CN107653456A - A kind of natural environmental-protective Deruster for metal for automation equipment - Google Patents
A kind of natural environmental-protective Deruster for metal for automation equipment Download PDFInfo
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- CN107653456A CN107653456A CN201710899372.6A CN201710899372A CN107653456A CN 107653456 A CN107653456 A CN 107653456A CN 201710899372 A CN201710899372 A CN 201710899372A CN 107653456 A CN107653456 A CN 107653456A
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- Prior art keywords
- metal
- protective
- deruster
- automation equipment
- natural environmental
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention relates to anti-corrosion of metal field, discloses a kind of natural environmental-protective Deruster for metal for automation equipment.The rust remover contains following components:45 65wt% organic acids, 2 10wt% lecithin, 1 5wt% aminosals, surplus is water.Inventive formulation is all using nontoxic, pollution-free, degradable natural material, it is environment-friendly, cost is relatively low, and technique is simple, removes rusty stain positive effect, and the metal after the rust remover processing of the present invention, there is certain counnter attack rust effect, therefore the next step can be directly entered without washing after use, even if having, a small amount of residual is also harmless to operating personnel and surrounding devices, in the derusting anti-corrosive technique for the food automated production equipment that is particularly suitable for use in.
Description
Technical field
The present invention relates to anti-corrosion of metal field, more particularly to a kind of natural environmental-protective metal-derusting for automation equipment
Agent.
Background technology
The material that automated production equipment and its part are commonly used is generally steel, and corrosion easily occurs during use.Pass
The chemical derusting of system can chemically react usually using strong acid, acid with iron rust and metal oxide, generate solubility salt, from
And reaching the purpose of derusting, while derusting, sour and can and underlying metal react and release hydrogen, and Hydrogen Energy is to iron rust and indissoluble
Oxide skin produces pressure, be advantageous to they peeling and high price iron reduction, accelerate the process of pickling, but traditional acid solution is handled
Method there is also it is obvious the defects of:The generation of a large amount of hydrogen can make steel produce Hydrogen Brittleness Phenomena i.e. in processing procedure, cause gold
The mechanical properties decrease of category, influence the intensity of steel in itself;Acid mist is easily formed simultaneously, influences health and the corrosion week of operating personnel
The equipment and environment enclosed;The consumption of acid solution is also larger, increases processing cost;This kind of acid can form excessive erosion to steel.In addition,
It is substantial amounts of to produce residue, need to often it discharge, both heavy corrosion industrial pipeline, and contaminated soil and environment.
The Chinese patent of Application No. 201310646506.5 discloses a kind of neutral without phosphorus rust remover, and normal temperature uses, right
Environmental nonpollution, and anti-rust problem can be improved.But this rust remover is mainly using the complexing derusting of a large amount of complexing agents, cost
It is higher, higher is required to pH value.
The Chinese patent of Application No. 201611218731.9 discloses a kind of natural rust remover, contains sword in the rust remover
Auricle grass extract, it is safe and non-toxic, there is good rust removing function to metal, but this rust remover be paste or solid-state, it is necessary to
Rusty part use is applied to, it is troublesome in poeration, it is not suitable for automated production.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of natural environmental-protective metal-derusting for automation equipment
Agent, avoid, using disagreeableness raw materials of environment such as inorganic acid and phosphorus, to spray or soaking use, it is easy to operate, to operator
Member and surrounding apparatus are harmless, in the derusting anti-corrosive technique for the food automated production equipment that is particularly suitable for use in.
The present invention concrete technical scheme be:The rust remover contains following components:45-65wt% organic acids, 2-10wt% ovum
Phosphatide, 1-5wt% aminosals, surplus are water.
Organic acid is used as main derusting composition, to environment nontoxic pollution-free.But because organic acid acidity is compared and salt
Acid or sulfuric acid are weaker, therefore add lecithin as accelerator, and lecithin is a kind of natural surfactant, can be helped organic
Acid infiltration, wetting metal surface, promote the progress of descaling process;In addition, lecithin can also be used as dispersant simultaneously, prevent organic
Mutually assemble between acid, increase active area;Aminosal has the function that inhibition, also containing organic in being especially formulated
Acid, protein can be promoted to hydrolyze, therefore requirement of the formula of the present invention to raw material is relatively low, can reduce cost.
Preferably, the rust remover contains following components:55-62wt% organic acids, 5-8wt% lecithin, 2-4wt% hydrolysis
Protein, surplus are water.
Preferably, the organic acid is citric acid or lactic acid.
Preferably, the aminosal is the hydrolysate of human body or animal hair.
Preferably, the preparation method of the aminosal is:After hair is carried out into broken pretreatment, pawpaw egg is added
White enzyme and water, and pH value is adjusted to 6-8, filtered after digesting 2.5-4h through anion exchange resin, obtain aminosal.
Preferably, the aminosal is the waste liquid after human body or animal hair hydrolysis extraction cystine.
The amino acids industry in China flourished in recent years, particularly hair-hydrolyzation method production CYSTINE, however, according to survey
Examination, extract in a large amount of mother liquors after cystine, also containing 10 kinds of amino acid are had more than, directly discharge and waste resource, but due to
It also cannot be used directly for manufacturing food or medicine containing poisonous and harmful substances such as a small amount of heavy metals in hair, and be used as rust remover
Raw material, without increasing the post-processing steps such as removal of impurities, purification, both reduce cost, and environment-friendly, solve hair-hydrolyzation
Waste water.
