CN107641485A - Heat foamable glue and preparation method thereof - Google Patents

Heat foamable glue and preparation method thereof Download PDF

Info

Publication number
CN107641485A
CN107641485A CN201610579298.5A CN201610579298A CN107641485A CN 107641485 A CN107641485 A CN 107641485A CN 201610579298 A CN201610579298 A CN 201610579298A CN 107641485 A CN107641485 A CN 107641485A
Authority
CN
China
Prior art keywords
heat
expandable microsphere
temperature
glue
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610579298.5A
Other languages
Chinese (zh)
Inventor
何俊
李国烜
王薇
肖剑
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XINFENG JIELI ELECTRICAL MATERIAL CO Ltd
Original Assignee
XINFENG JIELI ELECTRICAL MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XINFENG JIELI ELECTRICAL MATERIAL CO Ltd filed Critical XINFENG JIELI ELECTRICAL MATERIAL CO Ltd
Priority to CN201610579298.5A priority Critical patent/CN107641485A/en
Publication of CN107641485A publication Critical patent/CN107641485A/en
Pending legal-status Critical Current

Links

Landscapes

  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention provides a kind of heat foamable glue and preparation method thereof.The heat foamable glue includes the first heat-expandable microsphere and the second heat-expandable microsphere;The particle diameter of first heat-expandable microsphere is 10~30 μm, and the initial temperature of its expansion is 70~100 DEG C;The particle diameter of second heat-expandable microsphere is 8~25 μm, and the initial temperature of its foaming is 90~120 DEG C.Two kinds of different heat-expandable microspheres of blowing temperature are mixed obtained heat foamable glue by the heat foamable glue of the present invention, to heat sensitive adhesive tape foaming when, heat sensitive adhesive tape can not only pass through the expansion Automatic-falling of heat foamable glue, also controllable different temperatures section is foamed simultaneously, and meets different foaming effects.The degree and process that control heat sensitive adhesive tape is peeled off by substrate.

