CN107652883A - A kind of mat glass coating being used for instead of hydrofluoric acid etch effect - Google Patents

A kind of mat glass coating being used for instead of hydrofluoric acid etch effect Download PDF

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Publication number
CN107652883A
CN107652883A CN201610583001.2A CN201610583001A CN107652883A CN 107652883 A CN107652883 A CN 107652883A CN 201610583001 A CN201610583001 A CN 201610583001A CN 107652883 A CN107652883 A CN 107652883A
Authority
CN
China
Prior art keywords
glass coating
poly
hydrofluoric acid
instead
acid etch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610583001.2A
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Chinese (zh)
Inventor
张崇明
刘子元
刘培东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Xinlihua Color Material Co Ltd
Original Assignee
Tianjin Xinlihua Color Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Xinlihua Color Material Co Ltd filed Critical Tianjin Xinlihua Color Material Co Ltd
Priority to CN201610583001.2A priority Critical patent/CN107652883A/en
Publication of CN107652883A publication Critical patent/CN107652883A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of mat glass coating for being used to replace hydrofluoric acid etch effect, the percentage by weight of the glass coating is：Organic siliconresin 45 60%, poly(tributoxy titanium) 0.2 0.6%, aluminium acetylacetonate 0.3 0.6%, hollow glass micropearl 5 10%, quartz sand 8 15%, Tissuemat E 1 3%, nanometer silicon dioxide particle 0.2 1.0%, polyamide wax 0.5 1.5%, butyl acetate 15 25% and mixing divalence dimethyl phthalate 10 15%.The present invention, which is sprayed on simple glass to dry by 180 DEG C of 10min, is achieved with acid etching effect, and effect is good, and rapidly and efficiently, film is uniform and complete, and adhesive force is strong, and hardness is high, has good promotional value.

Description

A kind of mat glass coating being used for instead of hydrofluoric acid etch effect
【Technical field】
It is more particularly to a kind of to be used to apply instead of the mat glass of hydrofluoric acid etch effect the present invention relates to a kind of mat glass coating Material.
【Background technology】
Glass coating is one kind of coating, and the usual unusual light of glass surface, common coating is difficult to adhere in glass surface, good Glass coating stable and hard paint film, the spy that high transparency, high glaze can be shown in appearance are formed in glass surface Point, at present, the most glass coating film uniformity of in the market are poor, poor adhesive force, and hardness is low.Therefore, it is proposed that a kind of use In the mat glass coating for replacing hydrofluoric acid etch effect.
【The content of the invention】
It is a primary object of the present invention to provide a kind of mat glass coating being used for instead of hydrofluoric acid etch effect, it is sprayed on common Dried on glass by 180 DEG C of 10min and be achieved with acid etching effect, effect is good, and rapidly and efficiently, film is uniform and complete, attached Put forth effort by force, hardness is high, has good promotional value, effectively can solve the problems, such as in background technology.
To achieve the above object, the technical scheme taken of the present invention is：
A kind of mat glass coating for being used to replace hydrofluoric acid etch effect, the percentage by weight of the glass coating are：
Organic siliconresin 45-60%, poly(tributoxy titanium) 0.2-0.6%, aluminium acetylacetonate 0.3-0.6%, hollow glass micropearl 5-10%, Quartz sand 8-15%, Tissuemat E 1-3%, nanometer silicon dioxide particle 0.2-1.0%, polyamide wax 0.5-1.5%, butyl acetate 15-25% and mixing divalence dimethyl phthalate 10-15%.
Further, the percentage by weight of the glass coating is：
Organic siliconresin 45%, poly(tributoxy titanium) 0.2%, aluminium acetylacetonate 0.3%, hollow glass micropearl 5%, quartz sand 8%, poly- second Alkene wax 1%, nanometer silicon dioxide particle 0.2%, polyamide wax 0.5%, butyl acetate 15% and mixing divalence dimethyl phthalate 10%.
Further, the percentage by weight of the glass coating is：
It is organic siliconresin 60%, poly(tributoxy titanium) 0.6%, aluminium acetylacetonate 0.6%, hollow glass micropearl 10%, quartz sand 15%, poly- Ethylene waxes 3%, nanometer silicon dioxide particle 1.0%, polyamide wax 1.5%, butyl acetate 25% and mixing divalence dimethyl phthalate 15%.
Further, the percentage by weight of the glass coating is：
Organic siliconresin 52.5%, poly(tributoxy titanium) 0.4%, aluminium acetylacetonate 0.45%, hollow glass micropearl 7.5%, quartz sand 11.5%th, Tissuemat E 2%, nanometer silicon dioxide particle 0.6%, polyamide wax 1.0%, butyl acetate 20% and mixing divalent acid two Methyl esters 12.5%.
Further, the parts by weight of the organic siliconresin are：
45 parts of dimethyldimethoxysil,ne, 15 parts of phenyltrimethoxysila,e, 25 parts of trimethylolpropane and ethylene glycol ethyl ether 40 parts of acetate.
Compared with prior art, the present invention has the advantages that：It is sprayed on simple glass and is done by 180 DEG C of 10min Dry to be achieved with acid etching effect, effect is good, and rapidly and efficiently, film is uniform and complete, and adhesive force is strong, and hardness is high, has fine Promotional value.
【Embodiment】
To be easy to understand the technical means, the inventive features, the objects and the advantages of the present invention, with reference to specific Embodiment, the present invention is expanded on further.
Specific embodiment 1：
Organic siliconresin 45%, poly(tributoxy titanium) 0.2%, aluminium acetylacetonate 0.3%, hollow glass micropearl 5%, quartz sand 8%, poly- second Alkene wax 1%, nanometer silicon dioxide particle 0.2%, polyamide wax 0.5%, butyl acetate 15% and mixing divalence dimethyl phthalate 10%.
Specific embodiment 2：
It is organic siliconresin 60%, poly(tributoxy titanium) 0.6%, aluminium acetylacetonate 0.6%, hollow glass micropearl 10%, quartz sand 15%, poly- Ethylene waxes 3%, nanometer silicon dioxide particle 1.0%, polyamide wax 1.5%, butyl acetate 25% and mixing divalence dimethyl phthalate 15%.
Specific embodiment 3：
Organic siliconresin 52.5%, poly(tributoxy titanium) 0.4%, aluminium acetylacetonate 0.45%, hollow glass micropearl 7.5%, quartz sand 11.5%th, Tissuemat E 2%, nanometer silicon dioxide particle 0.6%, polyamide wax 1.0%, butyl acetate 20% and mixing divalent acid two Methyl esters 12.5%.
Specific embodiment 4：
45 parts of dimethyldimethoxysil,ne, 15 parts of phenyltrimethoxysila,e, 25 parts of trimethylolpropane and ethylene glycol ethyl ether 40 parts of acetate.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (5)

