CN107652773A - A kind of high adhesion force environmental printing ink - Google Patents

A kind of high adhesion force environmental printing ink Download PDF

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Publication number
CN107652773A
CN107652773A CN201711102560.8A CN201711102560A CN107652773A CN 107652773 A CN107652773 A CN 107652773A CN 201711102560 A CN201711102560 A CN 201711102560A CN 107652773 A CN107652773 A CN 107652773A
Authority
CN
China
Prior art keywords
parts
printing ink
adhesion force
high adhesion
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711102560.8A
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Chinese (zh)
Inventor
黄健俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201711102560.8A priority Critical patent/CN107652773A/en
Publication of CN107652773A publication Critical patent/CN107652773A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of high adhesion force environmental printing ink, comprising 0.2 3 parts of 37 parts of 8 12 parts of 9 16 parts of 10 15 parts of acrylic resin, phenolic resin, Lauxite, polyurethane resin liquid, graphene in parts by weight, 8 18 parts of oleic acid esters, 10 20 parts of isopropanol, 6 10 parts of AEO, 6~10 carbon 3 18 parts of 13 parts of 20 2 parts of fatty acid ester, bleeding agent, pigment.The present patent application is formulated brief environmental protection, in performance but also no less than high performance pigments on the market, especially adhesive force and lasting colour retention in terms of, therefore there is very high promotional value.

Description

A kind of high adhesion force environmental printing ink
Technical field
The present invention relates to printing-ink field, more particularly to a kind of high adhesion force environmental printing ink.
Background technology
Ink is one of very crucial factor for ensureing printing quality.The existing ink for being used to print always has various The problem of：Some ink contains benzene, ketones derivant, and environmental pollution is larger；Some ink adaptability is poor, for different Paper adhesive force cannot be guaranteed, or total adhesive force is not strong enough；Some ink combination properties are good, but composition toxicity is too big, to print Dataller people has chronic body harm.
For problem above, between feature of environmental protection raw material and performance always there is certain contradiction, and for the sector and Speech, breaks this contradiction and is particularly important.
The content of the invention
It is an object of the invention to provide a kind of high adhesion force environmental printing ink, adhesive force, and materials are effectively improved Environmental protection, degradable, pigment is also environmentally friendly composition, overcomes problems of the prior art.
In order to realize the above object the technical scheme is that：
A kind of high adhesion force environmental printing ink, include the component of following parts by weight：
Acrylic resin 10-15 parts
Phenolic resin 9-16 parts
Lauxite 8-12 parts
Polyurethane resin liquid 3-7 parts
Graphene 0.2-3 parts
Oleic acid esters 8-18 parts
Isopropanol 10-20 parts
AEO 6-10 parts
Fatty acid ester 20-32 parts of 6~10 carbon
Pigment 3-18 parts.
Preferably, the fatty acid ester of 6~10 carbon is the esterification of acetic acid, propionic acid, butyric acid and butanol, amylalcohol, hexanol Reaction product.
Further, the butanol, amylalcohol, hexanol are the correspondent alcohol that molecular structure contains side chain.
Preferably, the oleic acid esters are the alcohol acid anhydride of carbon number 10~14 and the monoesters compound of oleic acid.
Preferably, the pigment is carbon black, titanium dioxide, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, iron oxide red In one kind or its combination.
The beneficial effects of the present invention are：Inventive formulation environmental protection, prints good combination property.Alcohols, fatty acid ester, oleic acid Esters and various types of resins are environmentally friendly for the ink formulations of main body, without noxious materials such as phenyl ring, ketones；Graphene is to strengthening absorption affinity With special efficacy, attachment and lasting unfading are greatly enhanced；Pigment is also environmental protection, and black, white, blue, green, red cooperation can expire The requirement of the most of print colors of foot.The present patent application is formulated brief environmental protection, in performance but also no less than on the market In terms of high performance pigments, especially adhesive force and lasting colour retention, therefore there is very high promotional value.
Embodiment
In order to illustrate more clearly of the embodiment of the present application or technical scheme of the prior art, letter will be made to embodiment below Singly introduce.
Embodiment 1
A kind of high adhesion force environmental printing ink, include the component of following parts by weight：
10 parts of acrylic resin
16 parts of phenolic resin
12 parts of Lauxite
7 parts of polyurethane resin liquid
0.2 part of graphene
8 parts of oleic acid esters
10 parts of isopropanol
10 parts of AEO
20 parts of the fatty acid ester of 6~10 carbon
3 parts of pigment；
The fatty acid ester of 6~10 carbon is isoamyl acetate；The oleic acid esters are the alcohol acid anhydride and oil of carbon number 12 The monoesters compound of acid；The pigment is in carbon black, titanium dioxide, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, iron oxide red A kind of or its combination.
Experiment：The ink prepared is put into container, with 20J/cm2,480~1200nm of wavelength light irradiation 120min, it is then placed in dark surrounds 120min.Result of the test attachment fastness 98.6%.
Embodiment 2
A kind of high adhesion force environmental printing ink, include the component of following parts by weight：
15 parts of acrylic resin
11 parts of phenolic resin
9 parts of Lauxite
3 parts of polyurethane resin liquid
3 parts of graphene
18 parts of oleic acid esters
20 parts of isopropanol
8 parts of AEO
32 parts of the fatty acid ester of 6~10 carbon
18 parts of pigment；
The fatty acid ester of 6~10 carbon is butyric acid dissident's ester；The oleic acid esters are the alcohol acid anhydride and oil of carbon number 10 The monoesters compound of acid；The pigment is in carbon black, titanium dioxide, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, iron oxide red A kind of or its combination.
Experiment：The ink prepared is put into container, with 20J/cm2,480~1200nm of wavelength light irradiation 120min, it is then placed in dark surrounds 120min.Result of the test attachment fastness 97.2%.
Embodiment 3
A kind of high adhesion force environmental printing ink, include the component of following parts by weight：
12 parts of acrylic resin
9 parts of phenolic resin
8 parts of Lauxite
5 parts of polyurethane resin liquid
1.1 parts of graphene
16 parts of oleic acid esters
15 parts of isopropanol
6 parts of AEO
29 parts of the fatty acid ester of 6~10 carbon
9 parts of pigment；
The fatty acid ester of 6~10 carbon is isobutyl propionate；The oleic acid esters are the alcohol acid anhydride and oil of carbon number 14 The monoesters compound of acid；The pigment is in carbon black, titanium dioxide, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, iron oxide red A kind of or its combination.
Experiment：The ink prepared is put into container, with 20J/cm2,480~1200nm of wavelength light irradiation 120min, it is then placed in dark surrounds 120min.Result of the test attachment fastness 99.1%.
Above example is only illustrating the preferred technical solution of the present invention, it is noted that for the general of the art For logical technical staff, under the premise without departing from the principles of the invention, some improvement made or equivalent substitution, this is accordingly to be regarded as The protection domain of invention, it should cover in scope of the presently claimed invention.

