CN107663363A - A kind of matrix composite of ABS PBT polyamide three - Google Patents

A kind of matrix composite of ABS PBT polyamide three Download PDF

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CN107663363A
CN107663363A CN201711171767.0A CN201711171767A CN107663363A CN 107663363 A CN107663363 A CN 107663363A CN 201711171767 A CN201711171767 A CN 201711171767A CN 107663363 A CN107663363 A CN 107663363A
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parts
abs
pbt
polyamide
matrix composite
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宋懂强
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Nantong Zhanpeng Plastic Co Ltd
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Nantong Zhanpeng Plastic Co Ltd
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Priority to CN201711171767.0A priority Critical patent/CN107663363A/en
Priority to PCT/CN2017/116560 priority patent/WO2019100472A1/en
Publication of CN107663363A publication Critical patent/CN107663363A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K2003/026—Phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2231—Oxides; Hydroxides of metals of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/262—Alkali metal carbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/382—Boron-containing compounds and nitrogen
    • C08K2003/385—Binary compounds of nitrogen with boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of matrix composite of ABS PBT polyamide three, belong to plastics arts, the matrix composite of ABS PBT polyamide three is used as the matrix of the composite using ABS, PBT and polyamide, contain multiple functions auxiliary agent simultaneously, by the species and content that optimize auxiliary agent, so that the matrix composite of ABS PBT polyamide three has excellent weather resistance, anti-wear performance and mechanical performance, while there is good antistatic property and heat conductivility.

Description

A kind of matrix composite of ABS-PBT- polyamide three
Technical field
The present invention relates to plastics arts, more particularly to a kind of matrix composite of ABS-PBT- polyamide three.
Background technology
ABS resin is one of five big synthetic resin, its impact resistance, heat resistance, lower temperature resistance, chemical proofing and electricity Gas function admirable, also have the characteristics that easy processing, product size are stable, lustrous surface is good, easy application, coloring can be with Carry out the secondary operation such as surface metallization, plating, welding, hot pressing and bonding, be widely used in machinery, automobile, electronic apparatus, The industrial circles such as instrument and meter, weaving and building, it is a kind of extremely wide thermoplastic engineering plastic of purposes.And existing ABS functions It is single, and the composite based on ABS resin only has a resin matrix.How a kind of ABS-PBT- polyamide three base is designed Composite material, it is industry urgent problem to be solved.
The content of the invention
A kind of base of ABS-PBT- polyamide three is provided it is an object of the invention to avoid weak point of the prior art Composite material.
The purpose of the present invention is achieved through the following technical solutions：
A kind of matrix composite of ABS-PBT- polyamide three is provided, the matrix composite of ABS-PBT- polyamide three by with The parts by weight composition of lower component：ABS 80-100 parts；PBT 80-100 parts；Polyamide 6 0-80 parts；Polyvinyl chloride 10-20 parts； Butadiene-styrene rubber 5-15 parts；Epoxy resin 10-15 parts；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyl -4- hydroxyphenylmethyls） Benzene 1-3 parts；Potassium carbonate 5-10 parts；Boron nitride particle 5-10 parts；Calcium sulfate particle 3-6 parts；Phosphorus heteropoly tungstic acid 1-2 parts；Ji Wusi Alcohol 1-5 parts；HMPA 3-5 parts；Thiol methyl tin 1-3 parts；Benzoyl peroxide 1-3 parts；Titanium cyanines copper 0.5-1 parts； Aluminate coupling agent 1-4 parts；Sodium chloride 1-3 parts；Sodium carbonate 1-4 parts；Graphene oxide 2-5 parts, multi-walled carbon nanotube 1-3 parts； Black phosphorus alkene 1-4 parts；Silver nano-grain 2-6 parts；Copper sulfide 1-4 parts；Cithrol 3-6 parts；PPOX triol 6-10 parts；Ammonium molybdate 1-5 parts；Butyryl citric acid tri-n-hexyl ester 3-6 parts；Vanadic anhydride 1-3 parts；Melamine 1-4 parts；Silicon is received Rice noodles 1-5 parts；Alkali-free glass fibre 2-6 parts；Tin oxide 1-5 parts.