  1. A kind of 1. mat glass coating being used for instead of hydrofluoric acid etch effect, it is characterised in that：The weight of the glass coating Percentage is：
    Organic siliconresin 45-60%, poly(tributoxy titanium) 0.2-0.6%, aluminium acetylacetonate 0.3-0.6%, hollow glass micropearl 5-10%, Quartz sand 8-15%, Tissuemat E 1-3%, nanometer silicon dioxide particle 0.2-1.0%, polyamide wax 0.5-1.5%, butyl acetate 15-25% and mixing divalence dimethyl phthalate 10-15%.
  2. 2. the mat glass coating according to claim 1 being used for instead of hydrofluoric acid etch effect, it is characterised in that：It is described The percentage by weight of glass coating is：
    Organic siliconresin 45%, poly(tributoxy titanium) 0.2%, aluminium acetylacetonate 0.3%, hollow glass micropearl 5%, quartz sand 8%, poly- second Alkene wax 1%, nanometer silicon dioxide particle 0.2%, polyamide wax 0.5%, butyl acetate 15% and mixing divalence dimethyl phthalate 10%.
  3. 3. the mat glass coating according to claim 1 being used for instead of hydrofluoric acid etch effect, it is characterised in that：It is described The percentage by weight of glass coating is：
    It is organic siliconresin 60%, poly(tributoxy titanium) 0.6%, aluminium acetylacetonate 0.6%, hollow glass micropearl 10%, quartz sand 15%, poly- Ethylene waxes 3%, nanometer silicon dioxide particle 1.0%, polyamide wax 1.5%, butyl acetate 25% and mixing divalence dimethyl phthalate 15%.
  4. 4. the mat glass coating according to claim 1 being used for instead of hydrofluoric acid etch effect, it is characterised in that：It is described The percentage by weight of glass coating is：
    Organic siliconresin 52.5%, poly(tributoxy titanium) 0.4%, aluminium acetylacetonate 0.45%, hollow glass micropearl 7.5%, quartz sand 11.5%th, Tissuemat E 2%, nanometer silicon dioxide particle 0.6%, polyamide wax 1.0%, butyl acetate 20% and mixing divalent acid two Methyl esters 12.5%.
  5. 5. the mat glass coating according to claim 1 being used for instead of hydrofluoric acid etch effect, it is characterised in that：It is described The parts by weight of organic siliconresin are：
    45 parts of dimethyldimethoxysil,ne, 15 parts of phenyltrimethoxysila,e, 25 parts of trimethylolpropane and ethylene glycol ethyl ether 40 parts of acetate.
CN201610583001.2A 2016-07-23 2016-07-23 A kind of mat glass coating being used for instead of hydrofluoric acid etch effect Withdrawn CN107652883A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610583001.2A CN107652883A (en) 2016-07-23 2016-07-23 A kind of mat glass coating being used for instead of hydrofluoric acid etch effect

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610583001.2A CN107652883A (en) 2016-07-23 2016-07-23 A kind of mat glass coating being used for instead of hydrofluoric acid etch effect

Publications (1)

Publication Number Publication Date
CN107652883A true CN107652883A (en) 2018-02-02

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981209A (en) * 2019-12-26 2020-04-10 佛山晶美莱科技有限公司 Environment-friendly frosting powder

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105219260A (en) * 2015-11-05 2016-01-06 单华俊 Double-layer polyester modified organic silicon tangerine line coating and its production and use
CN105885592A (en) * 2016-06-27 2016-08-24 安徽省思维新型建材有限公司 Relief coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105219260A (en) * 2015-11-05 2016-01-06 单华俊 Double-layer polyester modified organic silicon tangerine line coating and its production and use
CN105885592A (en) * 2016-06-27 2016-08-24 安徽省思维新型建材有限公司 Relief coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981209A (en) * 2019-12-26 2020-04-10 佛山晶美莱科技有限公司 Environment-friendly frosting powder

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Application publication date: 20180202