Claims (4)

1. a kind of high adhesion force environmental printing ink, it is characterised in that include the component of following parts by weight：
Acrylic resin 10-15 parts
Phenolic resin 9-16 parts
Lauxite 8-12 parts
Polyurethane resin liquid 3-7 parts
Graphene 0.2-3 parts
Oleic acid esters 8-18 parts
Isopropanol 10-20 parts
AEO 6-10 parts
Fatty acid ester 20-32 parts of 6~10 carbon
Bleeding agent 1-3 parts
Pigment 3-18 parts.
A kind of 2. high adhesion force environmental printing ink according to claim 1, it is characterised in that the fat of 6~10 carbon Fat acid esters is acetic acid, propionic acid, butyric acid and butanol, amylalcohol, the esterification reaction product of hexanol.
A kind of 3. high adhesion force environmental printing ink according to claim 2, it is characterised in that the butanol, amylalcohol, oneself Alcohol is the correspondent alcohol that molecular structure contains side chain.
4. a kind of high adhesion force environmental printing ink according to claim 1, it is characterised in that the oleic acid esters are carbon The alcohol acid anhydride of atomicity 10~14 and the monoesters compound of oleic acid.
CN201711102560.8A 2017-11-07 2017-11-07 A kind of high adhesion force environmental printing ink Withdrawn CN107652773A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711102560.8A CN107652773A (en) 2017-11-07 2017-11-07 A kind of high adhesion force environmental printing ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711102560.8A CN107652773A (en) 2017-11-07 2017-11-07 A kind of high adhesion force environmental printing ink

Publications (1)

Publication Number Publication Date
CN107652773A true CN107652773A (en) 2018-02-02

Family

ID=61121293

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711102560.8A Withdrawn CN107652773A (en) 2017-11-07 2017-11-07 A kind of high adhesion force environmental printing ink

Country Status (1)

Country Link
CN (1) CN107652773A (en)

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WW01 Invention patent application withdrawn after publication
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Application publication date: 20180202