CN107653673A - It is a kind of that there is super-hydrophobic and titanium dioxide/bafta of self-cleaning function - Google Patents
It is a kind of that there is super-hydrophobic and titanium dioxide/bafta of self-cleaning function Download PDFInfo
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- CN107653673A CN107653673A CN201711109397.8A CN201711109397A CN107653673A CN 107653673 A CN107653673 A CN 107653673A CN 201711109397 A CN201711109397 A CN 201711109397A CN 107653673 A CN107653673 A CN 107653673A
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- bafta
- tio
- hydrophobic
- sodium hydroxide
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 230000003075 superhydrophobic effect Effects 0.000 title claims abstract description 23
- 238000004140 cleaning Methods 0.000 title claims abstract description 19
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 14
- 229920000742 Cotton Polymers 0.000 claims abstract description 62
- 239000004744 fabric Substances 0.000 claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000008367 deionised water Substances 0.000 claims abstract description 26
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 26
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- YSBQKZZHQPPKEL-UHFFFAOYSA-N ethanol;tetrafluorosilane Chemical compound CCO.F[Si](F)(F)F YSBQKZZHQPPKEL-UHFFFAOYSA-N 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 90
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 10
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 10
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 125000000129 anionic group Chemical group 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 7
- 108091003079 Bovine Serum Albumin Proteins 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 229940098773 bovine serum albumin Drugs 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 230000001699 photocatalysis Effects 0.000 abstract description 6
- 238000007146 photocatalysis Methods 0.000 abstract description 5
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000002105 nanoparticle Substances 0.000 abstract description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- -1 diameter 1-100nm Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000002086 nanomaterial Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 240000004528 Catalpa ovata Species 0.000 description 1
- 235000010005 Catalpa ovata Nutrition 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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Abstract
There is super-hydrophobic and titanium dioxide/bafta of self-cleaning function the invention discloses a kind of, nano-TiO is generated by the internal in-situ in bafta2Particle and by TiO2Nano particle is coated among BSA, obtains BSA/TiO2/ BSA modified cotton fabrics, then by above-mentioned BSA/TiO2/ BSA modified cotton fabrics are immersed in 1 24h in the silicon fluoride ethanol solution of volume fraction 1 10%, after reaction terminates, are cleaned repeatedly with deionized water, are dried in vacuo and obtain a kind of having super-hydrophobic and self-cleaning function titanium dioxide/bafta.The present invention has the advantages that simple to operate, reaction condition temperature, and bafta can obtain excellent super-hydrophobic, automatically cleaning, antibacterial, uvioresistant, photocatalysis, crease-resistant and washing fastness.
Description
Technical field
There is super-hydrophobic and titanium dioxide/bafta of self-cleaning function, function of dominant nano material the present invention relates to a kind of
And textile material field.
Background technology
It is super-hydrophobic（superhydrophobicity）Phenomenon refers to water droplet in one of the contact angle of the surface of solids more than 150 °
The special physical phenomenon of kind.Research shows that the micro-rough structure and low-surface-energy of material surface cause super-hydrophobic phenomenon
Main cause.Thus preparing super hydrophobic material has two class methods：First, in hydrophobic material surface structure micro nano structure；Second,
Micro-nano surface modification low-surface energy substance with hierarchy（Zhou Sisi, manage spontaneous, Li Qiang, Lu Chunhua, Xu Zhong Chinese catalpas Zn
Piece builds super-hydrophobic ZnO surfaces [J] Acta PhySico-Chimica Sinicas, 2009,25 (08) through hydro-thermal reaction and silicon fluoride modification:1593-
1598）.In view of super-hydrophobic phenomenon has good application prospect in fields such as waterproof, oil/water separation, automatically cleaning, freezings, surpass
The preparation and application of hydrophobic material cause the concern of numerous researchers.
Nano-TiO2It is a kind of important inorganic nano material.Nano-TiO2, also known as titanium dioxide, diameter 1-100nm, product
Outward appearance is fluffy white powder, has the performance such as uvioresistant, antibacterial, self-cleaning, anti-aging, in photocatalysis, clean energy resource, change
There are extensive research and application in the fields such as cosmetic, functional fibre, plastics, ink, coating, paint, fine ceramics, photoelectric material
（The amination modified nano-TiOs of Zhang Weiwei2Prepare and study real silk fabric uvioresistant performance [D] University Of Suzhou, 2015）.
