CN107674934A - A kind of air supply system and technique of novel direct-reduction iron reformer - Google Patents

A kind of air supply system and technique of novel direct-reduction iron reformer Download PDF

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Publication number
CN107674934A
CN107674934A CN201711261304.3A CN201711261304A CN107674934A CN 107674934 A CN107674934 A CN 107674934A CN 201711261304 A CN201711261304 A CN 201711261304A CN 107674934 A CN107674934 A CN 107674934A
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CN
China
Prior art keywords
gas
reformer
vertical
catalyst
heat exchange
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CN201711261304.3A
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Chinese (zh)
Inventor
薛钟安
刘建兵
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Shanxi Metallurgical Engineering Technology Co Ltd
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Shanxi Metallurgical Engineering Technology Co Ltd
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Priority to CN201711261304.3A priority Critical patent/CN107674934A/en
Publication of CN107674934A publication Critical patent/CN107674934A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/14Multi-stage processes processes carried out in different vessels or furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0073Selection or treatment of the reducing gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/02Making spongy iron or liquid steel, by direct processes in shaft furnaces

Abstract

The invention discloses a kind of air supply system and technique of novel direct-reduction iron reformer, the technique be by shaft furnace discharge top gas it is scrubbed after be divided into gas 1 and gas 2;Gas 1 and unstripped gas, which merge to be passed through in vertical reformer feed gas passage, carries out catalytic reforming reaction, and caused reformation gas is delivered to shaft furnace production DRI as also Primordial Qi, and closed cycle uses;Gas 2 and combustion air are delivered to the flue gas that convection section goes out with vertical reformation fire grate and carry out heat exchange, the flue gas to cool by heat exchange is discharged by chimney, it is delivered to vertical reformer as fuel gas through heat exchange elevated temperature gas 2 and makees fuel gas and use, is also delivered to vertical reformer through heat exchange heating combustion air and makees combustion-supporting gas and use.The present invention is filled with the catalyst formed by porous checker brick dipping nickel in vertical reformer, using standby vertical reformer as shared regenerating furnace, the light regeneration of catalyst is realized without sulfur removal technology can, reduces energy resource consumption and cost of investment.