Description

Heat foamable glue and preparation method thereof
Technical field
The present invention relates to the technical field of lithium ion battery, in particular to a kind of heat foamable glue and preparation method thereof.
Background technology
Lithium ion battery has high operating voltage, energy density big (in light weight), long circulation life, memory-less effect and nothing The advantages that pollution, there is safe and reliable and energy fast charging and discharging again, turn into main force's power supply of each electronic product.By It is the free of contamination secondary cell of environmental type in lithium ion battery, meeting the big development of countries nowadays energy environment protection aspect needs Ask, increased sharply in the usage amount of all trades and professions.At present secondary lithium battery except be widely used in it is daily known to mobile phone, Outside the digital electronic goods such as notebook computer and MP3, in recent years in terms of some high power batteries such as electric car, electric bicycle Also have begun to use.
At present in lithium ion battery electrode using continuity coating production negative electrode and anode, coating be lithium ion battery just Key link in the making of pole, good positive electrode have a direct impact to performances such as battery capacities.So-called coating just refers to pasty state Polymer, molten polymer or polymer solution are coated on the method that composite membrane is made on film, for lithium ion battery Speech, coated substrate (film) is metal foil, generally copper foil or aluminium foil.
Coating process will be put into coating machine (being referred to as unreeling) from substrate and out (claim from coating machine to the substrate after coating To unreel) some series-operations and use laser cleaning localizing electrode surface after being coated with, to facilitate and tab welding. But because in laser cleaning, aluminium foil or copper foil surface have high-temperature oxydation, cause aluminium foil or copper foil performance to reduce, because This, this method reduce unit capacity after the service life of lithium ion battery.
Involved foamed glue band is made primarily directed to semiconductor, multi-layer ceramics pad and other minor items at present Interim fixation in technique.For the sector application characteristic:It is required that at a certain temperature, it can foam and come off, separate well Small electronic product.Therefore, its foamed glue being related to band emphasis is entered for starting blowing temperature or optimal foaming temperature Professional etiquette is determined, and in foaming process, usually single temperature range, is seldom related to carrying out in different temperatures range intervals Foaming, which is peeled off, to be required, so, the heat-expandable microsphere added is generally single microballoon, even or more foam microspheres mixing Use, its temperature range is also essentially identical.
As in patent ZL 201110404492.7 different foam microspheres are carried out with related definition, but defined expansion is micro- Ball is substantially left at 130 degree in the specific identical starting blowing temperature in same temperature section and optimal foaming temperature, its optimum temperature It is right.There is also such in same patent JP-A-2002-003800, JP-A-2002-121505 or JP-A-2004-018761 Problem:Its blowing temperature is substantially single temperature range.Or the initial expansion temperature section base of different mixing expandable microspheres This is overlapping.
In addition, also few correlations are reported for work application of the foamed glue band in lithium ion battery industry at present, more without reference to To specific formula and multistage blowing temperature section.
The content of the invention
In view of this, the invention provides a kind of heat foamable glue, including the first heat-expandable microsphere and the second thermal expansivity Microballoon;The particle diameter of first heat-expandable microsphere is 10~30 μm, and the initial temperature of its expansion is 70~100 DEG C;It is described The particle diameter of second heat-expandable microsphere is 8~25 μm, and the initial temperature of its foaming is 90~120 DEG C.
In some embodiments, the maximum swelling temperature of first heat-expandable microsphere is 105~140 DEG C;It is described The maximum swelling temperature of second heat-expandable microsphere is 125~155 DEG C.
In some embodiments, the mass ratio of first heat-expandable microsphere and second heat-expandable microsphere For 1:8~1:2.
Present invention also offers a kind of preparation method of heat foamable glue, including:
S10:First heat-expandable microsphere and the second heat-expandable microsphere are filtered out by particle size analyzer;First heat The particle diameter of dilatancy microballoon is 10~30 μm;The particle diameter of second heat-expandable microsphere is 8~25 μm;
S20:The first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere are mixed, stirred obtained Mix microballoon;
S30:It is well mixed microballoon is mixed made from step S20 with acrylate pressure-sensitive adhesive.
In some embodiments, the initial temperature of the expansion of first heat-expandable microsphere is 70~100 DEG C.
In some embodiments, the initial temperature of the expansion of second heat-expandable microsphere is 90~120 DEG C.
In some embodiments, the maximum swelling temperature of first heat-expandable microsphere is 105~140 DEG C.
In some embodiments, the maximum swelling temperature of second heat-expandable microsphere is 125~155 DEG C.
In some embodiments, the mass ratio of first heat-expandable microsphere and second heat-expandable microsphere For 1:8~1:2.
In some embodiments, microballoon is mixed in the step S30 with acrylate pressure-sensitive adhesive using mass ratio as 1:6~ 1:1 is well mixed.
The advantages of heat foamable glue provided by the invention and preparation method thereof, is:
For in lithium ion battery industry using heat sensitive adhesive tape main purpose be in order to guard electrode be coated with continuity it is poly- During compound slurry, protect substrate so that substrate without laser cleaning can direct soldering polar ear, avoid substrate swash During light cleans, because temperature is too high and oxidized, the phenomenon that causes the performance of substrate to reduce.Therefore, except requiring:It is full Outside the certain starting blowing temperature of foot and maximum swelling temperature, it is necessary to mobility, baking with reference to the polymer paste of coating Need to the association outside heat sensitive adhesive tape protection zone while also to combine actual operation during technique and foaming and intumescing.
