CN106917304B - A kind of graphite olefinic functionality cotton fabric and preparation method thereof - Google Patents
A kind of graphite olefinic functionality cotton fabric and preparation method thereof Download PDFInfo
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- CN106917304B CN106917304B CN201710224815.1A CN201710224815A CN106917304B CN 106917304 B CN106917304 B CN 106917304B CN 201710224815 A CN201710224815 A CN 201710224815A CN 106917304 B CN106917304 B CN 106917304B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of graphite olefinic functionality cotton fabrics and preparation method thereof, belong to intelligent wearing, function textile technical field, it is characterized in that, graphene oxide is subjected to amino or thiolated modified first, it carries out compound obtaining graphene oxide reactive dye with reactive dyes with multi-reactive groups again, cotton fabric is disseminated in gained graphene oxide reactive dye under ultrasound condition and obtains graphene oxide cotton fabric, most restores to obtain graphite olefinic functionality cotton fabric through reducing agent afterwards；The present invention collects dyeing and electric conductivity finishing functions in a bath, assigns common cotton woven graphite alkene excellent electrical functions, and stability, heat-resisting quantity, colorfastness to rubbing are significantly improved.
Description
Technical field
The present invention relates to intelligent wearing, function textile technical fields, and in particular to a kind of graphite olefinic functionality cotton fabric and
Preparation method.
Background technology
With the continuous development of human society, decoration that existing clothing has hides the simple functions such as body, warming and cannot expire
The needs of sufficient people, function textile have been increasingly becoming the mainstream of textile product research and development instantly, such as intelligence wearing, electromagnetic screen
Cover cloth, antistatic clothing etc..Grapheme material is being weaved because of performances such as its unique two-dimensional structure and significant electricity, mechanics
Application in product increasingly attracts much attention, and becomes the new approach of currently related function textile research, it is intended to assign
The excellent electricity of textile grapheme material, mechanical property are given, such as application No. is 201510540291.8 Chinese invention patents
Shen Qing Publication a kind of graphene/cotton compliant conductive fabric and preparation method thereof, by the method for dipping-drying in cotton fabric
Surface covers graphene oxide, and graphene oxide reduction is then become graphene by the method that in-situ chemical restores, to
There is persistence difference in the good electric conductivity of providing cotton fabric.Application No. is 201610665999.0 Chinese inventions
A kind of patent application publication preparation method of manganese dioxide/graphene compound carbonizing cotton fabric, by graphene oxide with impregnate-
The mode of coating handles cotton fabric, and by manganese dioxide nano particle deposition in graphene oxide coating surface, to obtain well
Electric conductivity, but cotton fabric and graphene oxide lack the combination of chemical bond by molecular separating force in the product structure,
Poor water resistance.
In addition, it is two baths, technological process that the prior art carries out graphene conductive arrangement and dyeing to cotton fabric
Long, operation is more complex, and often fabric need to be made to be firmly combined with finishing agent by crosslinking agent in prior art, it is affected by environment compared with
Greatly, technique is more complex.
Invention content
The technical problem to be solved by the present invention is in view of the deficiencies of the prior art, provide a kind of graphite olefinic functionality cotton fabric
And preparation method thereof, this technique collects dyeing and electric conductivity finishing functions in a bath, assigns common cotton woven graphite alkene excellent electricity
Function is learned, and stability, heat-resisting quantity, colorfastness to rubbing have remarkable result.
