CN107674531A - A kind of environmental protection coating material for timber and preparation method thereof - Google Patents

A kind of environmental protection coating material for timber and preparation method thereof Download PDF

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Publication number
CN107674531A
CN107674531A CN201711044044.4A CN201711044044A CN107674531A CN 107674531 A CN107674531 A CN 107674531A CN 201711044044 A CN201711044044 A CN 201711044044A CN 107674531 A CN107674531 A CN 107674531A
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CN
China
Prior art keywords
parts
timber
environmental protection
coating material
cellulose
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CN201711044044.4A
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Chinese (zh)
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倪佐才
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Individual
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Priority to CN201711044044.4A priority Critical patent/CN107674531A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

Abstract

The invention discloses a kind of environmental protection coating material for timber, including following components, as mass fraction, 25 parts of 40 50 parts of poly-methyl acrylate emulsion, 10 15 parts of modification infusorial earth, 10 15 parts of cellulose derivative, 25 parts of reactive diluent, 13 parts of organic silicon defoamer, 10 15 parts of deionized water, 25 parts of thickener and titanium dioxide.The invention also discloses a kind of preparation method of the environmental protection coating material for timber.The coating application forms cladding film after wood surface desiccation in wood surface, avoid timber ingress of air and moisture, prevent the corruption of timber, substantially increase the performance of timber, and modification infusorial earth can effectively adsorb pernicious gas in coating, leaking for pernicious gas is avoided, the feature of environmental protection is strong after application.