It is understood that when rear end (using coating sizing-agent drying as node) foams, easily occur and heat sensitive adhesive tape surface The polymer paste thickness increase in the region that surrounding is connected, while groove shape also be present.Equally, in front end foaming, easily go out The lug bonding pad of existing polymer paste pollution heat sensitive adhesive tape protection, and in heat sensitive adhesive tape foaming process, because curling easily goes out Now glue the polymer paste of the lug bonding pad of the non-thermal sensitive tape protection of damage.
Two kinds of different heat-expandable microspheres of blowing temperature are mixed obtained heat hair by the heat foamable glue of the present invention Steep glue, to heat sensitive adhesive tape foaming when, heat sensitive adhesive tape not only can be by the expansion Automatic-falling of heat foamable glue, while may be used also The different temperatures section of control is foamed, and meets different foaming effects.The degree and enter that control heat sensitive adhesive tape is peeled off by substrate Journey.
In summary, the present invention has the advantages of above-mentioned many and practical value, and there are no in like product similar Method publish or use and really belong to innovation.It provide not only a kind of heat foamable glue and preparation method thereof.And the technique In the case of lower-cost, you can accurately find out the important parameter in the preparation technology of lithium battery.Greatly reduce lithium Financial cost in the production of battery.Moreover, the unit capacity of lithium ion battery can be improved effectively, lithium-ion electric is improved The service life in pond.
Brief description of the drawings
It should be appreciated that the following drawings illustrate only certain embodiments of the present invention, therefore it is not construed as to model The restriction enclosed, for those of ordinary skill in the art, on the premise of not paying creative work, can also be according to these Accompanying drawing obtains other related accompanying drawings.
Fig. 1 is the flow chart of the preparation method of the heat foamable glue of an embodiment of the present invention.
Embodiment
The claim of the present invention is described in further detail with reference to the mode of specific embodiment, following Many details are elaborated in description in order to fully understand the present invention.
But the invention can be embodied in many other ways as described herein, those skilled in the art can be with Similar improvement is done in the case of without prejudice to intension of the present invention, therefore the present invention is not limited to the specific embodiments disclosed below.
Referring to Fig. 1, the invention provides a kind of heat foamable glue, including the first heat-expandable microsphere and the second thermal expansivity it is micro- Ball;The particle diameter of first heat-expandable microsphere is 10~30 μm, and the initial temperature of its expansion is 70~100 DEG C;Described The particle diameter of two heat-expandable microspheres is 8~25 μm, and the initial temperature of its foaming is 90~120 DEG C.
Further, the maximum swelling temperature of first heat-expandable microsphere is 105~140 DEG C;Second heat is swollen The maximum swelling temperature of swollen property microballoon is 125~155 DEG C.
Further, the mass ratio of first heat-expandable microsphere and second heat-expandable microsphere is 1:8~ 1:2.
Present invention also offers a kind of preparation method of heat foamable glue, including:
S10:First heat-expandable microsphere and the second heat-expandable microsphere are filtered out by particle size analyzer;First heat The particle diameter of dilatancy microballoon is 10~30 μm;The particle diameter of second heat-expandable microsphere is 8~25 μm;
S20:The first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere are mixed, stirred obtained Mix microballoon;
S30:It is well mixed microballoon is mixed made from step S20 with acrylate pressure-sensitive adhesive.
Further, the initial temperature of the expansion of first heat-expandable microsphere is 70~100 DEG C.
Further, the initial temperature of the expansion of second heat-expandable microsphere is 90~120 DEG C.
Further, the maximum swelling temperature of first heat-expandable microsphere is 105~140 DEG C.
Further, the maximum swelling temperature of second heat-expandable microsphere is 125~155 DEG C.
Further, the mass ratio of first heat-expandable microsphere and second heat-expandable microsphere is 1:8~ 1:2.
Further, microballoon is mixed in the step S30 with acrylate pressure-sensitive adhesive using mass ratio as 1:6~1:1 mixing Uniformly.
It is above-mentioned, in lithium ion battery industry using heat sensitive adhesive tape main purpose be in order to guard electrode continuity apply During cloth polymer paste, protect substrate so that substrate without laser cleaning can direct soldering polar ear, avoid substrate During laser cleaning, because temperature is too high and oxidized, the phenomenon that causes the performance of substrate to reduce.Therefore, except wanting Ask:Meet outside certain starting blowing temperature and maximum swelling temperature, it is necessary to mobility with reference to the polymer paste of coating, Need to the association outside heat sensitive adhesive tape protection zone while also to combine actual operation during baking process and foaming and intumescing.
It is understood that when rear end (using coating sizing-agent drying as node) foams, easily occur and heat sensitive adhesive tape surface The polymer paste thickness increase in the region that surrounding is connected, while groove shape also be present.Equally, in front end foaming, easily go out The lug bonding pad of existing polymer paste pollution heat sensitive adhesive tape protection, and in heat sensitive adhesive tape foaming process, because curling easily goes out Now glue the polymer paste of the lug bonding pad of the non-thermal sensitive tape protection of damage.
Two kinds of different heat-expandable microspheres of blowing temperature are mixed obtained heat hair by the heat foamable glue of the present invention Steep glue, to heat sensitive adhesive tape foaming when, heat sensitive adhesive tape not only can be by the expansion Automatic-falling of heat foamable glue, while may be used also The different temperatures section of control is foamed, and meets different foaming effects.The degree and enter that control heat sensitive adhesive tape is peeled off by substrate Journey.
In summary, the present invention has the advantages of above-mentioned many and practical value, and there are no in like product similar Method publish or use and really belong to innovation.It provide not only a kind of heat foamable glue and preparation method thereof.And the technique In the case of lower-cost, you can accurately find out the important parameter in the preparation technology of lithium battery.Greatly reduce lithium Financial cost in the production of battery.Moreover, the unit capacity of lithium ion battery can be improved effectively, lithium-ion electric is improved The service life in pond.