The technical solution that the present invention solves above-mentioned technical problem is as follows：The preparation side of the graphite olefinic functionality cotton fabric
Method, which is characterized in that graphene oxide is subjected to amino or thiolated modified first, then is answered with reactive dyes with multi-reactive groups
Conjunction obtains graphene oxide reactive dye, disseminates cotton fabric in gained graphene oxide reactive dye under ultrasound condition
To graphene oxide cotton fabric, most restores to obtain graphite olefinic functionality cotton fabric through reducing agent afterwards, comprise the technical steps that：
Step 1：Graphene oxide is modified
Graphene oxide is dissolved in the alcoholic solution of modifying agent, is ultrasonically treated, takes out and filters separation, is cleaned with pure water dry
Drying after net, is made modified graphene oxide；The modifying agent uses octadecylamine or 3-mercaptopropyi trimethoxy silane, amino
Or sulfydryl occurs covalent reaction with the hydroxyl on graphene oxide and obtains amino or mercapto-functionalized graphene oxide, the oxygen
The mass ratio of graphite alkene and modifying agent is 1:1-2, controls temperature at 20-80 DEG C when ultrasonic, ultrasonic time 1-10h；It is dry
Temperature is 20-120 DEG C, drying time 1-2h；
Step 2：Modified graphene oxide is compound with reactive dye
Reactive dyes with multi-reactive groups is dissolved with pure water, and reactive dye solution is added in modified graphene oxide obtained by step 1
In, it is ultrasonically treated under room temperature, graphene oxide reactive dye is made；Amino, fragrant amino, alcoxyl in reactive dyes with multi-reactive groups
The groups such as base occur covalent reaction with the hydroxyl in graphene oxide, carboxyl, epoxy bond, amino groups and are combined, and make active dye
Material is organically combined to obtain graphene oxide reactive dye by chemical bond with graphene oxide；The multi-active base activity dye
The mass ratio of material and dissolving pure water is 1:The mass ratio of 10-20, modified graphene oxide and reactive dyes with multi-reactive groups is 1:
1-4, sonication treatment time 10-15h；
Step 3：The preparation of graphene oxide cotton fabric
Cotton fabric is put into the graphene oxide reactive dye solution obtained by step 2 and adds salt fixation, in ultrasound environments
Graphene oxide cotton fabric is made in dip dyeing；A variety of bases such as a chloro-s-triazine base, amino contained by graphene oxide reactive dye
Group have higher affinity to fiber, with Van der Waals force, hydrogen bond, covalent bond hybrid mode anchor on fiber obtain oxidation stone
Black alkene cotton fabric；A concentration of 20-50g/L of the fixation salt, dip dyeing temperature are 70-100 DEG C, immerged time 1-3h, bath raio
It is 1:10-30；
Step 4：Redox graphene cotton fabric
Graphene oxide cotton fabric obtained by step 3 is restored with reducing agent, drying after being used in combination pure water to clean
Graphite olefinic functionality cotton fabric；The mass ratio of the graphene oxide cotton fabric and reducing agent is 0.2-0.3:1, the concentration of reducing agent
For 10-20g/L, reduction temperature is 40-60 DEG C, recovery time 12-36h, and drying temperature is 40-150 DEG C, drying time 1-
5h。
The reactive dyes with multi-reactive groups uses KD type reactive dye.
Modifier concentration is 1% in the step 1, and the solvent of modifying agent uses ethyl alcohol.
Fixation salt uses sodium sulphate in the step 3.
First the graphene oxide cotton made from deionized water rinsing step three is knitted before reducing agent reduction in the step 4
Object.
Reducing agent in the step 4 using sodium dithionite, sodium sulfite, glucose, ascorbic acid, hydrazine hydrate,
One or two or more kinds of mixtures in boron hydracid sodium.
The present invention also provides a kind of graphite olefinic functionality cotton fabrics, which is characterized in that is made using above-mentioned preparation method.
The beneficial effects of the invention are as follows：The excellent electric conductivity of providing cotton fabric, reactive dye and graphene in structure
Be bonded with chemical bonds, and a variety of groups such as a chloro-s-triazine base, amino contained by reactive dye with Van der Waals force, hydrogen bond,
The hybrid mode of covalent bond anchors on fiber, and stability, heat-resisting quantity, crock fastness are significantly improved, and can make common cotton
Fabric has electrical functions, solves the problems, such as that cotton fabric is functional single, and the dyeing of this technique collection and conductive sexual function are whole
It manages in a bath, shortens technological process, preparation process is simple, without adding crosslinking agent, is easy to large-scale production, prevents in electromagnetism
The multiple fields such as shield, intelligence wearing, function textile possess preferable market prospects.
Specific implementation mode
The present invention is described in further detail with reference to embodiment, so that the public preferably grasps the embodiment party of the present invention
Method, illustrated embodiment are served only for explaining the present invention, be not intended to limit the scope of the present invention.