Description

A kind of air supply system and technique of novel direct-reduction iron reformer
Technical field
The invention belongs to metallurgical technology field, is related to a kind of technology of DRI, more particularly to a kind of Novel direct Connect the air supply system and technique of reduced iron reformer.
Background technology
DRI refers to that a kind of iron ore is less than under the conditions of fusion temperature the also ironmaking of original production sponge iron in stove Production process.Sponge iron is a kind of substitute of steel scrap, is that electric furnace refines clean steel, the indispensable impurity diluent of high-quality steel, It is the high-quality cooling agent of pneumatic steelmaking, is to develop the indispensable raw material of Ferrous Metallurgy short route.2014, the whole world was directly also Former iron yield is 74,500,000 tons, and direct-reduction technique is classified as one of Main way of development of iron & steel industry.
Due to following deficiency be present in Direct Reducing Iron Process:(1)Because Direct Reducing Iron Process needs to use catalyst, And catalyst is expensive, cost is generally 240,000/ton, in order to avoid reformer catalyst poisoning causes the waste of catalyst, Need to set up complicated fine desulfurizing technology and/or catalyst regeneration process, desulfurization is carried out to unstripped gas, not only limit raw material The species of gas, and, it is necessary to which stop production to overhaul replacing or regeneration, not only have a strong impact on life after the catalyst poisoning in reformer The normal operation of production, and increase cost of investment;(2)It is more big using the reformer of horizontal arrangement, floor space;(3)Due to de- Sulphur technique is higher to the pressure of source of the gas, it usually needs first source of the gas is boosted and is depressured is used again after desulfurization, to fuel blower fan and Compressor has higher requirement, it is necessary to expend substantial amounts of power resource.
The content of the invention
It is new directly also the invention discloses one kind in order to solve the problems, such as that Direct Reducing Iron Process is present in the prior art The air supply system and technique of former iron reformer, it is filled with the vertical reformer and is urged by what porous checker brick dipping nickel was formed Agent, using standby vertical reformer as shared regenerating furnace, the light regeneration of catalyst is realized without sulfur removal technology can, is dropped Low energy expenditure and cost of investment.
The technical proposal of the invention is realized in this way:
On the one hand, the invention discloses a kind of air supply system of novel direct-reduction iron reformer, N+M vertical reformers, M are individual Shaft furnace, washer, convection section, unstripped gas blower fan, combustion fan, purging motor, wherein N number of vertical reformer is as shared regeneration Stove uses;Fuel gas passageway and feed gas passage are provided with the vertical reformer, be filled with the feed gas passage by The catalyst that porous checker brick dipping nickel is formed, and entered by the unstripped gas in the flue gas and feed gas passage in fuel gas passageway Row heat exchange;Gas import is reformed by pipeline and the outlet of the reformer feed gas passage on the shaft furnace, for inciting somebody to action Feed gas catalytic without desulfurization reforms gas and is delivered to shaft furnace production DRI caused by reforming, the furnace roof on the shaft furnace Gas exports the inlet communication with washer, and the outlet of the washer passes through the pipeline top gas import with the convection section respectively With the inlet communication of unstripped gas blower fan;The outlet of the unstripped gas blower fan passes through pipeline and the vertical reformer feed gas passage Inlet communication;Fuel gas outlet, gas approach, exhanst gas outlet, combustion air inlet, combustion-supporting sky are additionally provided with the convection section Gas exports, and the gas approach of the convection section connects with the fuel gas passageway of the vertical reformer, the flue gas of the convection section Outlet is connected by pipeline with chimney, and the combustion air inlet of the convection section connects with combustion fan, the combustion of the convection section The outlet of material gas and fuel gas passageway of the combustion air exports respectively with the vertical reformer connect, for will be by being changed with flue gas The top gas of heat heating is passed through in fuel gas passageway as the combustion air of fuel gas and heat exchange heating;
