CN107663905A - Heat-barrier material for building - Google Patents
Heat-barrier material for building Download PDFInfo
- Publication number
- CN107663905A CN107663905A CN201610607374.9A CN201610607374A CN107663905A CN 107663905 A CN107663905 A CN 107663905A CN 201610607374 A CN201610607374 A CN 201610607374A CN 107663905 A CN107663905 A CN 107663905A
- Authority
- CN
- China
- Prior art keywords
- heat
- barrier material
- synthetic resin
- paper tinsel
- building
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 46
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 31
- 239000000057 synthetic resin Substances 0.000 claims abstract description 31
- 239000003063 flame retardant Substances 0.000 claims abstract description 27
- 239000006260 foam Substances 0.000 claims abstract description 20
- 238000009413 insulation Methods 0.000 claims abstract description 20
- 238000005187 foaming Methods 0.000 claims abstract description 19
- 238000009941 weaving Methods 0.000 claims abstract description 16
- 239000011152 fibreglass Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- 239000004088 foaming agent Substances 0.000 claims abstract description 10
- 239000003381 stabilizer Substances 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000007789 gas Substances 0.000 claims description 9
- 239000003365 glass fiber Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- -1 carbonyl amines Chemical class 0.000 claims description 5
- 230000005496 eutectics Effects 0.000 claims description 4
- 238000003466 welding Methods 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 150000001639 boron compounds Chemical class 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000003475 lamination Methods 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 2
- 230000000903 blocking effect Effects 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000000395 magnesium oxide Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229920001684 low density polyethylene Polymers 0.000 abstract description 26
- 239000004702 low-density polyethylene Substances 0.000 abstract description 26
- 230000000694 effects Effects 0.000 abstract description 19
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 8
- 239000012774 insulation material Substances 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000002937 thermal insulation foam Substances 0.000 description 3
- 239000004156 Azodicarbonamide Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 2
- 235000019399 azodicarbonamide Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007888 film coating Substances 0.000 description 2
- 238000009501 film coating Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000505 pernicious effect Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- UZGKAASZIMOAMU-UHFFFAOYSA-N 124177-85-1 Chemical class NP(=O)=O UZGKAASZIMOAMU-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
- E04B1/806—Heat insulating elements slab-shaped with air or gas pockets included in the slab
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Fluid Mechanics (AREA)
- Materials Engineering (AREA)
- Acoustics & Sound (AREA)
- General Chemical & Material Sciences (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Building Environments (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of heat-barrier material for building, 60~75wt% low density polyethylene (LDPE) (LDPE) resin will be mixed, 7~13wt% fire retardant, 14~17wt% foaming agent, 0.3~0.6wt% stabilizer, 0.6~1.0wt% crosslinking agent, the synthetic resin foaming body (10) to be foamed after 0.8~1.2wt% surfactant is placed in center, bonding is clipped in fiberglass weaving piece (20) and additional insulation paper tinsel (40) between the heat-insulated paper tinsel in side (21) and the heat-insulated paper tinsel of opposite side (22), thus after the fire resistance of synthetic resin foams (10) and the fire resistance zoarium of fiberglass weaving piece (20), it can ensure that flame retardant effect is stronger, effect of heat insulation can also be made to perform to maximum.
Description
Technical field
The present invention relates to a kind of heat-barrier material (INSULATOR FOR BUILDING) for building, more particularly to a kind of ECDC
After the fire resistance of resin foams and the fire resistance zoarium of fiberglass weaving piece, it can ensure that flame retardant effect is stronger, also
Effect of heat insulation can be made to perform to the heat-barrier material for building of maximum.
Background technology
Generally, heat-barrier material for building is used as interior exterior material for building, and it is bonded on building masonry wall, separates room
Inside and outside hot gas, to keep indoor temperature.
Fig. 1 a are the reflections for possessing anti-flammability of prior art literature (Republic of Korea's registered patent publication the 1383043rd)
The stereogram of type heat-barrier material, Fig. 1 b are the exploded perspectives of the reflection type thermal insulation material for possessing anti-flammability of prior art literature
Figure, Fig. 1 c are the partial magnified sectional views of the reflection type thermal insulation material for possessing anti-flammability of prior art literature.
