CN107674447A - A kind of transparent binder of paving and preparation method thereof - Google Patents

A kind of transparent binder of paving and preparation method thereof Download PDF

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Publication number
CN107674447A
CN107674447A CN201710961602.7A CN201710961602A CN107674447A CN 107674447 A CN107674447 A CN 107674447A CN 201710961602 A CN201710961602 A CN 201710961602A CN 107674447 A CN107674447 A CN 107674447A
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CN
China
Prior art keywords
transparent
paving
resin
sbs
base oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710961602.7A
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Chinese (zh)
Inventor
闫国杰
施曙东
袁月
许严
虞成忠
马利志
邓国民
邱轶
徐韵淳
黄震霆
石剑
李交
王腾飞
夏庆宇
周维维
陈韬
宋健
张浩刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Puxing Road And Bridge Construction Engineering Co Ltd
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Shanghai Puxing Road And Bridge Construction Engineering Co Ltd
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Publication date
Application filed by Shanghai Puxing Road And Bridge Construction Engineering Co Ltd filed Critical Shanghai Puxing Road And Bridge Construction Engineering Co Ltd
Priority to CN201710961602.7A priority Critical patent/CN107674447A/en
Publication of CN107674447A publication Critical patent/CN107674447A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • C08L101/02Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention discloses transparent binder of a kind of paving and preparation method thereof, the transparent binder includes transparent base oil, resin, SBS and PE, the transparent binder is prepared by weight percentage, the volume of transparent base oil is the 25.0%~45.0% of total volume, resin volume is the 45.0%~65.0% of total volume, SBS volumes are that 5.0%~15.0%, the PE volumes of total volume are the 0.2%~2.5% of total volume.The base oil and resin that the transparent binder of paving in the present invention uses are Transparent color, SBS and PE is white, pass through certain proportioning again, so as to obtain transparent paving material, the transparent binder of paving of the present invention is applied to the original color of the pavement materials such as building stones can be presented completely in paving, the landscape design that road pavement is mated formation plays an important role, and the transparent performance of mixture is excellent, and economic benefit and environmental benefit are good.

Description

A kind of transparent binder of paving and preparation method thereof
Technical field
The present invention relates to highway construction field of material technology, the transparent binder of espespecially a kind of paving and its preparation side Method.
Background technology
In recent years, as China BRT, pavement, park and the construction upsurge at scenic spot, Colorful Asphalt Pavement technology and colour drip Blue or green pavement construction is in the period of a high speed development.Colorful Asphalt Pavement technology is mainly added using decolouring pitch or color asphalt Add pigment (red, yellow, blue etc.) mix paving mix.
For from pavement construction total tune and material source, black asphalt pavement will be China's road construction Principal mode, and Colorful Asphalt Pavement also has certain application market under particular circumstances.For the angle to get close to nature, Pavement of road can show that the original color of pavement material (building stones etc.) and state etc. can more make road thawing cylinders;From design For angle, the vestige of black and colored designs is excessively obvious, is mated formation using transparent binder and can hide design and nature Among;For the angle of color, mated formation using transparent binder and various colors and state is more readily formed, and be not in Black and the colored road surface discoloration that road surface occurs after prolonged.But in existing paving material There is no a transparent material, existing black and colored ground surface material can not achievement unit branch face landscape design.
Therefore, the applicant is directed to providing transparent binder of a kind of paving and preparation method thereof.
The content of the invention
It is an object of the invention to provide transparent binder of a kind of paving and preparation method thereof, it can enable road surface Pavement material original color and state are enough shown, makes road preferably assimilated into nature, makes pavement of road design preferably hidden It is hidden among nature, while the transparent binder preparation cost of the paving is relatively low, economic and profitable, excellent performance, it is durable Property it is good, maintenance is convenient.
Technical scheme provided by the invention is as follows:
A kind of transparent binder of paving, including transparent base oil, resin, SBS (polystyrene- Polybutadiene-polystyrene or styrene-butadiene triblock copolymer, styrene-butadiene Block copolymer) and PE (polyethylene, polyethylene), by weight percentage, the volume of the transparent base oil is total The 25.0%~45.0% of volume, the volume of the resin are the 45.0%~65.0% of total volume, and the volume of the SBS is total The 5.0%~15.0% of volume, the volume of the PE are the 0.2%~2.5% of total volume.
Preferably, the transparent base oil is naphthenic oil.
Preferably, the resin is the combination of hydrogenation resin or hydrogenation resin and non-hydrogenation resin.
Preferably, the SBS is star-shaped sbs or type SBS.