Embodiment 1
Graphene oxide is carried out amino or mercapto by a kind of preparation method of graphite olefinic functionality cotton fabric of the present embodiment first
Baseization be modified, then with reactive dyes with multi-reactive groups carry out it is compound obtain graphene oxide reactive dye, by cotton under ultrasound condition
Fabric is disseminated in gained graphene oxide reactive dye obtains graphene oxide cotton fabric, most restores to obtain stone through reducing agent afterwards
Black olefinic functionality cotton fabric, comprises the technical steps that：
Step 1：Graphene oxide is modified
The graphene oxide of 1 mass parts is dissolved in 1% octadecylamine alcoholic solution of 1 mass parts, is ultrasonically treated at 20 DEG C
10h takes out and filters separation, after being cleaned up with pure water at 20 DEG C dry 2h, modified graphene oxide is made；
Step 2：Modified graphene oxide is compound with reactive dye
The reactive brilliant bule KD-B of 1 mass parts is dissolved in the pure water of 10 mass parts, and the oxidation stone of modified 1 mass parts is added
Black alkene is ultrasonically treated 10h under room temperature, and graphene oxide reactive dye are made；
Step 3：The preparation of graphene oxide cotton fabric
Cotton fabric is put into the graphene oxide dye solution obtained by step 2 and adds sodium sulphate fixation, ultrasound at 70 DEG C
1h is disseminated, graphene oxide cotton fabric, the wherein a concentration of 20g/L of sodium sulphate, bath raio 1 is made: 30；
Step 4：Redox graphene cotton fabric
It is put into the ascorbic acid solution of a concentration of 10g/L after graphene oxide cotton fabric deionized water is flushed three times
Reduction reaction is carried out, wherein graphene oxide cotton fabric and the mass ratio of solid ascorbic acid is 0.2:36h is reacted at 0 DEG C of Isosorbide-5-Nitrae,
Then 5h is dried up to graphite olefinic functionality cotton fabric at 40 DEG C after being cleaned with pure water.
Embodiment 2
Graphene oxide is carried out amino or mercapto by a kind of preparation method of graphite olefinic functionality cotton fabric of the present embodiment first
Baseization be modified, then with reactive dyes with multi-reactive groups carry out it is compound obtain graphene oxide reactive dye, by cotton under ultrasound condition
Fabric is disseminated in gained graphene oxide reactive dye obtains graphene oxide cotton fabric, most restores to obtain stone through reducing agent afterwards
Black olefinic functionality cotton fabric, comprises the technical steps that：
Step 1：Graphene oxide is modified
The graphene oxide of 1 mass parts is dissolved in 1% octadecylamine alcoholic solution of 1.5 mass parts, at 50 DEG C at ultrasound
Manage 5h, take out and filter separation, after being cleaned up with pure water at 70 DEG C dry 1.5h, modified graphene oxide is made；
Step 2：Modified graphene oxide is compound with reactive dye
The reactive scarlet KD-B of 1 mass parts is dissolved in the pure water of 15 mass parts, and the oxidation of modified 0.4 mass parts is added
Graphene is ultrasonically treated 12h under room temperature, and graphene oxide reactive dye are made；
Step 3：The preparation of graphene oxide cotton fabric
Cotton fabric is put into the graphene oxide dye solution obtained by step 2 and adds sodium sulphate fixation, ultrasound at 85 DEG C
2h is disseminated, graphene oxide cotton fabric, the wherein a concentration of 35g/L of sodium sulphate, bath raio 1 is made: 20；
Step 4：Redox graphene cotton fabric
It is put into the sodium sulfite solution of a concentration of 15g/L after graphene oxide cotton fabric deionized water is flushed three times
Reduction reaction is carried out, the wherein mass ratio of graphene oxide cotton fabric and solid sodium sulfite is 0.25:It is reacted at 1,50 DEG C
For 24 hours, 3h is dried up to graphite olefinic functionality cotton fabric at 100 DEG C after then being cleaned with pure water.