According to the reflection type thermal insulation material for possessing anti-flammability of prior art literature, as shown in Fig. 1 a to Fig. 1 c, it is by such as
Lower part is formed：Anti-flammability insulation foam 210, it is by polypropylene (PP) resin, polyethylene (PE) resin, low density polyethylene (LDPE)
(LDPE) a kind of fire retardant 58~62 in the weight % of a kind of resin 36~40 in resin, organic fire-retardant, inorganic combustion inhibitor
The flame retardant resin mixture that the weight % and weight % of antioxidant 1~3 is formed forms holey, more abortive haul shapes
Each hole 211 is surrounded by next door 212 and reflectance coating 220, so as to form the air layer with heat-blocking action, the thickness of holey
The thickness ratio in next door 212 of the degree with forming hole 211 is 10：8；Aluminum reflectance coating 220, it is bonded in a manner of thermal welding fire-retardant
The upper and lower surface of property insulation foam 210, and possess hot line reflecting properties；And anti-corrosion film coating 230, reflecting
On the aerial surface of exposure of film 220, thickness is carried out up to 0.5 ± 0.1 μm of film coating with polyester (PET) resin.
But account for 58~62 weights according to fire retardant in the reflection type thermal insulation material for possessing anti-flammability of prior art literature
% is measured, in this case, as by polypropylene (PP) resin, polyethylene (PE) resin or low density polyethylene (LDPE) (LDPE) resin
To harden into image-stone block the same for the anti-flammability insulation foam 210 of the result thing formed of foaming, and finally will be unable to be used as building
Heat-barrier material, especially, even if it is fit with aluminum reflectance coating 220, still suffer from the limitation that flame retardant effect can not be performed to maximum
Property.
Prior art literature
Patent document
Republic of Korea's registered patent publication the 1383043rd (possesses reflection type thermal insulation material and its manufacturer of anti-flammability
Method；2014.04.08 bulletin)
Republic of Korea registers utility model No. 0432661 (heat-barrier material for building of publication；2006.12.06 bulletin)
(the interior exterior heat-barrier material for building of Korean published Patent publication the 2009-0132093rd；2009.12.30
It is open)
(the radiation heat-reflecting heat-insulating material of Korean published Patent publication the 2011-0123830th；It is 2011.11.16 public
Open)
Republic of Korea's registered patent publication No. 1196488 (heat-reflecting heat-insulating material and its manufacture method；2012.11.01
Bulletin)
The content of the invention
Technical problem
It is an object of the invention to provide a kind of heat-barrier material for building, fire resistance and glass through synthetic resin foams
After the fire resistance zoarium of fiber weaving piece, it can be ensured that flame retardant effect is stronger, moreover it is possible to effect of heat insulation is performed to maximum.
It is an object of the invention to provide a kind of heat-barrier material for building, the very thin thickness of fiberglass weaving piece, can but borrow
Help it is woven intersection body between numerous stomata, play circulation air, condensation collect and dry etc. function, heat-insulated performance can be made
To ultimate attainment, and it is simple to manufacture, can guarantee that productivity ratio.
It is an object of the invention to provide a kind of heat-barrier material for building, compared with general glass fibre, can be obviously reduced
Its thickness, it is ensured that diminution occupy space, more can ensure that logistics movement and logistics keeping simplicity, significantly reduce cost of transportation and
Keeping cost, and more can ensure that the simplicity operated during the inside and outside wall for being adhered to building.
It is an object of the invention to provide a kind of heat-barrier material for building, suppression smog occurs, non-toxic and innocuousness is prominent,
It is safe, so as to realize environmental protection.
Technical scheme
To reach above-mentioned purpose, of the invention is essentially characterized in that, including：Synthetic resin foams, by 60~75wt%
Low density polyethylene (LDPE) (LDPE) resin, 7~13wt% fire retardant, 14~17wt% foaming agent, 0.3~0.6wt%
Stabilizer, 0.6~1.0wt% crosslinking agent, 0.8~1.2wt% surfactant foam after mixing and formed；Glass fibre is knitted
Piece is made, is clipped between the heat-insulated paper tinsel in side and the heat-insulated paper tinsel of opposite side, and is adhered on the one side of above-mentioned synthetic resin foams；With
And additional insulation paper tinsel, it is adhered on the another side of above-mentioned synthetic resin foams.
Invention effect
Effect of the invention is that the fire resistance of fire resistance and fiberglass weaving piece through synthetic resin foams
After zoarium, it can be ensured that flame retardant effect is stronger, moreover it is possible to effect of heat insulation is performed to maximum.