Preferably, the PE is LDPE (Low Density Polyethylene, low density polyethylene (LDPE)) or LLDPE (lines Type low density polyethylene (LDPE)).
A kind of preparation method of the transparent binder of the paving, including step:
S10:Transparent base oil, resin, SBS and PE are weighed respectively according to above-mentioned volume scope;
S20:The transparent base oil is heated to 120~145 DEG C;
S30:The resin is added in the transparent base oil, persistently stirs and heats, make temperature rise to 140~ 160℃;
S40:After the resin melts completely in the transparent base oil, the SBS is added, adds the PE;
S50:Product in heating stepses S40, its temperature is risen to 165~175 DEG C, persistently stir 20~30min;
S60:Product in step S50 is placed in 165~175 DEG C of baking oven and is incubated, stands 20~30min of development, most The transparent binder of paving is made eventually.
Base oil, the resin that the transparent binder of a kind of paving provided by the invention uses are Transparent color, use SBS and PE are white, so as to be made transparent paving material, the transparent binder be applied in paving can be in completely The original color of pavement material, the landscape designs that road pavement is mated formation such as existing building stones play an important role, and the transparent performance of mixture Excellent, economic benefit and environmental benefit are good, and its preparation method is simple to operate, and cost is relatively low.
Brief description of the drawings
Below by a manner of clearly understandable, preferred embodiment is described with reference to the drawings, above-mentioned characteristic, skill to the present invention Art feature, advantage and its implementation are further described.
Fig. 1 is a kind of flow signal of specific embodiment of the preparation method of the transparent binder of paving of the present invention Figure.
Embodiment
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, control is illustrated below The embodiment of the present invention.It should be evident that drawings in the following description are only some embodiments of the present invention, for For those of ordinary skill in the art, on the premise of not paying creative work, other can also be obtained according to these accompanying drawings Accompanying drawing, and obtain other embodiments.To make simplified form, only schematically show and phase of the present invention in each figure The part of pass, they do not represent its practical structures as product.
Embodiment one
This specific embodiment discloses a kind of transparent binder of paving, by following components and the raw material of percentage by weight It is prepared:The volume of transparent base oil is the 25.0% of total volume, and the volume of resin is mixing for 57.5%, SBS of total volume The volume measured as 15.0%, PE of total volume is the 2.5% of total volume.In this specific embodiment, transparent base oil is specifically adopted With naphthenic oil, resin specifically uses hydrogenation resin, and SBS specifically uses star-shaped sbs, and PE specifically uses LDPE.
The preparation method of the transparent binder of paving in the present embodiment, including step:
S10:Naphthenic oil, hydrogenation resin, star-shaped sbs and LDPE are weighed respectively according to the requirement of above-mentioned percentage by weight;
S20:Transparent base oil is heated to 120 DEG C;
S30:Resin is added in naphthenic oil, persistently stirs and heats, temperature is risen to 140 DEG C;
S40:After resin melts completely in transparent base oil, SBS is added, adds PE;
S50:Product in heating stepses S40, its temperature is risen to 165 DEG C, persistently stir 30min;
S60:Product in step S50 is placed in 165 DEG C of baking oven and is incubated, development 30min is stood, road surface is finally made Mat formation transparent binder.
Transparent binder made from this specific embodiment is detected using water transparency method of testing, and its transparency is more than 2 Rice.The transparent binder is applied to the original color of the pavement materials such as building stones can be presented completely in paving, and road pavement is mated formation Landscape design play an important role, the transparent performance of mixture is excellent, and economic benefit and environmental benefit are good.
Embodiment two
This specific embodiment discloses a kind of transparent binder of paving, by following components and the raw material of percentage by weight It is prepared:The volume of transparent base oil is the 40.0% of total volume, and the volume of resin is mixing for 54.0%, SBS of total volume The volume measured as 5.0%, PE of total volume is the 1.0% of total volume.In this specific embodiment, transparent base oil specifically uses Naphthenic oil, resin specifically use hydrogenation resin, and SBS specifically uses star-shaped sbs, and PE specifically uses LLDPE.
The preparation method of the transparent binder of paving in the present embodiment, including step:
S10:Naphthenic oil, hydrogenation resin, star-shaped sbs and LDPE are weighed respectively according to the requirement of above-mentioned percentage by weight;
S20:Transparent base oil is heated to 125 DEG C;
S30:Resin is added in naphthenic oil, persistently stirs and heats, temperature is risen to 145 DEG C;
S40:After resin melts completely in transparent base oil, SBS is added, adds PE;
S50:Product in heating stepses S40, its temperature is risen to 167 DEG C, persistently stir 28min;
S60:Product in step S50 is placed in 167 DEG C of baking oven and is incubated, development 28min is stood, road surface is finally made Mat formation transparent binder.