Embodiment 3
Graphene oxide is carried out amino or mercapto by a kind of preparation method of graphite olefinic functionality cotton fabric of the present embodiment first
Baseization be modified, then with reactive dyes with multi-reactive groups carry out it is compound obtain graphene oxide reactive dye, by cotton under ultrasound condition
Fabric is disseminated in gained graphene oxide reactive dye obtains graphene oxide cotton fabric, most restores to obtain stone through reducing agent afterwards
Black olefinic functionality cotton fabric, comprises the technical steps that：
Step 1：Graphene oxide is modified
The graphene oxide of 1 mass parts is dissolved in 1% octadecylamine alcoholic solution of 2 mass parts, is ultrasonically treated at 80 DEG C
1h takes out and filters separation, after being cleaned up with pure water at 120 DEG C dry 1h, modified graphene oxide is made；
Step 2：Modified graphene oxide is compound with reactive dye
Huang KD-B in the activity of 1 mass parts is dissolved in the pure water of 20 mass parts, and the oxygen of modified 0.25 mass parts is added
Graphite alkene is ultrasonically treated 15h under room temperature, and graphene oxide reactive dye are made；
Step 3：The preparation of graphene oxide cotton fabric
Cotton fabric is put into the graphene oxide dye solution obtained by step 2 and adds sodium sulphate fixation, is surpassed at 100 DEG C
Sound disseminates 3h, and graphene oxide cotton fabric, the wherein a concentration of 50g/L of sodium sulphate, bath raio 1 is made: 30；
Step 4：Redox graphene cotton fabric
The sodium dithionite that a concentration of 20g/L is put into after graphene oxide cotton fabric deionized water is flushed three times is molten
Reduction reaction is carried out in liquid, the mass ratio of wherein graphene oxide cotton fabric and solid sodium dithionite is 0.3:At 1,60 DEG C
12h is reacted, 1h is dried at 150 DEG C up to graphite olefinic functionality cotton fabric after then being cleaned with pure water.
Graphite olefinic functionality cotton fabric made from the method for graphene oxide solution is directly padded with the cotton fabric of the prior art
As a comparison case 1, the graphite olefinic functionality cotton fabric made from surface of cotton fabric direct spraying graphite ene coatings as a comparison case 2,
Compounding dressing liquid containing graphene is subjected to graphite olefinic functionality cotton fabric as a comparison case 3 made from final finishing to cotton fabric；
The comparative example 1 is used cotton fabric with bath raio 1:30 oxide impregnation graphene solutions carry out two leachings two and roll, and roll
Remaining rate is 80%, and then wherein graphene oxide concentration is cleaned with embodiment 1 with deionized water, then dry 25min at 70 DEG C,
5min is baked at 120 DEG C to be made；
The comparative example 2 is atomized graphene dispersing solution by spray gun, and the dispersion liquid of atomization is then sprayed at cotton and is knitted
Object surface and vapor away dispersion solvent be made, wherein dispersion solvent use ethyl alcohol, a concentration of 1g/L of graphene dispersing solution；
The comparative example 3 is used cotton fabric with bath raio 1:30 impregnated graphite alkene/polyurethane compositional liquor carries out two leachings two
It rolls, pick-up 80%, wherein the mass fraction of graphene is 1%, is then cleaned with deionized water, then dry 25min at 70 DEG C,
5min is baked at 120 DEG C to be made.
Function cotton fabric made from comparative example 1, comparative example 2, comparative example 3 and above-described embodiment is subjected to surface electricity respectively
Resistance rate is tested and crock fastness test, and wherein surface resistivity test equipment uses GEST-121 volumetric surface resistance determinators
（Beijing Guan Cejing power utilization instrument devices Co., Ltd system）, standard is executed with reference to GB/T12703.4-2010, crock fastness tester
Device uses YG571B type dyefastness frictiographs, is produced by Wenzhou border high detection Instrument Ltd., executes standard reference
GB3920-1997；Test data is shown in Table 1.