The effect of the present invention also resides in, the very thin thickness of fiberglass weaving piece, but can be by between woven intersection body
Numerous stomata, play circulation air, the function such as condensation is collected and is dried, can make it is heat-insulated perform to ultimate attainment, and be simple to manufacture,
It can guarantee that productivity ratio.
The effect of the present invention also resides in, and compared with general glass fibre, its thickness can be obviously reduced, it is ensured that diminution occupies
Space, more can ensure that the simplicity of logistics movement and logistics keeping, reduce cost of transportation and keeping cost significantly, and more can be true
Protect the simplicity for being adhered to and being operated during the inside and outside wall of building.
The effect of the present invention also resides in, and suppression smog occurs, non-toxic and innocuousness is prominent, safe, so as to realize
Environmental protection.
Brief description of the drawings
Fig. 1 a are the stereograms of the reflection type thermal insulation material for possessing anti-flammability of prior art literature.
Fig. 1 b are the exploded perspective views of the reflection type thermal insulation material for possessing anti-flammability of prior art literature.
Fig. 1 c are the partial magnified sectional views of the reflection type thermal insulation material for possessing anti-flammability of prior art literature.
Fig. 2 a are the exploded perspective views of the heat-barrier material for building of the present invention.
Fig. 2 b are the profiles for including building inwall of heat-barrier material for building to illustrate the invention.
Fig. 2 c are to represent the fiberglass weaving piece and the heat-insulated paper tinsel in side suitable for the heat-barrier material for building of the present invention
The concept map of laminated appearance.
Fig. 3 a to Fig. 3 c are the test report copies of the heat-barrier material for building of the present invention.
Description of reference numerals
10：Synthetic resin foaming body
20：Fiberglass weaving piece
21：The heat-insulated paper tinsel in side
22：The heat-insulated paper tinsel of opposite side
P：Polyurethanes welding film
40：Additional insulation paper tinsel
50：Additional synthetic resin foaming body
60：Other heat-insulated paper tinsels
G：Next door
A：Air chamber
Embodiment
Referring to the drawings, the preferred embodiment of the heat-barrier material for building of the present invention is illustrated, if the embodiment can have
Dry, by these embodiments, it is better understood objects, features and advantages of the present invention.
Fig. 2 a be the present invention heat-barrier material for building exploded perspective view, Fig. 2 b be to illustrate the invention it is for building every
The profile for including building inwall of hot material.
As shown in Figure 2 a and 2 b, heat-barrier material for building of the invention includes：Synthetic resin foams 10；Glass fibre
Woven sheet 20, it is clipped between the heat-insulated paper tinsel 21 in side and the heat-insulated paper tinsel 22 of opposite side, is adhered on the one side of synthetic resin 10；And
Additional insulation paper tinsel 40, it is adhered on the another side of synthetic resin foams 10.
At this moment, synthetic resin foams 10 are by 60~75wt% low density polyethylene (LDPE) (LDPE) resin, 7~13wt%
Fire retardant, 14~17wt% foaming agent, 0.3~0.6wt% stabilizer, 0.6~1.0wt% crosslinking agent, 0.8~
After 1.2wt% surfactant mixing, formation of foaming.
Low density polyethylene (LDPE) (LDPE；Low Density PolyEthylene) it is the synthetic resin made of ethene, its
Water resistance, chemical resistance and electrical insulating property with brilliance, are often used as packaging material, sound-absorbing material, cable insulation etc.,
In the present invention, it is used as the main material of heat-barrier material for building, is 60~75wt%, to ensure fire-retardant effect, fire retardant is extremely
14wt% should be maintained less, and is hard such as stone when avoiding foaming, it is ensured that soft buffering and the performance bent, should be at most limited in
17wt%, in addition, in order that stable mixing together when fire retardant and the mutual mixing and foaming of low density polyethylene (LDPE), should match somebody with somebody
Close 0.3~0.6wt% stabilizer, 0.6~1.0wt% crosslinking agent, 0.8~1.2wt% surfactant.
Will be provided with above-mentioned weight than synthetic resin foams 10, be clipped in the heat-insulated paper tinsel 21 in side and the heat-insulated paper tinsel 22 of opposite side it
Between fiberglass weaving piece 20 and additional insulation paper tinsel 40 clip together, make synthetic resin foams 10 fire resistance and
The anti-flammability of fiberglass weaving piece 20 is fit, it is ensured that flame retardant effect is stronger, and effect of heat insulation is performed to maximum.