Preferably, the matrix composite of ABS-PBT- polyamide three is made up of the parts by weight of following components：ABS 90 parts；100 parts of PBT；70 parts of polyamide；15 parts of polyvinyl chloride；10 parts of butadiene-styrene rubber；12 parts of epoxy resin；1,3,5- front threes Base -2,4,6-（3,5- di-t-butyl -4- hydroxyphenylmethyls）2 parts of benzene；7 parts of potassium carbonate；8 parts of boron nitride particle；Calcium sulfate particle 5 Part；1 part of phosphorus heteropoly tungstic acid；3 parts of pentaerythrite；4 parts of HMPA；2 parts of thiol methyl tin；3 parts of benzoyl peroxide； 0.5 part of titanium cyanines copper；2 parts of aluminate coupling agent；3 parts of sodium chloride；3 parts of sodium carbonate；4 parts of graphene oxide, multi-walled carbon nanotube 2 Part；2 parts of black phosphorus alkene；4 parts of silver nano-grain；2 parts of copper sulfide；4 parts of cithrol；8 parts of PPOX triol；Molybdenum Sour 3 parts of ammonium；4 parts of butyryl citric acid tri-n-hexyl ester；2 parts of vanadic anhydride；3 parts of melamine；3 parts of silicon nanowires；Alkali-free glass 4 parts of fiber；2 parts of tin oxide.
Preferably, the matrix composite of ABS-PBT- polyamide three is made up of the parts by weight of following components：ABS 100 parts；80 parts of PBT；80 parts of polyamide；18 parts of polyvinyl chloride；12 parts of butadiene-styrene rubber；15 parts of epoxy resin；1,3,5- front threes Base -2,4,6-（3,5- di-t-butyl -4- hydroxyphenylmethyls）1 part of benzene；9 parts of potassium carbonate；9 parts of boron nitride particle；Calcium sulfate particle 5 Part；2 parts of phosphorus heteropoly tungstic acid；4 parts of pentaerythrite；5 parts of HMPA；3 parts of thiol methyl tin；1 part of benzoyl peroxide； 1 part of titanium cyanines copper；3 parts of aluminate coupling agent；2 parts of sodium chloride；3 parts of sodium carbonate；4 parts of graphene oxide, 1 part of multi-walled carbon nanotube； 2 parts of black phosphorus alkene；4 parts of silver nano-grain；3 parts of copper sulfide；5 parts of cithrol；7 parts of PPOX triol；Molybdic acid 2 parts of ammonium；5 parts of butyryl citric acid tri-n-hexyl ester；2 parts of vanadic anhydride；3 parts of melamine；2 parts of silicon nanowires；Alkali-free glass is fine 6 parts of dimension；4 parts of tin oxide.
Preferably, the matrix composite of ABS-PBT- polyamide three is made up of the parts by weight of following components：ABS 80 parts；90 parts of PBT；80 parts of polyamide；12 parts of polyvinyl chloride；7 parts of butadiene-styrene rubber；11 parts of epoxy resin；1,3,5- trimethyls- 2,4,6-（3,5- di-t-butyl -4- hydroxyphenylmethyls）1 part of benzene；10 parts of potassium carbonate；6 parts of boron nitride particle；Calcium sulfate particle 4 Part；2 parts of phosphorus heteropoly tungstic acid；2 parts of pentaerythrite；5 parts of HMPA；2 parts of thiol methyl tin；3 parts of benzoyl peroxide； 0.5 part of titanium cyanines copper；4 parts of aluminate coupling agent；3 parts of sodium chloride；2 parts of sodium carbonate；5 parts of graphene oxide, multi-walled carbon nanotube 2 Part；3 parts of black phosphorus alkene；3 parts of silver nano-grain；2 parts of copper sulfide；4 parts of cithrol；10 parts of PPOX triol； 5 parts of ammonium molybdate；4 parts of butyryl citric acid tri-n-hexyl ester；3 parts of vanadic anhydride；2 parts of melamine；3 parts of silicon nanowires；Alkali-free glass 5 parts of glass fiber；5 parts of tin oxide.
Beneficial effects of the present invention：The matrix composite of ABS-PBT- polyamide three of the present invention has excellent weatherability Energy, anti-wear performance and mechanical performance, while there is good antistatic property and heat conductivility.
Added with potassium carbonate, boron nitride particle, calcium sulfate in the matrix composite of ABS-PBT- polyamide three of the present invention Particle, sodium chloride, sodium carbonate, graphene oxide, multi-walled carbon nanotube, black phosphorus alkene, silver nano-grain, copper sulfide, it is a variety of inorganic The mutual cooperation effect of material, effectively increase heat conductivility, the antistatic behaviour of the matrix composite of ABS-PBT- polyamide three Can, simultaneously added with silicon nanowires, alkali-free glass fibre, tin oxide, it is cross-linked with each other between multiple material, effectively increases ABS- The toughness and tensile strength of the matrix composite of PBT- polyamide three.