Description

A kind of environmental protection coating material for timber and preparation method thereof
Technical field
The present invention relates to wood producing manufacture field, specifically, is related to a kind of environmental protection coating material and its system for timber Preparation Method.
Background technology
Timber is a kind of structural material, is widely used in Furniture manufacture and building industry, and present timber is using process In, it is welcomed by the people in order to increase the attractive in appearance and practical performance of timber in the coating of external coating one of timber.
But present paint spraying is after wood surface, because existing coating is using being difficult in wood surface shape later Into cladding film, existing timber is caused to be difficult to avoid that corrosion, the use to people causes certain inconvenience.
The content of the invention
It is an object of the invention to provide a kind of environmental protection coating material for timber and preparation method thereof, to solve above-mentioned background The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of environmental protection coating material for timber, including following components, as mass fraction, poly-methyl acrylate emulsion 40-50 parts, modification infusorial earth 10-15 parts, cellulose derivative 10-15 parts, reactive diluent 2-5 parts, organic silicon defoamer 1-3 Part, deionized water 10-15 parts, thickener 2-5 parts and titanium dioxide 2-5 parts.
As the further scheme of the present invention:The above-mentioned environmental protection coating material for timber, including following components, by mass fraction Meter, poly-methyl acrylate emulsion 42-47 parts, modification infusorial earth 11-13 parts, cellulose derivative 11-12 parts, reactive diluent 3-4 parts, organic silicon defoamer 2-3 parts, deionized water 11-13 parts, thickener 2-3 parts and titanium dioxide 3-4 parts.
As further scheme of the invention:For the environmental protection coating material of timber, including following components, by mass fraction Meter, it is 45 parts of poly-methyl acrylate emulsion, 12 parts of modification infusorial earth, 12 parts of cellulose derivative, 3 parts of reactive diluent, organic 3 parts of 2 parts of silicon defoaming agent, 13 parts of deionized water, 3 parts of thickener and titanium dioxide.
As further scheme of the invention:The above-mentioned environmental protection coating material for timber, described modification infusorial earth utilize Diatomite, cetrimonium bronmide, 4 bromide and polyacrylamide are with 10:2:2:1 proportioning is mixed Stirring, it is acidified within 1 hour through persalt solution left standstill after stirring, drying, which is pulverized, to be prepared.
As further scheme of the invention:For the environmental protection coating material of timber, described cellulose derivative is methyl Cellulose, carboxymethyl cellulose, ethyl cellulose, hydroxyethyl cellulose, cyanethyl cellulose, hydroxypropyl cellulose and hydroxypropyl One or more of mixtures in methylcellulose.
As further scheme of the invention:For the environmental protection coating material of timber, described thickener be sodium bentonite, One or more of mixtures in organobentonite, attapulgite soil, molecular sieve, Silica hydrogel.
The preparation method of the above-mentioned environmental protection coating material for timber, is concretely comprised the following steps:
S1, diatomite modified:By diatomite, cetrimonium bronmide, 4 bromide and polyacrylamide With 10:2:2:1 proportioning is mixed, and the mixture of preparation is disperseed by high speed, high shear mixing, after high speed is disperseed Mixed material be transferred to double rod machines and mill 2-3 times and be prepared into intermediate blend, intermediate blend is passed through into hydrochloric acid solution Stand 1 hour and be acidified, drying, which is pulverized, to be prepared;
S2, by poly-methyl acrylate emulsion, modification infusorial earth, cellulose derivative, reactive diluent, organosilicon defoam Agent is mixed, mixing speed 1000-1500r/min, is stirred 30min, is prepared mixture A;
S3, deionized water is added in mixture A prepared by step S2, adjust the concentration of mixture, prepare mixture B;
S4, addition thickener is thickened in mixture B prepared by step S3, and is added titanium dioxide and mixed colours, Detected, pack and get product.
Compared with prior art, the beneficial effects of the invention are as follows:
The coating application forms cladding film after wood surface desiccation in wood surface, avoids timber ingress of air And moisture, it is therefore prevented that the corruption of timber, substantially increase the performance of timber, and modification infusorial earth can have in coating Effect absorption pernicious gas, avoids leaking for pernicious gas, the feature of environmental protection is strong after application.
Embodiment
Technical scheme is described in more detail with reference to embodiment.
Embodiment 1
A kind of environmental protection coating material for timber, including following components, as mass fraction, poly-methyl acrylate emulsion 40 Part, 10 parts of modification infusorial earth, 10 parts of cellulose derivative, 2 parts of reactive diluent, 1 part of organic silicon defoamer, deionized water 10 2 parts of part, 2 parts of thickener and titanium dioxide.
Described modification infusorial earth utilizes diatomite, cetrimonium bronmide, 4 bromide and polypropylene Acid amides is with 10:2:2:1 proportioning is mixed, and is acidified within 1 hour through persalt solution left standstill after stirring, drying is pulverized It is prepared.
Described cellulose derivative be methylcellulose, carboxymethyl cellulose, ethyl cellulose, hydroxyethyl cellulose, One or more of mixtures in cyanethyl cellulose, hydroxypropyl cellulose and hydroxypropyl methyl cellulose.