In field of textiles, nano-TiO2Can providing cotton fabric is super-hydrophobic, antibacterial, deodorization, automatically cleaning, crease-resistant, ultraviolet screen
Cover and the function such as photocatalysis.By nano-TiO2The inherent shortcoming of bafta can be effectively improved by being combined with bafta, expanded cotton and knitted
The scope of application of thing, improve the added value of bafta.Such as University of Anhui Zhang Ye is using butyl titanate as raw material, using different
Method synthesizes nano-TiO2, and fabric face is arranged, then pass through the difluoro heptyl hydroxypropyl methyl two of low-surface energy substance ten
Methoxy silane is subsequently modified, and prepares the functional fabric with super-hydrophobic, uvioresistant and photocatalysis performance（Open firelight or sunlight TiO2
The preparation of nano-particle and its application [D] the University of Anhui on fabric, 2011）.Resource and environment institute of Shaanxi Tech Univ
Xue Chaohua uses TiO2Colloidal sol handles bafta, and then respectively using stearic acid, 1H, 1H, 2H, 2H be complete-fluorine dodecyl trichlorine
Silane and both combine to fabric face carry out low-surface-energy processing, prepare super-hydrophobic cotton fabric.Test result indicates that：TiO2
Introducing be not only roughened micron order fiber surface, so as to obtain micro-nano coarse structure fabric face, strengthen fabric hydrophobicity
Can, it can also make fabric that there is good ultraviolet screener performance.Work as TiO2Mass fraction be 0.8% when, W protection
It can reach optimal（Xue Chaohua, Jia Shuntian, a quiet titania sol-gels method prepare fluorine-containing super-hydrophobic cotton fabric [J] prints
Dye, 2009,35 (23):1-4）.
But current nano-TiO2Modification to bafta is mainly realized by finishing method.Finishing method is mainly adopted
With impregnate, pad, coating or the methods of spraying by nano-TiO2Arrange on bafta, it has, and technique is simple, operability
The advantage such as strong.But there is nano material in process easily to reunite, nano material is received in fiber and fabric face skewness
The problem of rice material is low with fiber binding strength（Zhou Shunli, Wang Feng, Xiong Zujiang, Wang Rui, Yang Chunfang, Zhang Xiuqin, the bright book bases of sun
Circulate a notice of in photocatalytic self-cleaning fabric progress [J] the macromolecules of nano titanium oxide, 2017, (04):9-18）.
The content of the invention
In view of the above problems, the present invention provides it is a kind of have super-hydrophobic and titanium dioxide/bafta of self-cleaning function and
Its preparation method.
The technical scheme is that：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 10-18%, bath raio 1:50,70 DEG C of reaction 180min,
Neutrality is washed till repeatedly with deionized water, and sodium hydroxide is obtained after drying and is modified cotton；Then above-mentioned sodium hydroxide modification cotton is disperseed
In ethanol, bath raio 1:Condensing reflux 60min under 50,80 DEG C of nitrogen protective conditions, add alcohol ether sulfosuccinic acid monoesters disodium
Salt, after at the uniform velocity stirring 60min, ABVN and dibenzoyl peroxide are added, continues stirring reaction 1-12h, after filtering
Cleaned repeatedly using ethanol, deionized water, anionic bafta is obtained after vacuum drying；The alcohol ether sulfosuccinic acid monoesters
The mass ratio that disodium salt is modified cotton with sodium hydroxide is 1:1-1:3, the quality of the ABVN is modified for sodium hydroxide
The 0.01%-0.5% of cotton, the quality of the dibenzoyl peroxide are modified the 0.01%-0.5% of cotton for sodium hydroxide；（2）Will be above-mentioned
Anion bafta is immersed in 60 DEG C of mass fraction 0.1-1% bovine serum albumin(BSA)（BSA）60min in solution, obtains BSA
Modified cotton fabric；（3）Above-mentioned BSA modified cotton fabrics are immersed in the 1-10g/L butyl titanate aqueous solution, bath raio 1:50,
It is slowly added to neopelex（SDBS）, the mass ratio of the SDBS and butyl titanate are 2:1-1:2, ultrasound
After 30min, move in autoclave, 200 DEG C of hydro-thermal reaction 1-12h, after reaction terminates, cleaned, done repeatedly with deionized water
Dry processing obtains TiO2/ BSA modified cotton fabrics；（4）By above-mentioned TiO2/ BSA modified cotton fabrics are immersed in 60 DEG C of mass fraction
60min in 0.1-1% BSA solution, cleaned repeatedly with deionized water, be dried in vacuo and obtain BSA/TiO2/ BSA modified cotton fabrics；
（5）By above-mentioned BSA/TiO2/ BSA modified cotton fabrics are immersed in 1-24h in volume fraction 1-10% silicon fluoride ethanol solution, instead
After should terminating, cleaned repeatedly with deionized water, be dried in vacuo and obtain that there is super-hydrophobic and self-cleaning function titanium dioxide/cotton to knit
Thing.