The test result of table 1 comparative example and embodiment fabric
| Classification | Untreated cotton fabric | Comparative example 1 | Comparative example 2 | Comparative example 3 | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Sheet resistance/Ω | Insulator | 4.21*105 | 7.85*102 | 8.83*104 | 9.54*102 | 2.78*103 | 1.13*103 |
| Wash 25 rear surface resistance/Ω | Insulator | 8.87*106 | 6.58*108 | 4.35*105 | 9.67*102 | 2.48*103 | 1.36*103 |
| 80 DEG C of following table surface resistance growth rate/% | -- | 3.2 | 1.4 | 0.4 | 0.4 | 0.2 | 0.25 |
| 100 DEG C of following table surface resistance growth rate/% | -- | 5.2 | 2.5 | 2.2 | 0.4 | 0.3 | 0.4 |
| 120 DEG C of following table surface resistance growth rate/% | -- | 8.6 | 6.4 | 7.8 | 1.1 | 1.4 | 1.0 |
| 150 DEG C of following table surface resistance growth rate/% | -- | 13.4 | 21.3 | 10.9 | 2.7 | 2.3 | 2.3 |
| 200 DEG C of following table surface resistance growth rate/% | -- | 25.4 | 40.6 | 18.6 | 4.1 | 4.3 | 4.6 |
| Dry friction color fastness/grade | 3-4 | 3 | 3 | 4 | 5 | 4-5 | 5 |
| Wet friction color fastness/grade | 3 | 2-3 | 2-3 | 3 | 4-5 | 4 | 4-5 |
From the data in table 1, it can be seen that the surface of cotton fabric resistance after this method arranges is substantially reduced, i.e., electric conductivity obviously carries
Height is significantly improved compared with comparative example 1 and comparative example 3, and electric conductivity still keeps higher level after washing 25 times, right
Although 2 sheet resistance of ratio is smaller, electric conductivity is remarkably decreased after washing 25 times, i.e., persistence is poor, and comparative example 2
Technique be easy to cause coating thickness unevenness, cause the uneven stabilization of electric conductivity；The table of comparative example 1, comparative example 2, comparative example 3
Surface resistance with temperature raising increase substantially, and respectively 100 DEG C, 120 DEG C, 120 DEG C of following table surface resistance growth rates be more than just 5%,
And graphene cotton fabric produced by the present invention increases electric conductivity with temperature and still keeps excellent, even if in 200 DEG C of lower surface electricity
Growth rate is hindered still 5% hereinafter, i.e. thermal stability is significantly improved；Dry fastness and fastness to wet rubbing and source textile and right
Ratio is compared and is significantly improved, therefore has significant creative feature.
The invention has the advantages that graphene cotton fabric providing cotton fabric made from preparation method provided by the invention is excellent
Different electric conductivity, reactive dye are bonded with chemical bonds with graphene in structure, and the chlorine contained by reactive dye is equal
A variety of groups such as triazine radical, amino are anchored at the hybrid mode of Van der Waals force, hydrogen bond, covalent bond on fiber, stability, resistance to height
Warm nature, crock fastness are significantly improved, and common cotton fabric can be made to have electrical functions, and it is single to solve cotton fabric functionality
The problem of, and this technique collects dyeing and electric conductivity finishing functions in a bath, shortens technological process, preparation process is simple, is not necessarily to
Crosslinking agent is added, large-scale production is easy to, is possessed preferably in multiple fields such as electromagnetic protection, intelligence wearing, function textiles
Market prospects.
Above-described embodiment is exemplary, and is not considered as limiting the invention, all according to scope of the present invention patent
The equivalent changes and modifications done should all belong to the covering scope of the present invention.