It is to be appreciated that the preparation that the heat foamable glue can be not only used for lithium battery can be also used for other species batteries Preparation
For the ease of understanding the present invention, technical scheme is further illustrated with reference to embodiment.Applicant Statement, the present invention illustrate the detailed process equipment of the present invention and technological process, but not office of the invention by above-described embodiment It is limited to above-mentioned detailed process equipment and technological process, that is, does not mean that the present invention should rely on above-mentioned detailed process equipment and technique stream Cheng Caineng is implemented.Person of ordinary skill in the field is it will be clearly understood that any improvement in the present invention, to each original of product of the present invention The equivalence replacement of material and the addition of auxiliary element, the selection of concrete mode etc., all fall within protection scope of the present invention and open model Within enclosing.
Embodiment 1
Particle diameter is filtered out as 10 μm by particle size analyzer, the initial temperature of foaming is 70 DEG C, and maximum swelling temperature is 105 DEG C the first heat-expandable microsphere, and particle diameter is 8 μm, and the initial temperature of foaming is 90 DEG C, and maximum swelling temperature is 125 DEG C the Two heat-expandable microspheres;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:8 is mixed 1h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:6 well mixed mixing Uniformly.
Embodiment 2
Particle diameter is filtered out as 30 μm by particle size analyzer, the initial temperature of foaming is 100 DEG C, and maximum swelling temperature is 140 DEG C of the first heat-expandable microsphere, and particle diameter are 25 μm, and the initial temperature of foaming is 120 DEG C, and maximum swelling temperature is 155 DEG C of second heat-expandable microsphere;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:2 is mixed 10h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:3 well mixed mixing Uniformly.
Embodiment 3
Particle diameter is filtered out as 15 μm by particle size analyzer, the initial temperature of foaming is 80 DEG C, and maximum swelling temperature is 130 DEG C the first heat-expandable microsphere, and particle diameter is 15 μm, and the initial temperature of foaming is 100 DEG C, and maximum swelling temperature is 135 DEG C Second heat-expandable microsphere;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:4 is mixed 5h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:1 well mixed mixing Uniformly.
Embodiment 4
Particle diameter is filtered out as 20 μm by particle size analyzer, the initial temperature of foaming is 85 DEG C, and maximum swelling temperature is 115 DEG C the first heat-expandable microsphere, and particle diameter is 20 μm, and the initial temperature of foaming is 95 DEG C, and maximum swelling temperature is 140 DEG C Second heat-expandable microsphere;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:5 is mixed 6h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:2 well mixed mixing Uniformly.
Embodiment 5
Particle diameter is filtered out as 18 μm by particle size analyzer, the initial temperature of foaming is 77 DEG C, and maximum swelling temperature is 136 DEG C the first heat-expandable microsphere, and particle diameter is 12 μm, and the initial temperature of foaming is 95 DEG C, and maximum swelling temperature is 140 DEG C Second heat-expandable microsphere;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:3 is mixed 8h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:5 well mixed mixing Uniformly.
Embodiment 6
Particle diameter is filtered out as 12 μm by particle size analyzer, the initial temperature of foaming is 93 DEG C, and maximum swelling temperature is 124 DEG C the first heat-expandable microsphere, and particle diameter is 12 μm, and the initial temperature of foaming is 95 DEG C, and maximum swelling temperature is 140 DEG C Second heat-expandable microsphere;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:3 is mixed 8h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:4 well mixed mixing Uniformly.
Embodiment 7
Particle diameter is filtered out as 22 μm by particle size analyzer, the initial temperature of foaming is 82 DEG C, and maximum swelling temperature is 129 DEG C the first heat-expandable microsphere, and particle diameter is 22 μm, and the initial temperature of foaming is 104 DEG C, and maximum swelling temperature is 133 DEG C Second heat-expandable microsphere;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:4 is mixed 10h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:2 well mixed mixing Uniformly.
Embodiment 8
Particle diameter is filtered out as 14 μm by particle size analyzer, the initial temperature of foaming is 74 DEG C, and maximum swelling temperature is 132 DEG C the first heat-expandable microsphere, and particle diameter is 16 μm, and the initial temperature of foaming is 92 DEG C, and maximum swelling temperature is 137 DEG C Second heat-expandable microsphere;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:3 is mixed 3h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:6 well mixed mixing Uniformly.
Embodiment 9
Particle diameter is filtered out as 27 μm by particle size analyzer, the initial temperature of foaming is 90 DEG C, and maximum swelling temperature is 105 DEG C the first heat-expandable microsphere, and particle diameter is 9 μm, and the initial temperature of foaming is 118 DEG C, and maximum swelling temperature is 152 DEG C Second heat-expandable microsphere;
S20:It is 1 by the first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere example in mass ratio:8 is mixed 1h is stirred after conjunction, is stirred.
S30:Microballoon will be mixed made from step S20 with acrylate pressure-sensitive adhesive using mass ratio as 1:1 well mixed mixing Uniformly.
Applicant states that the present invention can only for of the invention by a series of describe in detail of those listed above Row embodiment illustrates, but the invention is not limited in above-mentioned detailed process equipment and technological process.And i.e. not Mean that the present invention should rely on above-mentioned detailed process equipment and technological process and could implement.Person of ordinary skill in the field should This is clear, any improvement in the present invention, and the equivalence replacement and auxiliary element to each raw material of product of the present invention are added, are specific square Selection of formula etc., within the scope of all falling within protection scope of the present invention and disclosing.