Compared with prior art, the advantage of the invention is that：The advantages that simple to operate, reaction condition temperature, bafta can obtain
Excellent super-hydrophobic, automatically cleaning, antibacterial, uvioresistant, photocatalysis, crease-resistant and washing fastness.
Embodiment
The invention will be further elucidated with reference to specific embodiments.
Embodiment 1：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 10%, bath raio 1:50,70 DEG C of reaction 180min, are used
Deionized water is washed till neutrality repeatedly, and sodium hydroxide is obtained after drying and is modified cotton；Then above-mentioned sodium hydroxide modification cotton is scattered in
In ethanol, bath raio 1:Condensing reflux 60min under 50,80 DEG C of nitrogen protective conditions, alcohol ether mono sulfosuccinates are added,
After at the uniform velocity stirring 60min, ABVN and dibenzoyl peroxide are added, continues stirring reaction 1h, second is used after filtering
Alcohol, deionized water are cleaned repeatedly, and anionic bafta is obtained after vacuum drying；The alcohol ether mono sulfosuccinates
The mass ratio that cotton is modified with sodium hydroxide is 1:1, the quality of the ABVN is modified the 0.01% of cotton for sodium hydroxide,
The quality of the dibenzoyl peroxide is that sodium hydroxide is modified the 0.01% of cotton.（2）Above-mentioned anionic bafta is immersed in
The bovine serum albumin(BSA) of 60 DEG C of mass fraction 0.1%（BSA）60min in solution, obtain BSA modified cotton fabrics.（3）Will be above-mentioned
BSA modified cotton fabrics are immersed in the 1g/L butyl titanate aqueous solution, bath raio 1:50, it is slowly added to neopelex
（SDBS）, the mass ratio of the SDBS and butyl titanate are 2:After 1, ultrasonic 30min, move in autoclave, 200 DEG C of water
Thermal response 1h, after reaction terminates, cleaned repeatedly with deionized water, drying process obtains TiO2/ BSA modified cotton fabrics.（4）Will be upper
State TiO2/ BSA modified cotton fabrics are immersed in 60min in the BSA solution of 60 DEG C of mass fraction 0.1%, repeatedly clear with deionized water
Wash, be dried in vacuo and obtain BSA/TiO2/ BSA modified cotton fabrics.（5）By above-mentioned BSA/TiO2/ BSA modified cotton fabrics are immersed in body
1h in the silicon fluoride ethanol solution of fraction 1%, reaction terminate after, cleaned repeatedly with deionized water, be dried in vacuo obtain have surpass
Hydrophobic and titanium dioxide/bafta of self-cleaning function.