It is preferred that synthetic resin foams 10 possess air chamber A, the air chamber A is surrounded by next door G, and full of interior can be blocked
The air of outer hot gas.
Because being had differences between temperature caused by the temperature transmitted from building masonry wall and interior, so as to inside and outside generating chamber
Temperature difference, in the present invention, by the fiberglass weaving piece 20 being clipped between the heat-insulated paper tinsel 21 in side and the heat-insulated paper tinsel 22 of opposite side
With additional insulation paper tinsel 40, air chamber A is full of air, significantly reduces heat transfer, so further enhancing effect of heat insulation.
Especially, air chamber A is full of air, compared to pyroconductivity be 0.036W/m.K synthetic resin foams 10, with
Relatively low pyroconductivity 0.02W/m.K air layer, further doubles effect of heat insulation.
Fig. 2 c are represented suitable for heat-barrier material for building of the invention in the heat-insulated paper tinsel 21 in side and the heat-insulated paper tinsel of opposite side
The concept map of the outward appearance of glass fibre manufacture piece 20 is clamped between 22.
When clamping glass fibre manufacture piece 20 between the heat-insulated paper tinsel 21 in side and the heat-insulated paper tinsel 22 of opposite side, as shown in Figure 2 c,
Characterized in that, polyurethanes welding film P is placed in into centre, simple realization eutectic connects lamination, and at this moment eutectic connects laminating temperature and is
90~120 DEG C.
Fiberglass weaving piece 20 is that glass fibre intersected into (Cross) woven thin slice, and its thickness is 0.1~2mm, pole
It is thin, there is pliability as the heat-insulated paper tinsel 22 of paper tinsel 21 and opposite side heat-insulated with side, so being capable of volume to volume rand supply side progress
Mutual lamination, the very thin thickness of this fiberglass weaving piece 20 but can be by numerous between woven intersection body
Stomata, play circulation air, the function such as condensation is collected and is dried, make it is heat-insulated perform to ultimate attainment, and be simple to manufacture, can guarantee that life
Yield.
Especially, compared with general glass fibre, its thickness can be obviously reduced, it is ensured that diminution occupies space, more can ensure that
Logistics movement and the simplicity of logistics keeping, reduce cost of transportation and keeping cost, more can ensure that and be adhered to building significantly
The simplicity operated during the inside and outside wall of thing.
Meanwhile foundation embodiments of the invention, additional synthetic resin foaming body 50 can be also bonded on additional insulation paper tinsel 40,
The additional synthetic resin foaming body 50 be by 60~75wt% low density polyethylene (LDPE) (LDPE) resin, 7~13wt% it is fire-retardant
Agent, 14~17wt% foaming agent, 0.3~0.6wt% stabilizer, 0.6~1.0wt% crosslinking agent, 0.8~1.2wt%
Surfactant mixing after, formation of foaming, other heat-insulated paper tinsels 60 can be also bonded on this synthetic resin foaming body 50, when
So it can also expand multiple layers again.
In addition, additional synthetic resin foaming body 50 also possesses air chamber A certainly, the air chamber A is surrounded by next door G, and is full of
The air of indoor and outdoor hot gas can be blocked.
In addition, fire retardant is one kind in magnesium hydroxide, aluminium hydroxide and boron compound, foaming agent is ammonium class or phosphoamide
Class, stabilizer are silicone oil, and crosslinking agent is hydrogen peroxide, and surfactant is alkylbenzenesulfonate (alkylbenzene
sulfonate)。
The problem of existing fire retardant, is, when manufacturing heat-barrier material for building and when producing flame, can produce a large amount of
Poisonous and pernicious gas, especially, toxicity can be carried when conventional halogen compounds and antimony oxide use parallel, can be produced during burning
Raw substantial amounts of halogen gas, so with harmful to human, cause the problems such as equipment corrosion, and magnesium hydroxide, aluminium hydroxide
Be the fire retardant that can solve this shortcoming with boron compound, and there is no pernicious gas, be suppress caused by smog, it is non-toxic and
Environment friendly flame retardant that innocuousness protrudes, safe, can be efficiently applied to the present invention.