Claims (10)

1. heat foamable glue, it is characterised in that:Including the first heat-expandable microsphere and the second heat-expandable microsphere;First heat is swollen The particle diameter of swollen property microballoon is 10~30 μm, and the initial temperature of its expansion is 70~100 DEG C;Second heat-expandable microsphere Particle diameter is 8~25 μm, and the initial temperature of its foaming is 90~120 DEG C.
2. heat foamable glue as claimed in claim 1, it is characterised in that:The maximum swelling temperature of first heat-expandable microsphere For 105~140 DEG C;The maximum swelling temperature of second heat-expandable microsphere is 125~155 DEG C.
3. heat foamable glue as claimed in claim 1, it is characterised in that:First heat-expandable microsphere and second heat are swollen The mass ratio of swollen property microballoon is 1:8~1:2.
4. the preparation method of heat foamable glue as claimed in claim 1, it is characterised in that:Including:
S10:First heat-expandable microsphere and the second heat-expandable microsphere are filtered out by particle size analyzer;First thermal expansion Property microballoon particle diameter be 10~30 μm;The particle diameter of second heat-expandable microsphere is 8~25 μm;
S20:The first heat-expandable microsphere obtained in S10 and the second heat-expandable microsphere are mixed, stirs and mixing is made Microballoon;
S30:It is well mixed microballoon is mixed made from step S20 with acrylate pressure-sensitive adhesive.
5. the preparation method of heat foamable glue as claimed in claim 4, it is characterised in that:First heat-expandable microsphere it is swollen Swollen initial temperature is 70~100 DEG C.
6. the preparation method of heat foamable glue as claimed in claim 4, it is characterised in that:Second heat-expandable microsphere it is swollen Swollen initial temperature is 90~120 DEG C.
7. the preparation method of heat foamable glue as claimed in claim 4, it is characterised in that:First heat-expandable microsphere is most Big expansion temperature is 105~140 DEG C.
8. the preparation method of heat foamable glue as claimed in claim 4, it is characterised in that:Second heat-expandable microsphere is most Big expansion temperature is 125~155 DEG C.
9. the preparation method of heat foamable glue as claimed in claim 4, it is characterised in that:First heat-expandable microsphere and institute The mass ratio for stating the second heat-expandable microsphere is 1:8~1:2.
10. the preparation method of heat foamable glue as claimed in claim 4, it is characterised in that:In the step S30 mix microballoon with Acrylate pressure-sensitive adhesive is using mass ratio as 1:6~1:1 is well mixed.
CN201610579298.5A 2016-07-21 2016-07-21 Heat foamable glue and preparation method thereof Pending CN107641485A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610579298.5A CN107641485A (en) 2016-07-21 2016-07-21 Heat foamable glue and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610579298.5A CN107641485A (en) 2016-07-21 2016-07-21 Heat foamable glue and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107641485A true CN107641485A (en) 2018-01-30