Claims (7)
1. a kind of preparation method of graphite olefinic functionality cotton fabric, which is characterized in that graphene oxide is carried out amino or mercapto first
Baseization be modified, then with reactive dyes with multi-reactive groups carry out it is compound obtain graphene oxide reactive dye, by cotton under ultrasound condition
Fabric is disseminated in gained graphene oxide reactive dye obtains graphene oxide cotton fabric, most restores to obtain stone through reducing agent afterwards
Black olefinic functionality cotton fabric, comprises the technical steps that：
Step 1：Graphene oxide is modified
Graphene oxide is dissolved in the alcoholic solution of modifying agent, is ultrasonically treated, takes out and filters separation, after being cleaned up with pure water
Modified graphene oxide is made in drying；The modifying agent uses octadecylamine or 3-mercaptopropyi trimethoxy silane, the oxidation
The mass ratio of graphene and modifying agent is 1:1-2, controls temperature at 20-80 DEG C when ultrasonic, ultrasonic time 1-10h；Dry temperature
Degree is 20-120 DEG C, drying time 1-2h；
Step 2：Modified graphene oxide is compound with reactive dye
Reactive dyes with multi-reactive groups is dissolved with pure water, and modified graphene oxide obtained by step 1 is added in reactive dye solution,
It is ultrasonically treated under room temperature, graphene oxide reactive dye is made；The quality of the reactive dyes with multi-reactive groups and dissolving pure water
Than being 1:The mass ratio of 10-20, modified graphene oxide and reactive dyes with multi-reactive groups is 1:1-4, sonication treatment time 10-
15h；
Step 3：The preparation of graphene oxide cotton fabric
Cotton fabric is put into the graphene oxide reactive dye solution obtained by step 2 and adds salt fixation, is soaked in ultrasound environments
Graphene oxide cotton fabric is made in dye；A concentration of 20-50g/L of the fixation salt, dip dyeing temperature is 70-100 DEG C, when dip dyeing
Between be 1-3h, bath raio 1:10-30；
Step 4：Redox graphene cotton fabric
Graphene oxide cotton fabric obtained by step 3 is restored with reducing agent, drying graphite after being used in combination pure water to clean
Olefinic functionality cotton fabric；The mass ratio of the graphene oxide cotton fabric and reducing agent is 0.2-0.3:1, reducing agent it is a concentration of
10-20g/L, reduction temperature are 40-60 DEG C, recovery time 12-36h, and drying temperature is 40-150 DEG C, drying time 1-5h.
2. the preparation method of graphite olefinic functionality cotton fabric according to claim 1, which is characterized in that the multi-active base is lived
Property dyestuff use KD type reactive dye.
3. the preparation method of graphite olefinic functionality cotton fabric according to claim 1, which is characterized in that change in the step 1
Property agent concentration be 1%, the solvent of modifying agent uses ethyl alcohol.
4. the preparation method of graphite olefinic functionality cotton fabric according to claim 1, which is characterized in that solid in the step 3
Color salt uses sodium sulphate.
5. the preparation method of graphite olefinic functionality cotton fabric according to claim 1, which is characterized in that in the step 4 also
Graphene oxide cotton fabric made from deionized water rinsing step three is first used before former agent reduction.
6. the preparation method of graphite olefinic functionality cotton fabric according to claim 1, which is characterized in that in the step 4
Reducing agent is using sodium dithionite, sodium sulfite, glucose, ascorbic acid, hydrazine hydrate, one kind in boron hydracid sodium or two kinds
Above mixture.
7. a kind of graphite olefinic functionality cotton fabric, which is characterized in that use preparation method system as claimed in any one of claims 1 to 6
?.
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| CN111705530A (en) * | 2020-06-30 | 2020-09-25 | 北京石墨烯研究院 | Graphene modified fiber/fabric and preparation method thereof |
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| CN115995348B (en) * | 2023-03-23 | 2023-07-28 | 今朝时代(青岛)新能源科技有限公司 | Three-dimensional electrode material applied to super capacitor and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102995394A (en) * | 2012-12-17 | 2013-03-27 | 常州大学 | Graphene oxide-based anti-bacterial finishing agent for dyeing, and preparation method and application thereof |
| CN106012544A (en) * | 2016-08-10 | 2016-10-12 | 苏州佰锐生物科技有限公司 | Graphene/polyaniline conductive cotton fabric production method |
-
2017
- 2017-04-07 CN CN201710224815.1A patent/CN106917304B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102995394A (en) * | 2012-12-17 | 2013-03-27 | 常州大学 | Graphene oxide-based anti-bacterial finishing agent for dyeing, and preparation method and application thereof |
| CN106012544A (en) * | 2016-08-10 | 2016-10-12 | 苏州佰锐生物科技有限公司 | Graphene/polyaniline conductive cotton fabric production method |
Non-Patent Citations (1)
| Title |
|---|
| 氧化石墨烯的制备及纯棉织物的抗静电整理;苗广远;《印染》;20161031(第20期);第35-37、45页 * |
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