CN106010146A - Polishing-free UV (Ultraviolet) priming paint - Google Patents
Polishing-free UV (Ultraviolet) priming paint Download PDFInfo
- Publication number
- CN106010146A CN106010146A CN201610511086.3A CN201610511086A CN106010146A CN 106010146 A CN106010146 A CN 106010146A CN 201610511086 A CN201610511086 A CN 201610511086A CN 106010146 A CN106010146 A CN 106010146A
- Authority
- CN
- China
- Prior art keywords
- priming paint
- exempt
- polish
- levelling agent
- polishing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides polishing-free UV (Ultraviolet) priming paint. The polishing-free UV priming paint is prepared from the following raw materials in percentage by weight: 40.9 to 61.4 percent of epoxy acrylic resin, 25 to 40 percent of active monomer, 2 to 4 percent of initiating agent, 0.1 to 0.5 percent of flatting agent, 0.1 to 0.5 percent of dispersing agent, 0.1 to 0.5 percent of anti-settling agent, 5.1 to 30.7 percent of filler and 0.1 to 0.5 percent of anti-foaming agent. After the polishing-free UV priming paint provided by the invention is used to coat a base material, finish paint can be directly sprayed without polishing, the surface effect of the finish paint is the same as the polished plane effect, and the adhesive force of the priming paint and the finish paint is very good.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to one and exempt from UV priming paint of polishing.
Background technology
UV photocuring technology is to utilize light trigger under ultraviolet light irradiates, and causes unsaturated organic monomers to carry out
Be polymerized, be grafted, the chemical reaction such as crosslinking thus reach a kind of emerging technology solidified rapidly.With tradition thermosetting
The coating that change or other method are made is compared, and UV photocureable coating is suitable for heat-sensitive substrate material, has film forming simultaneously
The plurality of advantages such as speed is fast, capacity usage ratio is high, coating property is excellent and pollution-free.Because its efficient application is solid
Change and eco-friendly feature, be widely used in the application of the multiple base materials such as timber, metal, plastics.
UV coating range the most on the market is narrower, is particularly used in some hard, low-surface-energies
Base material on adhesive ability poor, need to set up operation, thus reduce work efficiency.Existing UV priming paint
After base material primer coating solidify, need abrasive band to the cured density board sanding surface having white primer,
Spraying second base oil or finish paint the most again, such as China Patent Publication No. CN103694862 A uses exactly
The method.If the priming paint of CN103694862 A is not polished, the most directly it is coated with finish paint, it may appear that
Problems with: 1, film coated surface effect out-of-flatness, sense organ is bad, does not has and is coated with the function that light beautifies；2、
Priming paint is bad with the attachment in finish paint face.
Summary of the invention
For solving the poor adhesive force of existing UV priming paint and needing the problem of polishing operation, the present invention proposes one
Plant and exempt from UV priming paint of polishing, after this UV priming paint is coated with above cloth base material, it is not necessary to polishing just energy direct spraying finish paint,
And finish paint surface effect is such as the plane effect of polishing, and priming paint is also very good with the adhesive force of finish paint.
The technical scheme is that and be achieved in that:
One exempts from UV priming paint of polishing, and calculates according to percetage by weight, makes including following raw material:
Epoxy acrylic resin 40.9～61.4%, activated monomer 25～40%, initiator 2～4%, levelling
Agent 0.1～0.5%, dispersant 0.1～0.5%, anti-settling agent 0.1～0.5%, filler 5.1～30.7%, disappear
Infusion 0.1～0.5%.
Further, described activated monomer is acrylic monomers or acrylic acid derivative monomer, preferably 3 third
Glycols diacrylate.
Further, described initiator is alpha-alcohol ketone derivant and the one or two kinds of in acylphosphine oxide.
Further, described initiator is 1-hydroxy-cyciohexyl phenyl ketone (2,4,6-trimethylbenzene first double with phenyl
Acyl group) one or two kinds of in phosphine oxide.