Described thickener is one kind in sodium bentonite, organobentonite, attapulgite soil, molecular sieve, Silica hydrogel Or several mixtures.
A kind of preparation method of environmental protection coating material for timber, is concretely comprised the following steps:
S1, diatomite modified:By diatomite, cetrimonium bronmide, 4 bromide and polyacrylamide With 10:2:2:1 proportioning is mixed, and the mixture of preparation is disperseed by high speed, high shear mixing, after high speed is disperseed Mixed material be transferred to double rod machines and mill 2-3 times and be prepared into intermediate blend, intermediate blend is passed through into hydrochloric acid solution Stand 1 hour and be acidified, drying, which is pulverized, to be prepared.
S2, by poly-methyl acrylate emulsion, modification infusorial earth, cellulose derivative, reactive diluent, organosilicon defoam Agent is mixed, mixing speed 1000-1500r/min, is stirred 30min, is prepared mixture A.
S3, deionized water is added in mixture A prepared by step S2, adjust the concentration of mixture, prepare mixture B.
S4, addition thickener is thickened in mixture B prepared by step S3, and is added titanium dioxide and mixed colours, Detected, pack and get product.
Embodiment 2
A kind of environmental protection coating material for timber, including following components, as mass fraction, poly-methyl acrylate emulsion 45 Part, 12 parts of modification infusorial earth, 12 parts of cellulose derivative, 3 parts of reactive diluent, 2 parts of organic silicon defoamer, deionized water 13 3 parts of part, 3 parts of thickener and titanium dioxide.
Described modification infusorial earth utilizes diatomite, cetrimonium bronmide, 4 bromide and polypropylene Acid amides is with 10:2:2:1 proportioning is mixed, and is acidified within 1 hour through persalt solution left standstill after stirring, drying is pulverized It is prepared.
Described cellulose derivative be methylcellulose, carboxymethyl cellulose, ethyl cellulose, hydroxyethyl cellulose, One or more of mixtures in cyanethyl cellulose, hydroxypropyl cellulose and hydroxypropyl methyl cellulose.
Described thickener is one kind in sodium bentonite, organobentonite, attapulgite soil, molecular sieve, Silica hydrogel Or several mixtures.
A kind of preparation method of environmental protection coating material for timber, is concretely comprised the following steps:
S1, diatomite modified:By diatomite, cetrimonium bronmide, 4 bromide and polyacrylamide With 10:2:2:1 proportioning is mixed, and the mixture of preparation is disperseed by high speed, high shear mixing, after high speed is disperseed Mixed material be transferred to double rod machines and mill 2-3 times and be prepared into intermediate blend, intermediate blend is passed through into hydrochloric acid solution Stand 1 hour and be acidified, drying, which is pulverized, to be prepared.
S2, by poly-methyl acrylate emulsion, modification infusorial earth, cellulose derivative, reactive diluent, organosilicon defoam Agent is mixed, mixing speed 1000-1500r/min, is stirred 30min, is prepared mixture A.
S3, deionized water is added in mixture A prepared by step S2, adjust the concentration of mixture, prepare mixture B.
S4, addition thickener is thickened in mixture B prepared by step S3, and is added titanium dioxide and mixed colours, Detected, pack and get product.
Embodiment 3
A kind of environmental protection coating material for timber, including following components, as mass fraction, poly-methyl acrylate emulsion 50 Part, 15 parts of modification infusorial earth, 15 parts of cellulose derivative, 5 parts of reactive diluent, 3 parts of organic silicon defoamer, deionized water 15 5 parts of part, 5 parts of thickener and titanium dioxide.
Described modification infusorial earth utilizes diatomite, cetrimonium bronmide, 4 bromide and polypropylene Acid amides is with 10:2:2:1 proportioning is mixed, and is acidified within 1 hour through persalt solution left standstill after stirring, drying is pulverized It is prepared.
Described cellulose derivative be methylcellulose, carboxymethyl cellulose, ethyl cellulose, hydroxyethyl cellulose, One or more of mixtures in cyanethyl cellulose, hydroxypropyl cellulose and hydroxypropyl methyl cellulose.
Described thickener is one kind in sodium bentonite, organobentonite, attapulgite soil, molecular sieve, Silica hydrogel Or several mixtures.
A kind of preparation method of environmental protection coating material for timber, is concretely comprised the following steps:
S1, diatomite modified:By diatomite, cetrimonium bronmide, 4 bromide and polyacrylamide With 10:2:2:1 proportioning is mixed, and the mixture of preparation is disperseed by high speed, high shear mixing, after high speed is disperseed Mixed material be transferred to double rod machines and mill 2-3 times and be prepared into intermediate blend, intermediate blend is passed through into hydrochloric acid solution Stand 1 hour and be acidified, drying, which is pulverized, to be prepared.
S2, by poly-methyl acrylate emulsion, modification infusorial earth, cellulose derivative, reactive diluent, organosilicon defoam Agent is mixed, mixing speed 1000-1500r/min, is stirred 30min, is prepared mixture A.
S3, deionized water is added in mixture A prepared by step S2, adjust the concentration of mixture, prepare mixture B.
S4, addition thickener is thickened in mixture B prepared by step S3, and is added titanium dioxide and mixed colours, Detected, pack and get product.
The better embodiment of the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party Formula, can also be on the premise of present inventive concept not be departed from one skilled in the relevant art's possessed knowledge Various changes can be made.