The purging motor connects with the feed gas passage of the vertical reformer, when catalyst poisoning in vertical reformer, Start the vertical reformer as shared regenerating furnace to replace the vertical reformer of catalyst poisoning, and by purging motor to urging Regeneration gas is advertised in the vertical reformer of agent poisoning, realizes that catalyst regenerates;
Wherein, N >=1, M >=1
As a kind of preferred embodiment, the catalyst is formed by the thick nickel coatings of porous checker brick dipping 0.5-1mm.
The bottom of the vertical reformer side is provided with raw material gas inlet, is set on the top of the vertical reformer opposite side Have and reform gas outlet, be arranged in parallel feed gas passage provided with a series of between raw material gas inlet and the outlet of reformation gas, and will urge Agent, which is placed in, to be uniformly distributed in feed gas passage, and the furnace wall of the vertical reformer is made of refractory material.
As a kind of preferred embodiment, the regeneration gas is air or oxygen, or the regeneration gas is by as blowing The nitrogen of scavenging and as main regeneration gas air or oxygen form.The process of regeneration is:The nitrogen for being first passed through purge gass blows Sweep, then be passed through main regeneration gas air or oxygen and regenerated, be then passed through nitrogen purging again.
As a kind of preferred embodiment, the catalyst is to impregnate the thick nickel of 0.1 ± 0.05mm by porous checker brick to apply What layer was formed.
On the other hand, the invention also discloses a kind of air feed craft of novel direct-reduction iron reformer, shaft furnace is discharged Top gas it is scrubbed after be divided into gas 1 and gas 2;
Gas 1 and unstripped gas, which merge, is passed through the raw material that vertical reformer is filled with the catalyst formed by porous checker brick dipping nickel Catalytic reforming reaction is carried out in gas passage, caused reformation gas is delivered to shaft furnace production DRI as also Primordial Qi, closed circuit Recycle;
Gas 2 and combustion air are delivered to the flue gas that convection section goes out with vertical reformation fire grate and carry out heat exchange, are dropped by heat exchange The flue gas of temperature is discharged by chimney, is delivered to vertical reformer as fuel gas through heat exchange elevated temperature gas 2 and is made fuel gas and uses, Vertical reformer, which is also delivered to, through heat exchange heating combustion air makees combustion-supporting gas use;Catalyst poisoning in vertical reformer When, start as the vertical reformer for sharing regenerating furnace to replace the vertical reformer of catalyst poisoning, and pass through purging motor Regeneration gas is advertised into the vertical reformer of catalyst poisoning.
As a kind of preferred embodiment, the regeneration gas is air or oxygen, when vertical reformer run a period of time, When causing reforming efficiency to reduce because of catalyst poisoning, air or oxygen is blasted, the sulphur that is enriched with the porous checker brick of nickel will be impregnated Carbon burning, the nickel of poisoning is reduced to nickel again, recover catalytic capability.
It is preferred that the regeneration gas can also be by the nitrogen as purge gass, the air or oxygen as main regeneration gas, And the nitrogen composition blown as after.When vertical reformer operation a period of time, cause to reform because of catalyst poisoning and imitate When rate reduces, nitrogen purging is first blasted, through diffusing the unstripped gas in the vertical reformer of hole discharge, then by blasting air or oxygen Gas carries out catalyst regeneration;After the completion of catalyst regeneration, then blast nitrogen the air in reformer is purged it is clean, into standby Use state.