Transparent binder made from this specific embodiment is detected using water transparency method of testing, and its transparency is more than 2 Rice.The transparent binder is applied to the original color of the pavement materials such as building stones can be presented completely in paving, and road pavement is mated formation Landscape design play an important role, the transparent performance of mixture is excellent, and economic benefit and environmental benefit are good.
Embodiment three
This specific embodiment discloses a kind of transparent binder of paving, by following components and the raw material of percentage by weight It is prepared:The volume of transparent base oil is the 45.0% of total volume, and the volume of resin is mixing for 45.0%, SBS of total volume The volume measured as 9.8%, PE of total volume is the 0.2% of total volume.In this specific embodiment, transparent base oil specifically uses Naphthenic oil, resin specifically specifically use type SBS using the combination of hydrogenation resin and non-hydrogenation resin, SBS, and PE is specifically used LLDPE。
The preparation method of the transparent binder of paving in the present embodiment, including step:
S10:According to the requirement of above-mentioned percentage by weight weigh respectively naphthenic oil, hydrogenation resin and non-hydrogenation resin combination, Type SBS and LLDPE;
S20:Transparent base oil is heated to 130 DEG C;
S30:Resin is added in naphthenic oil, persistently stirs and heats, temperature is risen to 150 DEG C;
S40:After resin melts completely in transparent base oil, SBS is added, adds PE;
S50:Product in heating stepses S40, its temperature is risen to 169 DEG C, persistently stir 26min;
S60:Product in step S50 is placed in 169 DEG C of baking oven and is incubated, development 26min is stood, road surface is finally made Mat formation transparent binder.
Transparent binder made from this specific embodiment is detected using water transparency method of testing, and its transparency is more than 2 Rice.The transparent binder is applied to the original color of the pavement materials such as building stones can be presented completely in paving, and road pavement is mated formation Landscape design play an important role, the transparent performance of mixture is excellent, and economic benefit and environmental benefit are good.
Example IV
This specific embodiment discloses a kind of transparent binder of paving, by following components and the raw material of percentage by weight It is prepared:The volume of transparent base oil is the 27.0% of total volume, and the volume of resin is mixing for 65.0%, SBS of total volume The volume measured as 6.5%, PE of total volume is the 1.5% of total volume.In this specific embodiment, transparent base oil specifically uses Naphthenic oil, resin specifically use hydrogenation resin, and SBS specifically uses type SBS, and PE specifically uses LDPE.
The preparation method of the transparent binder of paving in the present embodiment, including step:
S10:Naphthenic oil, hydrogenation resin, type SBS and LDPE are weighed respectively according to the requirement of above-mentioned percentage by weight;
S20:Transparent base oil is heated to 135 DEG C;
S30:Resin is added in naphthenic oil, persistently stirs and heats, temperature is risen to 155 DEG C;
S40:After resin melts completely in transparent base oil, SBS is added, adds PE;
S50:Product in heating stepses S40, its temperature is risen to 171 DEG C, persistently stir 24min;
S60:Product in step S50 is placed in 171 DEG C of baking oven and is incubated, development 24min is stood, road surface is finally made Mat formation transparent binder.
Transparent binder made from this specific embodiment is detected using water transparency method of testing, and its transparency is more than 2 Rice.The transparent binder is applied to the original color of the pavement materials such as building stones can be presented completely in paving, and road pavement is mated formation Landscape design play an important role, the transparent performance of mixture is excellent, and economic benefit and environmental benefit are good.
Embodiment five
This specific embodiment discloses a kind of transparent binder of paving, by following components and the raw material of percentage by weight It is prepared:The volume of transparent base oil is the 35.0% of total volume, and the volume of resin is mixing for 50.0%, SBS of total volume The volume measured as 13.0%, PE of total volume is the 2.0% of total volume.In this specific embodiment, transparent base oil is specifically adopted With naphthenic oil, resin specifically uses hydrogenation resin, and SBS specifically uses star-shaped sbs, and PE specifically uses LLDPE.
The preparation method of the transparent binder of paving in the present embodiment, including step:
S10:Naphthenic oil, hydrogenation resin, star-shaped sbs and LLDPE are weighed respectively according to the requirement of above-mentioned percentage by weight;
S20:Transparent base oil is heated to 145 DEG C;
S30:Resin is added in naphthenic oil, persistently stirs and heats, temperature is risen to 160 DEG C;
S40:After resin melts completely in transparent base oil, SBS is added, adds PE;
S50:Product in heating stepses S40, its temperature is risen to 175 DEG C, persistently stir 20min;
S60:Product in step S50 is placed in 175 DEG C of baking oven and is incubated, development 20min is stood, road surface is finally made Mat formation transparent binder.