It is compared with the prior art, the beneficial effects of the invention are as follows:Inventive formulation all using it is nontoxic, pollution-free, can drop
The natural material of solution, environment-friendly, cost is relatively low, and technique is simple, removes rusty stain positive effect, and through the rust remover of the present invention
After processing, there is certain counnter attack rust effect, therefore without washing, the next step can be directly entered, remained on a small quantity even if having
It is harmless to operating personnel and surrounding devices, in the derusting anti-corrosive technique for the food automated production equipment that is particularly suitable for use in.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
After hair is carried out into broken pretreatment, papain and water are added, and adjusts pH value to 8, is digested after 4h through anion
Exchanger resin filters, and obtains aminosal.
45wt% citric acids, 10wt% lecithin, 3wt% hair-hydrolyzation protein, 40wt% water are mixed evenly, produced
Natural environmental-protective Deruster for metal.
Embodiment 2
After hair is carried out into broken pretreatment, papain and water are added, and adjusts pH value to 7, is digested after 3h through anion
Exchanger resin filters, and obtains aminosal.
65wt% citric acids, 2wt% lecithin, 1wt% hair-hydrolyzation protein, 32wt% water are mixed evenly, produced
Natural environmental-protective Deruster for metal.
Embodiment 3
After hair is carried out into broken pretreatment, papain and water are added, and adjusts pH value to 6, it is extracted after digesting 3.5h
In cystine, residual waste solution is hair-hydrolyzation protein.
58wt% citric acids, 6wt% lecithin, 5wt% hair-hydrolyzation protein, 33wt% water are mixed evenly, produced
Natural environmental-protective Deruster for metal.
Raw materials used in the present invention, equipment, it is the conventional raw material, equipment of this area unless otherwise noted;In the present invention
Method therefor, it is the conventional method of this area unless otherwise noted.
It is described above, only it is presently preferred embodiments of the present invention, not the present invention is imposed any restrictions, it is every according to the present invention
Any simple modification, change and the equivalent transformation that technical spirit is made to above example, still fall within the technology of the present invention side
The protection domain of case.
Claims (6)
1. a kind of natural environmental-protective Deruster for metal for automation equipment, it is characterised in that the rust remover contains following components:
45-65wt% organic acids, 2-10wt% lecithin, 1-5wt% aminosals, surplus are water.
2. it is used for the natural environmental-protective Deruster for metal of automation equipment as claimed in claim 1, it is characterised in that the rust remover
Contain following components:55-62wt% organic acids, 5-8wt% lecithin, 2-4wt% aminosals, surplus are water.
3. it is used for the natural environmental-protective Deruster for metal of automation equipment as claimed in claim 1, it is characterised in that described organic
Acid is citric acid or lactic acid.
4. it is used for the natural environmental-protective Deruster for metal of automation equipment as claimed in claim 1, it is characterised in that the hydrolysis
Protein is the hydrolysate of human body or animal hair.
5. the natural environmental-protective Deruster for metal for automation equipment as described in claim 1 or 4, it is characterised in that described
The preparation method of aminosal is:After hair is carried out into broken pretreatment, add papain and water, and adjust pH value to
6-8, filtered after digesting 2.5-4h through anion exchange resin, obtain aminosal.
6. the natural environmental-protective Deruster for metal for automation equipment as described in claim 1 or 4, it is characterised in that described
Aminosal is the waste liquid after human body or animal hair hydrolysis extraction cystine.
Priority Applications (1)
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CN201710899372.6A CN107653456A (en) | 2017-09-28 | 2017-09-28 | A kind of natural environmental-protective Deruster for metal for automation equipment |
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CN201710899372.6A CN107653456A (en) | 2017-09-28 | 2017-09-28 | A kind of natural environmental-protective Deruster for metal for automation equipment |
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CN201710899372.6A Pending CN107653456A (en) | 2017-09-28 | 2017-09-28 | A kind of natural environmental-protective Deruster for metal for automation equipment |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3253815B2 (en) * | 1994-10-19 | 2002-02-04 | 日本パーオキサイド株式会社 | Cleaning method for stainless steel equipment and cleaning agent |
CN1804125A (en) * | 2006-01-19 | 2006-07-19 | 重庆大学 | Metal pickling inhibitor and method for preparing the same |
CN101389229A (en) * | 2006-01-04 | 2009-03-18 | 利品乐食品公司 | Protein hydrolysates and method of making |
CN105970234A (en) * | 2016-06-21 | 2016-09-28 | 上海机动车检测中心 | Reagent for cleaning black metal fracture |
-
2017
- 2017-09-28 CN CN201710899372.6A patent/CN107653456A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3253815B2 (en) * | 1994-10-19 | 2002-02-04 | 日本パーオキサイド株式会社 | Cleaning method for stainless steel equipment and cleaning agent |
CN101389229A (en) * | 2006-01-04 | 2009-03-18 | 利品乐食品公司 | Protein hydrolysates and method of making |
CN1804125A (en) * | 2006-01-19 | 2006-07-19 | 重庆大学 | Metal pickling inhibitor and method for preparing the same |
CN105970234A (en) * | 2016-06-21 | 2016-09-28 | 上海机动车检测中心 | Reagent for cleaning black metal fracture |
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Application publication date: 20180202 |