Foaming agent can enumerate the ammonium carbonate of ammonium class and the azodicarbonamide (Azodicarbonamide) of carbonyl amines, this
Kind foaming agent makes low density polyethylene (LDPE) together with stabilizer silicone oil, crosslinking agent hydrogen peroxide, surfactant alkylbenzenesulfonate
After being steeped with fire retardant hybrid concurrency, gas can be leaked and reduce to minimum, and promote its mixing together, it is ensured that the conjunction as its result thing
The anti-flammability and thermal insulation of resin foaming body 10, while can also to greatest extent reduce and nuisance caused by fire occurs
Matter.
Embodiment
For the heat-barrier material for building according to the present invention, Institute for Research and Technology of South Korea is according to territory ocean portion's bulletin the
No. 2012-624 implements performance test, and its test report is as shown in Fig. 3 a to 3c.
Fig. 3 a to Fig. 3 c are the test report copies of the heat-barrier material for building of the present invention.
【Table 1】
As shown in Fig. 3 a and table 1, it is ready to after the heat-barrier material sample for building 1,2,3 according to the present invention, implements fire
The result of calamity experiment, the standard of total rate of heat release is 8MJ/m2, and according to the present invention heat-barrier material sample 1 for building, 2,3 points
Wei not 0.8MJ/m2, 0.3MJ/m2, 0.8MJ/m2, therefore it is suitable, rate of heat release continues to exceed 200kw/m2Time (s) mark
Standard is below 10s, and according to the heat-barrier material sample 1 for building of the present invention, 2,3 be respectively 0s, 0s, 0s, therefore suitable, is occurred
The crack of all meltings, the insertion of heartwood and cavity etc. are unchanged during fire, therefore suitably, being averaged for mouse stops the time
The standard of (min, s) is 9min, and the heat-barrier material for building according to the present invention is 14m 12s, 13m 48s, therefore suitably.
【Chart 1】
As shown in Fig. 3 b and chart 1, the heat-barrier material for building of the foundation present invention of preparation is the sample for possessing altogether 3-tier architecture
This, wherein, the black in chart 1 represents No. 1 sample, and red represents No. 2 samples, and blueness represents No. 3 samples, and can confirm right side
Total rate of heat release in 0.8MJ/m2Below.
【Table 2】
As shown in Fig. 3 c and upper table 2, the heat-barrier material for building of the foundation present invention of preparation is the sample for possessing altogether 3-tier architecture
Sheet 1 and 2, for sample 1 in 23.1mm, 29.9g, the time that stops of 8 mouse is 14min 31s, standard deviation 00min
19s, it is 14min 12s averagely to stop the time, because its standard is in more than 9min, therefore judges that it is suitable, sample 2 in 23.1mm,
During 31.7g, the time that stops of 8 mouse is 14min 25s, and standard deviation is 00min 37s, and it is 13min averagely to stop the time
48s, because its standard is in more than 9min, therefore judge that its is suitable.
【Chart 2】
As shown in Fig. 3 c, table 2 and chart 2, the heat-barrier material for building of the foundation present invention of preparation is that possess 3-tier architecture altogether
Sample 1, for sample 1 in 23.1mm, 29.9g, 8 mouse (M1, M2, M3, M4, M5, M6, M7, M8) stop time difference
For 14min 36s, 14min33s, 13min 48s, 14min 45s, 15min 00s, 14min 35s, 14min 28s, 14min
26s, standard deviation are 00min 19s, and it is 14min 12s averagely to stop the time, because its standard is in more than 9min, therefore judge that it is suitable
Preferably.
【Chart 3】
As shown in Fig. 3 c, table 2 and chart 3, the heat-barrier material for building of the foundation present invention of preparation is that possess 3-tier architecture altogether
Sample 2, for sample 2 in 23.1mm, 31.7g, 8 mouse (M1, M2, M3, M4, M5, M6, M7, M8) stop time difference
For 15min 00s, 14min56s, 13min 47s, 14min 10s, 13min 10s, 14min 50s, 14min 57s, 14min
33s, standard deviation are 00min 37s, and it is 13min 48s averagely to stop the time, because its standard is in more than 9min, therefore judge that it is suitable
Preferably.
As the content confirmed in the embodiment above, according to heat-barrier material for building of the invention through judging,
It is by the anti-flammability of synthetic resin foaming body 10, and fiberglass weaving piece 20, air chamber A, the heat-insulated paper tinsel 21 in side, opposite side
Heat-insulated paper tinsel 22, additional insulation paper tinsel 40, additional synthetic resin foaming body 50, other heat-insulated paper tinsels 60, when fire occurs, total heat release
The continuous overtime 200kw/m of rate, rate of heat release2Time (s), heartwood all meltings, insertion crack and cavity etc. change,
Being averaged for mouse stops the time (min, s) and is judged as suitably, with low weight, low occupying, it can be ensured that it is efficient fire-retardant and
Effect of heat insulation.