Embodiment 2：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 12%, bath raio 1:50,70 DEG C of reaction 180min, are used
Deionized water is washed till neutrality repeatedly, and sodium hydroxide is obtained after drying and is modified cotton；Then above-mentioned sodium hydroxide modification cotton is scattered in
In ethanol, bath raio 1:Condensing reflux 60min under 50,80 DEG C of nitrogen protective conditions, alcohol ether mono sulfosuccinates are added,
After at the uniform velocity stirring 60min, ABVN and dibenzoyl peroxide are added, continues stirring reaction 3h, second is used after filtering
Alcohol, deionized water are cleaned repeatedly, and anionic bafta is obtained after vacuum drying；The alcohol ether mono sulfosuccinates
The mass ratio that cotton is modified with sodium hydroxide is 1:2, the quality of the ABVN is modified the 0.1% of cotton for sodium hydroxide, institute
The quality for stating dibenzoyl peroxide is modified the 0.1% of cotton for sodium hydroxide.（2）Above-mentioned anionic bafta is immersed in 60
DEG C mass fraction 0.5% bovine serum albumin(BSA)（BSA）60min in solution, obtain BSA modified cotton fabrics.（3）By above-mentioned BSA
Modified cotton fabric is immersed in the 5g/L butyl titanate aqueous solution, bath raio 1:50, it is slowly added to neopelex
（SDBS）, the mass ratio of the SDBS and butyl titanate are 1:After 1, ultrasonic 30min, move in autoclave, 200 DEG C of water
Thermal response 6h, after reaction terminates, cleaned repeatedly with deionized water, drying process obtains TiO2/ BSA modified cotton fabrics.（4）Will be upper
State TiO2/ BSA modified cotton fabrics are immersed in 60min in the BSA solution of 60 DEG C of mass fraction 0.5%, repeatedly clear with deionized water
Wash, be dried in vacuo and obtain BSA/TiO2/ BSA modified cotton fabrics.（5）By above-mentioned BSA/TiO2/ BSA modified cotton fabrics are immersed in body
12h in the silicon fluoride ethanol solution of fraction 5%, after reaction terminates, cleaned repeatedly with deionized water, be dried in vacuo and had
Super-hydrophobic and titanium dioxide/bafta of self-cleaning function.
Embodiment 3：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 18%, bath raio 1:50,70 DEG C of reaction 180min, are used
Deionized water is washed till neutrality repeatedly, and sodium hydroxide is obtained after drying and is modified cotton；Then above-mentioned sodium hydroxide modification cotton is scattered in
In ethanol, bath raio 1:Condensing reflux 60min under 50,80 DEG C of nitrogen protective conditions, alcohol ether mono sulfosuccinates are added,
After at the uniform velocity stirring 60min, ABVN and dibenzoyl peroxide are added, continues stirring reaction 12h, second is used after filtering
Alcohol, deionized water are cleaned repeatedly, and anionic bafta is obtained after vacuum drying；The alcohol ether mono sulfosuccinates
The mass ratio that cotton is modified with sodium hydroxide is 1:3, the quality of the ABVN is modified the 0.5% of cotton for sodium hydroxide, institute
The quality for stating dibenzoyl peroxide is modified the 0.5% of cotton for sodium hydroxide.（2）Above-mentioned anionic bafta is immersed in 60
DEG C mass fraction 1% bovine serum albumin(BSA)（BSA）60min in solution, obtain BSA modified cotton fabrics.（3）Above-mentioned BSA is changed
Property bafta is immersed in the 10g/L butyl titanate aqueous solution, bath raio 1:50, it is slowly added to neopelex
（SDBS）, the mass ratio of the SDBS and butyl titanate are 1:After 2, ultrasonic 30min, move in autoclave, 200 DEG C of water
Thermal response 12h, after reaction terminates, cleaned repeatedly with deionized water, drying process obtains TiO2/ BSA modified cotton fabrics.（4）Will
Above-mentioned TiO2/ BSA modified cotton fabrics are immersed in 60min in the BSA solution of 60 DEG C of mass fraction 1%, repeatedly clear with deionized water
Wash, be dried in vacuo and obtain BSA/TiO2/ BSA modified cotton fabrics.（5）By above-mentioned BSA/TiO2/ BSA modified cotton fabrics are immersed in body
24h in the silicon fluoride ethanol solution of fraction 10%, after reaction terminates, cleaned repeatedly with deionized water, be dried in vacuo and had
Super-hydrophobic and titanium dioxide/bafta of self-cleaning function.
Obviously, the above embodiment of the present invention is only intended to clearly illustrate example of the present invention, and is not pair
The restriction of embodiments of the present invention.For those of ordinary skill in the field, may be used also on the basis of the above description
To make other changes in different forms.Here all embodiments can not be exhaustive.It is every to belong to this hair
Row of the obvious changes or variations that bright technical scheme is amplified out still in protection scope of the present invention.
