the inventive method is not departed from, can also make
Some improvement and supplement, these are improved and supplement also should be regarded as protection scope of the present invention.All those skilled in the art,
Without departing from the spirit and scope of the present invention, when made using disclosed above technology contents it is a little more
Dynamic, modification and the equivalent variations developed, it is the equivalent embodiment of the present invention；Meanwhile all substantial technologicals pair according to the present invention
The variation, modification and evolution for any equivalent variations that above-described embodiment is made, still fall within the scope of technical scheme
It is interior.
Claims (9)
- A kind of 1. method that directional water guiding fabric is obtained using corona treatment, it is characterised in that this method is by following 3 steps Rapid composition：Step 1：Fabric is pre-processed with inert gas plasma；Step 2：With oxygen gas plasma to carrying out surface activation process to fabric；Step 3：Plasma-coated processing is applied to fabric one side with hexamethyldisiloxane steam.
- A kind of 2. method that directional water guiding fabric is obtained using corona treatment as claimed in claim 1, it is characterised in that： In the step 1 and step 2, plasma type is low-voltage capacitor discharge plasma.
- 3. a kind of method that directional water guiding fabric is obtained using corona treatment as claimed in claim 1 or 2, its feature are existed In：In the step 1, inert gas is one or more of combinations in helium, argon gas, xenon.
- 4. a kind of method that directional water guiding fabric is obtained using corona treatment as claimed in claim 1 or 2, its feature are existed In：In the step 1, inert gas plasma processing electric discharge air pressure vacuum is 1 × 10-2Mbar~3 × 10-2Mbar, put Electrical power is 100W~150W, and processing time is 2min~3min.
- 5. a kind of method that directional water guiding fabric is obtained using corona treatment as claimed in claim 1 or 2, its feature are existed In：In the step 2, oxygen gas plasma processing electric discharge air pressure vacuum is 2 × 10-2Mbar~4 × 10-2Mbar, discharge work( Rate is 100W~150W, and processing time is 3min~5min.
- A kind of 6. method that directional water guiding fabric is obtained using corona treatment as claimed in claim 1, it is characterised in that： In the step 3, while applying plasma-coated processing to fabric one side with hexamethyldisiloxane steam, in fabric another side Apply protection.
- A kind of 7. method that directional water guiding fabric is obtained using corona treatment as claimed in claim 6, it is characterised in that： In the step 3, fabric another side is by taping or film is protected.
- A kind of 8. method that directional water guiding fabric is obtained using corona treatment as claimed in claim 1, it is characterised in that： In the step 3, hexamethyldisiloxane steam fabric one side is applied the electric discharge air pressure vacuum of plasma-coated processing for 1 × 10-1Mbar~2 × 10-1Mbar, discharge power are 100W~150W, and processing time is 2.5min~3.5min.
- A kind of 9. method that directional water guiding fabric is obtained using corona treatment as claimed in claim, it is characterised in that： The fabric is the knitted fabric or woven fabric of the pure spinning or blending of cotton, hair, silk, fiber crops or viscose rayon.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108893971A (en) * | 2018-07-05 | 2018-11-27 | 南通赛晖科技发展股份有限公司 | A kind of device and method for antifouling moisture permeable fabrics online processing |
| CN109736094A (en) * | 2018-12-24 | 2019-05-10 | 浙江理工大学 | It is a kind of to assign the hydrophilic single side of silk fabric single side hydrophobic cold plasma method for sorting |
| CN110616563A (en) * | 2019-11-01 | 2019-12-27 | 疏博（上海）纳米科技有限公司 | Preparation method of super-oleophobic textile |
| CN111086312A (en) * | 2019-12-04 | 2020-05-01 | 江阴芗菲服饰有限公司 | Anti-ultraviolet composite knitted fabric and processing method thereof |
| CN112301725A (en) * | 2019-08-02 | 2021-02-02 | 香港纺织及成衣研发中心 | Waterproof fabric obtained by plasma technology and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108893971A (en) * | 2018-07-05 | 2018-11-27 | 南通赛晖科技发展股份有限公司 | A kind of device and method for antifouling moisture permeable fabrics online processing |
| CN109736094A (en) * | 2018-12-24 | 2019-05-10 | 浙江理工大学 | It is a kind of to assign the hydrophilic single side of silk fabric single side hydrophobic cold plasma method for sorting |
| CN112301725A (en) * | 2019-08-02 | 2021-02-02 | 香港纺织及成衣研发中心 | Waterproof fabric obtained by plasma technology and preparation method thereof |
| CN112301725B (en) * | 2019-08-02 | 2023-04-07 | 香港纺织及成衣研发中心 | Waterproof fabric obtained by plasma technique |
| CN110616563A (en) * | 2019-11-01 | 2019-12-27 | 疏博（上海）纳米科技有限公司 | Preparation method of super-oleophobic textile |
| CN111086312A (en) * | 2019-12-04 | 2020-05-01 | 江阴芗菲服饰有限公司 | Anti-ultraviolet composite knitted fabric and processing method thereof |
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