Further, described levelling agent is organosilicon series levelling agent, preferably polyester modification polysiloxane
Levelling agent or polyether-modified polysiloxane levelling agent.
Further, described dispersant is polyacrylate dispersant.
Further, described anti-settling agent is aerosil or organobentonite.
Further, described defoamer is polyacrylate defoamer or acrylic acid defoamer, described filler
For Pulvis Talci or titanium dioxide.
The preparation method of the UV priming paint of the present invention is: carried out by above-mentioned raw materials simple in room temperature light protected environment
Mixing and stirring.
Beneficial effects of the present invention:
1, the UV priming paint of the present invention carries out screening discovery by great many of experiments to various raw materials, and gained priming paint is coated with
After cloth is on base material, it is not necessary to polishing, i.e. can reach finish paint surface effect such as the plane effect of polishing, the end
Paint also very good with the adhesive force of finish paint.
2, the present invention effectively controls UV priming paint under wider photo curing condition, causes top layer solidification not exclusively,
And deep cure is complete, plane effect is the best simultaneously.
Detailed description of the invention
Embodiment 1
One exempts from UV priming paint of polishing, and calculates according to percetage by weight, makes including following raw material:
Epoxy acrylic resin 40.9%, tripropylene glycol class diacrylate 27.1%, 1-hydroxy-cyciohexyl benzene
Base ketone 2%, double (2,4, the 6-trimethylbenzoyl) phosphine oxide 2% of phenyl, polyether-modified polysiloxane
Levelling agent 0.25%, polyacrylate dispersant 0.25%, aerosil 0.25%, Pulvis Talci
27%, polyacrylate defoamer 0.25%.
Preparation method: above-mentioned raw materials is carried out in room temperature light protected environment simple mixing and stirring.
Embodiment 2
Epoxy acrylic resin 57%, acrylic monomers 25%, 1-hydroxy-cyciohexyl phenyl ketone 3.1%,
Polyester modification polysiloxane levelling agent 0.1%, polyacrylate dispersant 0.5%, organobentonite
0.1%, titanium dioxide 13.7%, acrylic acid defoamer 0.5%.
Preparation method: above-mentioned raw materials is carried out in room temperature light protected environment simple mixing and stirring.
Embodiment 3
Epoxy acrylic resin 40.7%, tripropylene glycol class diacrylate 40%, double (2,4, the 6-front threes of phenyl
Base benzoyl) phosphine oxide 3.3%, polyether-modified polysiloxane levelling agent 0.5%, polyacrylate divides
Powder 0.1%, aerosil 0.5%, Pulvis Talci 14.8%, polyacrylate defoamer 0.1%.
Preparation method: above-mentioned raw materials is carried out in room temperature light protected environment simple mixing and stirring.
Embodiment 4
UV priming paint embodiment 1-3 prepared is as test group, and common UV priming paint
(CN103694862 A) as a control group, is respectively coated on base material, and test group is not polished, right
Polish according to group, on priming paint, be then all coated with finish paint, cross cut test after solidification, and use 3M adhesive tape
Stickup is pullled, and test group and matched group are all without pull-away situation occurs.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all at this
Within bright spirit and principle, any modification, equivalent substitution and improvement etc. made, should be included in this
Within bright protection domain.
Claims (10)
1. exempt from UV priming paint of polishing for one kind, it is characterised in that calculate according to percetage by weight, including following former
Material is made:
Epoxy acrylic resin 40.9～61.4%, activated monomer 25～40%, initiator 2～4%, levelling
Agent 0.1～0.5%, dispersant 0.1～0.5%, anti-settling agent 0.1～0.5%, filler 5.1～30.7%, disappear
Infusion 0.1～0.5%.
The most according to claim 1 exempt from polish UV priming paint, it is characterised in that described activated monomer is
Acrylic monomers or acrylic acid derivative monomer.
The most according to claim 2 exempt from polish UV priming paint, it is characterised in that described activated monomer is
Tripropylene glycol class diacrylate.