As a kind of preferred embodiment, the catalyst is to impregnate the thick nickel of 0.1 ± 0.05mm by porous checker brick to apply What layer was formed.
The present invention compared with prior art, has the advantages that:
(1)Using vertical reformer is covered, by the way of a part of normal use another part regeneration supply, on the one hand it is catalyzed more Agent regeneration technology is simple, reduces investment, easy to operation;On the other hand vertical reformer is used, floor space is greatly decreased;
(2)Vertical reformer uses specific Bilateral heating mode, enhances homogeneous heating effect;
(3)Using porous checker brick leaching nickel mode, not only catalyst is simple to manufacture catalyst in vertical reformer, and is manufactured Cost is greatly reduced(The price of catalyst in the present invention is about 20,000 yuan/ton, and the price of traditional catalyst be about 240,000/ Ton);
(4)Because catalyst regenerates, easy to operate, cost is low, and a small amount of sulphur contained in DRI selection is taken off in steel-making Remove so that the sulfur removal technology that unstripped gas supply need not be complicated, and then make the applicability of unstripped gas wide, optional coke-stove gas, The kinds of gas sources such as natural gas, coal gas, coal bed gas, facilitate Supplying gas condition;
(5)The integrated artistic of the present invention is simple and convenient to operate, it is not necessary to unstripped gas boosting reduced pressure operation again, often covers the confession of operation Gas blower fan(Unstripped gas blower fan and purging motor difference)Only need a common blower fan, without this kind of high energy consumption in the prior art, The blower fan of high cost, blower fan quantity are reduced, and greatly save power resource;
(6)The present invention uses low pressure plenum system, is easy to shaft furnace to operate, and the requirement to system equipment and pipeline reduces, and then drops Low investment cost and fault rate.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing There is the required accompanying drawing used in technology description to be briefly described, it should be apparent that, drawings in the following description are only this Some embodiments of invention, for those of ordinary skill in the art, without having to pay creative labor, may be used also To obtain other accompanying drawings according to these accompanying drawings.
Fig. 1 is the artwork of the embodiment of the present invention 1.
Fig. 2 is the sectional view of vertical reformer in the embodiment of the present invention 1.
In figure:1st, the vertical reformers of 1#;2nd, the vertical reformers of 2#;3rd, the vertical reformers of 3#;4th, 1# shaft furnaces;5th, 2# shaft furnaces; 6th, 1# washers;7th, 2# washers;8th, 1# unstripped gas blower fan;9th, 2# unstripped gas blower fan;10th, 1# convection sections;11st, 2# convection sections; 12nd, 1# chimneys;13rd, 2# chimneys;14th, 1# combustion fans;15th, 2# combustion fans;16th, 3# purging motors.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made Embodiment, belong to the scope of protection of the invention.
Embodiment 1
The air supply system of novel direct-reduction iron reformer as illustrated in fig. 1 and 2, including the vertical reformers 1 of 1#, the vertical reformers of 2# 2nd, the vertical reformers 3 of 3#, 1# shaft furnaces 4,2# shaft furnaces 5,1# washers 6,2# washers 7,1# unstripped gas blower fan 8,2# unstripped gas wind Machine 9,1# convection sections 10,2# convection sections 11,1# chimneys 12,2# chimneys 13,1# purging motors 14,2# purging motors 15,3# purgings Blower fan 16 and a series of valves for being used to realize that pipeline is opened, closes and switched, the vertical reformers 2 of wherein 2#, which are used as, to be shared Regenerating furnace uses;Fuel gas passageway and feed gas passage are equipped with vertical reformer, is filled with feed gas passage by more The catalyst that hole checker brick dipping nickel is formed, and carried out by the unstripped gas in the flue gas and feed gas passage in fuel gas passageway Heat exchange;1# shaft furnaces 4(2# shaft furnaces 5)On the import of reformation gas pass through pipeline and the vertical reformers 1 of 1#(The vertical reformers 3 of 3#)Raw material The outlet of gas passage, 1# is delivered to