Using ABS, PBT and polyamide as three matrixes in the matrix composite of ABS-PBT- polyamide three of the present invention, simultaneously Added with various auxiliary agents, by the content for optimizing each component so that complemented each other between each component, the ABS-PBT- polyamides of formation The matrix composite excellent combination property of amine three, is suitable for multiple fields.
Embodiment
The present invention is described in further detail with reference to embodiments.
The present invention provides a kind of matrix composite of ABS-PBT- polyamide three, and the matrix of ABS-PBT- polyamide three is answered Condensation material is made up of the parts by weight of following components：ABS 80-100 parts；PBT 80-100 parts；Polyamide 6 0-80 parts；Polychlorostyrene second Alkene 10-20 parts；Butadiene-styrene rubber 5-15 parts；Epoxy resin 10-15 parts；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyls -4- Hydroxyphenylmethyl）Benzene 1-3 parts；Potassium carbonate 5-10 parts；Boron nitride particle 5-10 parts；Calcium sulfate particle 3-6 parts；Phosphorus heteropoly tungstic acid 1- 2 parts；Pentaerythrite 1-5 parts；HMPA 3-5 parts；Thiol methyl tin 1-3 parts；Benzoyl peroxide 1-3 parts；Titanium cyanines Copper 0.5-1 parts；Aluminate coupling agent 1-4 parts；Sodium chloride 1-3 parts；Sodium carbonate 1-4 parts；Graphene oxide 2-5 parts, more wall carbon are received Mitron 1-3 parts；Black phosphorus alkene 1-4 parts；Silver nano-grain 2-6 parts；Copper sulfide 1-4 parts；Cithrol 3-6 parts；Polyoxy Change propylene triol 6-10 parts；Ammonium molybdate 1-5 parts；Butyryl citric acid tri-n-hexyl ester 3-6 parts；Vanadic anhydride 1-3 parts；Melamine 1-4 parts；Silicon nanowires 1-5 parts；Alkali-free glass fibre 2-6 parts；Tin oxide 1-5 parts.
Embodiment 1
A kind of matrix composite of ABS-PBT- polyamide three is provided, the matrix composite of ABS-PBT- polyamide three by with The parts by weight composition of lower component：90 parts of ABS；100 parts of PBT；70 parts of polyamide；15 parts of polyvinyl chloride；10 parts of butadiene-styrene rubber； 12 parts of epoxy resin；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyl -4- hydroxyphenylmethyls）2 parts of benzene；7 parts of potassium carbonate；Nitrogen Change 8 parts of boron particles；5 parts of calcium sulfate particle；1 part of phosphorus heteropoly tungstic acid；3 parts of pentaerythrite；4 parts of HMPA；Mercaptan first 2 parts of base tin；3 parts of benzoyl peroxide；0.5 part of titanium cyanines copper；2 parts of aluminate coupling agent；3 parts of sodium chloride；3 parts of sodium carbonate；Oxidation 4 parts of graphene, 2 parts of multi-walled carbon nanotube；2 parts of black phosphorus alkene；4 parts of silver nano-grain；2 parts of copper sulfide；Cithrol 4 Part；8 parts of PPOX triol；3 parts of ammonium molybdate；4 parts of butyryl citric acid tri-n-hexyl ester；2 parts of vanadic anhydride；Melamine 3 Part；3 parts of silicon nanowires；4 parts of alkali-free glass fibre；2 parts of tin oxide.
Embodiment 2
A kind of matrix composite of ABS-PBT- polyamide three is provided, the matrix composite of ABS-PBT- polyamide three by with The parts by weight composition of lower component：100 parts of ABS；80 parts of PBT；80 parts of polyamide；18 parts of polyvinyl chloride；12 parts of butadiene-styrene rubber； 15 parts of epoxy resin；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyl -4- hydroxyphenylmethyls）1 part of benzene；9 parts of potassium carbonate；Nitrogen Change 9 parts of boron particles；5 parts of calcium sulfate particle；2 parts of phosphorus heteropoly tungstic acid；4 parts of pentaerythrite；5 parts of HMPA；Mercaptan first 3 parts of base tin；1 part of benzoyl peroxide；1 part of titanium cyanines copper；3 parts of aluminate coupling agent；2 parts of sodium chloride；3 parts of sodium carbonate；Aoxidize stone Black 4 parts of alkene, 1 part of multi-walled carbon nanotube；2 parts of black phosphorus alkene；4 parts of silver nano-grain；3 parts of copper sulfide；Cithrol 5 Part；7 parts of PPOX triol；2 parts of ammonium molybdate；5 parts of butyryl citric acid tri-n-hexyl ester；2 parts of vanadic anhydride；Melamine 3 Part；2 parts of silicon nanowires；6 parts of alkali-free glass fibre；4 parts of tin oxide.