Family

ID=61108848

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610579298.5A Pending CN107641485A (en) 2016-07-21 2016-07-21 Heat foamable glue and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107641485A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102559101A (en) * 2011-12-07 2012-07-11 新丰杰力电工材料有限公司 Thermal-spalling acrylic ester pressure-sensitive adhesive, adhesive tape and preparation method thereof
CN104371610A (en) * 2014-12-03 2015-02-25 新丰杰力电工材料有限公司 Preparation method and application of thermal-peeling acrylic ester pressure-sensitive adhesive
CN105419669A (en) * 2015-12-25 2016-03-23 新丰杰力电工材料有限公司 Production method of thermal-stripping acrylate pressure-sensitive adhesive tape

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102559101A (en) * 2011-12-07 2012-07-11 新丰杰力电工材料有限公司 Thermal-spalling acrylic ester pressure-sensitive adhesive, adhesive tape and preparation method thereof
CN104371610A (en) * 2014-12-03 2015-02-25 新丰杰力电工材料有限公司 Preparation method and application of thermal-peeling acrylic ester pressure-sensitive adhesive
CN105419669A (en) * 2015-12-25 2016-03-23 新丰杰力电工材料有限公司 Production method of thermal-stripping acrylate pressure-sensitive adhesive tape

Similar Documents

Publication Publication Date Title
CN106159206B (en) Method for preparing lithium ion battery pole pieces
US7138210B2 (en) Punched electrode and rechargeable lithium battery using the same
KR101684074B1 (en) A manufacturing method of all-solid battery using wet-dry process
CN104064709B (en) Ceramic diaphragm and its prepare the method and battery of lithium rechargeable battery
CN109728249A (en) A kind of interface protection structure, preparation method and the battery comprising the structure
CN105428576A (en) Composite ceramic coating, lithium ion battery composite ceramic diaphragm and lithium ion battery
KR101103198B1 (en) A forming method of electrode active material layer of a secondary battery developing dispersibility of electroconductive particles
KR20110042118A (en) Battery electrode plate, forming method thereof and battery having the same
CN105489893A (en) Graphite anode material for lithium-ion battery and preparation method of graphite anode material
CN105810885A (en) Positive pole piece and lithium ion battery
JP2008103098A (en) Manufacturing method of electrode plate for nonaqueous electrolyte secondary battery and its manufacturing equipment
KR102608052B1 (en) Electrochemical devices and electronic devices including them
CN109546150A (en) Negative plate, lithium-rich negative plate thereof, lithium ion secondary battery and preparation method
CN110498671A (en) A kind of ceramic coating and preparation method for lithium battery pole slice containing boehmite
KR20140074282A (en) Nonaqueous electrolyte secondary cell
CN105206779A (en) Ceramic diaphragm and preparation method thereof
CN107641477A (en) A kind of heat sensitive adhesive tape and preparation method thereof and application
CN103151509B (en) Lithium titanate-graphene nano composite electrode material and preparation method thereof
CN110148706B (en) Battery pole piece, preparation method thereof, battery core and battery
EP3716387A1 (en) Battery cell and battery using the same
Yamaki et al. Safety evaluation of rechargeable cells with lithium metal anodes and amorphous V2O5 cathodes
JP6068500B2 (en) Square battery pack with new structure
JP2007095477A (en) Battery and method of manufacturing same
CN107641485A (en) Heat foamable glue and preparation method thereof
EP4120460A1 (en) Separator, lithium-ion cell, and electric apparatus

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180130

RJ01 Rejection of invention patent application after publication