Claims (7)

1. a kind of environmental protection coating material for timber, it is characterised in that including following components, as mass fraction, polymethyl Sour fat liquor 40-50 parts, modification infusorial earth 10-15 parts, cellulose derivative 10-15 parts, reactive diluent 2-5 parts, organosilicon Defoamer 1-3 parts, deionized water 10-15 parts, thickener 2-5 parts and titanium dioxide 2-5 parts.
2. a kind of environmental protection coating material for timber according to claim 1, it is characterised in that including following components, by matter Measure fraction meter, poly-methyl acrylate emulsion 42-47 parts, modification infusorial earth 11-13 parts, cellulose derivative 11-12 parts, activity Diluent 3-4 parts, organic silicon defoamer 2-3 parts, deionized water 11-13 parts, thickener 2-3 parts and titanium dioxide 3-4 parts.
3. a kind of environmental protection coating material for timber according to claim 1, it is characterised in that including following components, by matter Measure fraction meter, 45 parts of poly-methyl acrylate emulsion, 12 parts of modification infusorial earth, 12 parts of cellulose derivative, reactive diluent 3 Part, 2 parts of organic silicon defoamer, 13 parts of deionized water, 3 parts of thickener and 3 parts of titanium dioxide.
4. according to a kind of any described environmental protection coating materials for timber of claim 1-3, it is characterised in that described modified silicon Diatomaceous earth is using diatomite, cetrimonium bronmide, 4 bromide and polyacrylamide with 10:2:2:1 proportioning Mixed, be acidified within 1 hour through persalt solution left standstill after stirring, drying, which is pulverized, to be prepared.
A kind of 5. environmental protection coating material for timber according to claim 4, it is characterised in that described cellulose derivative For methylcellulose, carboxymethyl cellulose, ethyl cellulose, hydroxyethyl cellulose, cyanethyl cellulose, hydroxypropyl cellulose and One or more of mixtures in hydroxypropyl methyl cellulose.
6. a kind of environmental protection coating material for timber according to claim 5, it is characterised in that described thickener is sodium base One or more of mixtures in bentonite, organobentonite, attapulgite soil, molecular sieve, Silica hydrogel.
A kind of a kind of 7. preparation method of environmental protection coating material for timber as described in claim 1-3 is any, it is characterised in that Concretely comprise the following steps:
S1, diatomite modified:By diatomite, cetrimonium bronmide, 4 bromide and polyacrylamide with 10: 2:2:1 proportioning is mixed, and the mixture of preparation is disperseed by high speed, high shear mixing, mixed after disperseing at a high speed Compound material, which is transferred to double rod machines, mill 2-3 time and is prepared into intermediate blend, and intermediate blend is passed through into hydrochloric acid solution standing 1 Hour acidifying, drying, which is pulverized, to be prepared;
S2, poly-methyl acrylate emulsion, modification infusorial earth, cellulose derivative, reactive diluent, organic silicon defoamer entered Row mixes, mixing speed 1000-1500r/min, stirs 30min, prepares mixture A;
S3, deionized water is added in mixture A prepared by step S2, adjust the concentration of mixture, prepare mixture B;
S4, addition thickener is thickened in mixture B prepared by step S3, and is added titanium dioxide and mixed colours, and is carried out Detection, packaging are got product.
CN201711044044.4A 2017-10-31 2017-10-31 A kind of environmental protection coating material for timber and preparation method thereof Withdrawn CN107674531A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108442177A (en) * 2018-04-14 2018-08-24 福建省大投科技有限公司 A kind of the stone fibrous paper and processing method of low-density

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CN101182058A (en) * 2007-11-07 2008-05-21 寻甸先锋硅藻土开发有限公司 Method for preparing coal mine water additive by concomitancy of diatomite purification
CN102389776A (en) * 2011-10-09 2012-03-28 广东省生态环境与土壤研究所 Metal heavy absorbent and preparation method and use thereof
CN105731760A (en) * 2016-01-29 2016-07-06 长沙学院 Modified diatomite and preparation method thereof, sludge conditioner and sludge treatment method
CN106693885A (en) * 2016-12-14 2017-05-24 潍坊金原微生物肥料有限公司 Production method of diatomite adsorption film for sewage treatment
CN107189608A (en) * 2017-07-01 2017-09-22 荥经力宏技术推广服务有限公司 A kind of timber environmental protection coating material and preparation method thereof

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* Cited by examiner, † Cited by third party
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CN1587082A (en) * 2004-09-30 2005-03-02 北京工业大学 Composite natural micro porous material sewage treating agent
CN101182058A (en) * 2007-11-07 2008-05-21 寻甸先锋硅藻土开发有限公司 Method for preparing coal mine water additive by concomitancy of diatomite purification
CN102389776A (en) * 2011-10-09 2012-03-28 广东省生态环境与土壤研究所 Metal heavy absorbent and preparation method and use thereof
CN105731760A (en) * 2016-01-29 2016-07-06 长沙学院 Modified diatomite and preparation method thereof, sludge conditioner and sludge treatment method
CN106693885A (en) * 2016-12-14 2017-05-24 潍坊金原微生物肥料有限公司 Production method of diatomite adsorption film for sewage treatment
CN107189608A (en) * 2017-07-01 2017-09-22 荥经力宏技术推广服务有限公司 A kind of timber environmental protection coating material and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108442177A (en) * 2018-04-14 2018-08-24 福建省大投科技有限公司 A kind of the stone fibrous paper and processing method of low-density

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Application publication date: 20180209