as also Primordial Qi for the feed gas catalytic without desulfurization to be reformed into caused gas of reforming Shaft furnace 4(2# shaft furnaces 5)Produce DRI, 1# shaft furnaces 4(2# shaft furnaces 5)On top gas outlet with 1# washers 6(2# is washed Wash device 7)Inlet communication, 1# washers 6(2# washers 7)Outlet by pipeline respectively with 1# convection sections 10(2# convection sections 11)Top gas import and 1# unstripped gas blower fan 8(2# unstripped gas blower fan 9)Inlet communication;1# unstripped gas blower fan 8(2# raw materials Gas blower fan 9)Outlet pass through pipeline and the vertical reformers 1 of 1#(The vertical reformers 3 of 3#)The inlet communication of feed gas passage;1# pairs Flow section 10(2# convection sections 11)On be additionally provided with fuel gas outlet, gas approach, exhanst gas outlet, combustion air inlet, combustion air Outlet, 1# convection sections 10(2# convection sections 11)Gas approach and the vertical reformers 1 of 1#(The vertical reformers 3 of 3#)Fuel gas lead to Road connects, 1# convection sections 10(2# convection sections 11)Exhanst gas outlet pass through pipeline and 1# chimneys 12(2# chimneys 13)Connection, 1# pairs Flow section 10(2# convection sections 11)Combustion air inlet and 1# combustion fans 14(2# combustion fans 15)Connection, 1# convection sections 10 (2# convection sections 11)Fuel gas outlet and combustion air exports reformer 1 vertical with 1# respectively(The vertical reformers 3 of 3#)Combustion The connection of gas passage is expected, for will lead to by the combustion air for being used as fuel gas and heat exchange heating with the top gas that flue gas heat exchange heats up Enter in fuel gas passageway.
Wherein, each vertical reformer side in the vertical reformers 1 of 1#, the vertical reformers 2 of 2#, the vertical reformers 3 of 3# Bottom is provided with raw material gas inlet, is provided with the top of vertical reformer opposite side and reforms gas outlet, in raw material gas inlet and reformation Feed gas passage is arranged in parallel provided with a series of between gas outlet, and catalyst is placed in and is uniformly distributed in feed gas passage, The furnace wall of vertical reformer is made of refractory material;The catalyst is by nickel coating thick porous checker brick dipping 1mm Formed.
The technique is:By shaft furnace discharge top gas it is scrubbed after be divided into gas 1 and gas 2;
Gas 1 and unstripped gas, which merge, is passed through the vertical reformers 1 of 1#(The vertical reformers 3 of 3#)It is filled with and impregnates nickel by porous checker brick Catalytic reforming reaction is carried out in the feed gas passage of the catalyst of formation, caused reformation gas is delivered to 1# shaft furnaces as also Primordial Qi 4(2# shaft furnaces 5)DRI is produced, closed cycle uses;
Gas 2 and combustion air are delivered to 1# convection sections 10(2# convection sections 11)Reformer 1 vertical with 1#(The vertical reformers 3 of 3#) The flue gas of discharge carries out heat exchange, and the flue gas to cool by heat exchange passes through 1# chimneys 12(2# chimneys 13)Discharge, through heat exchange Elevated temperature gas 2 is delivered to the vertical reformers 1 of 1# as fuel gas(The vertical reformers 3 of 3#)Make fuel gas use, through heat exchange liter Warm combustion air is also delivered to the vertical reformers 1 of 1#(The vertical reformers 3 of 3#)Make combustion-supporting gas to use;When in the vertical reformers 1 of 1# Catalyst poisoning when, start the vertical reformers 2 of 2# as shared regenerating furnace to replace the vertical reformations of the 1# of catalyst poisoning Stove 1, and regeneration gas is advertised into the vertical reformers 1 of 1# of catalyst poisoning by 3# purging motors 16.
Specifically blowing method is:Nitrogen purging is first blasted, through diffusing the unstripped gas in the hole discharge vertical reformers 1 of 1#, so Afterwards catalyst regeneration is carried out by blasting air or oxygen;After the completion of catalyst regeneration, then nitrogen is blasted by the vertical reformations of 1# Air purging in stove 1 is clean, into stand-by state.
When vertical 3 catalyst poisonings of reformer of 3#, corresponding operation is performed.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.