Transparent binder made from this specific embodiment is detected using water transparency method of testing, and its transparency is more than 2 Rice.The transparent binder is applied to the original color of the pavement materials such as building stones can be presented completely in paving, and road pavement is mated formation Landscape design play an important role, the transparent performance of mixture is excellent, and economic benefit and environmental benefit are good.
It should be noted that above-described embodiment can independent assortment as needed.Described above is only the preferred of the present invention Embodiment, it is noted that for those skilled in the art, do not departing from the premise of the principle of the invention Under, some improvements and modifications can also be made, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (6)

  1. A kind of 1. transparent binder of paving, it is characterised in that:
    Including transparent base oil, resin, SBS and PE, by weight percentage, the volume of the transparent base oil is total volume 25.0%~45.0%, the volume of the resin is the 45.0%~65.0% of total volume, and the volume of the SBS is total volume 5.0%~15.0%, the PE volume are the 0.2%~2.5% of total volume.
  2. 2. the transparent binder of paving as claimed in claim 1, it is characterised in that:
    The transparent base oil is naphthenic oil.
  3. 3. the transparent binder of paving as claimed in claim 1, it is characterised in that:
    The resin is the mixing of hydrogenation resin or hydrogenation resin and non-hydrogenation resin.
  4. 4. the transparent binder of paving as claimed in claim 1, it is characterised in that:
    The SBS is star-shaped sbs or type SBS.
  5. 5. the transparent binder of paving as claimed in claim 1, it is characterised in that:
    The PE is LDPE or LLDPE.
  6. A kind of 6. preparation method of the transparent binder of the paving as any one of claim 1 to 5, it is characterised in that Including step:
    S10:Transparent base oil, resin, SBS and PE are weighed respectively according to the volume scope described in claim 1;
    S20:The transparent base oil is heated to 120~145 DEG C;
    S30:The resin is added in the transparent base oil, persistently stirs and heats, temperature is risen to 140~160 DEG C;
    S40:After the resin melts completely in the transparent base oil, the SBS is added, adds the PE;
    S50:Product in heating stepses S40, its temperature is risen to 165~175 DEG C, persistently stir 20~30min;
    S60:Product in step S50 is placed in 165~175 DEG C of baking oven and is incubated, stands 20~30min of development, final system Obtain the transparent binder of paving.
CN201710961602.7A 2017-10-17 2017-10-17 A kind of transparent binder of paving and preparation method thereof Pending CN107674447A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108559227A (en) * 2018-05-08 2018-09-21 上海浦兴路桥建设工程有限公司 A kind of transparent binder of cold mixing and preparation method thereof
CN108625246A (en) * 2018-05-07 2018-10-09 上海浦兴路桥建设工程有限公司 A kind of complete thick formula flexibility shines road surface and preparation method thereof
CN108641379A (en) * 2018-05-08 2018-10-12 上海浦兴路桥建设工程有限公司 It is a kind of to emulsify transparent binder and preparation method thereof
CN109825024A (en) * 2019-01-10 2019-05-31 河南普绿环保科技有限公司 A kind of preparation method of road scavenging material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1478843A (en) * 2003-07-04 2004-03-03 华南理工大学 Light colour cementitous material for road and its preparation method
CN104058631A (en) * 2014-06-04 2014-09-24 吴江市明港道桥工程有限公司 Colorless cementing material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1478843A (en) * 2003-07-04 2004-03-03 华南理工大学 Light colour cementitous material for road and its preparation method
CN104058631A (en) * 2014-06-04 2014-09-24 吴江市明港道桥工程有限公司 Colorless cementing material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108625246A (en) * 2018-05-07 2018-10-09 上海浦兴路桥建设工程有限公司 A kind of complete thick formula flexibility shines road surface and preparation method thereof
CN108559227A (en) * 2018-05-08 2018-09-21 上海浦兴路桥建设工程有限公司 A kind of transparent binder of cold mixing and preparation method thereof
CN108641379A (en) * 2018-05-08 2018-10-12 上海浦兴路桥建设工程有限公司 It is a kind of to emulsify transparent binder and preparation method thereof
CN109825024A (en) * 2019-01-10 2019-05-31 河南普绿环保科技有限公司 A kind of preparation method of road scavenging material

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Application publication date: 20180209