Claims (2)
1. a kind of have super-hydrophobic and titanium dioxide/bafta of self-cleaning function and preparation method thereof, it is characterised in that：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 10-18%, bath raio 1:50,70 DEG C of reaction 180min,
Neutrality is washed till repeatedly with deionized water, and sodium hydroxide is obtained after drying and is modified cotton；Then above-mentioned sodium hydroxide modification cotton is disperseed
In ethanol, bath raio 1:Condensing reflux 60min under 50,80 DEG C of nitrogen protective conditions, add alcohol ether sulfosuccinic acid monoesters disodium
Salt, after at the uniform velocity stirring 60min, ABVN and dibenzoyl peroxide are added, continues stirring reaction 1-12h, after filtering
Cleaned repeatedly using ethanol, deionized water, anionic bafta is obtained after vacuum drying；The alcohol ether sulfosuccinic acid monoesters
The mass ratio that disodium salt is modified cotton with sodium hydroxide is 1:1-1:3, the quality of the ABVN is modified for sodium hydroxide
The 0.01%-0.5% of cotton, the quality of the dibenzoyl peroxide are modified the 0.01%-0.5% of cotton for sodium hydroxide；（2）Will be above-mentioned
Anionic bafta is immersed in 60 DEG C of mass fraction 0.1-1% bovine serum albumin(BSA)（BSA）60min in solution, is obtained
BSA modified cotton fabrics；（3）Above-mentioned BSA modified cotton fabrics are immersed in the 1-10g/L butyl titanate aqueous solution, bath raio 1:
50, it is slowly added to neopelex（SDBS）, the mass ratio of the SDBS and butyl titanate are 2:1-1:2, ultrasound
After 30min, move in autoclave, 200 DEG C of hydro-thermal reaction 1-12h, after reaction terminates, cleaned, done repeatedly with deionized water
Dry processing obtains TiO2/ BSA modified cotton fabrics；（4）By above-mentioned TiO2/ BSA modified cotton fabrics are immersed in 60 DEG C of mass fraction
60min in 0.1-1% BSA solution, cleaned repeatedly with deionized water, be dried in vacuo and obtain BSA/TiO2/ BSA modified cotton fabrics；
（5）By above-mentioned BSA/TiO2/ BSA modified cotton fabrics are immersed in 1-24h in volume fraction 1-10% silicon fluoride ethanol solution, instead
After should terminating, cleaned repeatedly with deionized water, be dried in vacuo and obtain that there is super-hydrophobic and self-cleaning function titanium dioxide/cotton to knit
Thing.
2. obtained by claim 1 preparation method a kind of with super-hydrophobic and titanium dioxide/bafta of self-cleaning function.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110258108A (en) * | 2019-05-29 | 2019-09-20 | 安徽元和工贸有限责任公司 | A kind of anti-crease finishing method of cotton fabric |
| CN112691556A (en) * | 2020-12-31 | 2021-04-23 | 天津理工大学 | Method for preparing oil-water separation membrane by using melt-blown cloth layer of waste mask |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101876144A (en) * | 2010-07-06 | 2010-11-03 | 西安工程大学 | Method for modifying cotton fabrics by adopting tetrabutyl titanate |
| CN103215804A (en) * | 2013-04-02 | 2013-07-24 | 西安工程大学 | Method for modifying and dyeing polyester fiber by use of silver-doped nano titanium dioxide disperse dye |
| CN105350282A (en) * | 2015-12-12 | 2016-02-24 | 中原工学院 | Preparation method for fluoride-free super-hydrophobic cotton fabric |
-
2017
- 2017-11-11 CN CN201711109397.8A patent/CN107653673A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101876144A (en) * | 2010-07-06 | 2010-11-03 | 西安工程大学 | Method for modifying cotton fabrics by adopting tetrabutyl titanate |
| CN103215804A (en) * | 2013-04-02 | 2013-07-24 | 西安工程大学 | Method for modifying and dyeing polyester fiber by use of silver-doped nano titanium dioxide disperse dye |
| CN105350282A (en) * | 2015-12-12 | 2016-02-24 | 中原工学院 | Preparation method for fluoride-free super-hydrophobic cotton fabric |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110258108A (en) * | 2019-05-29 | 2019-09-20 | 安徽元和工贸有限责任公司 | A kind of anti-crease finishing method of cotton fabric |
| CN110258108B (en) * | 2019-05-29 | 2022-04-01 | 依文服饰股份有限公司 | Crease-resistant finishing method for cotton fabric |
| CN112691556A (en) * | 2020-12-31 | 2021-04-23 | 天津理工大学 | Method for preparing oil-water separation membrane by using melt-blown cloth layer of waste mask |
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