Claims (9)

  1. A kind of 1. air supply system of novel direct-reduction iron reformer, it is characterised in that including:N+M vertical reformers, M are individual perpendicular Stove, washer, convection section, unstripped gas blower fan, combustion fan, purging motor, wherein N number of vertical reformer is as shared regenerating furnace Use;Fuel gas passageway and feed gas passage are provided with the vertical reformer, is filled with the feed gas passage by more The catalyst that hole checker brick dipping nickel is formed, and carried out by the unstripped gas in the flue gas and feed gas passage in fuel gas passageway Heat exchange;Outlet of the gas import by pipeline and the reformer feed gas passage is reformed on the shaft furnace, for will not Feed gas catalytic through desulfurization reforms gas and is delivered to shaft furnace production DRI caused by reforming, the top gas on the shaft furnace Outlet and the inlet communication of washer, the outlet of the washer by pipeline respectively with the top gas import of the convection section and The inlet communication of unstripped gas blower fan;The outlet of the unstripped gas blower fan passes through pipeline and the vertical reformer feed gas passage Inlet communication;Fuel gas outlet, gas approach, exhanst gas outlet, combustion air inlet, combustion air are additionally provided with the convection section Outlet, the gas approach of the convection section connect with the fuel gas passageway of the vertical reformer, and the flue gas of the convection section goes out Mouth is connected by pipeline with chimney, and the combustion air inlet of the convection section connects with combustion fan, the fuel of the convection section Gas export and fuel gas passageway of the combustion air exports respectively with the vertical reformer connect, for will by with flue gas heat exchange The top gas of heating is passed through in fuel gas passageway as the combustion air of fuel gas and heat exchange heating;
    The purging motor connects with the feed gas passage of the vertical reformer, when catalyst poisoning in vertical reformer, Start the vertical reformer as shared regenerating furnace to replace the vertical reformer of catalyst poisoning, and by purging motor to urging Regeneration gas is advertised in the vertical reformer of agent poisoning, realizes that catalyst regenerates;
    Wherein, N >=1, M >=1.
  2. 2. the air supply system of novel direct-reduction iron reformer as claimed in claim 1, it is characterised in that:The catalyst be by What nickel coating thick porous checker brick dipping 0.5-1mm was formed.
  3. 3. the air supply system of novel direct-reduction iron reformer as claimed in claim 1, it is characterised in that:The vertical reformer The bottom of side is provided with raw material gas inlet, is provided with the top of the vertical reformer opposite side and reforms gas outlet, in unstripped gas Feed gas passage is arranged in parallel provided with a series of between import and the outlet of reformation gas, and catalyst is placed in and is uniformly distributed in raw material In gas passage, the furnace wall of the vertical reformer is made of refractory material.
  4. 4. the air supply system of novel direct-reduction iron reformer as claimed in claim 1, it is characterised in that:The regeneration gas is sky Gas or oxygen.
  5. 5. the air supply system of novel direct-reduction iron reformer as claimed in claim 1, it is characterised in that:The regeneration gas be by What the nitrogen as purge gass and the air or oxygen as main regeneration gas formed.
  6. A kind of 6. air feed craft of novel direct-reduction iron reformer, it is characterised in that:The top gas that shaft furnace is discharged is scrubbed After be divided into gas 1 and gas 2;
    Gas 1 and unstripped gas, which merge, is passed through the raw material that vertical reformer is filled with the catalyst formed by porous checker brick dipping nickel Catalytic reforming reaction is carried out in gas passage, caused reformation gas is delivered to shaft furnace production DRI as also Primordial Qi, closed circuit Recycle;
    Gas 2 and combustion air are delivered to the flue gas that convection section goes out with vertical reformation fire grate and carry out heat exchange, are dropped by heat exchange The flue gas of temperature is discharged by chimney, is delivered to vertical reformer as fuel gas through heat exchange elevated temperature gas 2 and is made fuel gas and uses, Vertical reformer, which is also delivered to, through heat exchange heating combustion air makees combustion-supporting gas use;Catalyst poisoning in vertical reformer When, start as the vertical reformer for sharing regenerating furnace to replace the vertical reformer of catalyst poisoning, and pass through purging motor Regeneration gas is advertised into the vertical reformer of catalyst poisoning.
  7. 7. the air supply system of novel direct-reduction iron reformer as claimed in claim 6, it is characterised in that:The regeneration gas is sky Gas or oxygen.
  8. 8. the air supply system of novel direct-reduction iron reformer as claimed in claim 6, it is characterised in that:The regeneration gas be by What the nitrogen as purge gass and the air or oxygen as main regeneration gas formed.
  9. 9. the air supply system of novel direct-reduction iron reformer as claimed in claim 6, it is characterised in that:The catalyst be by What nickel coating thick porous checker brick dipping 0.5-1mm was formed.
CN201711261304.3A 2017-12-04 2017-12-04 A kind of air supply system and technique of novel direct-reduction iron reformer Pending CN107674934A (en)

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CN110578027A (en) * 2019-10-09 2019-12-17 中石化南京工程有限公司 novel reforming furnace for producing reducing gas
CN110578027B (en) * 2019-10-09 2024-04-30 中石化南京工程有限公司 Novel reformer for producing reducing gas

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110578027A (en) * 2019-10-09 2019-12-17 中石化南京工程有限公司 novel reforming furnace for producing reducing gas
CN110578027B (en) * 2019-10-09 2024-04-30 中石化南京工程有限公司 Novel reformer for producing reducing gas

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Application publication date: 20180209