Embodiment 3
A kind of matrix composite of ABS-PBT- polyamide three is provided, the matrix composite of ABS-PBT- polyamide three by with The parts by weight composition of lower component：80 parts of ABS；90 parts of PBT；80 parts of polyamide；12 parts of polyvinyl chloride；7 parts of butadiene-styrene rubber；Epoxy 11 parts of resin；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyl -4- hydroxyphenylmethyls）1 part of benzene；10 parts of potassium carbonate；Nitridation 6 parts of boron particles；4 parts of calcium sulfate particle；2 parts of phosphorus heteropoly tungstic acid；2 parts of pentaerythrite；5 parts of HMPA；Thiol methyl 2 parts of tin；3 parts of benzoyl peroxide；0.5 part of titanium cyanines copper；4 parts of aluminate coupling agent；3 parts of sodium chloride；2 parts of sodium carbonate；Aoxidize stone Black 5 parts of alkene, 2 parts of multi-walled carbon nanotube；3 parts of black phosphorus alkene；3 parts of silver nano-grain；2 parts of copper sulfide；Cithrol 4 Part；10 parts of PPOX triol；5 parts of ammonium molybdate；4 parts of butyryl citric acid tri-n-hexyl ester；3 parts of vanadic anhydride；Melamine 2 Part；3 parts of silicon nanowires；5 parts of alkali-free glass fibre；5 parts of tin oxide.
The matrix composite of ABS-PBT- polyamide three of the present invention has excellent weather resistance, anti-wear performance and machine Tool performance, while there is good antistatic property and heat conductivility.The matrix composite wood of ABS-PBT- polyamide three of the present invention In material added with potassium carbonate, boron nitride particle, calcium sulfate particle, sodium chloride, sodium carbonate, graphene oxide, multi-walled carbon nanotube, Black phosphorus alkene, silver nano-grain, copper sulfide, the mutual cooperation effect of a variety of inorganic material, effectively increase ABS-PBT- polyamide Heat conductivility, the antistatic property of three matrix composites are more simultaneously added with silicon nanowires, alkali-free glass fibre, tin oxide It is cross-linked with each other between kind material, effectively increases the toughness and tensile strength of the matrix composite of ABS-PBT- polyamide three.This Using ABS, PBT and polyamide as three matrixes in the matrix composite of ABS-PBT- polyamide three of invention, simultaneously added with various Auxiliary agent, by the content for optimizing each component so that complemented each other between each component, the matrix of ABS-PBT- polyamide three of formation is answered Condensation material excellent combination property, is suitable for multiple fields.
Finally it should be noted that above example is merely to illustrate technical scheme rather than the present invention is protected The limitation of scope, although being explained in detail with reference to preferred embodiment to the present invention, one of ordinary skill in the art should manage Solution, can modify or equivalent substitution to technical scheme, without departing from technical solution of the present invention essence and Scope.

Claims (4)

1. a kind of matrix composite of ABS-PBT- polyamide three, it is characterised in that the matrix of ABS-PBT- polyamide three is answered Condensation material is made up of the parts by weight of following components：ABS 80-100 parts；PBT 80-100 parts；Polyamide 6 0-80 parts；Polychlorostyrene second Alkene 10-20 parts；Butadiene-styrene rubber 5-15 parts；Epoxy resin 10-15 parts；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyls -4- Hydroxyphenylmethyl）Benzene 1-3 parts；Potassium carbonate 5-10 parts；Boron nitride particle 5-10 parts；Calcium sulfate particle 3-6 parts；Phosphorus heteropoly tungstic acid 1- 2 parts；Pentaerythrite 1-5 parts；HMPA 3-5 parts；Thiol methyl tin 1-3 parts；Benzoyl peroxide 1-3 parts；Titanium cyanines Copper 0.5-1 parts；Aluminate coupling agent 1-4 parts；Sodium chloride 1-3 parts；Sodium carbonate 1-4 parts；Graphene oxide 2-5 parts, more wall carbon are received Mitron 1-3 parts；Black phosphorus alkene 1-4 parts；Silver nano-grain 2-6 parts；Copper sulfide 1-4 parts；Cithrol 3-6 parts；Polyoxy Change propylene triol 6-10 parts；Ammonium molybdate 1-5 parts；Butyryl citric acid tri-n-hexyl ester 3-6 parts；Vanadic anhydride 1-3 parts；Melamine 1-4 parts；Silicon nanowires 1-5 parts；Alkali-free glass fibre 2-6 parts；Tin oxide 1-5 parts.