The most according to claim 1 exempt from polish UV priming paint, it is characterised in that described initiator is α
-hydroxy-ketone derivant and the one or two kinds of in acylphosphine oxide.
The most according to claim 4 exempt from polish UV priming paint, it is characterised in that described initiator is 1-
One or two in hydroxy-cyciohexyl phenyl ketone (2,4,6-trimethylbenzoyl) phosphine oxide double with phenyl
Kind.
The most according to claim 1 exempt from polish UV priming paint, it is characterised in that described levelling agent is for having
Machine silicon series levelling agent.
The most according to claim 6 exempt from polish UV priming paint, it is characterised in that described levelling agent is poly-
Ester modified polysiloxane levelling agent or polyether-modified polysiloxane levelling agent.
The most according to claim 1 exempt from polish UV priming paint, it is characterised in that described dispersant is poly-
Acrylate dispersant.
The most according to claim 1 exempt from polish UV priming paint, it is characterised in that described anti-settling agent is gas
Aerosil or organobentonite.
The most according to claim 1 exempt from polish UV priming paint, it is characterised in that described defoamer is
Polyacrylate defoamer or acrylic acid defoamer, described filler is Pulvis Talci or titanium dioxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610511086.3A CN106010146A (en) | 2016-06-30 | 2016-06-30 | Polishing-free UV (Ultraviolet) priming paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610511086.3A CN106010146A (en) | 2016-06-30 | 2016-06-30 | Polishing-free UV (Ultraviolet) priming paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106010146A true CN106010146A (en) | 2016-10-12 |
Family
ID=57106119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610511086.3A Pending CN106010146A (en) | 2016-06-30 | 2016-06-30 | Polishing-free UV (Ultraviolet) priming paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106010146A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107858092A (en) * | 2017-11-02 | 2018-03-30 | 朱先涛 | One kind exempts from UV cold coatings of polishing |
| CN107987684A (en) * | 2017-11-16 | 2018-05-04 | 君子兰化工（上海）有限公司 | Can not sanding recoating woodenware with high attachment UV environment-friendly spray coating based white primers |
| CN108948815A (en) * | 2018-06-27 | 2018-12-07 | 淮北百壹领域建筑科技有限公司 | A kind of plastics solidification priming paint |
| CN109651936A (en) * | 2019-01-07 | 2019-04-19 | 浙江恒峰家居有限公司 | A kind of high osmosis UV priming paint for furniture |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161862A (en) * | 2011-02-25 | 2011-08-24 | 上海长润发涂料有限公司 | Ultraviolet (UV) light-curable polyurethane acrylic resin composite |
| CN102277069A (en) * | 2011-09-05 | 2011-12-14 | 江苏海田技术有限公司 | Ultraviolet (UV) and high leveling sanding priming paint |
-
2016
- 2016-06-30 CN CN201610511086.3A patent/CN106010146A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161862A (en) * | 2011-02-25 | 2011-08-24 | 上海长润发涂料有限公司 | Ultraviolet (UV) light-curable polyurethane acrylic resin composite |
| CN102277069A (en) * | 2011-09-05 | 2011-12-14 | 江苏海田技术有限公司 | Ultraviolet (UV) and high leveling sanding priming paint |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107858092A (en) * | 2017-11-02 | 2018-03-30 | 朱先涛 | One kind exempts from UV cold coatings of polishing |
| CN107987684A (en) * | 2017-11-16 | 2018-05-04 | 君子兰化工（上海）有限公司 | Can not sanding recoating woodenware with high attachment UV environment-friendly spray coating based white primers |
| CN108948815A (en) * | 2018-06-27 | 2018-12-07 | 淮北百壹领域建筑科技有限公司 | A kind of plastics solidification priming paint |
| CN109651936A (en) * | 2019-01-07 | 2019-04-19 | 浙江恒峰家居有限公司 | A kind of high osmosis UV priming paint for furniture |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |
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| RJ01 | Rejection of invention patent application after publication |