Industrial applicability
Present invention can apply to the related industrial fields of building heat insulating decoration material.
Claims (7)
- A kind of 1. heat-barrier material for building, it is characterised in that including：Synthetic resin foams (10), by 60~75wt% ldpe resin, 7~13wt% fire retardant, 14~ 17wt% foaming agent, 0.3~0.6wt% stabilizer, 0.6~1.0wt% crosslinking agent, 0.8~1.2wt% surface are lived Property agent mixing after foam and form；Fiberglass weaving piece (20), it is clipped between the heat-insulated paper tinsel in side (21) and the heat-insulated paper tinsel of opposite side (22), and is adhered to described On the one side of synthetic resin foams (10)；AndAdditional insulation paper tinsel (40), it is adhered on the another side of the synthetic resin foams (10).
- 2. heat-barrier material for building according to claim 1, it is characterised in that the synthetic resin foaming body (10) possesses Air chamber (A), the air chamber (A) are surrounded by next door (G) and full of the air for blocking indoor and outdoor hot gas.
- 3. heat-barrier material for building according to claim 1, it is characterised in that be clipped in the heat-insulated paper tinsel in the side (21) and another Glass fibre manufacture piece (20) between the heat-insulated paper tinsel in side (22) is that polyurethanes welding film (P) is placed in into middle eutectic to connect lamination Form.
- 4. heat-barrier material for building according to claim 3, it is characterised in that the eutectic connect laminating temperature for 90~ 120℃。
- 5. heat-barrier material for building according to claim 1, it is characterised in that also include：Additional synthetic resin foaming body (50), by 60~75wt% ldpe resin, 7~13wt% fire retardant, 14~17wt% foaming agent, 0.3~0.6wt% stabilizer, 0.6~1.0wt% crosslinking agent, 0.8~1.2wt% table Foam and form after the activating agent mixing of face, and be bonded on the additional insulation paper tinsel (40)；Other heat-insulated paper tinsels (60), are bonded on the synthetic resin foaming body (50).
- 6. heat-barrier material for building according to claim 5, it is characterised in that the additional synthetic resin foaming body (50) Possesses air chamber (A), the air chamber (A) is surrounded by next door (G) and full of the air for blocking indoor and outdoor hot gas.
- 7. heat-barrier material for building according to any one of claim 1 to 6, it is characterised in that the fire retardant is hydrogen One kind in magnesia, aluminium hydroxide and boron compound, the foaming agent are ammonium class or carbonyl amines, and the stabilizer is silicon Oil, the crosslinking agent are hydrogen peroxide, and the surfactant is alkylbenzenesulfonate.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090132093A (en) * | 2008-06-20 | 2009-12-30 | 주식회사 토일론 | The internal and external heat insulator for architecture |
| CN201874111U (en) * | 2010-11-25 | 2011-06-22 | 苏州市君悦新材料科技有限公司 | Heat insulation material for building |
| JP2014102277A (en) * | 2012-11-16 | 2014-06-05 | Dow Chemical Company | Flame-proof panel for exhibition |
| CN204076963U (en) * | 2013-07-24 | 2015-01-07 | 现代重工业株式会社 | Heat insulating member |
| CN105756212A (en) * | 2016-02-24 | 2016-07-13 | 张日龙 | Building board |
-
2016
- 2016-07-28 CN CN201610607374.9A patent/CN107663905B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090132093A (en) * | 2008-06-20 | 2009-12-30 | 주식회사 토일론 | The internal and external heat insulator for architecture |
| CN201874111U (en) * | 2010-11-25 | 2011-06-22 | 苏州市君悦新材料科技有限公司 | Heat insulation material for building |
| JP2014102277A (en) * | 2012-11-16 | 2014-06-05 | Dow Chemical Company | Flame-proof panel for exhibition |
| CN204076963U (en) * | 2013-07-24 | 2015-01-07 | 现代重工业株式会社 | Heat insulating member |
| CN105756212A (en) * | 2016-02-24 | 2016-07-13 | 张日龙 | Building board |
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