2. the matrix composite of ABS-PBT- polyamide three according to claim 1, it is characterised in that the ABS-PBT- The matrix composite of polyamide three is made up of the parts by weight of following components：90 parts of ABS；100 parts of PBT；70 parts of polyamide；It is poly- 15 parts of vinyl chloride；10 parts of butadiene-styrene rubber；12 parts of epoxy resin；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyl -4- hydroxyls Benzyl）2 parts of benzene；7 parts of potassium carbonate；8 parts of boron nitride particle；5 parts of calcium sulfate particle；1 part of phosphorus heteropoly tungstic acid；3 parts of pentaerythrite； 4 parts of HMPA；2 parts of thiol methyl tin；3 parts of benzoyl peroxide；0.5 part of titanium cyanines copper；2 parts of aluminate coupling agent； 3 parts of sodium chloride；3 parts of sodium carbonate；4 parts of graphene oxide, 2 parts of multi-walled carbon nanotube；2 parts of black phosphorus alkene；4 parts of silver nano-grain；Sulphur Change 2 parts of copper；4 parts of cithrol；8 parts of PPOX triol；3 parts of ammonium molybdate；Butyryl citric acid tri-n-hexyl ester 4 Part；2 parts of vanadic anhydride；3 parts of melamine；3 parts of silicon nanowires；4 parts of alkali-free glass fibre；2 parts of tin oxide.
3. the matrix composite of ABS-PBT- polyamide three according to claim 1, it is characterised in that the ABS-PBT- The matrix composite of polyamide three is made up of the parts by weight of following components：100 parts of ABS；80 parts of PBT；80 parts of polyamide；It is poly- 18 parts of vinyl chloride；12 parts of butadiene-styrene rubber；15 parts of epoxy resin；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyl -4- hydroxyls Benzyl）1 part of benzene；9 parts of potassium carbonate；9 parts of boron nitride particle；5 parts of calcium sulfate particle；2 parts of phosphorus heteropoly tungstic acid；4 parts of pentaerythrite； 5 parts of HMPA；3 parts of thiol methyl tin；1 part of benzoyl peroxide；1 part of titanium cyanines copper；3 parts of aluminate coupling agent；Chlorine Change 2 parts of sodium；3 parts of sodium carbonate；4 parts of graphene oxide, 1 part of multi-walled carbon nanotube；2 parts of black phosphorus alkene；4 parts of silver nano-grain；Vulcanization 3 parts of copper；5 parts of cithrol；7 parts of PPOX triol；2 parts of ammonium molybdate；5 parts of butyryl citric acid tri-n-hexyl ester； 2 parts of vanadic anhydride；3 parts of melamine；2 parts of silicon nanowires；6 parts of alkali-free glass fibre；4 parts of tin oxide.
4. the matrix composite of ABS-PBT- polyamide three according to claim 1, it is characterised in that the ABS-PBT- The matrix composite of polyamide three is made up of the parts by weight of following components：80 parts of ABS；90 parts of PBT；80 parts of polyamide；Polychlorostyrene 12 parts of ethene；7 parts of butadiene-styrene rubber；11 parts of epoxy resin；1,3,5- trimethyls -2,4,6-（3,5- di-t-butyl -4- hydroxy benzenes first Base）1 part of benzene；10 parts of potassium carbonate；6 parts of boron nitride particle；4 parts of calcium sulfate particle；2 parts of phosphorus heteropoly tungstic acid；2 parts of pentaerythrite；Six 5 parts of methyl phosphoric triamide；2 parts of thiol methyl tin；3 parts of benzoyl peroxide；0.5 part of titanium cyanines copper；4 parts of aluminate coupling agent；Chlorine Change 3 parts of sodium；2 parts of sodium carbonate；5 parts of graphene oxide, 2 parts of multi-walled carbon nanotube；3 parts of black phosphorus alkene；3 parts of silver nano-grain；Vulcanization 2 parts of copper；4 parts of cithrol；10 parts of PPOX triol；5 parts of ammonium molybdate；4 parts of butyryl citric acid tri-n-hexyl ester； 3 parts of vanadic anhydride；2 parts of melamine；3 parts of silicon nanowires；5 parts of alkali-free glass fibre；5 parts of tin oxide.
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